Patents by Inventor Kiyotsuna Toyohara

Kiyotsuna Toyohara has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20100227963
    Abstract: There are provided a resin composition comprising a polylactic acid which (i) comprises a poly-L-lactic acid (component B-1) and a poly-D-lactic acid (component B-4), (ii) has a weight ratio of the component B-1 to the component B-4 (component B-1/component B-4) of 10/90 to 90/10, and (iii) shows a proportion of melt peaks at 195° C. or higher to all melt peaks in a temperature rising process in measurement by a differential scanning calorimeter (DSC) of at least 20%; a molded article of the resin composition; and methods for producing the resin composition and the molded article.
    Type: Application
    Filed: January 17, 2007
    Publication date: September 9, 2010
    Applicants: TEIJIN CHEMICALS LTD., TEIJIN LIMITED
    Inventors: Katsuhiko Hironaka, Fumitaka Kondo, Keiichiro Ino, Yuichi Matsuno, Kiyotsuna Toyohara, Hirotaka Suzuki
  • Publication number: 20100222486
    Abstract: The object of this invention is to provide a resin composition that contains a polymer obtained from biomass resources and constitutes molded articles excellent in heat resistance, mechanical properties and durable stability, this invention including a resin composition comprising (i) a resin component containing 95 to 5% by weight of an aromatic polycarbonate (component A) and 5 to 95% by weight of polylactic acid (component B), (ii) 0.001 to 10 parts by weight, per 100 parts by weight of the resin component, of a phosphoric ester metal salt (component C), and (iii) 0.01 to 5 parts by weight, per 100 parts by weight of the polylactic acid (component B), of a terminal blocker (component F), the stereo-complex crystal content (X) of the following expression (I) being 80% or more, X (%)={?Hb/(?Ha+?Hb)}×100??(I) wherein ?Ha and ?Hb are a melting enthalpy (?Ha) of a crystal melting point that appears at lower than 190° C. and a melting enthalpy (?Hb) of a crystal melting point that appears at 190° C.
    Type: Application
    Filed: October 15, 2008
    Publication date: September 2, 2010
    Inventors: Yuichi Matsuno, Fumitaka Kondo, Kiyotsuna Toyohara
  • Publication number: 20100160597
    Abstract: A manufacturing apparatus of polylactic acid having at least an inlet and an outlet of a substance to be reacted and an exhaust port provided in a horizontal reaction vessel not having continuous rotating shafts in a direction of center line of a rotating shaft of a stirring blade provided in the reaction vessel and a manufacture method. By removing low molecular weight substance in the polylactic acid, high-quality polylactic acid can be stably manufactured.
    Type: Application
    Filed: January 15, 2007
    Publication date: June 24, 2010
    Applicant: TEIJIN LIMITED
    Inventors: Hideshi Kurihara, Takeshi Katsuda, Kiyotsuna Toyohara, Ryuji Nonokawa, Hirotaka Suzuki, Kenji Ohashi
  • Publication number: 20100130699
    Abstract: A polylactic acid composition (A) comprising a polylactic acid component (B) comprising at least 90 mol % of an L-lactic acid unit and less than 10% of copolymerizing component units other than L-lactic acid, and a polylactic acid component (C) comprising at least 90 mol % of a D-lactic acid unit and less than 10 mol % of copolymerizing component units other than D-lactic acid, which is a mixed composition with a (B)/(C) weight ratio of between 10/90 and 90/10.
    Type: Application
    Filed: March 27, 2008
    Publication date: May 27, 2010
    Inventors: Midori Ikegame, Kiyotsuna Toyohara, Hideshi Kurihara
  • Publication number: 20100120991
    Abstract: It is an object of the present invention to provide a composition comprising polylactic acid and having improved injection moldability and an injection molded product thereof. The object of the present invention is attained by a specific polylactic acid composition which meets the following requirements (a) to (g) at the same time: (a) it must have a weight average molecular weight of 70,000 to 700,000; (b) the total content of Sn atom, Ti atom, Al atom and Ca atom must be 3 to 20 ppm; (c) it must contain a P atom in an amount of 3 to 3,000 ppm; (d) the (total number of gram-atoms of Sn, Ti, Al and Ca)/(number of gram-atoms of P) value must be 0.01 to 5; (e) the content of a compound having a molecular weight of 150 or less must be not more than 0.2 wt %; (f) the COOH terminal group concentration must be not more than 30 equivalents/ton; and (g) the melt viscosity (P) at a melting temperature of 230° C. must satisfy the following expression (1): 10 Pa·s<P<100 Pa·s??(1).
