Abstract: A method and apparatus for demodulating a plurality of frequency components output from a photodetector in a wavelength modulation spectroscopy system and determining absorption line shapes from the demodulated data. Demodulation is performed with a homodyne demodulator. Line center magnitudes of selected even harmonics of the demodulated output frequency components are measured and the absorption line shape is calculated from the relationship between these magnitudes.

Abstract: Disclosed are a method and apparatus for dual modulation of an optical spectroscopy laser. Demodulation is accomplished in a manner resulting in measurement of absorbance of a gas species, as well as stabilization of laser wavelength and baseline noise reduction.

Abstract: An improvement to a dual-modulation line-locking device for wavelength modulation spectroscopy employing a lowpass filter to generate a nonnormalized error signal and a bandpass filter and RMS-to-DC converter to generate a centering signal. When the error signal is approximately zero and the centering signal is large, the wavelength is coincident with the center of the absorption feature of the sample.

Abstract: A process for improving moisture analyzers or hygrometers that use optical absorption techniques to measure water vapor. Water vapor in the optical path outside the sample region is treated to exchange the hydrogen atoms for deuterium, so that the adsorbed water vapor is converted to heavy water, D.sub.2 O, and isotopically mixed HDO, thus reducing or eliminating the interference in any optical absorption apparatus for measuring water vapor, provided the spectral resolution is sufficient to resolve normal water absorptions from heavy water absorptions.

Abstract: The disclosure is directed to a method and apparatus for ionization modulated mass spectrometric analysis. Analog or digital data acquisition and processing can be used. Ions from a time variant source are detected and quantified. The quantified ion output is analyzed using a computer to provide a two-dimensional representation of at least one component present within an analyte.

Abstract: The disclosure relates to an apparatus and method for increasing the sensitivity of laser absorption detection of gas phase atoms and molecular species within a gaseous medium. An active optical element in a laser absorption detection system is translationally (longitudinally) vibrated a selected amplitude along the optical axis and at a desired frequency to eliminate fringes produced by interference fringe producing optical elements. The vibration frequency is preferably asynchronous with other modulation frequencies in the system.