Patents by Inventor Koichiro Asazawa

Koichiro Asazawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9130222
    Abstract: A fuel cell system of the present invention includes a fixing unit that fixes or releases hydrazine, a fuel cell to which hydrazine released in the fixing unit is supplied as fuel, a supply line for supplying an aqueous hydrazine solution from a hydrazine supply source to the fixing unit, a drain line for draining drained water from the fixing unit, a first sensing unit for detecting a hydrazine concentration in an aqueous hydrazine solution flowing in the supply line, a second sensing unit for detecting a hydrazine concentration in drained water flowing in the drain line, and a detection unit that detects the amount of hydrazine fixed in the fixing unit based on the concentration values detected by the first sensing unit and the second sensing unit.
    Type: Grant
    Filed: September 4, 2008
    Date of Patent: September 8, 2015
    Assignee: DAIHATSU MOTOR CO., LTD.
    Inventors: Koichiro Asazawa, Koji Yamada, Hirohisa Tanaka
  • Patent number: 8945791
    Abstract: In a fuel cell including an electrolyte layer allowing an anion component to migrate, and a fuel-side electrode and an oxygen-side electrode arranged to face each other while sandwiching the electrolyte layer, the oxygen-side electrode contains a first catalyst containing a first transition metal and polypyrrole, and a second catalyst containing a second transition metal and a porphyrin ring-containing compound so that the mixing ratio of the first catalyst relative to 100 parts by mass of the total amount of the first catalyst and the second catalyst is more than 10 parts by mass, and below 90 parts by mass.
    Type: Grant
    Filed: March 23, 2011
    Date of Patent: February 3, 2015
    Assignees: Daihatsu Motor Co. Ltd., STC UNM
    Inventors: Koichiro Asazawa, Koji Yamada, Hirohisa Tanaka, Kazuya Yamamoto, Tim Olson, Svitlana Pylypenko, Plamen Atanassov
  • Publication number: 20140066528
    Abstract: A graft chain containing an N-vinylimidazole derivative is introduced into a polymer substrate by radiation graft polymerization to obtain an alkyl substituted imidazolium salt by a reaction with an alkyl halide, so that an anion exchange membrane with high alkaline durability, in which a nucleophilic substitution reaction and an elimination reaction are inhibited, is obtained.
    Type: Application
    Filed: August 28, 2013
    Publication date: March 6, 2014
    Applicants: Daihatsu Motor Co., Ltd., Japan Atomic Energy Agency
    Inventors: Kimio YOSHIMURA, Hiroshi KOSHIKAWA, Tetsuya YAMAKI, Masaharu ASANO, Yasunari MAEKAWA, Hideyuki SHISHITANI, Koichiro ASAZAWA, Susumu YAMAGUCHI, Hirohisa TANAKA
  • Publication number: 20130280626
    Abstract: An anion conducting electrolyte membrane with high performance where the electric conductivity and the water uptake are balanced, and a method of manufacturing the same are disclosed. The anion conducting electrolyte membrane comprises: a polymeric material which consists of fluorine polymer, olefinic polymer, or aromatic polymer; weak base quaternary salt obtained by the reaction of grafts introduced by graft polymerizing vinyl monomer which contains halogenated alkyl groups using radiation and strong organic bases.
    Type: Application
    Filed: March 5, 2013
    Publication date: October 24, 2013
    Inventors: Kimio YOSHIMURA, Hiroshi KOSHIKAWA, Tetsuya YAMAKI, Masaharu ASANO, Yasunari MAEKAWA, Hideyuki SHISHITANI, Hirohisa TANAKA, Susumu YAMAGUCHI, Koichiro ASAZAWA, Kazuya YAMAMOTO, Fumihiro SANPEI
  • Patent number: 8557476
    Abstract: A fuel cell system of the present invention includes a fixing unit that fixes or releases hydrazine; a releasing liquid supplying unit that supplies a water-based releasing liquid for releasing hydrazine fixed in the fixing unit to the fixing unit; a fuel cell to which hydrazine released in the fixing unit is supplied as fuel; a sensing unit for detecting an amount of hydrazine supplied to the fuel cell; and a detection unit that detects an amount of hydrazine fixed in the fixing unit based on a predetermined theoretical hydrazine supply amount to the fuel cell and a hydrazine supply amount detected by the sensing unit.
