Abstract: Disclosed herein are electrolyte compositions comprising: a) a first solvent comprising a cyclic carbonate; b) a second solvent comprising a non-fluorinated acyclic carbonate; c) at least one electrolyte component selected from: i) a fluorinated acyclic carboxylic acid ester; ii) a fluorinated acyclic carbonate; iii) a fluorinated acyclic ether; or iv) a mixture thereof; and d) an electrolyte salt; wherein the electrolyte component is present in the electrolyte composition in the range of from about 0.05 weight percent to about 10 weight percent, based on the total weight of the first and second solvents.

Abstract: In a first aspect, a low haze polyimide film includes, a dianhydride, a diamine, and a color-tuning compound. The low haze polyimide film has a thickness in a range of from 1 to 150 um, an a* closer to zero with a |?a*| greater than 0.2 and a b* that is at most 0.2 further away from zero, or a b* closer to zero with a |?b*| greater than 0.2 and an a* that is at most 0.2 further away from zero, when compared to a low haze polyimide film of the same dianhydride and diamine composition, but without the color-tuning compound, and a haze of less than 4%. In a second aspect, an electronic device includes the low haze polyimide film of the first aspect.

Abstract: Disclosed herein are electrolyte compositions comprising a fluorinated solvent, at least one silyl oxalate represented by the formulas RR?Si(C2O4), wherein R and R? are each the same or different from each other and independently selected from C1-C8 alkyl, C2-C8 alkenyl, C2-C8 alkynyl, or C6-C10 aryl radical, optionally comprising at least one substituent selected from halogen, hydroxyl, alkoxy, carbonyl, and carboxyl groups; and LiPF6. Also disclosed herein are electrolyte compositions comprising a fluorinated solvent and a lithium oxalato phosphate salt represented by the formula LiPF(6-2q)(C2O4)q, wherein q is 1, 2 or 3; wherein the oxalato phosphate salt comprises at least a portion that is derived from at least one silyl oxalate as defined herein. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.

Abstract: In a first aspect, a multilayer film includes a first outer layer including a first thermoplastic polyimide, a core layer including a polyimide, and a second outer layer including a second thermoplastic polyimide. The polyimide of the core layer includes a first aromatic dianhydride including 3,3?,4,4?-biphenyl tetracarboxylic dianhydride and a first aromatic diamine including p-phenylenediamine. The multilayer film has a total thickness in a range of from 5 to 150 ?m. A thickness of the core layer is in a range of from 35 to 73% of the total thickness of the multilayer film. A minimum peel strength for at least one of the first and second outer layers, when adhered to copper foil and tested following ASTM method IPC-TM-650, method No. 2.4.9B, is greater than 0.9 kgf/cm (0.88 N/mm). In a second aspect, a metal-clad laminate includes the multilayer film of the first aspect and a first metal layer adhered to an outer surface of the first outer layer of the multilayer film.

Abstract: Described are electrolyte compositions containing a non-fluorinated carbonate, a fluorinated solvent, a cyclic sulfate, at least one lithium borate salt selected from lithium bis(oxalato)borate, lithium difluoro(oxalato)borate, lithium tetrafluoroborate, or mixtures thereof, and at least one electrolyte salt. The cyclic sulfate can be represented by the formula: wherein each A is independently a hydrogen or an optionally fluorinated vinyl, allyl, acetylenic, propargyl, or C1-C3 alkyl group. The electrolyte composition may further comprise a fluorinated cyclic carbonate. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.

Abstract: Described herein are: An electrolyte composition comprising a) a fluorinated solvent for an electrolyte salt; b) an oxalate salt represented by the Formula LiPF(6-2q)(Ox)q, wherein Ox is an oxalate moiety and q is 1, 2 or 3; and c) optionally, at least one electrolyte salt. In some embodiments, the electrolyte composition comprises a mole ratio of Ox/P in the range of from 0.001 to 5. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.

Abstract: Described are electrolyte compositions comprising a fluorinated solvent, an organic carbonate, a sultone, and optionally a borate. The fluorinated solvent may be a fluorinated acyclic carboxylic acid ester, a fluorinated acyclic carbonate, a fluorinated acyclic ether, or mixtures thereof. The organic carbonate may be fluorinated or non-fluorinated. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.

Abstract: Described are electrolyte compositions containing a non-fluorinated carbonate, a fluorinated solvent, a cyclic sulfate, at least one lithium borate salt selected from lithium bis(oxalato)borate, lithium difluoro(oxalato)borate, lithium tetrafluoroborate, or mixtures thereof, and at least one electrolyte salt. The cyclic sulfate can be represented by the formula: wherein each A is independently a hydrogen or an optionally fluorinated vinyl, allyl, acetylenic, propargyl, or C1-C3 alkyl group. The electrolyte composition may further comprise a fluorinated cyclic carbonate. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.

Abstract: Described herein are electrolyte compositions containing an organic carbonate, a fluorinated solvent, a cyclic sulfate, and at least one electrolyte salt. The cyclic sulfate can be represented by the formula: wherein each A is independently a hydrogen or an optionally fluorinated vinyl, allyl, acetylenic, propargyl, or C1-C3 alkyl group. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.

