Abstract: A lithium ion capacitor, including: an anode including: a conductive support; a first mixture coated on the conductive support including: an interclating_carbon; a conductive carbon black; and a PVDF binder in amounts as defined herein, and where the PVDF binder has a weight average molecular weight of from 300,000 to 400,000; and a second mixture coated on the first mixture, the second mixture comprising micron-sized lithium metal particles having an encapsulating shell comprised of LiPF6, mineral oil, and a thermoplastic binder. Also disclosed is a method of making and using the lithium ion capacitor.

Abstract: An anode in a lithium ion capacitor, including: a carbon composition comprising: a coconut shell sourced carbon in from 85 to 95 wt %; a conductive carbon in from 1 to 10 wt %; and a binder in from 3 to 8 wt %; and an electrically conductive substrate, wherein the coconut shell sourced carbon has a disorder (D) peak to graphitic (G) peak intensity ratio by Raman analysis of from 1.40 to 1.85; and by elemental analysis a hydrogen content of from 0.01 to 0.25 wt %; a nitrogen content of from 0.01 to 0.55 wt %; and an oxygen content of from 0.01 to 2 wt %. Also disclosed are methods of making and using the carbon composition.

Abstract: An electrode in an energy storage device, including: an activated carbon, including: a surface area of from 1000 to 1700 m2/g; a pore volume from 0.3 to 0.6 cc/g; a chemically bonded oxygen content of 0.01 to 1.5 wt %; and a pH of from 7.5 to 10. Also disclosed is a method of making the activated carbon, the electrode, and the energy storage device.

Abstract: An energy storage device such as an electric double layer capacitor has positive and negative electrodes, each including a blend of respective first and second activated carbon materials having distinct pore size distributions. The blend (mixture) of first and second activated carbon materials may be equal in each electrode.

Abstract: An anode in a lithium ion capacitor, including: a carbon composition comprising: a coconut shell sourced carbon in from 85 to 95 wt %; a conductive carbon in from 1 to 10 wt %; and a binder in from 3 to 8 wt %; and an electrically conductive substrate, wherein the coconut shell sourced carbon has a disorder (D) peak to graphitic (G) peak intensity ratio by Raman analysis of from 1.40 to 1.85; and by elemental analysis a hydrogen content of from 0.01 to 0.25 wt %; a nitrogen content of from 0.01 to 0.55 wt %; and an oxygen content of from 0.01 to 2 wt %. Also disclosed are methods of making and using the carbon composition.

Abstract: A lithium ion capacitor, including: an anode including: a conductive support; a first mixture coated on the conductive support including: a carbon sourced from coconut shell flour; a conductive carbon black; and a PVDF binder in amounts as defined herein, and where the PVDF binder has a weight average molecular weight of from 300,000 to 400,000; and a second mixture coated on the first mixture, the second mixture comprising micron-sized lithium metal particles having an encapsulating shell comprised of LiPF6, mineral oil, and a thermoplastic binder. Also disclosed is a method of making and using the lithium ion capacitor.

Abstract: A positive electrode for an energy storage device includes a first activated carbon material comprising pores having a size of ?1 nm, which provide a combined pore volume of >0.3 cm3/g, pores having a size of >1 nm to ?2 nm, which provide a combined pore volume of ?0.05 cm3/g, and <0.15 cm3/g combined pore volume of any pores having a size of >2 nm. A negative electrode for the energy storage device includes a second activated carbon material comprising pores having a size of ?1 nm, which provide a combined pore volume of ?0.3 cm3/g, pores having a size of >1 nm to ?2 nm, which provide a combined pore volume of ?0.05 cm3/g, and <0.15 cm3/g combined pore volume of any pores having a size of >2 nm. The total oxygen content in at least the first activated carbon material is at most 1.5 wt. %.

Abstract: An energy storage device such as an electric double layer capacitor has positive and negative electrodes, each including a blend of respective first and second activated carbon materials having distinct pore size distributions. The blend (mixture) of first and second activated carbon materials may be equal in each electrode.

Abstract: A carbon-based electrode includes activated carbon, carbon black, and a binder. The binder is fluoropolymer having a molecular weight of at least 500,000 and a fluorine content of 40 to 70 wt. %. A method of forming the carbon-based electrode includes providing a binder-less conductive carbon-coated current collector, pre-treating the carbon coating with a sodium napthalenide-based solution, and depositing onto the treated carbon coating a slurry containing activated carbon, carbon black and binder.

Abstract: A carbon-based electrode includes activated carbon, carbon black, and a binder. The binder is fluoropolymer having a molecular weight of at least 500,000 and a fluorine content of 40 to 70 wt. %. A method of forming the carbon-based electrode includes providing a binder-less conductive carbon-coated current collector, pre-treating the carbon coating with a sodium napthalenide-based solution, and depositing onto the treated carbon coating a slurry containing activated carbon, carbon black and binder.