    Type: Grant
    Filed: September 4, 2008
    Date of Patent: October 15, 2013
    Assignee: Daihatsu Motor Co., Ltd.
    Inventors: Koichiro Asazawa, Koji Yamada, Hirohisa Tanaka
  • Publication number: 20130189603
    Abstract: [Problem] To provide a fuel cell having excellent power generation performance, which includes a compound containing at least hydrogen and nitrogen as fuel and uses an anion exchange membrane as an electrolyte layer. [Solution] In a fuel cell 1 including an electrolyte layer 4 formed from an anion exchange membrane, a fuel side electrode 2 and an oxygen side electrode 3, both electrodes being disposed to face each other with the electrolyte layer 4 interposed therebetween, the fuel side electrode 2 contains lanthanum and nickel as a metal catalyst such that the content proportion of lanthanum is 10 to 30% relative to the total mole of the lanthanum and nickel. Further, a compound containing at least hydrogen and nitrogen, such as hydrazine, is used as fuel.
    Type: Application
    Filed: September 9, 2011
    Publication date: July 25, 2013
    Inventors: Tomokazu Sakamoto, Koichiro Asazawa, Koji Yamada, Hirohisa Tanaka
  • Publication number: 20130011765
    Abstract: In a fuel cell including an electrolyte layer allowing an anion component to migrate, and a fuel-side electrode and an oxygen-side electrode arranged to face each other while sandwiching the electrolyte layer, the oxygen-side electrode contains a first catalyst containing a first transition metal and polypyrrole, and a second catalyst containing a second transition metal and a porphyrin ring-containing compound so that the mixing ratio of the first catalyst relative to 100 parts by mass of the total amount of the first catalyst and the second catalyst is more than 10 parts by mass, and below 90 parts by mass.
    Type: Application
    Filed: March 23, 2011
    Publication date: January 10, 2013
    Applicants: STC UNM, DAIHATSU MOTOR CO., LTD.
    Inventors: Koichiro Asazawa, Koji Yamada, Hirohisa Tanaka, Kazuya Yamamoto, Tim Olson, Svitlana Pylypenko, Plamen Atanassov
  • Publication number: 20120121496
    Abstract: A hydrazine-fixing group such as a ketone group, a formyl group, a chlormethyl group or an amide group, which is capable of releasably fixing hydrazine, is introduced into a side chain of a synthetic resin, and hydrazine is fixed to the hydrazine-fixing group. Since a hydrazine storage resin of the present invention has a hydrazine-releasable group capable of releasing hydrazine, it is able to store hydrazine stably. In addition, hydrazine can be supplied by releasing hydrazine from the hydrazine-releasable group. Consequently, the hydrazine storage resin can be widely used in various industrial fields requiring supply of hydrazine.
    Type: Application
    Filed: January 26, 2012
    Publication date: May 17, 2012
    Applicants: OTSUKA CHEMICAL CO., LTD., DAIHATSU MOTOR CO., LTD., SANYO CHEMICAL INDUSTRIES, LTD.
    Inventors: Masatoshi TANIGUCHI, Akinori OKA, Takashi KITAJIMA, Ken SONOGI, Masaaki OKA, Hirohisa TANAKA, Koji YAMADA, Koichiro ASAZAWA
  • Publication number: 20120015281
    Abstract: A fuel cell includes an electrolyte layer; a fuel-side electrode to which fuel is supplied; and an oxygen-side electrode to which oxygen is supplied, the fuel-side electrode and the oxygen-side electrode being disposed to face each other with the electrolyte layer sandwiched therebetween. The electrolyte layer is an anion exchange membrane. The fuel-side electrode contains cobalt and nickel. The fuel includes a compound containing at least hydrogen and nitrogen. The proportion of the nickel content relative to total moles of cobalt and nickel in the fuel-side electrode is 70 mol % or less.
