Abstract: Disclosed is a method for readily and inexpensively producing zeolite without using an organic structure-directing agent (organic SDA). Specifically disclosed is a method whereby a gel containing a silica source, an alumina source, an alkaline source and water is reacted with zeolite seed crystals, to produce a zeolite with the same kind of skeletal structure as the zeolite. The gel used is a gel of a composition whereby, when a zeolite is synthesized from this gel only, the synthesized zeolite comprises at least one of the kinds of composite building units of the target zeolite.

Abstract: The purpose of/problem to be addressed by the present invention is to provide: an Fe(II)-substituted beta-type zeolite useful for the catalytic removal of a variety of gases; and a production method therefor. The SiO2/Al2O3 ratio in this Fe(II)-substituted beta-type zeolite is equal to or more than 7 but less than 10. This Fe(II)-substituted beta-type zeolite is obtained by being subjected to ionic exchange with Fe(II) ions. It is preferable that the Fe(II) loading amount be in the range of 0.001-0.4 mmol/g of the Fe(II)-substituted beta-type zeolite. It is preferable that the Fe(II)-substituted beta-type zeolite be produced using a method in which a beta-type zeolite having an SiO2/Al2O3 ratio of equal to or more than 7 but less than 10 is dispersed in an Fe(II) water-soluble-compound aqueous solution, and then mixed and agitated to cause the beta-type zeolite to carry Fe(II) ions.

Abstract: A process for producing a VET-type zeolite is provided in which the use of a structure-directing agent is minimized and the environmental burden can be minimized. This process for producing a VET-type zeolite comprises (1) mixing a zinc source, an element M1 source, an alkali source, and water so as to result in a reaction mixture having a specific composition in terms of molar ratio, (2) using, as seed crystals, a VET-type zeolite which has an M1O2/ZnO ratio of 5-30 and adding the zeolite to the reaction mixture in an amount of 0.1-30 wt % relative to the M1O2 contained in the reaction mixture, and (3) heating the reaction mixture to which the seed crystals have been added, at 80-200° C. in a hermetically closed state. M1 represents silicon or a mixture of silicon and germanium.

Abstract: Provided is a method for producing a MAZ-type zeolite, the method having an environmental impact which has been reduced as much as possible while not using a structure-directing agent as far as possible. In the method for producing a MAZ-type zeolite according to the present invention: (1) a silica source, an alumina source, an alkali source and water are mixed so as to form a reaction mixture that has a composition represented by a specific molar ratio; (2) a MAZ-type zeolite, which has a SiO2/Al2O3 ratio of 5-10, has an average particle diameter of at least 0.1 ?m and does not contain an organic compound, is added, as a seed crystal, into the reaction mixture in an amount of 0.1-30 weight % relative to the silica components in the reaction mixture; and (3) the reaction mixture, into which the seed crystal has been added, is heated at 80-200° C. in a closed system.

Abstract: Provided is a method that is for producing a PAU zeolite and that can have an environmental impact that is reduced while, as much as possible, not using a structure-defining agent. The method for producing a PAU zeolite produces by means of (1) mixing a silica source, an alumina source, an alkali source, and water in a manner so as to result in a reaction mixture having a composition represented by a specific mole ratio, (2) using as the seed crystal a PAU zeolite that does not contain organic compounds and has a SiO2/Al2O3 ratio of 4-15 and an average particle size of at least 100 nm, and adding same to the reaction mixture at a ratio of 0.1-20 wt % with respect to the silica component in the reaction mixture, and (3) subjecting the reaction mixture to which the seed crystal has been added to sealed-vessel heating at 80-200° C.

Abstract: The purpose of/problem addressed by the present invention is to provide: an Fe(II)-substituted MEL-type zeolite useful for the catalytic removal of a variety of gases; and a production method therefor. The SiO2/Al2O3 ratio in this Fe(II)-substituted MEL-type zeolite is in the range of 10-30 inclusive. This Fe(II)-substituted MEL-type zeolite is obtained by being subjected to ionic exchange with Fe(II) ions. It is preferable that the Fe(II) loading amount be in the range of 0.001-0.4 mmol/g of the Fe(II)-substituted MEL-type zeolite. It is preferable that the Fe(II)-substituted MEL-type zeolite be produced using a method in which an MEL-type zeolite having an SiO2/Al2O3 ratio in the range of 10-30 inclusive is dispersed in an Fe(II) water-soluble-compound aqueous solution, and then mixed and agitated to cause the MEL-type zeolite to carry Fe(II) ions.

Abstract: The method for producing an MTW-type zeolite according to the present invention includes: mixing a silica source, an alumina source, an alkali source, a lithium source, and water so as to obtain a reaction mixture having a composition represented by specific molar ratios; (2) adding an MTW-type zeolite which has a SiO2/Al2O3 ratio of 10 to 500 and does not contain an organic compound, as a seed crystal, to the reaction mixture in a proportion of 0.1 to 20% by weight relative to the silica component in the reaction mixture; and (3) airtightly heating the reaction mixture, to which the seed crystal has been added, at 100 to 200° C.

