Patents by Inventor Kazutoshi Watanabe

Kazutoshi Watanabe has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240099143
    Abstract: There is provided a piezoelectric stack including: a substrate (1); a bottom electrode film (2) on the substrate; a piezoelectric film (3) on the bottom electrode film, having a planar area smaller than a planar area of the bottom electrode film; a top electrode film (4) on the piezoelectric film; and an insulating film (5) provided from the top electrode film to the bottom electrode film and covering at least a part of a side surface of the piezoelectric film, wherein the insulating film has a slope (9a) filling a step between a top surface of the top electrode film and a top surface of the bottom electrode film, and the slope has a shape alleviating the step.
    Type: Application
    Filed: January 12, 2022
    Publication date: March 21, 2024
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Toshiaki KURODA, Kenji SHIBATA, Kazutoshi WATANABE, Takeshi KIMURA
  • Patent number: 11805700
    Abstract: There is provided a laminated substrate having a piezoelectric film, including: a substrate; a first electrode film provided on the substrate; and a piezoelectric film provided on the first electrode film, wherein an oxide film containing an oxide represented by a composition formula of RuOx or IrOx, is provided on the piezoelectric film.
    Type: Grant
    Filed: April 19, 2018
    Date of Patent: October 31, 2023
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji Shibata, Kazutoshi Watanabe, Fumimasa Horikiri
  • Patent number: 11800808
    Abstract: There is provided a piezoelectric stack, including: a substrate; an electrode film; and a piezoelectric film which is comprised of alkali niobium oxide of a perovskite structure represented by a composition formula of (K1-xNax)NbO3 (0<x<1), wherein the piezoelectric film comprises crystals having a grain size with a standard deviation of 0.42 ?m or less.
    Type: Grant
    Filed: July 30, 2020
    Date of Patent: October 24, 2023
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji Shibata, Kazutoshi Watanabe, Toshiaki Kuroda
  • Publication number: 20230276711
    Abstract: There is provided a piezoelectric stack, including: a substrate; an output-side bottom electrode film on the substrate; an output-side piezoelectric film, being an oxide film, on the output-side bottom electrode film; an output-side top electrode film on the output-side piezoelectric film; an input-side bottom electrode film on the substrate; an input-side piezoelectric film, being a nitride film, on the input-side bottom electrode film; an input-side top electrode film on the input-side piezoelectric film; and an ultrasonic output part and ultrasonic input part placed in such a manner as not overlapping each other when viewed from a top surface of the substrate, the ultrasonic output part comprising a stacked part of the output-side bottom electrode film, the output-side piezoelectric film, and the output-side top electrode film, the ultrasonic input part comprising a stacked part of the input-side bottom electrode film, the input-side piezoelectric film, and the input-side top electrode film.
    Type: Application
    Filed: February 24, 2021
    Publication date: August 31, 2023
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Toshiaki KURODA, Kenji SHIBATA, Kazutoshi WATANABE, Takeshi KIMURA
  • Patent number: 11744159
    Abstract: There is provided a piezoelectric laminate, including: a substrate; and a piezoelectric film formed on the substrate, wherein the piezoelectric film contains an alkali niobium oxide represented by a composition formula of (K1?xNax)NbO3 (0<x<1), having a perovskite structure, and contains a metallic element selected from a group consisting of Cu and Mn at a concentration of more than 0.6 at % and 2.0 at % or less.
    Type: Grant
    Filed: March 5, 2019
    Date of Patent: August 29, 2023
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji Shibata, Kazutoshi Watanabe, Fumimasa Horikiri
  • Publication number: 20230270013
    Abstract: There is provided a piezoelectric stack, including: a substrate; an oxide film on the substrate, containing zinc and oxygen as main elements; an electrode film on the oxide film; and a piezoelectric film on the electrode film, being an alkali niobium oxide film containing potassium, sodium, niobium, and oxygen and having a perovskite structure.
    Type: Application
    Filed: March 16, 2021
    Publication date: August 24, 2023
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Toshiaki KURODA, Kenji SHIBATA, Kazutoshi WATANABE, Takeshi KIMURA
  • Publication number: 20230142065
    Abstract: There is provided a piezoelectric stack, including: a substrate; an output-side bottom electrode film on the substrate; an output-side piezoelectric film, being an oxide film, on the output-side bottom electrode film; an output-side top electrode film on the output-side piezoelectric film; an input-side bottom electrode film on the substrate; an input-side piezoelectric film, being a nitride film, on the input-side bottom electrode film; an input-side top electrode film on the input-side piezoelectric film; and an ultrasonic output part and ultrasonic input part placed in such a manner as not overlapping each other when viewed from a top surface of the substrate, the ultrasonic output part comprising a stacked part of the output-side bottom electrode film, the output-side piezoelectric film, and the output-side top electrode film, the ultrasonic input part comprising a stacked part of the input-side bottom electrode film, the input-side piezoelectric film, and the input-side top electrode film.
