Abstract: Polymer composites containing carbon nanotubes often exhibit high glass transition temperatures, which can complicate their use in additive manufacturing processes. Extruded filaments containing carbon nanotubes and residual solvent can have desirably lowered glass transition temperatures. Extruded filaments can contain a polymer as a continuous phase, a nanomaterial such as carbon nanotubes homogeneously mixed throughout the continuous phase, and above 0% to about 15% solvent by weight.

Abstract: Conventional rechargeable batteries, such as lithium-ion batteries, are somewhat limited in their energy storage density. Sulfur-based batteries can provide improved energy storage density, but their use can be hampered by sulfur's low electrical conductivity. Energy storage devices, particularly batteries, can have a first electrode that includes a carbon nanotube aerogel, and an electroactive material containing sulfur that is incorporated in the carbon nanotube aerogel. Methods for forming an energy storage device can include incorporating an electroactive material containing sulfur in a carbon nanotube aerogel, compressing the carbon nanotube aerogel to form a compressed carbon nanotube aerogel, and disposing a first electrode containing the compressed carbon nanotube aerogel and the electroactive material in an electrolyte with a second electrode and a plurality of lithium ions, such that a separator material permeable to the lithium ions is between the first electrode and the second electrode.

Abstract: Polymer composites containing carbon nanotubes often exhibit high glass transition temperatures, which can complicate their use in additive manufacturing processes. Extruded filaments containing carbon nanotubes and residual solvent can have desirably lowered glass transition temperatures. Extruded filaments can contain a polymer as a continuous phase, a nanomaterial such as carbon nanotubes homogeneously mixed throughout the continuous phase, and above 0% to about 15% solvent by weight.

Abstract: Compressed carbon nanotube aerogel materials can be used in heat management and thermal shielding applications. Methods for heat management and thermal shielding of an object can include placing a compressed carbon nanotube aerogel material between an object and its surrounding environment, and establishing a thermal gradient within the compressed carbon nanotube aerogel material by exposing the compressed carbon nanotube aerogel material to the object or to the surrounding environment. When the object and the surrounding environment are in thermal communication with one another, the compressed carbon nanotube aerogel material can reduce an amount of heat transferred between the object and the surrounding environment. As a result of establishing the thermal gradient within the compressed carbon nanotube aerogel material, an electric current may be generated in some instances.

Abstract: Under one aspect, a method of making a nanotube switch includes: providing a substrate having a first conductive terminal; depositing a multilayer nanotube fabric over the first conductive terminal; and depositing a second conductive terminal over the multilayer nanotube fabric, the nanotube fabric having a thickness, density, and composition selected to prevent direct physical and electrical contact between the first and second conductive terminals. In some embodiments, the first and second conductive terminals and the multilayer nanotube fabric are lithographically patterned so as to each have substantially the same lateral dimensions, e.g., to each have a substantially circular or rectangular lateral shape. In some embodiments, the multilayer nanotube fabric has a thickness from 10 nm to 200 nm, e.g., 10 nm to 50 nm. The structure may include an addressable diode provided under the first conductive terminal or deposited over the second terminal.

Abstract: Compressed carbon nanotube aerogel materials can be used in heat management and thermal shielding applications. Methods for heat management and thermal shielding of an object can include placing a compressed carbon nanotube aerogel material between an object and its surrounding environment, and establishing a thermal gradient within the compressed carbon nanotube aerogel material by exposing the compressed carbon nanotube aerogel material to the object or to the surrounding environment. When the object and the surrounding environment are in thermal communication with one another, the compressed carbon nanotube aerogel material can reduce an amount of heat transferred between the object and the surrounding environment. As a result of establishing the thermal gradient within the compressed carbon nanotube aerogel material, an electric current may be generated in some instances.