Abstract: A method for producing an MTW-type zeolite, comprising (1) mixing an alumina source, an alkali source, a lithium source, and water so as to obtain a reaction mixture (2) Adding a seed crystal of an MTW-type zeolite before or while a silica source is added to the reaction mixture in a proportion of 0.1 to 20% by weight relative to the silica component in the reaction mixture. Mixing and stirring the reaction mixture. Wherein the MTW-type zeolite of the seed crystal has a SiO2/Al2O3 ratio of 10 to 500 and does not contain an organic compound. The reaction mixture has a composition represented by the following molar ratios: SiO2/Al2O3=12 to 200, Na2O/SiO2=0.1 to 0.3, Li2O/(Na2O+Li2O)=0.05 to 0.5 and H2O/SiO2=10 to 50. (3) Air tightly heating the reaction mixture, to which the seed crystal of the MTW type zeolite has been added, at 100 to 200° C.

Abstract: A skin gas measurement device includes a skin gas collecting unit that includes a skin gas collecting space having an opening that is to be attached to a skin surface, a porous material that is for adsorbing and concentrating a skin gas component that is emitted from the skin surface into the skin gas collecting space and that allows the adsorbed skin gas component to be desorbed at a relatively low temperature, and a heater for heating the porous material; and a skin gas measurement unit for measuring the skin gas component that is desorbed from the heated porous material.

Abstract: To provide a hydrocarbon reforming/trapping material which is capable of adsorbing and reforming a hydrocarbon. A hydrocarbon reforming/trapping material of the present invention has an SiO2/Al2O3 ratio of from 7 to 12, and contains an Fe(II)-substituted beta zeolite which is ion-exchanged by Fe(II) ions. The amount of supported Fe(II) is preferably 0.001-0.5 mmol/g with respect to the Fe(II)-substituted beta zeolite. This Fe(II)-substituted beta zeolite is suitably produced by dispersing and mixing a beta zeolite having an SiO2/Al2O3 ratio of from 7 to 12 in an aqueous solution of a water-soluble compound of divalent iron, and mixing and stirring the solution, so that Fe(II) ions are supported on the beta zeolite.

Abstract: Provided is a beta-type zeolite which has a high catalytic activity and is not easily deactivated. The beta-type zeolite of the invention has a substantially octahedral shape, has a Si/Al ratio of 5 or more, and is a proton-type zeolite. The Si/Al ratio is preferably 40 or more. This beta-type zeolite is preferably obtained by transforming a raw material beta-type zeolite synthesized without using a structure directing agent into an ammonium-type zeolite through ion exchange, then, exposing the beta-type zeolite to water vapor, and subjecting the exposed beta-type zeolite to an acid treatment.

Abstract: A process for producing a VET-type zeolite is provided in which the use of a structure-directing agent is minimized and the environmental burden can be minimized. This process for producing a VET-type zeolite comprises (1) mixing a zinc source, an element M1 source, an alkali source, and water so as to result in a reaction mixture having a specific composition in terms of molar ratio, (2) using, as seed crystals, a VET-type zeolite which has an M1O2/ZnO ratio of 5-30 and adding the zeolite to the reaction mixture in an amount of 0.1-30 wt % relative to the M1O2 contained in the reaction mixture, and (3) heating the reaction mixture to which the seed crystals have been added, at 80-200° C. in a hermetically closed state. M1 represents silicon or a mixture of silicon and germanium.

Abstract: To provide an Fe(II)-substituted beta type zeolite which has been ion-exchanged with Fe(II) ions and can effectively adsorb and remove nitrogen monoxide or hydrocarbon contained in gas to be cleaned, even if oxygen is present in the gas at a high concentration or the temperature of the gas is low. In the Fe(II)-substituted beta type zeolite, a ratio of SiO2/Al2O3 is preferably 10 to 18, a BET specific surface area is preferably 400 m2/g to 700 m2/g, a micropore specific surface area is preferably 290 m2/g to 500 m2/g, and a micropore volume is preferably 0.15 cm3/g to 0.25 cm3/g. The amount of Fe(II) supported is preferably 0.01% by mass to 6.5% by mass based on the Fe(II)-substituted beta type zeolite.

Abstract: Provided is a method for producing a MAZ-type zeolite, the method having an environmental impact which has been reduced as much as possible whilst not using a structure-directing agent as far as possible. In the method for producing a MAZ-type zeolite according to the present invention: (1) a silica source, an alumina source, an alkali source and water are mixed so as to form a reaction mixture that has a composition represented by a specific molar ratio; (2) a MAZ-type zeolite, which has a SiO2/Al2O3 ratio of 5-10, has an average particle diameter of at least 0.1 ?m and does not contain an organic compound, is added, as a seed crystal, into the reaction mixture in an amount of 0.1-30 weight % relative to the silica components in the reaction mixture; and (3) the reaction mixture, into which the seed crystal has been added, is heated at 80-200° C. in a closed system.

