Abstract: An anion conducting electrolyte membrane with high performance where the electric conductivity and the water uptake are balanced, and a method of manufacturing the same are disclosed. The anion conducting electrolyte membrane comprises: a polymeric material which consists of fluorine polymer, olefinic polymer, or aromatic polymer; weak base quaternary salt obtained by the reaction of grafts introduced by graft polymerizing vinyl monomer which contains halogenated alkyl groups using radiation and strong organic bases.

Abstract: A fuel cell system of the present invention includes a fixing unit that fixes or releases hydrazine, a fuel cell to which hydrazine released in the fixing unit is supplied as fuel, a supply line for supplying an aqueous hydrazine solution from a hydrazine supply source to the fixing unit, a drain line for draining drained water from the fixing unit, a first sensing unit for detecting a hydrazine concentration in an aqueous hydrazine solution flowing in the supply line, a second sensing unit for detecting a hydrazine concentration in drained water flowing in the drain line, and a detection unit that detects the amount of hydrazine fixed in the fixing unit based on the concentration values detected by the first sensing unit and the second sensing unit.

Abstract: In a fuel cell including an electrolyte layer allowing an anion component to migrate, and a fuel-side electrode and an oxygen-side electrode arranged to face each other while sandwiching the electrolyte layer, the oxygen-side electrode contains a first catalyst containing a first transition metal and polypyrrole, and a second catalyst containing a second transition metal and a porphyrin ring-containing compound so that the mixing ratio of the first catalyst relative to 100 parts by mass of the total amount of the first catalyst and the second catalyst is more than 10 parts by mass, and below 90 parts by mass.

Abstract: A graft chain containing an N-vinylimidazole derivative is introduced into a polymer substrate by radiation graft polymerization to obtain an alkyl substituted imidazolium salt by a reaction with an alkyl halide, so that an anion exchange membrane with high alkaline durability, in which a nucleophilic substitution reaction and an elimination reaction are inhibited, is obtained.

Abstract: An anion conducting electrolyte membrane with high performance where the electric conductivity and the water uptake are balanced, and a method of manufacturing the same are disclosed. The anion conducting electrolyte membrane comprises: a polymeric material which consists of fluorine polymer, olefinic polymer, or aromatic polymer; weak base quaternary salt obtained by the reaction of grafts introduced by graft polymerizing vinyl monomer which contains halogenated alkyl groups using radiation and strong organic bases.

Abstract: A fuel cell system of the present invention includes a fixing unit that fixes or releases hydrazine; a releasing liquid supplying unit that supplies a water-based releasing liquid for releasing hydrazine fixed in the fixing unit to the fixing unit; a fuel cell to which hydrazine released in the fixing unit is supplied as fuel; a sensing unit for detecting an amount of hydrazine supplied to the fuel cell; and a detection unit that detects an amount of hydrazine fixed in the fixing unit based on a predetermined theoretical hydrazine supply amount to the fuel cell and a hydrazine supply amount detected by the sensing unit.

Abstract: [Problem] To provide a fuel cell having excellent power generation performance, which includes a compound containing at least hydrogen and nitrogen as fuel and uses an anion exchange membrane as an electrolyte layer. [Solution] In a fuel cell 1 including an electrolyte layer 4 formed from an anion exchange membrane, a fuel side electrode 2 and an oxygen side electrode 3, both electrodes being disposed to face each other with the electrolyte layer 4 interposed therebetween, the fuel side electrode 2 contains lanthanum and nickel as a metal catalyst such that the content proportion of lanthanum is 10 to 30% relative to the total mole of the lanthanum and nickel. Further, a compound containing at least hydrogen and nitrogen, such as hydrazine, is used as fuel.

Abstract: In a fuel cell including an electrolyte layer allowing an anion component to migrate, and a fuel-side electrode and an oxygen-side electrode arranged to face each other while sandwiching the electrolyte layer, the oxygen-side electrode contains a first catalyst containing a first transition metal and polypyrrole, and a second catalyst containing a second transition metal and a porphyrin ring-containing compound so that the mixing ratio of the first catalyst relative to 100 parts by mass of the total amount of the first catalyst and the second catalyst is more than 10 parts by mass, and below 90 parts by mass.

Abstract: A hydrazine-fixing group such as a ketone group, a formyl group, a chlormethyl group or an amide group, which is capable of releasably fixing hydrazine, is introduced into a side chain of a synthetic resin, and hydrazine is fixed to the hydrazine-fixing group. Since a hydrazine storage resin of the present invention has a hydrazine-releasable group capable of releasing hydrazine, it is able to store hydrazine stably. In addition, hydrazine can be supplied by releasing hydrazine from the hydrazine-releasable group. Consequently, the hydrazine storage resin can be widely used in various industrial fields requiring supply of hydrazine.

