Patents by Inventor Klein A. Rodrigues
Klein A. Rodrigues has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20130137799Abstract: Anionic graft copolymers and scale inhibition compositions including the anionic graft copolymers in which the anionic graft copolymers include a natural component grafted with an ethylenically unsaturated anionic monomer where the anionic graft copolymer includes 1 or more reacted anhydroglucose units per every 100 anhydroglucose units in the anionic graft copolymer.Type: ApplicationFiled: July 30, 2010Publication date: May 30, 2013Applicant: AKZO NOBEL N.V.Inventors: Klein A. Rodrigues, Matthew M. Vanderhoof, John Ozbek
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Patent number: 8192838Abstract: The invention relates to polymers whose water solubility may be triggered by changes in pH, salt concentration, concentration of surfactant or a combination of both. The polymer is a copolymer or terpolymer containing from 2 to 60 mole percent of an amine functionality that has been neutralized with a fixed acid. Specifically films formed from these polymers will be insoluble at a higher pH, but will become soluble at a lower pH. The polymers are also insoluble at a higher salt concentration, but become soluble at a lower salt concentration. The polymers can be used to coat or encapsulate active ingredients, that are released based on changes in the environment, such as in the rinse cycle of a dishwasher or laundry washing machine.Type: GrantFiled: August 18, 2010Date of Patent: June 5, 2012Assignee: Akzo Nobel N.V.Inventors: Susanne H. Goodson, Klein A. Rodrigues
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Patent number: 8148312Abstract: The invention provides an aqueous bleaching solution for substrate treatment comprising a source of oxidant and a suspended polymer matrix having a plurality of optically functional particles associated with one or more copolymers present in the polymer matrix. The plurality of optically functional particles are associated with the copolymer during polymerization of at least one hydrophobic and at least one hydrophilic monomer so as to form a polymer matrix useful to impart an aqueous bleaching solution with optically functional properties providing a benefit to the solutions during storage, use and application to substrates for treatment.Type: GrantFiled: September 20, 2011Date of Patent: April 3, 2012Assignee: The Clorox CompanyInventors: Thomas W. Kaaret, Darin K. Griffith, Klein A. Rodrigues, William L. Smith
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Patent number: 8106118Abstract: A glass adhesion composition containing a copolymer having an acid and a substituted amide, silanol, or amine oxide functionality. The substituted amide, silanol, or amine oxide functionality provide excellent adhesion of the copolymer to glass, silica, sand and other silicon-based substances. The copolymer is useful as a fiberglass binder, and also useful in providing protective coatings on glass sheets. A fiberglass sizing composition is also provided having a copolymer that includes at least one acid group derived from at least one acid monomer, a hydrophobic comonomer, and a crosslinker.Type: GrantFiled: September 21, 2010Date of Patent: January 31, 2012Assignee: Akzo Nobel N.V.Inventors: Klein A. Rodrigues, James C. Long
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Publication number: 20120009279Abstract: The invention provides an aqueous bleaching solution for substrate treatment comprising a source of oxidant and a suspended polymer matrix having a plurality of optically functional particles associated with one or more copolymers present in the polymer matrix. The plurality of optically functional particles are associated with the copolymer during polymerization of at least one hydrophobic and at least one hydrophilic monomer so as to form a polymer matrix useful to impart an aqueous bleaching solution with optically functional properties providing a benefit to the solutions during storage, use and application to substrates for treatment.Type: ApplicationFiled: September 20, 2011Publication date: January 12, 2012Inventors: Thomas W. Kaaret, Darin K. Griffith, Klein A. Rodrigues, William L. Smith
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Patent number: 8062758Abstract: A self-stabilizing dispersion composition having a copolymer having at least one polymerizable acid-containing moiety, wherein the at least one acid-containing moiety is at least partially neutralized before or during polymerization, and at least one hydrophobic moiety. A process for producing such compositions is also provided, as well as a process for encapsulating water-insoluble actives in such copolymers.Type: GrantFiled: December 20, 2010Date of Patent: November 22, 2011Assignee: Akzo Nobel N.V.Inventors: Klein A Rodrigues, Darin K. Griffith
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Patent number: 8048837Abstract: The invention provides an aqueous bleaching solution for substrate treatment comprising a source of oxidant and a suspended polymer matrix having a plurality of optically functional particles associated with one or more copolymers present in the polymer matrix. The plurality of optically functional particles are associated with the copolymer during polymerization of at least one hydrophobic and at least one hydrophilic monomer so as to form a polymer matrix useful to impart an aqueous bleaching solution with optically functional properties providing a benefit to the solutions during storage, use and application to substrates for treatment.Type: GrantFiled: January 14, 2008Date of Patent: November 1, 2011Assignee: The Clorox CompanyInventors: Thomas W. Kaaret, Darin K. Griffith, Klein A. Rodrigues, William L. Smith