    Type: Application
    Filed: February 24, 2021
    Publication date: May 11, 2023
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Toshiaki KURODA, Kenji SHIBATA, Kazutoshi WATANABE, Takeshi KIMURA
  • Publication number: 20230135208
    Abstract: A piezoelectric stack, including: a substrate; an electrode film; and a piezoelectric film comprising an alkali niobium oxide of a perovskite structure represented by a composition formula of (K1-xNax)NbO3 (0<x<1), wherein an average light transmittance through the piezoelectric film in a wavelength region of visible light and near-infrared ray is 65% or more.
    Type: Application
    Filed: November 14, 2019
    Publication date: May 4, 2023
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji SHIBATA, Kazutoshi WATANABE, Fumimasa HORIKIRI
  • Publication number: 20230115136
    Abstract: There is provided a laminated substrate having a piezoelectric film, including: a substrate; and a piezoelectric film provided on the substrate interposing a base film, wherein the piezoelectric film has an alkali niobium oxide based perovskite structure represented by a composition formula of (K1-xNax)NbO3 (0<x<1) and preferentially oriented in (001) plane direction, and a sound speed of the piezoelectric film is 5100 m/s or more.
    Type: Application
    Filed: December 15, 2022
    Publication date: April 13, 2023
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji SHIBATA, Kazutoshi WATANABE, Fumimasa HORIKIRI
  • Patent number: 11557713
    Abstract: There is provided a laminated substrate having a piezoelectric film, including: a substrate; and a piezoelectric film provided on the substrate interposing a base film, wherein the piezoelectric film has an alkali niobium oxide based perovskite structure represented by a composition formula of (K1-xNax)NbO3 (0<x<1) and preferentially oriented in (001) plane direction, and a sound speed of the piezoelectric film is 5100 m/s or more.
    Type: Grant
    Filed: June 22, 2018
    Date of Patent: January 17, 2023
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji Shibata, Kazutoshi Watanabe, Fumimasa Horikiri
  • Publication number: 20220254988
    Abstract: A piezoelectric stack including: a substrate; an electrode film; and a piezoelectric film as a poly-crystal film comprising an alkali niobium oxide of a perovskite structure represented by a composition formula of (K1-xNax)NbO3 (0<x<1), wherein the piezoelectric film contains at least one element selected from a group consisting of Cu and Mn, and an amount of the element present at a grain boundary of crystals constituting the piezoelectric film is greater than that of the element present in a matrix phase of the crystals.
    Type: Application
    Filed: July 2, 2020
    Publication date: August 11, 2022
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Toshiaki KURODA, Kenji SHIBATA, Kazutoshi WATANABE, Takeshi KIMURA
  • Patent number: 11367826
    Abstract: There is provided a piezoelectric laminate, including: a substrate; and a piezoelectric film formed on the substrate, wherein the piezoelectric film is a film containing an alkali niobium oxide of a perovskite structure represented by a composition formula of (K1-xNax)NbO3 (0<x<1), and having Young's modulus of less than 100 GPa.
    Type: Grant
    Filed: March 8, 2019
    Date of Patent: June 21, 2022
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji Shibata, Kazutoshi Watanabe, Fumimasa Horikiri
  • Publication number: 20210359195
    Abstract: There is provided a laminated substrate with a piezoelectric thin film, comprising: a substrate; an electrode film formed on the substrate; and a piezoelectric thin film formed on the electrode film, wherein the piezoelectric thin film is made of an alkali niobium oxide represented by a composition formula of (K1-xNax)NbO3 (0<x<1), having a perovskite structure, and oriented preferentially in (001) plane direction, and contains a metallic element selected from a group consisting of Mn and Cu at a concentration of 0.2 at % or more and 0.6 at % or less.
    Type: Application
    Filed: July 28, 2021
    Publication date: November 18, 2021
    Inventors: Kenji SHIBATA, Kazutoshi WATANABE, Fumimasa HORIKIRI
  • Patent number: 11107971
    Abstract: There is provided a laminated substrate with a piezoelectric thin film, comprising: a substrate; an electrode film formed on the substrate; and a piezoelectric thin film formed on the electrode film, wherein the piezoelectric thin film is made of an alkali niobium oxide represented by a composition formula of (K1?xNax) NbO3 (0<x<1), having a perovskite structure, and oriented preferentially in (001) plane direction, and contains a metallic element selected from a group consisting of Mn and Cu at a concentration of 0.2 at % or more and 0.6 at % or less.
