Abstract: A support for a polymer electrolyte fuel cell catalyst satisfying the following requirements (A), (B), (C), and (D), and a producing method thereof, as well as a catalyst layer for a polymer electrolyte fuel cell and a fuel cell: (A) a specific surface area according to a BET analysis of a nitrogen adsorption isotherm is from 450 to 1500 m2/g. (B) a nitrogen adsorption and desorption isotherm forms a hysteresis loop in a range of relative pressure P/P0 of more than 0.47 but not more than 0.90, and a hysteresis loop area ?S0.47-0.9 is from 1 to 35 mL/g; (C) a relative pressure Pclose/P0 at which the hysteresis loop closes is more than 0.47 but not more than 0.70; and (D) a half-width of a G band detected by Raman spectrometry in a range of from 1500 to 1700 cm?1 is from 45 to 75 cm?1.

Abstract: A carbon material for catalyst carrier use excellent in both durability and power generation performance under operating conditions at the time of low humidity, in particular both durability of a carbon material for catalyst carrier use with respect to repeated load fluctuations due to startup and shutdown and power generation performance under operating conditions at the time of low humidity, and a catalyst for solid-polymer fuel cell use prepared using the same etc. are provided. To solve this technical problem, according to one aspect of the present invention, there is provided a carbon material for catalyst carrier use satisfying the following (A) to (D): (A) an oxygen content OICP of 0.1 to 3.0 mass % contained in the carbon material for catalyst carrier use; (B) a residual amount of oxygen O1200° C. of 0.1 to 1.5 mass % remaining after heat treatment in an inert gas (or vacuum) atmosphere at 1200° C.

Abstract: A support for a polymer electrolyte fuel cell catalyst satisfying the following requirements (A), (B), (C), and (D), and a producing method thereof, as well as a catalyst layer for a polymer electrolyte fuel cell and a fuel cell: (A) a specific surface area according to a BET analysis of a nitrogen adsorption isotherm is from 450 to 1500 m2/g. (B) a nitrogen adsorption and desorption isotherm forms a hysteresis loop in a range of relative pressure P/P0 of more than 0.47 but not more than 0.90, and a hysteresis loop area ?S0.47-0.9 is from 1 to 35 mL/g; (C) a relative pressure Pclose/P0 at which the hysteresis loop closes is more than 0.47 but not more than 0.70; and (D) a half-width of a G band detected by Raman spectrometry in a range of from 1500 to 1700 cm?1 is from 45 to 75 cm?1.

Abstract: Provided are: a supporting carbon material for a solid polymer fuel cell, said supporting carbon material making it possible to produce a high-performance solid polymer fuel cell in which there is little decrease in power generation performance as a result of repeated battery load fluctuation that inevitably occurs during operation of the solid polymer fuel cell; and a catalyst metal particle-supporting carbon material. The present invention relates to: a supporting carbon material for a solid polymer fuel cell, said supporting carbon material being a porous carbon material in which the specific surface area of mesopores having a pore diameter of 2-50 nm according to nitrogen adsorption measurement is 600-1,600 m2/g, the relative intensity ratio (IG?/IG) of the peak intensity (IG?) of the G-band 2,650-2,700 cm?1 range to the peak intensity (IG) of the G-band 1,550-1,650 cm?1 range in the Raman spectrum is 0.8-2.

Abstract: Provided are a supporting carbon material for a solid polymer fuel cell and a metal-catalyst-particle-supporting carbon material that, when used as a carrier for a solid polymer fuel cell catalyst, have excellent power generation performance in high-humidity conditions, which are conditions in which solid polymer fuel cells are operated. A supporting carbon material for a solid polymer fuel cell and a metal-catalyst-particle-supporting carbon material characterized in being a porous carbon material, the hydrogen content being 0.004-0.010% by mass, the nitrogen adsorption BET specific surface area being 600 m2/g-1500 m2/g, and the relative intensity ratio (ID/IG) between the peak intensity (ID) in the range of 1200-1400 cm?1 known as the D-band and the peak intensity (IG) in the range of 1500-1700 cm?1 known as the G-band, obtained from the Raman spectrum, being 1.0-2.0.

