Abstract: Described herein are shaped articles comprising a monolayer of microspheres partially embedded in its surface. The shaped articles are made via a transfer article (20), which comprises a microsphere monolayer (22) comprising a plurality of microspheres partially embedded in a first major surface of a transfer polymer layer (23), which is disposed on a support layer (21). The transfer article is shaped and a conformable substrate is contacted with the shaped transfer article, transferring the microspheres to the conformable substrate forming a shaped finished article having a surface comprising a monolayer of partially embedded microspheres.

Abstract: Barrier adhesive compositions include at least one polyisobutylene-containing polymer and a copolymeric additive that is a polyisobutylene-polysiloxane copolymer. The polyisobutylene-polysiloxane copolymers are prepared by the reaction of a hydridosilane-functional polysiloxane and an ethylenically unsaturated polyisobutylene oligomer. Barrier film articles include the barrier adhesive compositions and a film. The barrier film articles can be used to encapsulate organic electronic devices.

Abstract: Flexible, stretchable RFID tags are formed by a pocket that is formed from one or more substrates and layers of adhesive, and an electronic circuit that is located within this pocket. The RFID tags can include a stretchable substrate and an electronic circuit attached to the stretchable substrate by one or a finite number of discrete spaced apart attachment locations. When the pocket is formed by relatively thick adhesive layers adhering together one or more flexible substrates to form an internal cavity, the electronic circuit is located within this cavity and either is not adhered to any of the substrates of the cavity, and is free to move about within the cavity, or the electronic circuit can be attached to a substrate by a thin layer of adhesive.

Abstract: Flexible, stretchable RFID tags are formed by a pocket that is formed from one or more substrates and layers of adhesive, and an electronic circuit that is located within this pocket. The RFID tags can include a stretchable substrate and an electronic circuit attached to the stretchable substrate by one or a finite number of discrete spaced apart attachment locations. When the pocket is formed by relatively thick adhesive layers adhering together one or more flexible substrates to form an internal cavity, the electronic circuit is located within this cavity and either is not adhered to any of the substrates of the cavity, and is free to move about within the cavity, or the electronic circuit can be attached to a substrate by a thin layer of adhesive.

Abstract: Composite structures that include a first layer including a silicone block copolymer; a transition layer, the transition layer having a first surface contiguous with the first layer and a second opposing surface, the transition layer formed from the silicone block copolymer of the first layer; and a glass-like layer contiguous with the second surface of the transition layer, at least a portion of the glass-like layer formed from the transition layer.

Abstract: A film including a resin layer comprising a structured major surface opposite a second major surface, the structured major surface including a plurality of features; a barrier layer on the structured major surface; and a first adhesive layer on the barrier layer.

Abstract: A method of patterning a conductive layer to form transparent electrical conductors that does not require etching is disclosed. The method includes peeling a strippable polymer layer from a substrate coated with the conductive layer to pattern the conductive layer. In some embodiments, a resist matrix material is patterned over the conductive layer to prevent removal of the conductive layer beneath the resist matrix material. In other embodiments, a liner having a pressure sensitive adhesive surface is brought into contact with the patterned strippable polymer material to remove both the patterned strippable polymer material and the conductive layer beneath it.

Abstract: A barrier adhesive composition comprises polyisobutylene resin, hydrophobic nanoparticles and sorbent nanoparticles.

Abstract: A method of patterning a conductive layer to form transparent electrical conductors that does not require etching is disclosed. The method includes peeling a strippable polymer layer from a substrate coated with the conductive layer to pattern the conductive layer. In some embodiments, a resist matrix material is patterned over the conductive layer to prevent removal of the conductive layer beneath the resist matrix material. In other embodiments, a liner having a pressure sensitive adhesive surface is brought into contact with the patterned strippable polymer material to remove both the patterned strippable polymer material and the conductive layer beneath it.

Abstract: A barrier composite comprises (a) a gas-barrier film, (b) a polymeric transfer layer disposed on the gas-barrier film, and (c) a release liner disposed on the polymeric transfer layer opposite the gas-barrier film.

Abstract: The present invention relates to protection films comprising an optical film suitably sized for an illuminated display device, the optical film having perimeter surface portions defining a central region. The protection film further comprises a pressure sensitive adhesive layer at the perimeter surface portions of the optical film. The optical film and/or pressure sensitive adhesive layer has been adapted such that the at least the central region of the optical film contacts the illuminated display device or the central region of the optical film is bonded to the illuminated display device by means of a self-wetting layer. The protection film may be preassembled or may be provided as a kit, the kit comprising an optical film and a double-faced pressure sensitive tape.