    Type: Application
    Filed: March 3, 2010
    Publication date: January 19, 2012
    Applicant: Daihatsu Motor Co., Ltd.
    Inventors: Tomokazu Sakamoto, Koichiro Asazawa
  • Publication number: 20100233583
    Abstract: A fuel cell system of the present invention includes a fixing unit that fixes or releases hydrazine; a releasing liquid supplying unit that supplies a water-based releasing liquid for releasing hydrazine fixed in the fixing unit to the fixing unit; a fuel cell to which hydrazine released in the fixing unit is supplied as fuel; a sensing unit for detecting an amount of hydrazine supplied to the fuel cell; and a detection unit that detects an amount of hydrazine fixed in the fixing unit based on a predetermined theoretical hydrazine supply amount to the fuel cell and a hydrazine supply amount detected by the sensing unit.
    Type: Application
    Filed: September 4, 2008
    Publication date: September 16, 2010
    Applicant: Daihatsu Motor Co., Ltd.
    Inventors: Koichiro Asazawa, Koji Yamada, Hirohisa Tanaka
  • Publication number: 20100221643
    Abstract: A fuel cell system of the present invention includes a fixing unit that fixes or releases hydrazine, a fuel cell to which hydrazine released in the fixing unit is supplied as fuel, a supply line for supplying an aqueous hydrazine solution from a hydrazine supply source to the fixing unit, a drain line for draining drained water from the fixing unit, a first sensing unit for detecting a hydrazine concentration in an aqueous hydrazine solution flowing in the supply line, a second sensing unit for detecting a hydrazine concentration in drained water flowing in the drain line, and a detection unit that detects the amount of hydrazine fixed in the fixing unit based on the concentration values detected by the first sensing unit and the second sensing unit.
    Type: Application
    Filed: September 4, 2008
    Publication date: September 2, 2010
    Applicant: Daihatsu Motor Co.,Ltd.
    Inventors: Koichiro Asazawa, Kohi Yamada, Hirohisa Tanaka
  • Publication number: 20100035111
    Abstract: Provided is a fuel cell including an electrolyte allowing an anion component to migrate; a fuel-side electrode and an oxygen-side electrode being arranged in opposed relation to each other while sandwiching the electrolyte; a fuel supplying material for supplying fuel to the fuel-side electrode; and an oxygen supplying material for supplying oxygen to the oxygen-side electrode, in which the oxygen-side electrode and/or the fuel-side electrode contain(s) a transition metal, and at least one of a complex-forming organic compound and an electrically-conductive polymer.
    Type: Application
    Filed: September 7, 2007
    Publication date: February 11, 2010
    Applicant: Daihatsu Motor Co., Ltd.
    Inventors: Koichiro Asazawa, Koji Yamada, Hirohisa Tanaka
  • Publication number: 20090318662
    Abstract: A hydrazine-fixing group such as a ketone group, a formyl group, a chlormethyl group or an amide group, which is capable of releasably fixing hydrazine, is introduced into a side chain of a synthetic resin, and hydrazine is fixed to the hydrazine-fixing group. Since a hydrazine storage resin of the present invention has a hydrazine-releasable group capable of releasing hydrazine, it is able to store hydrazine stably. In addition, hydrazine can be supplied by releasing hydrazine from the hydrazine-releasable group. Consequently, the hydrazine storage resin can be widely used in various industrial fields requiring supply of hydrazine.
    Type: Application
    Filed: July 9, 2007
    Publication date: December 24, 2009
    Applicants: OTSUKA CHEMICAL CO., LTD., SANYO CHEMICAL INDUSTRIES, LTD., DAIHATSU MOTOR CO., LTD.