Abstract: A carbon material for catalyst carrier use excellent in both durability and power generation performance under operating conditions at the time of low humidity, in particular both durability of a carbon material for catalyst carrier use with respect to repeated load fluctuations due to startup and shutdown and power generation performance under operating conditions at the time of low humidity, and a catalyst for solid-polymer fuel cell use prepared using the same etc. are provided. To solve this technical problem, according to one aspect of the present invention, there is provided a carbon material for catalyst carrier use satisfying the following (A) to (D): (A) an oxygen content OICP of 0.1 to 3.0 mass % contained in the carbon material for catalyst carrier use; (B) a residual amount of oxygen O1200° C. of 0.1 to 1.5 mass % remaining after heat treatment in an inert gas (or vacuum) atmosphere at 1200° C.

Abstract: Provided are: a supporting carbon material for a solid polymer fuel cell, said supporting carbon material making it possible to produce a high-performance solid polymer fuel cell in which there is little decrease in power generation performance as a result of repeated battery load fluctuation that inevitably occurs during operation of the solid polymer fuel cell; and a catalyst metal particle-supporting carbon material. The present invention relates to: a supporting carbon material for a solid polymer fuel cell, said supporting carbon material being a porous carbon material in which the specific surface area of mesopores having a pore diameter of 2-50 nm according to nitrogen adsorption measurement is 600-1,600 m2/g, the relative intensity ratio (IG?/IG) of the peak intensity (IG?) of the G-band 2,650-2,700 cm?1 range to the peak intensity (IG) of the G-band 1,550-1,650 cm?1 range in the Raman spectrum is 0.8-2.

Abstract: This invention provides a metal encapsulated dendritic carbon nanostructure comprising a dendritic carbon nanostructure comprising a branched carbon-containing rod-shaped or annular material and a metallic body capsulated in the carbon nanostructure. There is also provided a dendritic carbon nanostructure comprising a branched carbon-containing rod-shaped or annular material.

Abstract: Provided are a supporting carbon material for a solid polymer fuel cell and a metal-catalyst-particle-supporting carbon material that, when used as a carrier for a solid polymer fuel cell catalyst, have excellent power generation performance in high-humidity conditions, which are conditions in which solid polymer fuel cells are operated. A supporting carbon material for a solid polymer fuel cell and a metal-catalyst-particle-supporting carbon material characterized in being a porous carbon material, the hydrogen content being 0.004-0.010% by mass, the nitrogen adsorption BET specific surface area being 600 m2/g-1500 m2/g, and the relative intensity ratio (ID/IG) between the peak intensity (ID) in the range of 1200-1400 cm?1 known as the D-band and the peak intensity (IG) in the range of 1500-1700 cm?1 known as the G-band, obtained from the Raman spectrum, being 1.0-2.0.

Abstract: This invention provides a carbon nanostructure including: carbon containing rod-shaped materials and/or carbon containing sheet-shaped materials which are bound three-dimensionally; and graphene multilayer membrane walls which are formed in the rod-shaped materials and/or the sheet-shaped materials; wherein air-sac-like pores, which are defined by the graphene multilayer membrane walls, are formed in the rod-shaped materials and/or the sheet-shaped materials.

Abstract: A carbon material for catalyst support use which, when used as a catalyst support, maintains a high porosity while being stable chemically, having electrical conductivity, being excellent in durability, and being excellent in diffusibility of the reaction starting materials and reaction products is provided. It is characterized by comprising dendritic carbon mesoporous structures which have 3D structures of branched carbon-containing rod shapes or carbon-containing ring shapes, having a pore size of 1 to 20 nm and a cumulative pore volume of 0.2 to 1.5 cc/g found by analyzing a nitrogen adsorption isotherm by the Dollimore-Heal method, and having a powder X-ray diffraction spectrum which has a peak corresponding to a 002 diffraction line of graphite between diffraction angles (2?: degrees) of 20 to 30 degrees and has a peak with a half value width of 0.1 degree to 1.0 degree at 25.5 to 26.5 degrees.

Abstract: The present invention provides a microporous carbon material capable of expressing functions that supported metal has while maintaining pore functions that the microporous carbon material inherently possesses. The microporous carbon material 5 includes: a three-dimensional long-range ordered structure within a range from 0.7 nm or more to 2 nm or less; and micropores 2a, wherein a transition metal 4 is supported on surfaces of the micropores 2a. The microporous carbon material is obtained by a method including: introducing an organic compound on a surface of and inside the micropores of a porous material containing transition metal, and obtaining a composite of the microporous carbon material containing the transition metal and the porous material by carbonizing the organic compound by a chemical vapor deposition method; and removing the porous material.

