Abstract: A process for producing an optically active 2-alkyl-1,1,3-trialkoxycarbonylpropane (2), comprising a step of asymmetric hydrolysis of 2-alkyl-1,1,3-trialokoxycarbonylpropane (1) by using an enzyme capable of selectively hydrolyzing an ester moiety of either one enantiomer of 2-alkyl-1,1,3-trialkoxycarbonylpropane (1), or by using a culture of a microorganism capable of producing the enzyme or a treated object thereof.

Abstract: Provided is a block copolymer film in which a microphase separation structure formed by a block copolymer is arranged perpendicularly to the film surface, and all components forming the block copolymer are uncovered to the film surface, whereby the microphase separation structure penetrates the film surface. A method of producing the block copolymer film includes the steps of extruding a melt of the block copolymer in one direction by extrusion molding or injection molding, cooling the extruded block copolymer to a temperature equal to or lower than glass transition temperatures of polymer components in the block copolymer to provide a prismatic or cylindrical extrusion molded product, and cutting the prismatic or cylindrical extrusion molded product in the direction perpendicular to the extrusion direction.

Abstract: An electro-conductive member for electrophotography, including an electro-conductive mandrel and an electro-conductive layer; and a process cartridge and an electrophotographic apparatus using the same. The layer contains a binder resin having a sulfo or a quaternary ammonium group as an ion exchange group, and an ion opposite in polarity to the ion exchange group. The resin has any one of structures represented by formulas (1)-1 and (1)-2, and any one of structures represented by formulas (2)-1 to (2)-3; and the resin has a molecular structure preventing occurrence of a matrix-domain structure. M represents an integer of 2-20, n represents an integer of 5-50, p represents an integer of 1-25, q represents an integer of 1-15, and r represents an integer of 1-12.

Abstract: An electrophotographic member is provided in which conductivity barely reduces and sufficient conductivity is obtained even under a low temperature and low humidity environment, a reduction in resistance beyond necessity is readily suppressed even under a high temperature and high humidity environment, and the bleeding of the quaternary ammonium salt can be suppressed.

Abstract: A method for manufacturing a patterned structural body by which a patterned structural body having a micropattern can be manufactured, a metal structural body-containing polymer film that can be used in the manufacture of the patterned structural body, and a method for manufacturing the polymer film are provided. The metal structural body-containing polymer film comprises a polymer film that includes a block copolymer having an ion-conductive segment and a non-ion-conductive segment and has a microphase-separated structure including ion-conductive domains and non-ion-conductive domains, and a metal structural body localized at the ion-conductive domains.

Abstract: An electrophotographic member having a high conductivity and having high adhesiveness to other layer, and a process cartridge and an electrophotographic apparatus using the electrophotographic member as a developer carrying member are provided. The electrophotographic member is an electrophotographic member including an electro-conductive mandrel and an electro-conductive layer, wherein the electro-conductive layer has a resin having a structure represented by the following structural formula (1), and an anion.

Abstract: To provide an electrically conducting member for electrophotography that has made itself kept from increasing in electrical resistance with time even in a low temperature and low humidity environment and also has made any ion conducting agent kept from bleeding to its surface. To also provide a process cartridge, and an electrophotographic image forming apparatus, that can stably form high-grade electrophotographic images over a long period of time in a variety of environments. The conductive member for electrophotography has an electrically conducting substrate and an electrically conducting layer, and the electrically conducting layer contains a resin having in the molecule at least one structure selected from structures represented by the formula (1), formula (2) and formula (3) each defined in the specification. The process cartridge and the electrophotographic image forming apparatus each make use of the same.

Abstract: The present invention provides an electrophotographic electrically conductive member in which conductivity needed for a charging member is secured, and defects in an image attributed to uneven discharging can be minimized independently of a long-term use and an environment of use. An electrophotographic electrically conductive member comprising an electrically conductive support and an electrically conductive layer, wherein the electrically conductive layer includes an ion conductive resin having a quaternary ammonium ion in a molecule structure as a binder resin, and a carrier molecule represented by the following formula (1) or (2): (wherein n1 and n2 each independently represent an integer of 1 to 4).