Abstract: A continuous method of manufacturing adhesives is provided. The method includes obtaining an actinic radiation-polymerizable adhesive precursor composition disposed on a major surface of an actinic radiation-transparent substrate and irradiating a first portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a first irradiation dosage. The method further includes moving the actinic radiation-transparent substrate and irradiating a second portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a second irradiation dosage. Optionally, the method also includes irradiating a third portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate prior to moving the substrate.

Abstract: A transparent electrode is described and includes metallic nanowires and a polymeric overcoat layer for protecting the nanowires from corrosion and abrasion. The polymeric overcoat layer includes nanoparticles, particularly antimony tin oxide, zinc oxide and/or indium tin oxide, and has a sheet resistance of greater than about 107 ohm/sq. The transparent electrode can be used in electronic displays such as polymer-dispersed liquid crystal, liquid crystal, electrophoretic, electrochromic, thermochromic, electroluminescent and plasma displays.

Abstract: A method of making an adhesive is provided, including obtaining an actinic radiation-polymerizable adhesive precursor composition disposed against a surface of an actinic radiation-transparent substrate and irradiating a first portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a first irradiation dosage. The method further includes irradiating a second portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a second irradiation dosage. The first portion and the second portion are adjacent to or overlapping with each other and the first irradiation dosage and the second irradiation dosage are not the same. The method forms an integral adhesive having a variable thickness in an axis normal to the surface of the actinic radiation-transparent substrate.

Abstract: The disclosed light directing article comprises a structured layer, an adhesive sealing layer, and barrier elements. The structured layer comprises multiple microstructured elements that are opposite a major surface. The adhesive sealing layer has a first region and a second region. The second region is in contact with the structured layer. The barrier element are at the first region. The first region with the barrier element and second region have sufficiently different properties to form a low refractive index layer between the adhesive sealing layer and the structured layer. The barrier element comprises a crosslinked polymeric matrix having a modulus of elasticity less than 4.4 GPa.

Abstract: A transparent electrode is described and includes metallic nanowires and a polymeric overcoat layer for protecting the nanowires from corrosion and abrasion. The polymeric overcoat layer includes nanoparticles, particularly antimony tin oxide, zinc oxide and/or indium tin oxide, and has a sheet resistance of greater than about 107 ohm/sq. The transparent electrode can be used in electronic displays such as polymer-dispersed liquid crystal, liquid crystal, electrophoretic, electrochromic, thermochromic, electroluminescent and plasma displays.

Abstract: Flexible, stretchable RFID tags are formed by a pocket that is formed from one or more substrates and layers of adhesive, and an electronic circuit that is located within this pocket. The RFID tags can include a stretchable substrate and an electronic circuit attached to the stretchable substrate by one or a finite number of discrete spaced apart attachment locations. When the pocket is formed by relatively thick adhesive layers adhering together one or more flexible substrates to form an internal cavity, the electronic circuit is located within this cavity and either is not adhered to any of the substrates of the cavity, and is free to move about within the cavity, or the electronic circuit can be attached to a substrate by a thin layer of adhesive.

Abstract: A transparent electrode is described and includes metallic nanowires and a polymeric overcoat layer for protecting the nanowires from corrosion and abrasion. The polymeric overcoat layer includes nanoparticles selected from the group consisting of antimony tin oxide, zinc oxide and indium tin oxide, and has a sheet resistance of greater than about 107 ohm/sq. The transparent electrode can be used in electronic displays such as polymer-dispersed liquid crystal, liquid crystal, electrophoretic, electrochromic, thermochromic, electroluminescent and plasma displays.

Abstract: Articles and methods of making light redirecting film constructions including a micro structured optical film bonded in selected areas to another film, and including a diffuser are described. The diffuser has an optical haze in the range of (20) to (85) percent and an optical clarity of no greater than (50) percent. The diffuser may be a surface diffuser and may be an asymmetric surface diffuser.

Abstract: A method of making an adhesive is provided, including obtaining an actinic radiation-polymerizable adhesive precursor composition disposed against a surface of an actinic radiation-transparent substrate and irradiating a first portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a first irradiation dosage. The method further includes irradiating a second portion of the actinic radiation-polymerizable adhesive precursor composition through the actinic radiation-transparent substrate for a second irradiation dosage. The first portion and the second portion are adjacent to or overlapping with each other and the first irradiation dosage and the second irradiation dosage are not the same. The method forms an integral adhesive having a variable thickness in an axis normal to the surface of the actinic radiation-transparent substrate.