Patents by Inventor Larry J. Shelestak
Larry J. Shelestak has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20160159680Abstract: A glass has a basic soda-lime-silica glass portion, and a colorant portion including total iron as Fe2O3 in the range of greater than zero to 0.10 weight percent, e.g. selected from the group of total iron as Fe2O3 in the range of greater than zero to 0.02 weight percent and total iron as Fe2O3 in the range of greater than 0.02 weight percent to less than 0.10 weight percent; redox ratio in the range of 0.2 to 0.6, and tin and/or tin compounds, e.g. SnO2 greater than 0.000 to 5.0 weight percent. In one embodiment of the invention, the glass has a tin side and an opposite air side, wherein the tin side of the glass is supported on a molten tin bath during forming of the glass. The tin concentration at the tin side of the glass is greater than, less than, or equal to the tin concentration in “body portion” of the glass. The “body portion” of the glass extending from the air side of the glass toward the tin side and terminating short of the tin side of the glass.Type: ApplicationFiled: February 18, 2016Publication date: June 9, 2016Inventors: Mark O. Naylor, Lawrence E. Jansen, Larry J. Shelestak
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Patent number: 9133049Abstract: A soda-lime-silica glass for solar collector cover plates and solar mirrors has less than 0.010 weight percent total iron as Fe2O3, a redox ratio of less than 0.350, less than 0.0025 weight percent CeO2, and spectral properties that include a visible transmission, and a total solar infrared transmittance, of greater than 90% at a thickness of 5.5 millimeters, and reduced solarization. In one non-limiting embodiment of invention, the glass is made by heating a pool of molten soda-lime-silica with a mixture of combustion air and fuel gas having an air firing ratio of greater than 11, or an oxygen firing ratio of greater than 2.31. In another non-limiting embodiment of the invention, streams of oxygen bubbles are moved through a pool of molten glass. In both embodiments, the oxygen oxidizes ferrous iron to ferric iron to reduce the redox ratio.Type: GrantFiled: October 17, 2012Date of Patent: September 15, 2015Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, Ronald L. Schwenninger
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Publication number: 20150246842Abstract: A low infrared absorbing lithium glass includes FeO in the range of 0.0005-0.015 wt. %, more preferably 0.001-0.010 wt. %, and a redox ratio in the range of 0.005-0.15, more preferably in the range of 0.005-0.10. The glass can be chemically tempered and used to provide a ballistic viewing cover for night vision goggles or scope. A method is provided to change a glass making process from making a high infrared absorbing lithium glass having FeO in the range of 0.02 to 0.04 wt. % and a redox ratio in the range of 0.2 to 0.4 to the low infrared absorbing lithium glass by adding additional oxidizers to the batch materials. A second method is provided to change a glass making process from making a low infrared absorbing lithium glass to the high infrared absorbing lithium glass by adding additional reducers to the batch material. In one embodiment of the invention the oxidizer is CeO2. An embodiment of the invention covers a glass made according to the method.Type: ApplicationFiled: May 14, 2015Publication date: September 3, 2015Inventors: George B. Goodwin, Mehran Arbab, Caroline S. Harris, Larry J. Shelestak, Calvin B. Blevins, James V. Hartmann
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Patent number: 8901021Abstract: A vehicle roof window includes an uncoated glass transparency having an Lta in the range of greater than 0% to 10%, and a solar factor in the range of equal to or less than 30%, measured at a thickness in the range of 3.6-4.1 millimeters (“mm”), e.g. at a thickness of 3.6 mm, 3.9 mm or 4.1 mm. The solar factor is determined in accordance to International Organization for Standardization (“ISO”) No. 13837.Type: GrantFiled: February 14, 2011Date of Patent: December 2, 2014Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, James P. Thiel