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Publication number: 20110196054Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, an infrared attenuating agent, and a polystyrene/polyethylene oxide copolymer are provided. In exemplary embodiments, the blowing agent contains an HFC. The maleic anhydride-styrene copolymer grafted with polyethylene oxide increases the cell size of the polymer foam and offsets or even negates the decreased cell size caused by an HFC blowing agent and/or infrared attenuating agents. In addition, the copolymer of maleic anhydride-styrene grafted with polyethylene oxide has a positive affect on the processability of the blowing agent(s) in the composition by both widening the process window and enhancing the solubility of the blowing agent in the polymer melt. Thus, the polystyrene/polyethylene oxide copolymer present in the inventive composition acts as a cell enlarger, a plasticizer, and a processing aid. A method of forming an extruded foam product is also provided.Type: ApplicationFiled: January 29, 2010Publication date: August 11, 2011Inventors: Yadollah Delaviz, Raymond M. Breindel, Klein Rodrigues, Bharat Patel
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Patent number: 7964686Abstract: Aqueous treatment composition for use as anti-scalant and dispersant. The composition includes a polymer containing low amounts of sulfonate that prove as effective in carbonate and phosphate inhibition as polymers containing much higher amounts of sulfonate.Type: GrantFiled: April 13, 2007Date of Patent: June 21, 2011Assignee: Akzo Nobel N.V.Inventors: Klein A. Rodrigues, Adrian Zuberbuehler, Stuart Holt, Kevin Beairsto
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Publication number: 20110085995Abstract: A self-stabilizing dispersion composition having a copolymer having at least one polymerizable acid-containing moiety, wherein the at least one acid-containing moiety is at least partially neutralized before or during polymerization, and at least one hydrophobic moiety. A process for producing such compositions is also provided, as well as a process for encapsulating water-insoluble actives in such copolymers.Type: ApplicationFiled: December 20, 2010Publication date: April 14, 2011Applicant: AKZO NOBEL N.V.Inventors: Klein A. Rodrigues, Darin K. Griffith
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Patent number: 7875359Abstract: A self-stabilizing dispersion composition having a copolymer having at least one polymerizable acid-containing moiety, wherein the at least one acid-containing moiety is at least partially neutralized before or during polymerization, and at least one hydrophobic moiety. A process for producing such compositions is also provided, as well as a process for encapsulating water-insoluble actives in such copolymers.Type: GrantFiled: January 13, 2005Date of Patent: January 25, 2011Assignee: Akzo Nobel N.V.Inventors: Klein A. Rodrigues, Darin K. Griffith
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Publication number: 20110009543Abstract: A glass adhesion composition containing a copolymer having an acid and a substituted amide, silanol, or amine oxide functionality. The substituted amide, silanol, or amine oxide functionality provide excellent adhesion of the copolymer to glass, silica, sand and other silicon-based substances. The copolymer is useful as a fiberglass binder, and also useful in providing protective coatings on glass sheets. A fiberglass sizing composition is also provided having a copolymer that includes at least one acid group derived from at least one acid monomer, a hydrophobic comonomer, and a crosslinker.Type: ApplicationFiled: September 21, 2010Publication date: January 13, 2011Applicant: Akzo Nobel N.V.Inventors: Klein A. Rodrigues, James C. Long
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Publication number: 20100311632Abstract: The invention relates to polymers whose water solubility may be triggered by changes in pH, salt concentration, concentration of surfactant or a combination of both. The polymer is a copolymer or terpolymer containing from 2 to 60 mole percent of an amine functionality that has been neutralized with a fixed acid. Specifically films formed from these polymers will be insoluble at a higher pH, but will become soluble at a lower pH. The polymers are also insoluble at a higher salt concentration, but become soluble at a lower salt concentration. The polymers can be used to coat or encapsulate active ingredients, that are released based on changes in the environment, such as in the rinse cycle of a dishwasher or laundry washing machine.Type: ApplicationFiled: August 18, 2010Publication date: December 9, 2010Applicant: Akzo Nobel N.V.Inventors: Susanne H. Goodson, Klein A. Rodrigues