Abstract: A fuel cell includes an electrolyte layer; a fuel-side electrode to which fuel is supplied; and an oxygen-side electrode to which oxygen is supplied, the fuel-side electrode and the oxygen-side electrode being disposed to face each other with the electrolyte layer sandwiched therebetween. The electrolyte layer is an anion exchange membrane. The fuel-side electrode contains cobalt and nickel. The fuel includes a compound containing at least hydrogen and nitrogen. The proportion of the nickel content relative to total moles of cobalt and nickel in the fuel-side electrode is 70 mol % or less.

Abstract: A fuel cell system of the present invention includes a fixing unit that fixes or releases hydrazine; a releasing liquid supplying unit that supplies a water-based releasing liquid for releasing hydrazine fixed in the fixing unit to the fixing unit; a fuel cell to which hydrazine released in the fixing unit is supplied as fuel; a sensing unit for detecting an amount of hydrazine supplied to the fuel cell; and a detection unit that detects an amount of hydrazine fixed in the fixing unit based on a predetermined theoretical hydrazine supply amount to the fuel cell and a hydrazine supply amount detected by the sensing unit.

Abstract: A fuel cell system of the present invention includes a fixing unit that fixes or releases hydrazine, a fuel cell to which hydrazine released in the fixing unit is supplied as fuel, a supply line for supplying an aqueous hydrazine solution from a hydrazine supply source to the fixing unit, a drain line for draining drained water from the fixing unit, a first sensing unit for detecting a hydrazine concentration in an aqueous hydrazine solution flowing in the supply line, a second sensing unit for detecting a hydrazine concentration in drained water flowing in the drain line, and a detection unit that detects the amount of hydrazine fixed in the fixing unit based on the concentration values detected by the first sensing unit and the second sensing unit.

Abstract: Provided is a fuel cell including an electrolyte allowing an anion component to migrate; a fuel-side electrode and an oxygen-side electrode being arranged in opposed relation to each other while sandwiching the electrolyte; a fuel supplying material for supplying fuel to the fuel-side electrode; and an oxygen supplying material for supplying oxygen to the oxygen-side electrode, in which the oxygen-side electrode and/or the fuel-side electrode contain(s) a transition metal, and at least one of a complex-forming organic compound and an electrically-conductive polymer.

Abstract: Hydrazine supply device (1) includes hydrazine fixing bath (2) which releasably fixes hydrazine and water/alkali, tank (3) for supplying water or an alkaline aqueous solution so as to release the hydrazine fixed in the hydrazine fixing bath (2), thereby achieving stable storage and supply of hydrazine. Thus, the device can be widely used in various industrial fields requiring the supply of hydrazine. Further, each of fuel cell system (10) and vehicle (14) comprises the hydrazine supply device (1) and fuel cell (13), thereby achieving safe utilization of hydrazine as fuel and reduction of burdens on the environmental load.

Abstract: A hydrazine-fixing group such as a ketone group, a formyl group, a chlormethyl group or an amide group, which is capable of releasably fixing hydrazine, is introduced into a side chain of a synthetic resin, and hydrazine is fixed to the hydrazine-fixing group. Since a hydrazine storage resin of the present invention has a hydrazine-releasable group capable of releasing hydrazine, it is able to store hydrazine stably. In addition, hydrazine can be supplied by releasing hydrazine from the hydrazine-releasable group. Consequently, the hydrazine storage resin can be widely used in various industrial fields requiring supply of hydrazine.

Abstract: The present invention concerns a fuel cell 1 comprising an electrolyte layer 4 made of an anion exchange membrane and a fuel side electrode 2 and an oxygen side electrode 3 disposed opposed to each other with the electrolyte layer 4 interposed therebetween, wherein the fuel side electrode 2 comprises cobalt incorporated therein as a metal catalyst. Further, as a fuel there is used a compound containing at least hydrogen and nitrogen such as hydrazine.

Abstract: In order to provide a fuel cell that can allow the direct supply of fuel and also can effectively generate electric power with a simple structure, a cell of the fuel cell is so constructed that a proton-shift medium comprising a solid polymer membrane and the like is interposed between a fuel-side electrode and an oxygen-side electrode, and a fuel comprising a compound containing at least hydrogen and nitrogen, such as hydrazine, is supplied directly to the fuel-side electrode.

Abstract: A dimethyl ether reforming catalyst that can reform dimethyl ether to produce a mixed gas of higher concentration of hydrogen and a fuel cell device using the dimethyl ether reforming catalyst. In the dimethyl ether reforming catalyst, copper, or copper and at least one transition metal except the copper is supported on a solid acid. A mixed gas obtained by a reforming device using the dimethyl ether reforming catalyst is fed to the fuel cell as a fuel gas.

Abstract: A fuel cell system includes a reforming device for producing a hydrogen-rich gas mixture by reforming a hydrogen-containing compound, and a fuel cell stack for generating electromotive fore by a reaction between hydrogen and oxygen. The fuel cell system further includes a hydrogen separating device disposed between the reforming device and the fuel cell stack. The hydrogen separating device is provided with hydrogen permeating means for obtaining a fuel gas by separating hydrogen gas from the gas mixture.