Abstract: The present disclosure provides methods for modifying polymeric resin materials after polymerization to make fine adjustments in the chemical or physical properties of the resin, or in modifying the structure of the polymer chains. The resulting resins may be useful in forming toner particles. In embodiments, a polymeric resin may have epoxy groups added to its backbone to increase its melting point. The resulting polymer, sometimes referred to herein as an epoxidized polymer, may, in turn, be reacted with wax-like components, to increase the compatibility of the polyester with waxes utilized in forming toner particles. In other embodiments, the resulting epoxidized polymer may be reacted with components possessing carboxylic acid groups to adjust the acid value and weight average molecular weight of the resin.

Abstract: Multi-stage fixing systems for fixing toner to a substrate, printing apparatuses and methods of fixing marking material to a substrate are provided. An exemplary embodiment of the multi-stage fixing systems includes a softening device for softening toner applied to a substrate by a marking device; and a fixing device for fixing the softened toner to the substrate. The fixing device includes a first fixing member including a first surface; a first thermal energy source for actively heating the first surface; and a second fixing member including a second surface, the first surface and the second surface form a fixing nip at which the substrate with softened toner is received. The first fixing member and the second fixing member are operable to apply heat and pressure to the substrate and softened toner received at the fixing nip to fix the toner to the substrate.

Abstract: Toners are provided which include a resin including at least one baroplastic polymer. The baroplastic polymer, in embodiments, may be a block copolymer with discrete low glass transition temperature (Tg) domains and high Tg domains that plasticize one another at ambient temperature when subjected to pressures of from about 500 psi (about 3.45 MPa) to about 10,000 psi (about 69 MPa), enabling them to be extruded and molded without heat. The resulting polymers, in turn, may then be utilized to form toners.

Abstract: The present disclosure provides processes for the production of block copolymer polyester resins suitable for use in manufacturing toners. In embodiments, the copolymers include both a crystalline block and an amorphous block, which can self-assemble to form nanoparticles suitable for use in forming toners.

Abstract: Radiation curable compositions, such as UV curable ink compositions, contain a polymeric dispersant, a curable material, that includes a carrier and at least one nanoscale fluorescent pigment particle and an optional non-fluorescent colorant. The fluorescent organic nanoparticle composition includes one or more fluorescent dyes dispersed in a polymeric matrix obtained by modified EA latex process or by emulsion polymerization. In a different embodiment, the nanoscale fluorescent pigment particle composition includes pigment molecules with at least one functional moiety, and a sterically bulky stabilizer compound including at least one functional group, the functional moiety of the pigment associates non-covalently with the functional group of the stabilizer, and the presence of the associated stabilizer limits the extent of particle growth and aggregation, to afford nanoscale-sized pigment particles.

Abstract: A method for producing a photochromic polyester, the method including: a) providing a reaction solution having at least one ester monomer, a photochromic compound having or functionalized to have at least one hydroxyl group, and a metal-free catalyst; b) reacting the at least one ester monomer and the photochromic compound using the metal-free catalyst to produce a polymeric product, where the polymeric product has a photochromic polyester; and c) separating the polymeric product from the reaction solution. A photochromic polyester includes a photochromic compound covalently linked to a polyester and the polyester is obtained by polymerizing a lactone.

Abstract: Fluorescent organic nanoparticles and a process for producing fluorescent organic nanoparticles having a size of less than about 500 nanometers comprising a polymeric matrix comprising one or more crosslinked polymer resins, and comprising one or more fluorescent dyes incorporated into the polymer matrix.

Abstract: The present disclosure provides blue toners and methods for their production. In embodiments, methods of the present disclosure include systems which may be utilized to predict the color properties of a blue toner, thereby permitting adjustment of the pigment loading and/or toner mass per unit area.

Abstract: Toners are provided which may be suitable for use in cold fusing pressure apparatus. The toners include low molecular weight amorphous resins and wax. The wax content is specific to optimize performance of toners used in a cold fusing pressure apparatus.

Abstract: The present disclosure provides toners and processes for making said toners. In embodiments, the toners include a fluorescent additive having a fluorescent agent. Toners are colorless when viewed under natural light but when exposed to UV light of a specific wavelength the toners are rendered bright green due to the presence of the fluorescent agent.

