Abstract: A balloon made from a laminate film including at least one bio-based polyester layer of at least about 19.0 pMC of radiocarbon (14C) content is disclosed. The laminate film could further have additional layers such as a second bio-based polyester resin-containing layer of at least about 21.5 pMC of radiocarbon (14C) content, a linear low density polyethylene bio-based resin-containing layer of at least about 94 pMC of radiocarbon (14C) content, a metal layer, or combinations thereof.

Abstract: The present invention is directed to a multilayer film having, as its main component, a hydroxy acid polymer with improved gas barrier and optional heat sealability. The oriented film of predominately hydroxy acid polymer having controlled shrink can be produced by melting and coextruding a hydroxy acid polymer with a much thinner layer of an amorphous aromatic copolyester to form a multilayer film that is quench cooled, then biaxially stretched at a process temperature above the glass transition and below the cold crystallization temperature of the hydroxy acid polymer. A heat-setting treatment with a controlled relaxation of the film above the hydroxy acid polymer glass transition temperature and below its melt temperature may be used to control shrinkage. The films thus obtained are vacuum metallized on the aromatic copolyester surface to produce environmentally friendly packaging from predominately renewable resources having improved gas barrier properties.

Abstract: A laminate film including at least one bio-based polyester layer. The polyester layer has a radiocarbon (14C) content of at least 21.5 pMC. The laminate film may further have additional layers such as a second bio-based polyester resin-containing layer of at least about 21.5 pMC radiocarbon content, a metal layer, or combinations thereof.

Abstract: A monoaxially oriented film including an ethylene-propylene impact copolymer and 3-15 wt % of a metallocene-catalyzed propylene-butene elastomer and 30-60 wt % of a crystalline propylene homopolymer which is oriented at least 3 times in the machine direction and exhibits excellent linear directional tear properties in the machine direction for retort pouch applications and has excellent heat seal performance both pre- and post-retorting. This film formulation and orientation is suitable for pouch applications requiring an “easy-tear” linear tear feature and excellent hermetic seal properties, particularly for retort pouches.

Abstract: A biaxially oriented laminate film including a core layer including a blend of crystalline polylactic acid polymer and an inorganic antiblock particle which is biaxially oriented at low transverse direction orientation temperatures to impart a degree of cavitation around the particles such that a matte or opaque appearance is obtained. The laminate film may further have additional layers such as a heat sealable layer disposed on one side of the core layer including an amorphous polylactic acid resin and/or a polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.

Abstract: A laminate film including at least one bio-based polyolefin layer including at least 53 pMC of radiocarbon (14C) content is disclosed. The laminate film may include additional layers such as a second bio-based polyolefin resin-containing layer of at least 53 pMC radiocarbon content, and a metal layer.

Abstract: Described are metallized biaxially oriented polylactic acid (BOPLA) films with a novel formulation that exhibits a softer feel and quieter sound, without jeopardizing film making stability. It has been found that when these films are metallized, moisture barrier properties are surprisingly improved compared to conventional metallized BOPLA films. Specifically, the moisture barrier of the films may be 2.0 g/m2/day or less at 38° C. and 90% relative humidity. The films can be used, for example, in packaging applications. The films have characteristics that are beneficial to converting processes, are economical, and maintain bio-compostability similar to typical BOPLA films.

Abstract: Described are biaxially oriented polylactic acid (BOPLA) films with a novel formulation that exhibits a softer feel and quieter sound, without jeopardizing film making stability. The films can be used, for example, in packaging applications. The films can be metallized, or combined with barrier coatings or layers, for improved gas barrier properties particularly for moisture vapor transmission barrier desired in packaging applications. The films can also be printing films for packaging applications and may be transparent or matte in appearance. The films have characteristics that are beneficial to converting processes, are economical, and maintain bio-compostability similar to typical BOPLA films.

Abstract: The present invention relates to methods of manufacturing multi-layered polyolefin films that provide excellent adhesion to cold seal cohesive formulations. A surface of the film is discharge-treated. It has been found that when the discharge-treated surface has at least 0.3% nitrogen functional groups, it provides an excellent cold seal receptive surface. A biaxially oriented polypropylene film made according the invention may also have a second skin layer, opposite the first layer, which may be used for metallizing, laminating, or printing.

Abstract: A laminate film including a first polylactic acid layer; a second metal-receiving layer including PVOH, EVOH, or a blend thereof on a side of the first polylactic acid layer; and a metal layer deposited on a side of the metal-receiving layer opposite the polylactic acid layer. The metal-receiving layer may be coextruded with the polylactic acid first layer or may be a coating applied to one side of the polylactic acid first layer. This laminate film exhibits excellent gas and moisture barrier properties, appearance, and metal adhesion. It may also include a heat sealable or winding improving layer on the side opposite the metal receiving-layer of the first polylactic acid layer.