    Type: Application
    Filed: March 31, 2008
    Publication date: May 13, 2010
    Applicants: TEIJIN LIMITED, MUSASHINO CHEMICAL LABORATORY ,
    Inventors: Kiyotsuna Toyohara, Ryuji Nonokawa, Kohei Endo, Shin To
  • Publication number: 20100093889
    Abstract: An object of the present invention is to provide a composition containing polylactic acid and having improved blow moldability and a blow molded product thereof. The polylactic acid composition meets the following requirements (a) to (g) at the same time: (a) the weight average molecular weight must be 70,000 to 700,000; (b) the total content (metal content) of Sn atom, Ti atom, Al atom and Ca atom must be 3 to 20 ppm; (c) the content of P atom must be 3 to 3,000 ppm; (d) the (total number of gram-atoms of Sn, Ti, Al and Ca)/(number of gram-atoms of P) value must be 0.01 to 5; (e) the content of a compound having a molecular weight of 150 or less must be not more than 0.2 wt %; (f) the COOH terminal group concentration must be not more than 30 equivalents/ton; and (g) the following expressions (1) and (2) must be satisfied: 10 Pa·s<P<100 Pa·s??(1) 10 MPa<S??(2) (P is a melt viscosity at 230° C. and S is a stress at 150° C.).
    Type: Application
    Filed: March 31, 2008
    Publication date: April 15, 2010
    Applicants: Teijin Limited, Musashino Chemical Laboratory, Ltd.
    Inventors: Kiyotsuna Toyohara, Ryuji Nonokawa, Kohei Endo, Midori Ikegame, Shin To
  • Publication number: 20100056751
    Abstract: It is an object of the present invention to produce a polylactic acid having a high molecular weight such as a weight average molecular weight (Mw) of more than 100,000 from which only a stereocomplex crystal is grown even by repeating melting and crystallization. The present invention is a process of producing a polylactic acid, including the steps of: (i) obtaining a solid by kneading together poly(L-lactic acid) and poly(D-lactic acid) at a temperature of 160 to 225° C. and crystallizing the kneaded product; and (ii) melt kneading the obtained solid.
    Type: Application
    Filed: February 6, 2008
    Publication date: March 4, 2010
    Inventors: Kiyotsuna Toyohara, Midori Ikegame, Hideki Yamane, Yoshiharu Kimura, Daisuke Masaki, Shin To
  • Publication number: 20090234094
    Abstract: A composition which comprises polylactide and has excellent heat stability, color and hydrolytic resistance. The composition comprises (i) polylactide, (ii) a metal catalyst and (iii) a hypophosphorous acid-based deactivator or a metaphosphoric acid-based deactivator.
    Type: Application
    Filed: October 4, 2006
    Publication date: September 17, 2009
    Inventors: Hirotaka Suzuki, Kiyotsuna Toyohara, Shin To
  • Publication number: 20090062437
    Abstract: It is an object of the present invention to provide a composition which contains polylactic acid and has excellent heat stability, mechanical strength and color. The composition contains 0.001 to 0.1 part by weight of a metal catalyst and 0.001 to 0.5 part by weight of a phosphono-fatty acid ester based on 100 parts by weight of polylactic acid.
    Type: Application
    Filed: March 28, 2007
    Publication date: March 5, 2009
    Applicant: TEIJIN LIMITED
    Inventors: Hirotaka Suzuki, Kiyotsuna Toyohara, Yuka Komazawa
  • Patent number: 7365148
    Abstract: A polycarbonate containing an ether diol residue producible from a polysaccharide and expressed by the following formula (1), and a diol residue expressed by the following formula (2) —O—(CmH2m)—O— ??(2) (here, m is an integer of 2 to 12), wherein said ether diol residue amounts to 65-98 wt. % of all the diol residues, and having a glass transition temperature of 90° C. or higher.
    Type: Grant
    Filed: June 14, 2004
    Date of Patent: April 29, 2008
    Assignee: Teijin Limited
    Inventors: Aya Ono, Kiyotsuna Toyohara, Hiroyoshi Minematsu, Yuuichi Kageyama
  • Publication number: 20080039579
    Abstract: It is an object of the present invention to provide polylactic acid containing a stereocomplex crystal and having excellent moldability, a high molecular weight, high crystallinity and a high melting point and a process for manufacturing the same. It is another object of the present invention to provide a composition comprising the polylactic acid and a molded product of the polylactic acid. The present invention is characterized from polylactic acid having a weight average molecular weight of 80,000 to 500,000 and a melting peak at 195° C. or higher which accounts for 80% or more of the total of melting peaks in the temperature elevation step when measured by a differential scanning calorimeter (DSC) and a process for manufacturing the same.