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Publication number: 20140309099Abstract: A glass has a basic soda-lime-silica glass portion, and a colorant portion including total iron as Fe2O3 selected from the group of total iron as Fe2O3 in the range of greater than zero to 0.02 weight percent; total iron as Fe2O3 in the range of greater than 0.02 weight percent to less than 0.10 weight percent and total iron as Fe2O3 in the range of 0.10 to 2.00 weight percent; redox ratio in the range of 0.2 to 0.6, and tin and/or tin compounds, e.g. SnO2 greater than 0.000 to 6.0 weight percent. In one embodiment of the invention, the glass has a tin side and an opposite air side, wherein the tin side of the glass is supported on a molten tin bath during forming of the glass. The tin concentration at the tin side of the glass is greater than, less than, or equal to the tin concentration in “body portion” of the glass. The “body portion” of the glass extending from the air side of the glass toward the tin side and terminating short of the tin side of the glass.Type: ApplicationFiled: April 14, 2014Publication date: October 16, 2014Applicant: PPG INDUSTRIES OHIO, INC.Inventors: Mark O. Naylor, Lawrence E. Jansen, Larry J. Shelestak
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Publication number: 20140144498Abstract: The present invention relates to a glass composition that includes: 57 to 75 percent by weight of SiO2; 3 to 11 percent by weight of Al2O3; 6 to 11 percent by weight of Na2O; 16 to 21 percent by weight of CaO; 0.01 to 0.1 percent by weight of Li2O; and less than 0.05 percent by weight of K2O. Each percent by weight is based on total weight of the glass composition. Glass products are also provided that have a bulk glass composition as described above. The glass products, such as flat glass products and glass substrates, have a strain point of at least 590° C. and a thermal expansion of at least 7.4 ppm/° C. The present invention also relates to magnetic recording articles and photovoltaic cells that include a glass substrate that has a bulk glass composition as described above.Type: ApplicationFiled: November 28, 2012Publication date: May 29, 2014Applicant: PPG INDUSTRIES OHIO, INC.Inventors: Larry J. Shelestak, James W. McCamy, Paul R. Ohodnicki, JR., Hong Li, Adam D. Polcyn
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Patent number: 8664132Abstract: A high transmittance glass includes: SiO2 in the range of 65 to 75 weight percent; Na2O in the range of 10 to 20 weight percent; CaO in the range of 5 to 15 weight percent; MgO in the range of 0 to 5 weight percent; Al2O3 in the range of 0 to 5 weight percent; K2O in the range of 0 to 5 weight percent; MnO2 in the range of 0.035 to 0.6 weight percent; FeO in the range of 0.0010 to 0.0030 weight percent; and Fe2O3 (total iron) in the range of 0.001 to 0.03 weight percent. The glass has a redox ratio in the range of 0.1 to 0.4.Type: GrantFiled: August 31, 2011Date of Patent: March 4, 2014Assignee: PPG Industries Ohio, Inc.Inventor: Larry J. Shelestak
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Patent number: 8440583Abstract: A blue colored, infrared and ultraviolet absorbing glass composition uses a standard soda-lime-silica glass base composition and additionally iron, cobalt, and additional colorants selected from the group of Er2O3, Cr2O3, CuO, NiO, TiO2, Nd2O3 and combinations thereof. The glass of the present invention has a luminous transmittance of up to 60 percent, a dominant wavelength in the range of 480 to 489 nanometers and an excitation purity of at least 8 percent at a thickness of 0.160 inches (4.06 millimeters). The glass composition can form transparent glass panels that have varying limited LTA from one another as panel sets for mounting in automobiles.Type: GrantFiled: May 27, 2010Date of Patent: May 14, 2013Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, Mehran Arbab