Abstract: The purpose of/problem to be addressed by the present invention is to provide: an Fe(II)-substituted beta-type zeolite useful for the catalytic removal of a variety of gases; and a production method therefor. The SiO2/Al2O3 ratio in this Fe(II)-substituted beta-type zeolite is equal to or more than 7 but less than 10. This Fe(II)-substituted beta-type zeolite is obtained by being subjected to ionic exchange with Fe(II) ions. It is preferable that the Fe(II) loading amount be in the range of 0.001-0.4 mmol/g of the Fe(II)-substituted beta-type zeolite. It is preferable that the Fe(II)-substituted beta-type zeolite be produced using a method in which a beta-type zeolite having an SiO2/Al2O3 ratio of equal to or more than 7 but less than 10 is dispersed in an Fe(II) water-soluble-compound aqueous solution, and then mixed and agitated to cause the beta-type zeolite to carry Fe(II) ions.

Abstract: The purpose of/problem addressed by the present invention is to provide: an Fe(II)-substituted MEL-type zeolite useful for the catalytic removal of a variety of gases; and a production method therefor. The SiO2/Al2O3 ratio in this Fe(II)-substituted MEL-type zeolite is in the range of 10-30 inclusive. This Fe(II)-substituted MEL-type zeolite is obtained by being subjected to ionic exchange with Fe(II) ions. It is preferable that the Fe(II) loading amount be in the range of 0.001-0.4 mmol/g of the Fe(II)-substituted MEL-type zeolite. It is preferable that the Fe(II)-substituted MEL-type zeolite be produced using a method in which an MEL-type zeolite having an SiO2/Al2O3 ratio in the range of 10-30 inclusive is dispersed in an Fe(II) water-soluble-compound aqueous solution, and then mixed and agitated to cause the MEL-type zeolite to carry Fe(II) ions.

Abstract: Provided is a method that is for producing a PAU zeolite and that can have an environmental impact that is reduced while, as much as possible, not using a structure-defining agent. The method for producing a PAU zeolite produces by means of (1) mixing a silica source, an alumina source, an alkali source, and water in a manner so as to result in a reaction mixture having a composition represented by a specific mole ratio, (2) using as the seed crystal a PAU zeolite that does not contain organic compounds and has a SiO2/Al2O3 ratio of 4-15 and an average particle size of at least 100 nm, and adding same to the reaction mixture at a ratio of 0.1-20 wt % with respect to the silica component in the reaction mixture, and (3) subjecting the reaction mixture to which the seed crystal has been added to sealed-vessel heating at 80-200° C.

Abstract: The present invention provides a beta zeolite that is useful as a catalyst, adsorbent agent, or the like, and that is both microporous and mesoporous. The beta zeolite is characterized by (i) the SiO2/Al2O3 ratio being 8-30, and the SiO2/ZnO ratio being 8-1000, (ii) the micropore surface area being 300-800 m2/g, (iii) the micropore volume being 0.1-0.3 cm3/g, and (iv) having mesopores having, in the state as synthesized, a diameter of 2-6 nm and a volume of 0.001-0.3 cm3/g. The beta zeolite is favorably produced by means of adding and reacting a zinc silicate beta zeolite as a seed crystal with a reaction mixture containing a silica source, an alumina source, an alkali source, and water.

Abstract: Provided is a beta-type zeolite which has a high catalytic activity and is not easily deactivated. The beta-type zeolite of the invention has a substantially octahedral shape, has a Si/Al ratio of 5 or more, and is a proton-type zeolite. The Si/Al ratio is preferably 40 or more. This beta-type zeolite is preferably obtained by transforming a raw material beta-type zeolite synthesized without using a structure directing agent into an ammonium-type zeolite through ion exchange, then, exposing the beta-type zeolite to water vapor, and subjecting the exposed beta-type zeolite to an acid treatment.

Abstract: Provided is a method for producing an MTW-type zeolite. The reaction mixture contains a silica source, an alumina source, an alkali source, and water is reacted with a seed crystal of a zeolite to produce an MTW-type zeolite. The reaction mixture has a composition, which makes a synthesized zeolite contain an MFI-type zeolite when the zeolite is synthesized solely from the reaction mixture, is used. As the seed crystal, a beta-type zeolite which has a ratio of SiO2/Al2O3 of 8 to 50 and does not contain a structure direction agent is used. The seed crystal is added to the reaction mixture, in a proportion of 0.1% by mass to 20% by mass based on a silica component in the reaction mixture. The reaction mixture to which the seed crystal has been added is heated at 100° C. to 200° C. in a sealed state.