Abstract: Red toners that approximate PANTONE® Red 032 and PANTONE® Warm Red are described. The colorant includes an orange colorant and a red colorant, where the orange colorant absorbs light having a wavelength of from about 400 to about 520 nm, and where the red colorant absorbs light having a wavelength of from about 500 to 580 nm.

Abstract: A toner includes a polymeric resin, a colorant, and a small molecule crystalline aromatic monoester having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline aromatic monoester may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline aromatic monoester as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline aromatic monoester in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline aromatic monoester in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline aromatic monoesters may include 2-Naphthyl benzoate.

Abstract: A toner includes a polymeric resin, a colorant, and a small molecule crystalline aromatic monoester having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline aromatic monoester may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline aromatic monoester as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline aromatic monoester in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline aromatic monoester in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline aromatic monoesters may include 2-Naphthyl benzoate.

Abstract: A polyester resin is described which includes bio-based, cyclohexadiene Diels-Alder reaction adduct monomer for use in toner for imaging devices.

Abstract: A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline aromatic ether having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline aromatic ether may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline aromatic ether as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline aromatic ether in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline aromatic ether in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline aromatic ethers may include benzyl 2-naphthyl ether.

Abstract: A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline diester having an aromatic core and a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline aromatic diester may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a significant solid to liquid phase transition peak for the small molecule compound as determined by differential scanning calorimetry, the enthalpy of fusion for the small molecule compound in the mixture being measured to be less than 10% of the enthalpy of fusion of the compound in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner.

Abstract: The instant disclosure describes a ring opening polymerization (ROP) of cyclic monomer components using a nucleophilic transesterification catalyst system in a neat, single pot reaction to obtain homopolymers and copolymers.

Abstract: An emulsion aggregation (EA) toner includes an amorphous polymeric resin, optionally a colorant, and a small molecule crystalline organic compound having molecular weight less than 1,000 g/mol and melting point less than the fusing temperature of the EA toner, wherein a mixture of the resin and the small molecule compound is characterized by a reduction in glass transition temperature from that of the resin and by the lack of a significant solid to liquid phase transition peak for the small molecule compound as determined by differential scanning calorimetry, the enthalpy of fusion for the small molecule compound in the mixture being measured to be less than 10% of the enthalpy of fusion of the compound in pure form. Furthermore, the EA toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner.

Abstract: A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline imide having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline imide may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline imide as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline imide in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline imide in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline imides may include N-alkyl and N-aryl imides, such as N-benzylphthalimide.

Abstract: A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline aromatic ether having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline aromatic ether may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline aromatic ether as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline aromatic ether in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline aromatic ether in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline aromatic ethers may include benzyl 2-naphthyl ether.

Abstract: A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline diester having an aromatic core and a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline aromatic diester may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a significant solid to liquid phase transition peak for the small molecule compound as determined by differential scanning calorimetry, the enthalpy of fusion for the small molecule compound in the mixture being measured to be less than 10% of the enthalpy of fusion of the compound in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner.

Abstract: A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline imide having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline imide may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline imide as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline imide in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline imide in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline imides may include N-alkyl and N-aryl imides, such as N-benzylphthalimide.

Abstract: An emulsion aggregation (EA) toner includes an amorphous polymeric resin, optionally a colorant, and a small molecule crystalline organic compound having molecular weight less than 1,000 g/mol and melting point less than the fusing temperature of the EA toner, wherein a mixture of the resin and the small molecule compound is characterized by a reduction in glass transition temperature from that of the resin and by the lack of a significant solid to liquid phase transition peak for the small molecule compound as determined by differential scanning calorimetry, the enthalpy of fusion for the small molecule compound in the mixture being measured to be less than 10% of the enthalpy of fusion of the compound in pure form. Furthermore, the EA toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner.

Abstract: A toner includes a polymeric resin, a colorant, and a small molecule crystalline aromatic monoester having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline aromatic monoester may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline aromatic monoester as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline aromatic monoester in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline aromatic monoester in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline aromatic monoesters may include 2-Naphthyl benzoate.

Abstract: The present embodiments relate to processes of preparing toner particles. More specifically, the processes produce toner particles having high pigment loadings and desired circularity. The processes include diluting the aggregated particulate mixture prior to coalescence.

Abstract: The disclosure describes a neat, one-pot scheme for reacting a hydroxyl propagating end of a polymer with a cyclic acid anhydride to form a free acid terminus.

Abstract: Toners are provided, which possess low melt properties capable of producing a low gloss finish. Methods for providing these resins and toners are also provided which include the process of controlling the gloss of the toner utilizing a slow acid addition during coalescence optionally combined with little or no chelating agent added during the aggregation process.

Abstract: The instant disclosure describes polyester synthesis processes, including processes for the ring-opening polymerization (ROP) of cyclic organic monomer components and components comprising a functional group using an organocatalyst system to effect ROP-based block copolymer preparation.

Abstract: The present disclosure relates to a toner design for a clear UV red fluorescence toner having a high lanthanide complex pigment loading, including methods of making the fluorescence toner using a saccharide or a sugar acid to avoid complexation of lanthanide ions from the pigment, with lower aggregation and coalescence temperatures in the preparation of toner particles, where the particles exhibit a narrow size distribution and good xerographic performance.

Abstract: A low melt or ultra low melt toner includes at least one amorphous polyester of an alkoxylated bisphenol based polyester, a crystalline polyester derived from the reaction of an aliphatic dicarboxylic acid or aromatic dicarboxylic acid with an aliphatic diol, at least one colorant and at least one fluorescence agent. Methods of authentication of the toner, of authentication of documents formed from the toner, of embedding information in documents, and the like are also set forth.