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Publication number: 20130070340Abstract: An antireflective coating includes a first high index of refraction coating layer; a first low index of refraction coating layer over the first high index of refraction coating layer; a second high index of refraction coating layer over the first low index of refraction coating layer; and a second low index of refraction coating layer over the second high index of refraction coating layer.Type: ApplicationFiled: May 16, 2012Publication date: March 21, 2013Applicant: PPG INDUSTRIES OHIO, INC.Inventors: Larry J. Shelestak, James P. Thiel
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Patent number: 8304358Abstract: A soda-lime-silica glass for solar collector cover plates and solar mirrors has less than 0.010 weight percent total iron as Fe2O3, a redox ratio of less than 0.350, less than 0.0025 weight percent CeO2, and spectral properties that include a visible transmission, and a total solar infrared transmittance, of greater than 90% at a thickness of 5.5 millimeters, and reduced solarization. In one non-limiting embodiment of invention, the glass is made by heating a pool of molten soda-lime-silica with a mixture of combustion air and fuel gas having an air firing ratio of greater than 11, or an oxygen firing ratio of greater than 2.31. In another non-limiting embodiment of the invention, streams of oxygen bubbles are moved through a pool of molten glass. In both embodiments, the oxygen oxidizes ferrous iron to ferric iron to reduce the redox ratio.Type: GrantFiled: November 21, 2008Date of Patent: November 6, 2012Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, Ronald L. Shewenninger
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Publication number: 20120275018Abstract: A glass transparency for an automotive roof window includes a solar control coating on a surface of a glass substrate to provide the coated glass with a solar factor in the range of equal to or less 30%, and an Lta in the range of greater than 0% to less than 50%. The solar factor is determined in accordance with ISO 13837 (2008). In another embodiment of the invention, the transparency is a laminated transparency having the solar control coating between two glass sheets.Type: ApplicationFiled: April 29, 2011Publication date: November 1, 2012Applicant: PPG INDUSTRIES OHIO, INC.Inventors: Songwei Lu, Larry J. Shelestak, James P. Thiel
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Publication number: 20120207995Abstract: A vehicle roof window includes an uncoated glass transparency having an Lta in the range of greater than 0% to 10%, and a solar factor in the range of equal to or less than 30%, measured at a thickness in the range of 3.6-4.1 millimeters (‘mm”), e.g. at a thickness of 3.6 mm, 3.9 mm or 4.1 mm. The solar factor is determined in accordance to International Organization for Standardization (“ISO”) No. 13837.Type: ApplicationFiled: February 14, 2011Publication date: August 16, 2012Applicant: PPG INDUSTRIES OHIO, INC.Inventors: Larry J. Shelestak, James P. Thiel
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Publication number: 20120058880Abstract: A high transmittance glass includes: SiO2 in the range of 65 to 75 weight percent; Na2O in the range of 10 to 20 weight percent; CaO in the range of 5 to 15 weight percent; MgO in the range of 0 to 5 weight percent; Al2O3 in the range of 0 to 5 weight percent; K2O in the range of 0 to 5 weight percent; MnO2 in the range of 0.035 to 0.6 weight percent; FeO in the range of 0.0010 to 0.0030 weight percent; and Fe2O3 (total iron) in the range of 0.001 to 0.03 weight percent. The glass has a redox ratio in the range of 0.1 to 0.4.Type: ApplicationFiled: August 31, 2011Publication date: March 8, 2012Applicant: PPG INDUSTRIES OHIO, INC.Inventor: Larry J. Shelestak