Abstract: Identifying marks are often used for authentication and tracking purposes with various types of articles, but the marks themselves can sometimes be subject to replication or removal by an outside entity, such as a person or group having malicious intent. This can make it easier for an outside entity to produce a counterfeit article or to sell a stolen article. Carbon nanotubes and other carbon nanomaterials can be used to form identifying marks that are not visible to the naked eye, thereby making the marks more difficult for an outside entity to tamper with. Various articles can include an identifying mark that is localized and not visible to the naked eye, the identifying mark being electrically conductive and containing a carbon nanomaterial. By electrically interrogating the article, such as through spatially measuring eddy currents about the article, the marks can be located and authenticated.

Abstract: Identifying marks are often used for authentication and tracking purposes with various types of articles, but they can sometimes be subject to replication or removal by an outside entity, such as a person or group having malicious intent. Carbon nanotubes and other carbon nanomaterials can be used to form identifying marks that are not visible to the naked eye, thereby making the marks more difficult for an outside entity to tamper with. Various articles can include an identifying mark that is not visible to the naked eye, the identifying mark containing a nanomaterial that includes a plurality of carbon nanotubes with a registered distribution of chiralities. The registered distribution of chiralities can be further tailored to increase the level of security provided by the mark.

Abstract: A three-dimensional (3-D) memory stack and a method of formation thereof are described. The 3-D memory stack includes a number of vertically stacked memory devices. Each memory device includes one or more memory cells. Each of the memory cells can be formed on a conductive material. Each memory device further includes one or more selector elements each configured to couple a memory cell of the one or more memory cells to a respective bit line. None of the selector elements is configured as a diode or a transistor element.

Abstract: Methods for fabricating graphene nanoelectronic devices with semiconductor compatible processes, which allow wafer scale fabrication of graphene nanoelectronic devices, is provided. One method includes the steps of preparing a dispersion of functionalized graphene in a solvent; and applying a coating of said dispersion onto a substrate and evaporating the solvent to form a layer of functionalized graphene; and defunctionalizing the graphene to form a graphene layer on the substrate.

Abstract: A nanotube based microstrip antenna element is provided along with arrays of same. The nanotube based microstrip antenna element comprises a dielectric substrate layer sandwiched between a ground plane layer and a conductive nanotube layer, the conductive nanotube layer shaped to form a radiating structure. In more advanced embodiments, the nanotube based microstrip antenna element further includes an integrated two terminal nanotube switch device such as to provide a selectability function to such microstrip antenna elements and reconfigurable arrays of same. Anisotropic nanotube fabric layers are also used to provide substantially transparent microstrip antenna structures which can be deposited over display screens and the like.

Abstract: Identifying marks are often used for authentication and tracking purposes with various types of articles, but they can sometimes be subject to replication or removal by an outside entity, such as a person or group having malicious intent. Carbon nanotubes and other carbon nanomaterials can be used to form identifying marks that are not visible to the naked eye, thereby making the marks more difficult for an outside entity to tamper with. Various articles can include an identifying mark that is not visible to the naked eye, the identifying mark containing a nanomaterial that includes a plurality of carbon nanotubes with a registered distribution of chiralities. The registered distribution of chiralities can be further tailored to increase the level of security provided by the mark.

Abstract: Conventional rechargeable batteries, such as lithium-ion batteries, are somewhat limited in their energy storage density. Sulfur-based batteries can provide improved energy storage density, but their use can be hampered by sulfur's low electrical conductivity. Energy storage devices, particularly batteries, can have a first electrode that includes a carbon nanotube aerogel, and an electroactive material containing sulfur that is incorporated in the carbon nanotube aerogel. Methods for forming an energy storage device can include incorporating an electroactive material containing sulfur in a carbon nanotube aerogel, compressing the carbon nanotube aerogel to form a compressed carbon nanotube aerogel, and disposing a first electrode containing the compressed carbon nanotube aerogel and the electroactive material in an electrolyte with a second electrode and a plurality of lithium ions, such that a separator material permeable to the lithium ions is between the first electrode and the second electrode.