Abstract: A method for pre-doping a lithium ion capacitor, including: compressing a lithium ion capacitor of the formula: C/S/A/S/C/S/A/S/C, where: /A/ is an anode coated on both sides with an anode carbon layer, and each anode carbon layer is further coated with lithium composite powder (LCP) layer; C/ is a cathode coated on one side with a layer of an cathode carbon mixture; and S is a separator; and a non-aqueous electrolyte; and conditioning the resulting compressed lithium ion capacitor, for example, at a rate of from C/20 to 4C, and the conditioning redistributes the impregnated lithium as lithium ions in the anode carbon structure. Also disclosed is an carbon coated anode having lithium composite powder (LCP) layer compressed on the carbon coated anode.

Abstract: A method of making activated carbon including: compressing a mixture of an alkali metal hydroxide, a carbon source, and a solid thermosetting polymer precursor into a pellet; and a first heating of the compressed mixture, as defined herein; and optionally crushing, washing, or both, the resulting first heated mixture, as defined herein; and optionally a second heating, as defined herein.

Abstract: A method of making activated carbon including: drying a carbon source having a volatile organic compound (VOC) content of 10 to 30 wt %, as defined herein; and milling the resulting dried carbon source to a powder. The method can further include a first heating of the resulting milled powder at from 200 to 450° C., for from 10 mins to 24 hrs. The method can further include making a mixture of the resulting first heated milled powder and an alkali metal hydroxide, and accomplishing a second heating of the milled powder and alkali metal hydroxide mixture, as defined herein.

Abstract: An anode in a lithium ion capacitor, including: a carbon composition comprising: a coconut shell sourced carbon in from 85 to 95 wt %; a conductive carbon in from 1 to 10 wt %; and a binder in from 3 to 8 wt %; and an electrically conductive substrate, wherein the coconut shell sourced carbon has a disorder (D) peak to graphitic (G) peak intensity ratio by Raman analysis of from 1.40 to 1.85; and by elemental analysis a hydrogen content of from 0.01 to 0.25 wt %; a nitrogen content of from 0.01 to 0.55 wt %; and an oxygen content of from 0.01 to 2 wt %. Also disclosed are methods of making and using the carbon composition.

Abstract: A lithium ion capacitor, including: an anode including: a conductive support; a first mixture coated on the conductive support including: a carbon sourced from coconut shell flour; a conductive carbon black; and a PVDF binder in amounts as defined herein, and where the PVDF binder has a weight average molecular weight of from 300,000 to 400,000; and a second mixture coated on the first mixture, the second mixture comprising micron-sized lithium metal particles having an encapsulating shell comprised of LiPF6, mineral oil, and a thermoplastic binder. Also disclosed is a method of making and using the lithium ion capacitor.

Abstract: Carbon-based electrodes such as for incorporation into ultracapacitors or other high power density energy storage devices, include activated carbon, carbon black, binder and at least one molecular sieve material. The molecular sieve component can adsorb and trap water, which can facilitate the use of the device at higher voltage, such as greater than 3V. The molecular sieve material may be incorporated into the carbon-based electrodes or formed as a layer over a carbon-based electrode surface.

Abstract: An electric double layer capacitor comprises first and second electrodes, each comprising respective first and second carbon materials having distinct pore size distributions. A pore volume ratio of the first carbon material is greater than a pore volume ratio of the second carbon material. The pore volume ratio R is defined as R=V1/V, where V1 is a total volume of pores having a pore size of less than 1 nm, and V is a total volume of pores having a pore size greater than 1 nm.

Abstract: An anode in a lithium ion capacitor, including: a carbon composition comprising: a coke sourced carbon, a conductive carbon, and a binder as defined herein; and an electrically conductive substrate supporting the carbon composition, wherein the coke sourced carbon has a disorder by Raman analysis as defined herein; and a hydrogen content; a nitrogen content; an and oxygen content as defined herein. Also disclosed is a method of making the anode, a method of making the lithium ion capacitor, and methods of use thereof.

Abstract: An anode in a lithium ion capacitor, including: a carbon composition comprising: a phenolic resin sourced carbon, a conductive carbon, and a binder as defined herein; and an electrically conductive substrate supporting the carbon composition, wherein the phenolic resin sourced carbon has a disorder by Raman analysis as defined herein; and a hydrogen content; a nitrogen content; an and oxygen content as defined herein. Also disclosed is a method of making the anode, a method of making the lithium ion capacitor, and methods of use thereof.

Abstract: An anode in a lithium ion capacitor, including: a carbon composition comprising: a coconut shell sourced carbon in from 85 to 95 wt %; a conductive carbon in from 1 to 10 wt %; and a binder in from 3 to 8 wt %; and an electrically conductive substrate, wherein the coconut shell sourced carbon has a disorder (D) peak to graphitic (G) peak intensity ratio by Raman analysis of from 1.40 to 1.85; and by elemental analysis a hydrogen content of from 0.01 to 0.25 wt %; a nitrogen content of from 0.01 to 0.55 wt %; and an oxygen content of from 0.01 to 2 wt %. Also disclosed are methods of making and using the carbon composition.