Abstract: A combinatorial method for discovering or optimizing materials is disclosed. The method uses solution-based components that are mixed and dispensed into regions on a substrate for drying and/or heat-treating. The drying and/or heat-treating produces materials that can be tested for a desired property.

Abstract: An apparatus and method for injection of one or more chemical components into a reaction chamber are disclosed. The apparatus includes a reaction chamber for receiving one or more libraries in a fixed position relative to the chamber and configured to form a sealed enclosure. An injection manifold is located within the reaction chamber and selectively movable relative to the libraries. The injection manifold is configured for receiving at least one fluid transfer line coupled to an external source for injection of one or more chemical components into the reaction chamber.

Abstract: A combinatorial method for discovering or optimizing materials is disclosed. The method uses solution-based components that are mixed and dispensed into regions on a substrate for drying and/or heat-treating. The drying and/or heat-treating produces materials that can be tested for a desired property.

Abstract: A cryogenic vessel includes a first, outer vessel assembly having an outer vessel and a liquid fill line assembly and a second, ullage space vessel having a bottom and disposed within the first, outer vessel, adjacent to the top of the first, outer vessel. The liquid fill line assembly has a venturi assembly adjacent the bottom of the ullage space vessel. The venturi assembly is structured to create a low pressure zone, relative to the ullage space vessel, during a fill procedure whereby, during a fill procedure, fluid is drawn from within the ullage space vessel into the fill line assembly.

Abstract: The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a pyridyl amine or a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.

Abstract: The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.

Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.

Abstract: An economizer circuit assembly for a cryogenic liquid vessel assembly is disclosed. The cryogenic liquid vessel assembly includes a first, outer shell and a second, inner shell defining a storage space. The storage space has a liquid space and a vapor space. The cryogenic vessel also has a delivery line extending from outside the first, outer vessel shell into the liquid space. The economizer circuit assembly includes a vent line and an integration device. The vent line extends from outside the first, outer shell into the cryogenic vessel. The vent line has a first end and a second end. The first end is disposed in the vapor space. The vent line and the delivery line are coupled, and in fluid communication at, the integration device.

Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.

Abstract: A dual purpose recirculation valve system for a cryogenic vessel includes a fill line, a delivery line assembly, a recirculation line and a recirculation valve. The cryogenic vessel defines a storage space and includes a pressure monitoring device structured to monitor the pressure in the storage space, as well as an electronic control system structured to receive input from the pressure monitoring device. The fill line is structured to be coupled to a bulk tank, whereby the storage space is filled with a cryogenic fluid. The delivery line assembly has a delivery coupling assembly and the delivery line assembly structured to remove the cryogenic fluid from the storage space and deliver the cryogenic fluid to the delivery coupling assembly. The recirculation line extends between, and is in fluid communication with both, the fill line and the delivery line assembly.

Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.

Abstract: The invention relates to liquid chromatography techniques for rapidly characterizing samples, such as polymer solutions, emulsions and dispersions, and to devices for implementing such techniques. The system includes a design that provides the ability to perform chromatographic separations by using mobile phase composition gradients and temperature gradients during separations. The invention accomplishes this by providing mixing zones for a plurality of fluids as well as heated and chilled feeds feeding the fluids to the mixing zones. Additionally, the system provides the ability to analyze separated components with a detector and/or collect separated fractions into vessels of a fraction collector for further separation and/or analysis.

Abstract: A combinatorial method for discovering or optimizing materials is disclosed. The method uses solution-based components that are mixed and dispensed into regions on a substrate for drying and/or heat-treating. The drying and/or heat-treating produces materials that can be tested for a desired property.

Abstract: A method of fitting a drive belt (15) to a drive belt system and a pulley assembly for performing the method, the belt system including a drive pulley (11), and at least one driven pulley (12, 13) preferably including an idler pulley (14) with the belt run around said pulleys being substantially planar, wherein in said method one pulley (14) is part of a pivotable pulley assembly (21), the pivotable pulley is tilted relative to the plane of the belt run, the belt (15) is fitted around the pulleys (11, 12, 13, 14) and the tilted pulley assembly (21) is then moved to lie substantially in the plane of the belt run to tension the belt.

Abstract: A cryogenic vessel includes a first, outer vessel assembly having an outer vessel and a liquid fill line assembly and a second, ullage space vessel having a bottom and disposed within the first, outer vessel, adjacent to the top of the first, outer vessel. The liquid fill line assembly has a venturi assembly adjacent the bottom of the ullage space vessel. The venturi assembly is structured to create a low pressure zone, relative to the ullage space vessel, during a fill procedure whereby, during a fill procedure, fluid is drawn from within the ullage space vessel into the fill line assembly.

Abstract: A liquid natural gas filling system structured to store a cryogenic fluid at a low pressure and fill a use vessel at a high pressure. The filling system includes a first, low pressure vessel, at least one second, high pressure vessel, a plurality of conduits, each conduit in the plurality having a valve, extending between, and in fluid communication within the first, low pressure vessel and the at least one second, high pressure vessel, a pressure building means coupled to the at least one second, high pressure vessel and structured to raise the pressure of a cryogenic liquid within the at least one second, high pressure vessel, and an outlet nozzle structured to be coupled to a use vessel, the outlet nozzle coupled via the plurality of conduits to, and in fluid communication with, the first, low pressure vessel and the second, high pressure vessel. The filling system is structured so that a cryogenic liquid may be stored in the first, low pressure vessel at a low pressure.

Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridylamine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.

Abstract: An apparatus for in-situ injection of one or more chemical components into a reaction chamber is disclosed. The apparatus includes a reaction chamber for receiving one or more libraries, each of the libraries comprising two or more samples. The reaction chamber is configured to form a sealed enclosure. The apparatus further includes an injection manifold supporting injectors for in-situ injection of one or more chemical components onto respective samples of the one or more libraries in the pressurized sealed reaction chamber.

Abstract: An apparatus for in-situ injection of one or more chemical components into a reaction chamber, comprising a reaction chamber for receiving one or more libraries including two or more samples; an injection module in fluid communication with the reaction chamber for permitting in-situ injection of one or more chemical components into the reaction chamber; and a selectively movable transport assembly supported by at least a portion of the reaction chamber for transporting the one or more libraries to the injection module.

Abstract: New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.