    Inventors: Masatoshi Taniguchi, Akinori Oka, Takashi Kitajima, Ken Sonogi, Masaaki Oka, Hirohisa Tanaka, Koji Yamada, Koichiro Asazawa
  • Publication number: 20090317670
    Abstract: Hydrazine supply device (1) includes hydrazine fixing bath (2) which releasably fixes hydrazine and water/alkali, tank (3) for supplying water or an alkaline aqueous solution so as to release the hydrazine fixed in the hydrazine fixing bath (2), thereby achieving stable storage and supply of hydrazine. Thus, the device can be widely used in various industrial fields requiring the supply of hydrazine. Further, each of fuel cell system (10) and vehicle (14) comprises the hydrazine supply device (1) and fuel cell (13), thereby achieving safe utilization of hydrazine as fuel and reduction of burdens on the environmental load.
    Type: Application
    Filed: July 9, 2007
    Publication date: December 24, 2009
    Applicants: OTSUKA CHEMICAL CO., LTD., DAIHATSU MOTOR CO., LTD.
    Inventors: Masatoshi Taniguchi, Akinori Oka, Takashi Kitajima, Ken Sonogi, Hirohisa Tanaka, Koji Yamada, Koichiro Asazawa
  • Publication number: 20080145733
    Abstract: The present invention concerns a fuel cell 1 comprising an electrolyte layer 4 made of an anion exchange membrane and a fuel side electrode 2 and an oxygen side electrode 3 disposed opposed to each other with the electrolyte layer 4 interposed therebetween, wherein the fuel side electrode 2 comprises cobalt incorporated therein as a metal catalyst. Further, as a fuel there is used a compound containing at least hydrogen and nitrogen such as hydrazine.
    Type: Application
    Filed: March 3, 2006
    Publication date: June 19, 2008
    Applicant: DAIHATSU MOTOR CO., LTD.
    Inventors: Koichiro Asazawa, Koji Yamada, Hirohisa Tanaka
  • Publication number: 20050095465
    Abstract: In order to provide a fuel cell that can allow the direct supply of fuel and also can effectively generate electric power with a simple structure, a cell of the fuel cell is so constructed that a proton-shift medium comprising a solid polymer membrane and the like is interposed between a fuel-side electrode and an oxygen-side electrode, and a fuel comprising a compound containing at least hydrogen and nitrogen, such as hydrazine, is supplied directly to the fuel-side electrode.
    Type: Application
    Filed: December 25, 2002
    Publication date: May 5, 2005
    Inventors: Hirohisa Tanaka, Koji Yamada, Koichiro Asazawa
  • Patent number: 6605559
    Abstract: A dimethyl ether reforming catalyst that can reform dimethyl ether to produce a mixed gas of higher concentration of hydrogen and a fuel cell device using the dimethyl ether reforming catalyst. In the dimethyl ether reforming catalyst, copper, or copper and at least one transition metal except the copper is supported on a solid acid. A mixed gas obtained by a reforming device using the dimethyl ether reforming catalyst is fed to the fuel cell as a fuel gas.
    Type: Grant
    Filed: August 31, 2000
    Date of Patent: August 12, 2003
    Assignee: Daihatsu Motor Co., Ltd.
    Inventors: Koji Yamada, Koichiro Asazawa, Hirohisa Tanaka
  • Patent number: 6475655
    Abstract: A fuel cell system includes a reforming device for producing a hydrogen-rich gas mixture by reforming a hydrogen-containing compound, and a fuel cell stack for generating electromotive fore by a reaction between hydrogen and oxygen. The fuel cell system further includes a hydrogen separating device disposed between the reforming device and the fuel cell stack. The hydrogen separating device is provided with hydrogen permeating means for obtaining a fuel gas by separating hydrogen gas from the gas mixture.
    Type: Grant
    Filed: June 21, 2000
    Date of Patent: November 5, 2002
    Assignee: Daihatsu Motor Co., Ltd.
    Inventors: Haruyuki Nakanishi, Hirohisa Tanaka, Koji Yamada, Masahiro Abe, Koichiro Asazawa