Abstract: A metallized laminate film exhibiting improved moisture barrier property as well as maintaining a high bio-polymer content and degradability property is disclosed. The laminate film includes a first core layer of polylactic acid polymer and a second skin layer comprising a polyolefin metal receiving layer. The metal receiving layer or the core layer, or both, may be blended with an amount of polar-modified tie-resin to improve bonding. Alternatively, a discrete tie-resin layer may be interposed between the polyolefin metal receiving layer and the crystalline polylactic acid polymer core layer. The polyolefin metal receiving layer may be discharge-treated on the side opposite the core layer and metallized.

Abstract: The present invention is directed to a multilayer film having, as its main component, a hydroxy acid polymer with improved gas barrier and optional heat sealability. The oriented film of predominately hydroxy acid polymer having controlled shrink can be produced by melting and coextruding a hydroxy acid polymer with a much thinner layer of an amorphous aromatic copolyester to form a multilayer film that is quench cooled, then biaxially stretched at a process temperature above the glass transition and below the cold crystallization temperature of the hydroxy acid polymer. A heat-setting treatment with a controlled relaxation of the film above the hydroxy acid polymer glass transition temperature and below its melt temperature may be used to control shrinkage. The films thus obtained are vacuum metallized on the aromatic copolyester surface to produce environmentally friendly packaging from predominately renewable resources having improved gas barrier properties.

Abstract: A biaxially oriented multilayer film comprising a skin layer of polyhydroxyalkanoate, a core layer of polylactic acid polymer and a sealant layer with a metal deposited upon one surface of the skin layer of polyhydroxyalkanoate polymer. This metallized, polyhydroxyalkanoate-coextruded polylactic acid film exhibits improved moisture barrier property versus a metallized, non-polyhydroxyalkanoate-coextruded polylactic acid film.

Abstract: Multi-layer biaxially oriented polylactic acid (BOPLA) film with a novel formulation improves the heat seal initiation temperature and heat seal performance of BOPLA films while maintaining good optical clarity. The film may include a core layer including polylactic acid base polymer resin, and a heat sealable layer including amorphous polylactic acid base polymer and a modifier comprising polycaprolactone or poly(butylene-adipate-co-butylene terephthalate).

Abstract: Metallized multi-layer biaxially oriented polylactic acid base polymer (BOPLA) films that exhibits improved barrier properties and metal adhesion. The films include a core layer including crystalline polylactic acid base polymer, a first skin layer consisting essentially of amorphous polylactic acid base polymer, and a metal layer on the first skin layer. The films may include a second skin layer consisting essentially of amorphous polylactic acid base polymer.

Abstract: A method for manufacturing a surface-treated laminated film is provided. The produced film should include at least a surface treated polyolefin-containing resin layer with a flame or corona treated surface and a heat sealable resin layer having a storage shear modulus of 400,000 Pa or less at 100 rad/s at 121° C., 100,000 Pa or less at 10 rad/s at 121° C., and 5000 Pa or less at 1 rad/s at 121° C. The method may involve coextruding a laminated film that includes at least a polyolefin-containing resin layer and a heat sealable resin layer. The laminated film may be simultaneously stretched in machine and traverse direction, and subsequently surface treated to produce a surface-treated laminated film.

Abstract: A multilayer film including a first layer including a polylactic acid polymer, a second layer of a metal primer, deposited upon one surface of the first polylactic acid polymer layer, and a third metal layer deposited on the second metal primer layer. This metal-primed and metallized polylactic acid film exhibits improved moisture barrier properties versus a non-metal-primed and metallized polylactic acid film and can be used as part of a lamination structure for food packaging applications.

Abstract: A biaxially oriented laminate film including a core layer including a blend of crystalline polylactic acid polymer and an inorganic antiblock particle which is biaxially oriented at low transverse direction orientation temperatures to impart a degree of cavitation around the particles such that a matte or opaque appearance is obtained. The laminate film may further have additional layers such as a heat sealable layer disposed on one side of the core layer including an amorphous polylactic acid resin and/or a polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.

Abstract: A metallized laminate film exhibiting improved moisture barrier property as well as maintaining a high bio-polymer content and degradability property is disclosed. The laminate film includes a first core layer of polylactic acid polymer and a second skin layer comprising a polyolefin metal receiving layer. The metal receiving layer or the core layer, or both, may be blended with an amount of polar-modified tie-resin to improve bonding. Alternatively, a discrete tie-resin layer may be interposed between the polyolefin metal receiving layer and the crystalline polylactic acid polymer core layer. The polyolefin metal receiving layer may be discharge-treated on the side opposite the core layer and metallized.

Abstract: The present invention relates to methods of manufacturing multi-layered polyolefin films that provide excellent adhesion to cold seal cohesive formulations. A surface of the film is discharge-treated. It has been found that when the discharge-treated surface has at least 0.3% nitrogen functional groups, it provides an excellent cold seal receptive surface. A biaxially oriented polypropylene film made according the invention may also have a second skin layer, opposite the first layer, which may be used for metallizing, laminating, or printing.