Abstract: Metal nitride coatings containing carbon can be either electrically conductive or substantially non-conductive depending on the degree to which they have been exposed to an oxidative environment. Substantially non-conductive metal nitride coatings can be used as protective layers in electrical devices. Particularly in an electrical device containing carbon nanomaterials, the metal nitride coatings can be used to mask the device's operational characteristics. Such devices can contain an electrical interconnect containing a carbon nanomaterial and a substantially non-conductive coating on the carbon nanomaterial. The substantially non-conductive coating can contain at least one substantially non-conductive metal nitride layer and at least some carbon. Methods for making such devices and metal nitride coatings are also described herein.

Abstract: Methods for using carbon nanomaterials to alter the operational output of a device are described herein. The methods can include providing a device that contains a carbon nanomaterial in a first state, and applying an input stimulus to the carbon nanomaterial so as to change the first state into a second state. In the first state, the carbon nanomaterial can be used to produce a normal operational output of the device, whereas the device can produce an altered operational output when the carbon nanomaterial is in the second state. When producing an altered operational output, the device can continue operating, but the altered operational output can be non-indicative of the true operational state of the device. Devices containing a carbon nanomaterial that can be reconfigured from a normal operational output to an altered operational output are also described herein.

Abstract: Certain applicator liquids and method of making the applicator liquids are described. The applicator liquids can be used to form nanotube films or fabrics of controlled properties. An applicator liquid for preparation of a nanotube film or fabric includes a controlled concentration of nanotubes dispersed in a liquid medium containing water. The controlled concentration is sufficient to form a nanotube fabric or film of preselected density and uniformity.

Abstract: An electrostatic discharge (ESD) protection circuit for protecting a protected circuit is coupled to an input pad. The ESD circuit includes a nanotube switch electrically having a control. The switch is coupled to the protected circuit and to a discharge path. The nanotube switch is controllable, in response to electrical stimulation of the control, between a de-activated state and an activated state. The activated state creates a current path so that a signal on the input pad flows to the discharge path to cause the signal at the input pad to remain within a predefined operable range for the protected circuit. The nanotube switch, the input pad, and the protected circuit may be on a semiconductor chip. The nanotube switch may be on a chip carrier. The deactivated and activated states may be volatile or non-volatile depending on the embodiment.

Abstract: Under one aspect, a method of cooling a circuit element includes providing a thermal reservoir having a temperature lower than an operating temperature of the circuit element; and providing a nanotube article in thermal contact with the circuit element and with the reservoir, the nanotube article including a non-woven fabric of nanotubes in contact with other nanotubes to define a plurality of thermal pathways along the article, the nanotube article having a nanotube density and a shape selected such that the nanotube article is capable of transferring heat from the circuit element to the thermal reservoir.

Abstract: Metal nitride coatings containing carbon can be either electrically conductive or substantially non-conductive depending on the degree to which they have been exposed to an oxidative environment. Substantially non-conductive metal nitride coatings can be used as protective layers in electrical devices. Particularly in an electrical device containing carbon nanomaterials, the metal nitride coatings can be used to mask the device's operational characteristics. Such devices can contain an electrical interconnect containing a carbon nanomaterial and a substantially non-conductive coating on the carbon nanomaterial. The substantially non-conductive coating can contain at least one substantially non-conductive metal nitride layer and at least some carbon. Methods for making such devices and metal nitride coatings are also described herein.

Abstract: Electrical devices containing carbon nanotubes can be passivated to protect the carbon nanotubes from degradation while substantially preserving the carbon nanotubes' electrical conductivity and switching characteristics. Such electrical devices can include a first metal contact, a switching layer containing a plurality of carbon nanotubes disposed on the first metal contact, a passivation layer containing amorphous carbon, a metal carbide, or any combination thereof that is disposed on at least a top surface of the switching layer, and a second metal contact disposed upon the passivation layer. Methods for forming the electrical devices can include disposing a passivation layer containing amorphous carbon on at least a top surface of the switching layer, and optionally heating to at least partially convert the amorphous carbon within the passivation layer into a metal carbide.