Abstract: The present invention provides a supported metal catalyst with excellent effectiveness factor of active metal particles which are also free from deactivation by contacting with ionomer. According to the present invention, provided is a supported metal catalyst, comprising a support that is a collective body of conductive particles; and dispersed active metal particles supported on the conductive particles, wherein the conductive particles include a plurality of pores, an average entrance pore diameter of the pores is 1 to 20 nm, a standard deviation of the average entrance pore diameter is equal to or less than 50% of the average entrance pore diameter, a number fraction of the active metal particles supported in a surface layer region of the conductive particles divided by the total number of the active metal particles is equal to or more than 50%, and the surface layer region is a region on a surface of the conductive particles or a region in the pores within a depth of 15 nm from the surface.

Abstract: The first object is to increase the life of a selective CO methanation catalyst, and the second object is to enhance the CO removal rate of a selective CO methanation catalyst to reduce the outlet CO concentration in a wide temperature range. Provided a selective CO methanation catalyst including a supported metal catalyst which selectively methanizes CO in a hydrogen-rich gas containing CO and CO2 and a coating layer which covers a surface of the supported metal catalyst, has many pores, and is configured to reduce a CO concentration on the surface of the supported metal catalyst.

Abstract: The first object is to increase the life of a selective CO methanation catalyst, and the second object is to enhance the CO removal rate of a selective CO methanation catalyst to reduce the outlet CO concentration in a wide temperature range. Provided a selective CO methanation catalyst including a supported metal catalyst which selectively methanizes CO in a hydrogen-rich gas containing CO and CO2 and a coating layer which covers a surface of the supported metal catalyst, has many pores, and is configured to reduce a CO concentration on the surface of the supported metal catalyst.

Abstract: Provided is a new catalyst capable of removing carbon monoxide economically without adding particular reaction gas externally. Also provided are a process for producing and an apparatus using such a catalyst. Impregnation of a Ni—Al composite oxide precursor of a nonstoichiometric composition prepared by the solution-spray plasma technique with a ruthenium salt to be supported and performing reduction treatment allows CO methanation reaction to selectively proceed even in the high-temperature range in which CO2 methanation reaction and reverse water-gas-shift reaction proceed preferentially with conventional catalysts. Selective CO methanation reaction occurs reproducibly with another Ni—Al composite oxide precursor or an additive metallic species.

Abstract: Provided is a new catalyst capable of removing carbon monoxide economically without adding particular reaction gas externally. Also provided are a process for producing and an apparatus using such a catalyst. Impregnation of a Ni—Al composite oxide precursor of a nonstoichiometric composition prepared by the solution-spray plasma technique with a ruthenium salt to be supported and performing reduction treatment allows CO methanation reaction to selectively proceed even in the high-temperature range in which CO2 methanation reaction and reverse water-gas-shift reaction proceed preferentially with conventional catalysts. Selective CO methanation reaction occurs reproducibly with another Ni—Al composite oxide precursor or an additive metallic species.

Abstract: A solid polymer electrolyte is made up of a polymer compound having a hydrocarbon aromatic group in the backbone thereof and including a side chain expressed by FORMULA 1: wherein “n” is 1, 2, 3, 4, 5, or 6. The solid polymer electrolyte may be incorporated into a membrane and may be used in a solution for covering an electrode catalyst.

Abstract: A solid polymer electrolyte is made up of a polymer compound having a hydrocarbon aromatic group in the backbone thereof and including a side chain expressed by FORMULA 1: CH2nSO3H??FORMULA 1 wherein “n” is 1, 2, 3, 4, 5, or 6. The solid polymer electrolyte may be incorporated into a membrane and may be used in a solution for covering an electrode catalyst.

Abstract: An object of the present invention is to provide a highly durable solid polymer electrolyte that has a deterioration resistance equal to or higher than that of the fluorine-containing solid polymer electrolytes or a deterioration resistance sufficient for practical purposes, and can be produced at a low cost. According to the present invention, there is provided a solid polymer electrolyte comprising a polyether ether sulfone that is used as an electrolyte and has sulfoalkyl groups bonded to its aromatic rings and represented by the general formula —(CH2)n—SO3H.

Abstract: According to the present invention, it is possible to provide a catalyst which includes metal clusters containing a non-platinum element as the catalyst active ingredient, these metal clusters having species of a metal having different valences, and exhibits an improved electrode performance per unit price of the used metal, compared to catalysts using platinum. When this catalyst is applied to an electrode catalyst for fuel cell, a low-cost fuel cell system can be realized without using expensive platinum as the active ingredient. This catalyst can be applied to DMFC and PEFC fuel cells.

Abstract: An object of the present invention is to provide a new exhaust gas purification apparatus for an internal combustion engine operated under a condition of an air fuel ratio leaner than a theoretical air fuel ratio, a method for purification of exhaust gas and an exhaust gas purification catalyst, which is suitable for suppressing degradation of the NOx purification catalyst by sulfur components.