Abstract: In accordance with various embodiments, there is a method of making a polyester. The method can include providing a monomer solution, the monomer solution including one or more cyclic esters in a concentration ranging from about 1 to about 100% and one or more solvents in a concentration ranging from about 99% to about 0%. The method of making a polyester can also include providing a packed-bed reactor including one or more immobilized enzymes, wherein the packed-bed reactor has an inlet and an outlet. The method can further include circulating the monomer solution through the packed-bed reactor to generate a solution enriched with polyester, such that the one or more immobilized enzymes convert the one or more cyclic esters to polyester in the packed-bed reactor during circulation and collecting the solution enriched with polyester exiting through the outlet.

Abstract: Multi-stage fixing systems for fixing toner to a substrate, printing apparatuses and methods of fixing marking material to a substrate are provided. An exemplary embodiment of the multi-stage fixing systems includes a softening device for softening toner applied to a substrate by a marking device; and a fixing device for fixing the softened toner to the substrate. The fixing device includes a first fixing member including a first surface; a first thermal energy source for actively heating the first surface; and a second fixing member including a second surface, the first surface and the second surface form a fixing nip at which the substrate with softened toner is received. The first fixing member and the second fixing member are operable to apply heat and pressure to the substrate and softened toner received at the fixing nip to fix the toner to the substrate.

Abstract: Aspects of the disclosure provide a printing method that can utilize a lightly pigmented toner along with a darkly pigmented toner to improve the image quality. The method can include receiving a dataset corresponding to a printing of a printing system using a darkly pigmented toner. The printing system may have an undesirable optical density printing range for the darkly pigmented toner. Further, the method can include converting the dataset to a first dataset corresponding to a first printing of the printing system using the darkly pigmented toner, and a second dataset corresponding to a second printing of the printing system using a lightly pigmented toner. The first dataset can avoid the undesirable optical density printing range for the darkly pigmented toner, and a combination of the first printing and the second printing providing a substantially same printed optical density corresponding to the received dataset.

Abstract: The present disclosure provides processes for producing images of excellent color fidelity when incorporating a magenta toner with a lower colorant loading in addition to a first magenta toner. In embodiments, the magenta pigmented particles may be magenta emulsion aggregation toners. In accordance with the present disclosure, a pair of magenta toners are matched in color, wherein the color of a first magenta toner printed at a predetermined halftone area coverage on a substrate substantially matches the color of the solid (100%) printed patch of the second magenta toner, which is lighter than the first magenta toner, thus avoiding a visible hue shift on the print that would otherwise be objectionable.

Abstract: The present disclosure provides processes for producing images of excellent color fidelity when incorporating a magenta toner with a lower colorant loading in addition to a first magenta toner. In embodiments, the magenta pigmented particles may be magenta emulsion aggregation toners. In accordance with the present disclosure, a pair of magenta toners are matched in color, wherein the color of a first magenta toner printed at a predetermined halftone area coverage on a substrate substantially matches the color of the solid (100%) printed patch of the second magenta toner, which is lighter than the first magenta toner, thus avoiding a visible hue shift on the print that would otherwise be objectionable.

Abstract: The present disclosure provides toners having a tunable gloss level, electrophotographic apparatuses for using such toners as well as processes for making such toners.

Abstract: The present disclosure provides toners having a tunable gloss level, electrophotographic apparatuses for using such toners as well as processes for making such toners.

Abstract: The present disclosure provides processes for producing images of excellent color fidelity when incorporating a cyan toner with a lower colorant loading in addition to a first cyan toner. In embodiments, the cyan pigmented particles may be cyan emulsion aggregation toners. In accordance with the present disclosure, a pair of cyan toners are matched in color, wherein the color of a first cyan toner printed at a predetermined halftone area coverage on a substrate substantially matches the color of the solid (100%) printed patch of the second cyan toner, which is lighter than the first cyan toner, thus avoiding a visible hue shift on the print that would otherwise be objectionable. In embodiments, the light cyan toner is color matched by adding a hue-adjusting colorant or combination of colorants which absorb wavelengths of light between 500 and 600 nanometers, and optionally adding a shade-adjusting colorant or combination of colorants which absorb wavelengths of light between 400 and 500 nanometers.

Abstract: The present disclosure provides blue toners and methods for their production. In embodiments, methods of the present disclosure include systems which may be utilized to predict the color properties of a blue toner, thereby permitting adjustment of the pigment loading and/or toner mass per unit area.

Abstract: A light-cyan radiation-curable gel ink including at least one curable monomer, at least one organic gellant, at least one photoinitiator, and a colorant. The colorant includes a cyan colorant, a hue-adjusting colorant that absorbs light having a wavelength of from about 500 to about 600 nm, and an optional shade-adjusting colorant that absorbs light having a wavelength of from about 400 to about 500 nm.