Abstract: Hardmasks and fabrication methods are presented for producing ferroelectric capacitors in a semiconductor device, wherein a hardmask comprising aluminum oxide or strontium tantalum oxide is formed above an upper capacitor electrode material, and capacitor electrode and ferroelectric layers are etched to define a ferroelectric capacitor stack.

Abstract: The present invention forms sidewall diffusion barrier layer(s) that mitigate hydrogen contamination of ferroelectric capacitors. Sidewall diffusion barrier layer(s) of the present invention are formed via a physical vapor deposition process at a low temperature. By so doing, the sidewall diffusion barrier layer(s) are substantially amorphous and provide superior protection against hydrogen diffusion than conventional and/or crystalline sidewall diffusion barrier layers.

Abstract: An embodiment of the invention is a method of fabricating a haze free, phase pure, PZT layer, 3, where a lead rich PZT film, 102, is formed over a phase pure stoichiometric PZT film, 101.

Abstract: An embodiment of the invention is a method of fabricating a haze free, phase pure, PZT film, 3, where a vacuum, an inert gas, or a mixture of an inert and oxidizer gas is used in the preheat step, 208, prior to the deposition, 210, of the PZT film, 3.

Abstract: An embodiment of the invention is a method of fabricating a haze free, phase pure, PZT film, 3, where a vacuum, an inert gas, or a mixture of an inert and oxidizer gas is used in the preheat step, 208, prior to the deposition, 210, of the PZT film, 3.

Abstract: The present invention forms sidewall diffusion barrier layer(s) that mitigate hydrogen contamination of ferroelectric capacitors. Sidewall diffusion barrier layer(s) of the present invention are formed via a physical vapor deposition process at a low temperature. By so doing, the sidewall diffusion barrier layer(s) are substantially amorphous and provide superior protection against hydrogen diffusion than conventional and/or crystalline sidewall diffusion barrier layers.

Abstract: A method for forming a thin aluminum-nitride film (112). Solid hydrazine cyanurate is heated to produce in-situ hydrazine (N2H4). The in-situ hydrazine reacts with a previously deposited ailminum layer (108) to form aluminum-nitride (112).

Abstract: An IC includes one or more gaps (18) substantially filled with silicon dioxide (30). The silicon dioxide (30) is deposited into the gaps (18) in response to the reaction of hexamethyldisiloxane (HMDSO) (26) with ozone (28) during a plasma-enhanced CVD (PECVD) process. The IC may be fabricated by inserting a substrate into a chamber. HMDSO (26) and ozone (28) are introduced into the chamber. The HMDSO (26) reacts with the ozone (28) to produce silicon dioxide (30), which is then deposited on the surface (10) of the substrate.

Abstract: A surface treatment for porous silica to enhance adhesion of overlying layers. Treatments include surface group substitution, pore collapse, and gap filling layer (520) which invades open surface pores (514) of xerogel (510).

Abstract: An improved method is provided for integrating HSQ into integrated circuit structures and processes, especially those requiring multiple levels of interconnect lines. In a preferred embodiment, interconnect lines 14 are first patterned and etched on a substrate 10. A low-k material such as hydrogen silsesquioxane (HSQ) 18 is spun across the surface of the wafer to fill areas between interconnect lines. A capping layer such as SiO.sub.2 20 is applied to on top of the low-k material. The HSQ is then heated to cure. A thick SiO.sub.2 planarization layer 22 may then be applied and planarized. In other embodiments, the HSQ and SiO.sub.2 process steps can be repeated for multiple layers of HSQ.

Abstract: A intermetal level dielectrics with fluorinated (co)polymers of parylene (142) between metal lines (112-120), and vapor deposition method for the (co)polymerization followed by fluorination of the (co)polymers.

Abstract: After formation of a sandwich over a substrate of a layer of silicon dioxide (3) followed by a layer of silicon (1) having a pad oxide (7) thereon and a patterned silicon nitride layer (9) over the pad oxide, the unmasked portion of the pad oxide and silicon are removed to provide mesas of silicon with silicon nitride thereover and possibly removal of some of the buried oxide layer. A flowable insulator (15), preferably silsesquioxane (H.sub.x SiO.sub.1.5, where x.ltoreq.1, depending upon the level of polymerization) in a contaminant-free, high purity solvent which is later removed during an annealing step, is placed over the exposed surface such that it fills the voids between the mesas of silicon with silicon nitride thereon and extends over the nitride. The flowable insulator, due to its flowability, provides a generally planar surface. The flowable insulator is etched back and a cap oxide (17) is optionally deposited over the etched back insulator layer.

Abstract: An improved method and structure is provided for integrating HSQ and other low dielectric constant materials, which may have undesirable properties, into integrated circuit structures and processes, especially those requiring multiple levels of interconnect lines. The present invention combines the advantages of SiO.sub.2 and low dielectric constant materials by creating a multilayer dielectric stack of alternating layers of low-k materials and traditional dielectrics. A stabilizing layer is inserted between layers of low-k films. Since the thickness of problematic low-k materials remain less than the cracking threshold, many of the problems discussed above are alleviated. The stabilizing prevents the nucleation and propagation of micro cracks. In a preferred embodiment, interconnect lines 14 are first patterned and etched on a substrate 10. A low-k material such as hydrogen silsesquioxane (HSQ) 18 is spun across the surface of the wafer to fill areas between interconnect lines.

Abstract: A method is described for controlling a plurality of nonuniformity parameters in processing discrete products such as semiconductor wafers through a module consisting of several individual processes using site models. The method uses a controlled process to compensate for a subsequent uncontrolled process, which allows process goals of one process to be optimized to enhance the output of a subsequent process of the same module.

Abstract: A method for measurement of dielectric constant of a thin film is disclosed which is non-destructive and avoids contact with the film and the substrate carrying it. A first characteristic of the substrate is measured using a capacitance measuring device. Then, the thin film is deposited on the substrate. The first characteristic of the substrate is measured a second time after the film has been deposited. Thereafter, the true film thickness is measured. A ratio of the measurements made with the capacitance measuring device is then established with the actual thickness measurement. The dielectric constant can then be derived from a lookup table or graph calibrated for the tools being used for the measurements.