Abstract: To provide an electrically conducting member for electrophotography which can not easily come to change in electrical resistance value even upon application of direct current and also has made any ion conducting agent kept from bleeding. The electrically conducting member has an electrically conducting substrate and an electrically conducting layer; the electrically conducting layer containing an epichlorohydrin rubber having in the molecular structure at least an alkylene oxide (AO) unit, an epichlorohydrin (ECH) unit and a unit having a sulfonate ion; the AO unit being at least one unit of an ethylene oxide unit, a propylene oxide unit and a butylene oxide unit; and the AO unit(s) in the rubber being in a content of 5 to 60% by mass in total and the ECH unit in the rubber being in a content of 30% by mass or more.

Abstract: The present invention provides an electrophotographic electrically conductive member in which conductivity needed for a charging member is secured, and defects in an image attributed to uneven discharging can be minimized independently of a long-term use and an environment of use. An electrophotographic electrically conductive member comprising an electrically conductive support and an electrically conductive layer, wherein the electrically conductive layer includes an ion conductive resin having a quaternary ammonium ion in a molecule structure as a binder resin, and a carrier molecule represented by the following formula (1) or (2): (wherein n1 and n2 each independently represent an integer of 1 to 4).

Abstract: To suppress an excessive reduction in resistance of an electro-conductive roller under an H/H environment and reduce a resistance value thereof under an L/L environment, provided is an electro-conductive member for electrophotography, comprising: an electro-conductive mandrel; and an electro-conductive layer provided on a periphery of the mandrel, wherein the electro-conductive layer contains a binder resin having an alkylene oxide structure, and a sulfo or a quaternary ammonium group as an ion exchange group, and an ion having polarity opposite to polarity of the ion exchange group, a water content of the electro-conductive layer under a temperature of 30° C. and a relative humidity of 80% is 10 mass % or less, and a spin-spin relaxation time of the electro-conductive layer, which is determined by pulse NMR measurement with a hydrogen core being a measurement core under a temperature of 15° C. and a relative humidity of 10%, is 200 ?sec or more.

Abstract: To provide an electrically conducting member for electrophotography which can not easily come to change in electrical resistance value even upon application of direct current and also has made any ion conducting agent kept from bleeding. The electrically conducting member has an electrically conducting substrate and an electrically conducting layer; the electrically conducting layer containing an epichlorohydrin rubber having in the molecular structure at least an alkylene oxide (AO) unit, an epichlorohydrin (ECH) unit and a unit having a sulfonate ion; the AO unit being at least one unit of an ethylene oxide unit, a propylene oxide unit and a butylene oxide unit; and the AO unit(s) in the rubber being in a content of 5 to 60% by mass in total and the ECH unit in the rubber being in a content of 30% by mass or more.

Abstract: To provide an electrically conducting member for electrophotography that has made itself kept from increasing in electrical resistance with time even in a low temperature and low humidity environment and also has made any ion conducting agent kept from bleeding to its surface. To also provide a process cartridge, and an electrophotographic image forming apparatus, that can stably form high-grade electrophotographic images over a long period of time in a variety of environments. The conductive member for electrophotography has an electrically conducting substrate and an electrically conducting layer, and the electrically conducting layer contains a resin having in the molecule at least one structure selected from structures represented by the formula (1), formula (2) and formula (3) each defined in the specification. The process cartridge and the electrophotographic image forming apparatus each make use of the same.

Abstract: An electrically conductive member for electrophotography is provided which has an electrically conductive mandrel and an electrically conductive layer on the peripheral surface of the mandrel; the electrically conductive layer containing a binder resin having as an ion exchange group a sulfo group or a quaternary ammonium salt group in the molecule and an ion with a polarity opposite to that of the ion exchange group; the binder resin further having any structure selected from the group consisting of structures represented by formulas (1)-1 to (1)-3, and any structure selected from the group consisting of structures represented by formulas (2)-1 and (2)-2, and having a molecular structure that prevents any matrix-domain structure from being formed in the electrically conductive layer.