    Type: Grant
    Filed: October 11, 2016
    Date of Patent: August 31, 2021
    Assignee: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji Shibata, Kazutoshi Watanabe, Fumimasa Horikiri
  • Publication number: 20210036214
    Abstract: There is provided a piezoelectric stack, including: a substrate; an electrode film; and a piezoelectric film which is comprised of alkali niobium oxide of a perovskite structure represented by a composition formula of (K1-xNax)NbO3 (0<x<1), wherein the piezoelectric film comprises crystals having a grain size with a standard deviation of more than 0.42 ?m.
    Type: Application
    Filed: July 30, 2020
    Publication date: February 4, 2021
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji SHIBATA, Kazutoshi WATANABE, Toshiaki KURODA
  • Publication number: 20210036213
    Abstract: There is provided a piezoelectric stack, including: a substrate; an electrode film; and a piezoelectric film which is comprised of alkali niobium oxide of a perovskite structure represented by a composition formula of (K1-xNax)NbO3 (0<x<1), wherein the piezoelectric film comprises crystals having a grain size with a standard deviation of 0.42 ?m or less.
    Type: Application
    Filed: July 30, 2020
    Publication date: February 4, 2021
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji SHIBATA, Kazutoshi WATANABE, Toshiaki KURODA
  • Publication number: 20210036212
    Abstract: There is provided a piezoelectric laminate, including: a substrate; an electrode film formed on the substrate; a layer comprised of lanthanum nickel oxide and formed on the electrode film; and a piezoelectric film formed on the layer comprised of lanthanum nickel oxide, and comprised of alkali niobium oxide of a perovskite structure represented by a composition formula of (K1?xNax)NbO3 (0<x<1), and containing a metallic element selected from a group consisting of Cu and Mn at a concentration of 0.2 at % or more and 2.0 at % or less, wherein the piezoelectric film has a breakdown voltage of 350 kV/cm or more.
    Type: Application
    Filed: July 30, 2020
    Publication date: February 4, 2021
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji SHIBATA, Kazutoshi WATANABE, Toshiaki KURODA
  • Publication number: 20210005805
    Abstract: There is provided a piezoelectric laminate, including: a substrate; a base layer formed on the substrate; and a piezoelectric film containing alkali niobium oxide and having a perovskite structure, which is formed on the base layer, as a polycrystalline film, and represented by a composition formula of (K1-xNax)NbO3 (0<x<1), wherein a crystal grain group forming the piezoelectric film includes a crystal grain having a ratio of 0.01 nm?1 or more and 0.1 nm?1 or less, which is the ratio of an outer peripheral length to a cross-sectional area when observing a cross-section of the crystal grain.
    Type: Application
    Filed: July 2, 2020
    Publication date: January 7, 2021
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Kenji SHIBATA, Kazutoshi WATANABE, Toshiaki KURODA
  • Publication number: 20200388746
    Abstract: There is provided a laminated substrate having a piezoelectric film, including: a substrate; a first electrode film provided on the substrate; and a piezoelectric film provided on the first electrode film, wherein an oxide film containing an oxide represented by a composition formula of RuOx or IrOx, is provided on the piezoelectric film.
    Type: Application
    Filed: April 19, 2018
    Publication date: December 10, 2020
    Applicant: Sumitomo Chemical Company, Limited
    Inventors: Kenji SHIBATA, Kazutoshi WATANABE, Fumimasa HORIKIRI
  • Patent number: 10837982
    Abstract: To avoid applying overload on both a probe and a sample surface, and to reduce time for measuring irregular shapes on the sample surface in performing an intermittent measurement method, provided is a scanning probe microscope including: a cantilever having a probe attached thereto, the scanning probe microscope being configured to scan a sample surface by intermittently bringing the probe into contact with the sample surface; and a control device configured to perform a first operation of bringing the probe and the sample surface into contact with each other, and a second operation of separating the probe and the sample surface from each other after the first operation. The control device executes the second operation by thermally deforming the cantilever.
    Type: Grant
    Filed: March 22, 2019
    Date of Patent: November 17, 2020
    Assignee: HITACHI HIGH-TECH SCIENCE CORPORATION
    Inventors: Masatsugu Shigeno, Hiroyoshi Yamamoto, Kazutoshi Watanabe