Abstract: The present disclosure is related to an electrolyte composition comprising a fluorinated ester solvent, a non-fluorinated carbonate, a lithium/boron compound and a lithium salt. Electrochemical cells comprising the electrolyte solvent have increased cycle life.

Abstract: Disclosed herein is a process for the manufacture of a fluoroelastomer composition containing fluoropolymer fibrils. The process comprises applying shear to a fluoroelastomer gum in a mixer while adding a liquid dispersion of fibrillatable fluoropolymer.

Abstract: There is a composition comprising 1 to 17.5 wt. % ionomer composition comprising halogen ionomer and 50 to 99 wt. % carbon-sulfur composite made from carbon powder having a surface area of about 50 to 4,000 square meters per gram and a pore volume of about 0.5 to 6 cubic centimeters per gram. The composite has 5 to 95 wt. % sulfur compound. There is also a layering comprising a plurality of coatings. Respective coatings in the plurality of coatings comprise respective compositions. The respective coatings comprise at least one ionomer composition comprising halogen ionomer and at least one carbon-sulfur composite of carbon powder and sulfur compound. There are also electrodes comprising the composition or layering and methods of using such in cells.

Abstract: There is a composition comprising 1 to 17.5 wt. % ionomer composition comprising hydrocarbon ionomer and 50 to 99 wt. % carbon-sulfur composite made from carbon powder having a surface area of about 50 to 4,000 square meters per gram and a pore volume of about 0.5 to 6 cubic centimeters per gram. The composite has 5 to 95 wt. % sulfur compound. There is also a layering comprising a plurality of coatings. Respective coatings in the plurality of coatings comprise respective compositions. The respective coatings comprise at least one ionomer composition comprising hydrocarbon ionomer and at least one carbon-sulfur composite of carbon powder and sulfur compound. There are also electrodes comprising the composition or layering and methods of using such in cells.

Abstract: An electrode comprising an aluminum or aluminum alloy current collector, a conductive interlayer disposed on the current collector and an electroactive material layer disposed on the conductive interlayer. The interlayer comprises an interlayer conductivity agent and an interlayer binding agent.

Abstract: There is a cell comprising an article comprising a hydrocarbon ionomer. The article may be any element in the cell, such as an interior wall, or a modification to an element, such as a film, a membrane, and a coating. The hydrocarbon ionomer is any polymer with ionic functionality, such as a polymeric (methacrylate) neutralized with lithium, and not containing halogen or halogen-containing substituents. The hydrocarbon ionomer may also be included in a composition within an element of the cell, such as a porous separator. The cell also comprises a positive electrode including sulfur compound, a negative electrode, a circuit coupling the positive electrode with the negative electrode, an electrolyte medium and an interior wall of the cell. In addition, there are methods of making the cell and methods of using the cell.

Abstract: There are cells comprising a sulfur-containing first electrode. The cells also comprise a lithium-containing second electrode associated with a total amount of electrode lithium, including electrochemically utilized electrode lithium. The cells also includes a circuit coupling the first electrode with the second electrode, an article comprising an ionomer and an electrolyte medium comprising at least one additive selected from one or more of the groups consisting of nitrogen-containing additives, sulfur-containing additives, and organic peroxide additives. There are also associated methods of making and methods of using the cells.

Abstract: There is an ionomer composite membrane comprising at least one laterally adjacent region and laterally isolated regions occupying about 0.1 to 80% by volume of the membrane and associated with pores having an average pore diameter dimension of about 0.1 to 150 microns. The membrane has an average thickness of about 3 to 500 microns and comprises a first material and a second material. A first region in the membrane comprises the first material and a second region comprises the second material. The first material comprises an ionomer. There is also a cell including the membrane. There also are related methods of making and using the membrane and cell.

Abstract: There is a cell comprising an article comprising a hydrocarbon ionomer. The article may be any element in the cell, such as an interior wall, or a modification to an element, such as a film, a membrane, and a coating. The hydrocarbon ionomer is any polymer with ionic functionality, and not containing halogen or halogen-containing substituents. The hydrocarbon ionomer may also be included in a composition within an element of the cell, such as a porous separator. The cell also comprises a positive electrode including sulfur compound, a negative electrode, a circuit coupling the positive electrode with the negative electrode, an electrolyte medium and an interior wall of the cell. In addition, there are methods of making the cell and methods of using the cell.

Abstract: Described are binder precursor compositions for cathodes containing polyamic acid which has a anhydride to amine ratio of greater than or equal to 0.985:1 to less than or equal to 1.10:1. These compositions are useful as cathodes in electrochemical cells, such as lithium ion batteries. Also described are electrodes comprising the binder precursor compositions and methods to prepare the electrodes.

Abstract: There is a composition comprising 1 to 17.5 wt. % ionomer composition comprising hydrocarbon ionomer and 50 to 99 wt. % carbon-sulfur composite made from carbon powder having a surface area of about 50 to 4,000 square meters per gram and a pore volume of about 0.5 to 6 cubic centimeters per gram. The composite has 5 to 95 wt. % sulfur compound. There is also a layering comprising a plurality of coatings. Respective coatings in the plurality of coatings comprise respective compositions. The respective coatings comprise at least one ionomer composition comprising hydrocarbon ionomer and at least one carbon-sulfur composite of carbon powder and sulfur compound. There are also electrodes comprising the composition or layering and methods of using such in cells.