Abstract: To suppress an excessive reduction in resistance of an electro-conductive roller under an H/H environment and reduce a resistance value thereof under an L/L environment, provided is an electro-conductive member for electrophotography, comprising: an electro-conductive mandrel; and an electro-conductive layer provided on a periphery of the mandrel, wherein the electro-conductive layer contains a binder resin having an alkylene oxide structure, and a sulfo or a quaternary ammonium group as an ion exchange group, and an ion having polarity opposite to polarity of the ion exchange group, a water content of the electro-conductive layer under a temperature of 30° C. and a relative humidity of 80% is 10 mass % or less, and a spin-spin relaxation time of the electro-conductive layer, which is determined by pulse NMR measurement with a hydrogen core being a measurement core under a temperature of 15° C. and a relative humidity of 10%, is 200 ?sec or more.

Abstract: An ion-conductive polymer composite membrane is provided which has both high gas barrier properties and high protonic conductivity. The ion-conductive polymer composite membrane includes an ion-conductive polymer and ion-conductive materials. The ion-conductive materials each include i) an inorganic layered structure including a plurality of layers formed of an inorganic compound and ii) a sulfobetaine-type or hydroxysulfobetaine-type ampholytic surfactant. The ampholytic surfactant is present between the layers formed of an inorganic compound. The present invention further provides a membrane-electrode assembly and a fuel cell which use the ion-conductive polymer composite membrane, and a process for producing the ion-conductive polymer composite membrane.

Abstract: An electroconductive member excellent in durability even when applying direct current voltage over a long period of time is provided. Disclosed is an electroconductive member including an electroconductive mandrel and an electroconductive layer, wherein: the electroconductive layer includes a binder resin and an electroconductive metal oxide particle dispersed in the electroconductive layer; the metal oxide particle has a group represented by the following structural formula (1) on the surface of the metal oxide particle; and the group represented by the following structural formula (1) is introduced by substituting a hydrogen atom of a hydroxyl group as a functional group originating from the metal oxide particle, with the group represented by the following structural formula (1): —R—SO3H.

Abstract: Provided is a conductive member for electrophotography whose electrical resistance hardly increases even by long-term application of a high voltage. The conductive member for electrophotography is a conductive member for electrophotography, including: a conductive support; and a conductive elastic layer, in which: the elastic layer contains an A-B-A type block copolymer constituted of a non-ion conducting block (A block) and an ion conducting block (B block) having an ion exchange group; the block copolymer forms a microphase-separated structure; and the A block forms any structure selected from the group consisting of a spherical structure, a cylindrical structure, and a bicontinuous structure, and the B block forms a matrix for the structure.

Abstract: Provided is an electro-conductive member for electrophotography that stably shows high electro-conductivity even under a low-temperature, low-humidity environment. The electro-conductive member for electrophotography has an electro-conductive mandrel and an electro-conductive layer. The electro-conductive layer contains an ionic electro-conductive resin and an ion carrier. The ionic electro-conductive resin has at least one structure selected from the group consisting of structures represented by the following formulae (1), (2), (3), and (4), and a structure represented by the following formula (5) (in the formula (1) to the formula (5), R1, R2, R3, and R4 each represent a divalent organic group, X1, X2, X3, and X4 each independently represent a sulfonic group or a quaternary ammonium base, and 1 represents an integer of 1 or more and 23 or less).

Abstract: Provided is the following electro-conductive member for electrophotography. The electrical resistance of the member hardly increases even by long-term energization, and hence the member is conducive to stable formation of high-quality electrophotographic images. The electro-conductive member for electrophotography, comprises: an electro-conductive mandrel and an electro-conductive layer, wherein said electro-conductive layer contains an A-B-A type triblock copolymer in which an A-block is a polystyrene having a cation exchange group, and a B-block is a polyolefin, and wherein said A-B-A type triblock copolymer forms a microphase-separated structure comprising a matrix phase formed of said B-block, and one phase formed of the A-block and having a structure selected from the group consisting of a cylindrical structure, a bicontinuous structure and a lamellar structure.