Abstract: This invention provides a carbon nanostructure including: carbon containing rod-shaped materials and/or carbon containing sheet-shaped materials which are bound three-dimensionally; and graphene multilayer membrane walls which are formed in the rod-shaped materials and/or the sheet-shaped materials; wherein air-sac-like pores, which are defined by the graphene multilayer membrane walls, are formed in the rod-shaped materials and/or the sheet-shaped materials.

Abstract: This invention provides a carbon nanostructure including: carbon containing rod-shaped materials and/or carbon containing sheet-shaped materials which are bound three-dimensionally; and graphene multilayer membrane walls which are formed in the rod-shaped materials and/or the sheet-shaped materials; wherein air-sac-like pores, which are defined by the graphene multilayer membrane walls, are formed in the rod-shaped materials and/or the sheet-shaped materials.

Abstract: This invention provides a metal encapsulated dendritic carbon nanostructure comprising a dendritic carbon nanostructure comprising a branched carbon-containing rod-shaped or annular material and a metallic body capsulated in the carbon nanostructure. There is also provided a dendritic carbon nanostructure comprising a branched carbon-containing rod-shaped or annular material.

Abstract: The present invention provides a microporous carbon material capable of expressing functions that supported metal has while maintaining pore functions that the microporous carbon material inherently possesses. The microporous carbon material 5 includes: a three-dimensional long-range ordered structure within a range from 0.7 nm or more to 2 nm or less; and micropores 2a, wherein a transition metal 4 is supported on surfaces of the micropores 2a. The microporous carbon material is obtained by a method including: introducing an organic compound on a surface of and inside the micropores of a porous material containing transition metal, and obtaining a composite of the microporous carbon material containing the transition metal and the porous material by carbonizing the organic compound by a chemical vapor deposition method; and removing the porous material.

Abstract: This invention relates to a photo- or heat-curable resin composition which yields a cured product with minimal cracking and high reliability. The resin composition of this invention comprises 100 parts by weight of the resin-forming component containing a photo- or heat-polymerizable unsaturated compound and 0.01-5 parts by weight of an inorganic filler such as silica sol with its average particle diameter controlled in the range 5 nm-0.5 &mgr;m. The composition exhibits high heat resistance and good microfabrication quality and is useful as a peripheral material of electronic parts such as semiconductor devices by the build-up process, for example, as a material for forming insulation layers in multilayer printed wiring boards.

Abstract: This invention relates to an insulating resin composition which exhibits high impact resistance and heat resistance and good adhesiveness to the plating metal, is selectively etchable by a permanganate salt commonly used in a plating operation and suited for an insulating layer in multilayer wiring boards. The insulating resin composition is a photo-polymerizable or thermally polymerizable resin composition comprising 3-10 parts by weight of a crosslinked elastic polymer per 100 parts by weight of a resin component (excluding the crosslinked elastic poly and including monomers) and said crosslinked elastic polymer has carboxyl groups and is dispersed with an average secondary particle diameter in the range of 0.5-2 &mgr;m.

Abstract: This invention relates to a photo- or heat-curable resin composition which yields a cured product with minimal cracking and high reliability. The resin composition of this invention comprises 100 parts by weight of (A) photo- or heat-polymerizable unsaturated compound composed of a polycarboxylic acid adduct of bisphenol-epoxy (meth)acrylate, 10-100 parts by weight of (B) alkylene oxide-modified product of (meth)acrylate or oligomers thereof, 0-50 parts by weight of (C) compound containing epoxy group and 0-50 parts by weight of (D) photopolymerization initiator or sensitizer. The composition exhibits high heat resistance and good microfabrication quality and is useful as a peripheral material of electronic parts such as semiconductor devices by the build-up process, for example, as a material for forming insulation layers in multilayer printed wiring boards.

Abstract: This invention relates to an insulating resin composition which exhibits high impact resistance and heat resistance and good adhesiveness to the plating metal, is selectively etchable by a permanganate salt commonly used in a plating operation and suited for an insulating layer in multilayer wiring boards. The insulating resin composition is a photo polymerizable or thermally polymerizable resin composition comprising 3-10 parts by weight of a crosslinked elastic polymer per 100 parts by weight of a resin component (excluding the crosslinked elastic poly and including monomers) and said crosslinked elastic polymer has carboxyl groups and is dispersed with an average secondary particle diameter in the range of 0.5-2 &mgr;m.