Abstract: A solid polymer electrolyte is made up of a polymer compound having a hydrocarbon aromatic group in the backbone thereof and including a side chain expressed by FORMULA 1: wherein “n” is 1, 2, 3, 4, 5, or 6. The solid polymer electrolyte may be incorporated into a membrane and may be used in a solution for covering an electrode catalyst.

Abstract: A semiconductor device containing a dielectric capacitor having an excellent step coverage for a device structure of high aspect ratio corresponding to high integration degree, as well as a manufacturing method therefor are provided. A dielectric capacitor of high integration degree is manufactured by forming a bottom electrode 46 and a top-electrode 48 comprising a homogeneous thin Ru film with 100% step coverage while putting a dielectric 47 therebetween on substrates 44, 45 having a three-dimensional structure with an aspect ratio of 3 or more by a MOCVD process using a cyclopentadienyl complex within a temperature range from 180° C. or higher to 250° C. or lower.

Abstract: An apparatus for purifying an exhaust gas of a diesel engine, characterized in that it has an NOx adsorption and reduction type catalyst and a diesel particulate filter for oxidizing and removing particulate matters in the exhaust gas, which are provided in the flow route for the exhaust gas and are arranged in the above described order from the upstream of the flow of the exhaust gas. The above arrangement allows the elevation of the temperature of the catalyst with ease and the precise control of the temperature and atmosphere therein, resulting in the achievement of satisfactory NOx purification performance, and the employment of the NOx adsorption and reduction type catalyst allows the enhancement of the rate of reduction of the NO2 captured, which shortens the time to keep a stoichiometric-rich atmosphere to a time of several seconds to several minutes.

Abstract: A solid polymer electrolyte is made up of a polymer compound having a hydrocarbon aromatic group in the backbone thereof and including a side chain expressed by FORMULA 1: CH2nSO3H??FORMULA 1 wherein “n” is 1, 2, 3, 4, 5, or 6. The solid polymer electrolyte may be incorporated into a membrane and may be used in a solution for covering an electrode catalyst.

Abstract: A solid polymer electrolyte is made up of a polymer compound having a hydrocarbon aromatic group in the backbone thereof and including a side chain expressed by FORMULA 1: wherein “n” is 1, 2, 3, 4, 5, or 6. The solid polymer electrolyte may be incorporated into a membrane and may be used in a solution for covering an electrode catalyst.

Abstract: A ferroelectric capacitor of the type having a top electrode, a ferroelectric thin film, and a bottom electrode, is characterized in that said ferroelectric thin film is a perovskite-type oxide containing Pb and said upper and bottom electrodes contain an intermetallic compound composed of Pt and Pb. An electronic device is provided with said ferroelectric capacitor. This construction is designed to solve the following problems. In a non-volatile ferroelectric memory (FeRAM), a degraded layer occurs near the interface between the PZT and the electrode due to hydrogen evolved during processing or due to diffusion of Pb from the PZT into the electrode. A stress due to a difference in lattice constant occurs in the interface between the electrode and the ferroelectric thin film. The degraded layer and the interfacial stress deteriorate the initial polarizing characteristics of the ferroelectric capacitor and also greatly deteriorate the polarizing characteristics after switching cycles.

Abstract: An object of the present invention is to provide a highly durable solid polymer electrolyte that has a deterioration resistance equal to or higher than that of the fluorine-containing solid polymer electrolytes or a deterioration resistance sufficient for practical purposes, and can be produced at a low cost. According to the present invention, there is provided a solid polymer electrolyte comprising a polyether ether sulfone that is used as a electrolyte and has sulfoalkyl groups bonded to its aromatic rings and represented by the general formula —(CH2)n—SO3H.

Abstract: For the stabilization of the reaction, especially, for maintaining reaction temperature, the feedback control by the feedback unit is performed for to the supply of air (, oxygen, or oxidizing agent), whereas other materials are supplied by the open-loop control according to the instruction of the flow selection unit which indicates a preset value depending on the required hydrogen production volume. In addition, the continuous flow setting unit capable of changing the flow continuously is employed for the supply system of the air, whereas the flow control of the other materials is performed by use of the discrete flow setting units each of which provides the discretized flow by use of the on-off combination of two or more on-off valves.

Abstract: An object of the present invention is to provide a highly durable solid polymer electrolyte that has a deterioration resistance equal to or higher than that of the fluorine-containing solid polymer electrolytes or a deterioration resistance sufficient for practical purposes, and can be produced at a low cost. According to the present invention, there is provided a solid polymer electrolyte comprising a polyether ether sulfone that is used as an electrolyte and has sulfoalkyl groups bonded to its aromatic rings and represented by the general formula —(CH2)n—SO3H.

Abstract: A semiconductor device containing a dielectric capacitor having an excellent step coverage for a device structure of high aspect ratio corresponding to high integration degree, as well as a manufacturing method therefor are provided. A dielectric capacitor of high integration degree is manufactured by forming a bottom electrode 46 and a top-electrode 48 comprising a homogeneous thin Ru film with 100% step coverage while putting a dielectric 47 therebetween on substrates 44, 45 having a three-dimensional structure with an aspect ratio of 3 or more by a MOCVD process using a cyclopentadienyl complex within a temperature range from 180° C. or higher to 250° C. or lower.