    Type: Application
    Filed: July 20, 2005
    Publication date: February 14, 2008
    Applicants: Teijin Limited, Musashino Chemical Laboratory, Ltd., Mutual Corporation, Yoshiharu Kimura
    Inventors: Yoshiharu Kimura, Zhen Tang, Kazuki Fukushima, Kiyotsuna Toyohara, Ryuji Nonokawa, Yasuhito Maeda, Masayuki Takada, Yuka Komazawa, Tsuyoshi Aoki
  • Patent number: 7326556
    Abstract: A microorganism which belongs to the genus Rhizobium and has the ability of degrading an aromatic polyester, and a method of degrading an aromatic polyester by using the microorganism. According to this method, the aromatic polyester can be degraded safely and relatively swiftly at a low cost.
    Type: Grant
    Filed: August 19, 2004
    Date of Patent: February 5, 2008
    Assignee: Teijin Limited
    Inventors: Kohei Oda, Yoshiharu Kimura, Kazumi Hiraga, Yasuhito Maeda, Kiyotsuna Toyohara, Hiroyoshi Minematsu
  • Publication number: 20070172651
    Abstract: A fiber structure is obtained by spinning of a solution of an L-lactic acid condensate and a D-lactic acid condensate by electrospinning. It is possible to provide a fiber structure comprising fibers with extremely small fiber diameters, as well as excellent heat resistance and biodegradability.
    Type: Application
    Filed: March 3, 2005
    Publication date: July 26, 2007
    Inventors: Takanori Miyoshi, Kiyotsuna Toyohara, Hiroyoshi Minematsu
  • Publication number: 20060228792
    Abstract: A microorganism which belongs to the genus Rhizobium and has the ability of degrading an aromatic polyester, and a method of degrading an aromatic polyester by using the microorganism. According to this method, the aromatic polyester can be degraded safely and relatively swiftly at a low cost.
    Type: Application
    Filed: August 19, 2004
    Publication date: October 12, 2006
    Inventors: Kohei Oda, Yoshiharu Kimura, Kazumi Hiraga, Yasuhito Maeda, Kiyotsuna Toyohara, Hiroyoshi Minematsu
  • Publication number: 20060149024
    Abstract: A polycarbonate containing an ether diol residue producible from a polysaccharide and expressed by the following formula (1), and a diol residue expressed by the following formula (2) —O—(CmH2m)—O—??(2) (here, m is an integer of 2 to 12), wherein said ether diol residue amounts to 65-98 wt. % of all the diol residues, and having a glass transition temperature of 90° C. or higher.
    Type: Application
    Filed: June 14, 2004
    Publication date: July 6, 2006
    Inventors: Aya Ono, Kiyotsuna Toyohara, Hiroyoshi Minematsu, Yuuichi Kageyama
  • Patent number: 6646060
    Abstract: A resin composition containing a mixture produced by blending a crystalline polyamide expressed e.g. by formula (1) (in the formula, R1 is a bivalent organic aromatic group or aliphatic group having a carbon number of 2 to 30, optionally having substituent and optionally containing non-reactive groups such as ether group and aromatic group in the main chain, and Ar1 is an aromatic residue having a carbon number of 6 to 45 and optionally having substituent) with a thermoplastic polyester. The resin composition has excellent mechanical characteristics such as high elastic modulus, flow properties and heat-resistance and is suitable as a material for an electronic part for surface mounting.
    Type: Grant
    Filed: January 10, 2001
    Date of Patent: November 11, 2003
    Assignee: Teijin Limited
    Inventors: Kiyotsuna Toyohara, Toyoaki Ishiwata, Daisuke Ozaki, Jiro Sadanobu
  • Patent number: 6569366
    Abstract: A meta-type wholly aromatic polyamide containing, as principal repeating units, meta-phenylenediamineisophthalamide units is dissolved in an amide compound solvent; the resultant polymer solution is subjected to a wet-spinning procedure wherein the polymer solution is extruded in the form of filamentary streams into a coagulation bath containing an amide compound-containing solvent and water but substantially not containing salts, through spinning orifices of a spinneret, to coagulate the extruded filamentary polymer solution streams in the coagulation bath; the coagulated porous undrawn filaments are subjected to a drawing procedure wherein the porous undrawn filaments are drawn in a plasticizing drawing bath containing an aqueous solution of an amide compound solvent; the resultant drawn filaments are washed with water, and then heat-treated (for example, further drawn at a draw ratio of 0.7 to 4.0 while being heated at a temperature of 250 to 400° C.
    Type: Grant
    Filed: October 15, 2001
    Date of Patent: May 27, 2003
    Assignee: Teijin Limited
    Inventors: Kiyotsuna Toyohara, Jiro Sadanobu, Tsutomu Nakamura