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Patent number: 7799421Abstract: The invention relates to polymers whose water solubility may be triggered by changes in pH, salt concentration, concentration of surfactant or a combination of both. The polymer is a copolymer or terpolymer containing from 2 to 60 mole percent of an amine functionality that has been neutralized with a fixed acid. Specifically films formed from these polymers will be insoluble at a higher pH, but will become soluble at a lower pH. The polymers are also insoluble at a higher salt concentration, but become soluble at a lower salt concentration. The polymers can be used to coat or encapsulate active ingredients, that are released based on changes in the environment, such as in the rinse cycle of a dishwasher or laundry washing machine.Type: GrantFiled: February 14, 2002Date of Patent: September 21, 2010Assignee: Akzo Nobel N.V.Inventors: Susanne H. Goodson, Klein A. Rodrigues
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Publication number: 20100012885Abstract: Hydrophobically modified polymers for use as anti-scalant and dispersant. The polymers are useful in compositions used in aqueous systems. The polymers include at least one hydrophilic acid monomer, wherein the at least one hydrophilic acid monomer is a polymerizable carboxylic acid or sulfonic acid functionality but not both. The polymers also include at least one hydrophobic moiety. A solvent-free process for preparing these polymers is also provided.Type: ApplicationFiled: September 23, 2009Publication date: January 21, 2010Applicant: Akzo Nobel N.V.Inventor: Klein A. RODRIGUES
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Publication number: 20080221005Abstract: The invention provides an aqueous bleaching solution for substrate treatment comprising a source of oxidant and a suspended polymer matrix having a plurality of optically functional particles associated with one or more copolymers present in the polymer matrix. The plurality of optically functional particles are associated with the copolymer during polymerization of at least one hydrophobic and at least one hydrophilic monomer so as to form a polymer matrix useful to impart an aqueous bleaching solution with optically functional properties providing a benefit to the solutions during storage, use and application to substrates for treatment.Type: ApplicationFiled: January 14, 2008Publication date: September 11, 2008Inventors: Thomas W. Kaaret, Darin K. Griffith, Klein A. Rodrigues, William L. Smith
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Publication number: 20080039358Abstract: Hydrophobically modified polymers for use as anti-scalant and dispersant. The polymers are useful in compositions used in aqueous systems. The polymers include at least one hydrophilic acid monomer, wherein the at least one hydrophilic acid monomer is a polymerizable carboxylic acid or sulfonic acid functionality but not both. The polymers also include at least one hydrophobic moiety. A solvent-free process for preparing these polymers is also provided.Type: ApplicationFiled: October 23, 2007Publication date: February 14, 2008Inventor: Klein Rodrigues
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Publication number: 20080021151Abstract: A glass adhesion composition containing a copolymer having an acid and a substituted amide, silanol, or amine oxide functionality. The substituted amide, silanol, or amine oxide functionality provide excellent adhesion of the copolymer to glass, silica, sand and other silicon-based substances. The copolymer is useful as a fiberglass binder, and also useful in providing protective coatings on glass sheets. A fiberglass sizing composition is also provided having a copolymer that includes at least one acid group derived from at least one acid monomer, a hydrophobic comonomer, and a crosslinker.Type: ApplicationFiled: August 1, 2007Publication date: January 24, 2008Applicant: National Starch and Chemical Investment Holding CorporationInventors: Klein Rodrigues, James Long
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Publication number: 20080004416Abstract: A glass adhesion composition containing a copolymer having an acid and a substituted amide, silanol, or amine oxide functionality. The substituted amide, silanol, or amine oxide functionality provide excellent adhesion of the copolymer to glass, silica, sand and other silicon-based substances. The copolymer is useful as a fiberglass binder, and also useful in providing protective coatings on glass sheets. A fiberglass sizing composition is also provided having a copolymer that includes at least one acid group derived from at least one acid monomer, a hydrophobic comonomer, and a crosslinker.Type: ApplicationFiled: September 10, 2007Publication date: January 3, 2008Applicant: National Starch and Chemical Investment Holding CorporationInventors: Klein Rodrigues, James Long
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Patent number: 7270853Abstract: A glass adhesion composition containing a copolymer having an acid and a substituted amide, silanol, or amine oxide functionality. The substituted amide, silanol, or amine oxide functionality provide excellent adhesion of the copolymer to glass, silica, sand and other silicon-based substances. The copolymer is useful as a fiberglass binder, and also useful in providing protective coatings on glass sheets. A fiberglass sizing composition is also provided having a copolymer that includes at least one acid group derived from at least one acid monomer, a hydrophobic comonomer, and a crosslinker.Type: GrantFiled: June 3, 2004Date of Patent: September 18, 2007Assignee: National Starch and Chemical Investment Holding CorporationInventors: Klein A. Rodrigues, James C. Long