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Publication number: 20110291436Abstract: A blue colored, infrared and ultraviolet absorbing glass composition uses a standard soda-lime-silica glass base composition and additionally iron, cobalt, and additional colorants selected from the group of Er2O3, Cr2O3, CuO, NiO, TiO2, Nd2O3 and combinations thereof. The glass of the present invention has a luminous transmittance of up to 60 percent, a dominant wavelength in the range of 480 to 489 nanometers and an excitation purity of at least 8 percent at a thickness of 0.160 inches (4.06 millimeters). The glass composition can form transparent glass panels that have varying limited LTA from one another as panel sets for mounting in automobiles.Type: ApplicationFiled: May 27, 2010Publication date: December 1, 2011Applicant: PPG INDUSTRIES OHIO, INC.Inventors: Larry J. Shelestak, Mehran Arbab
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Patent number: 8062749Abstract: An aircraft transparency in a glass piece, wherein the glass piece includes a chemically tempered first major surface and a chemically tempered opposite second major surface, a first case depth begins at the first major surface, a second case depth begins at the second major surface, and a tensile stress zone is within the glass piece between the end points of the first and the second case depths. The glass between the end points of the first and second case depth has a glass composition including: Ingredient Percent by weight SiO2 60 to 75; Al2O3 18 to 28; and Li2O 3 to 9, and the glass has at least one of the following properties (a) a log 10 viscosity temperature of at least 1413° F. and (b) a liquidus temperature of at least 2436° F.Type: GrantFiled: May 28, 2010Date of Patent: November 22, 2011Assignee: PPG Industries Ohio, IncInventors: Larry J. Shelestak, George B. Goodwin, Amarendra Mishra, James M. Baldauff
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Publication number: 20110079048Abstract: A glass composition for chemical tempering includes oxides in wt % ranges of: SiO2 60 to 75; Al2O3 18 to 28; Li2O 3 to 9; Na2O 0 to 3; K2O 0 to 0.5; CaO 0 to 3; MgO 0 to 3; ZrO2 0 to 3; where MgO+CaO is 0 to 6 wt %; Al2O3+ZrO2 is 18 to 28 wt %, and Na2O+K2O is 0.05 to 3.00 wt %. The glass has a log 10 viscosity temperature in the temperature range of 1328° F. (720° C.) to 1499° F. (815° C.); a liquidus temperature in the temperature range of 2437° F. (1336° C.) to 2575° F. (1413° C.), and a log 7.6 softening point temperature in the temperature range of 1544° F. (840° C.) to 1724° F. (940° C.). The chemically tempered glass has, among other properties, an abraded modulus of rupture of 72 to 78 KPSI, and a modulus of rupture of 76 to 112 KPSI.Type: ApplicationFiled: December 13, 2010Publication date: April 7, 2011Applicant: SCHOTT AGInventors: LARRY J. SHELESTAK, GEORGE B. GOODWIN, AMARENDRA MISHRA, JAMES M. BALDAUFF
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Patent number: 7871703Abstract: A glass composition for chemical tempering includes oxides in wt % ranges of: SiO2 60 to 75; Al2O3 18 to 28; Li2O 3 to 9; Na2O 0 to 3; K2O 0 to 0.5; CaO 0 to 3; MgO 0 to 3; ZrO2 0 to 3; where MgO+CaO is 0 to 6 wt %; Al2O3+ZrO2 is 18 to 28 wt %, and Na2O+K2O is 0.05 to 3.00 wt %. The glass has a log 10 viscosity temperature in the temperature range of 1328° F. (720° C.) to 1499° F. (815° C.); a liquidus temperature in the temperature range of 2437° F. (1336° C.) to 2575° F. (1413° C.), and a log 7.6 softening point temperature in the temperature range of 1544° F. (840° C.) to 1724° F. (940° C.). The chemically tempered glass has, among other properties, an abraded modulus of rupture of 72 to 78 KPSI, and a modulus of rupture of 76 to 112 KPSI.Type: GrantFiled: June 26, 2009Date of Patent: January 18, 2011Assignee: Schott AGInventors: Larry J. Shelestak, George B. Goodwin, Amarendra Mishra, James M. Baldauff
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Patent number: 7825051Abstract: A glass composition is disclosed. The glass composition includes base glass composition including SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent, and BaO from 0 to 1 weight percent, and a colorant and property modifying portion including total iron from up to 0.02 weight percent, CeO2 from 0.05 weight percent to 1.5 weight percent, CoO up to 50 PPM, Se up to 15 PPM, Cr2O3 up to 500 PPM, CuO up to 0.5 weight percent, V2O5 up to 0.3 weight percent, TiO2 up to 1 weight percent, NiO up to 200 PPM, Er2O3 up to 3 weight percent, MnO2 up to 0.6 weight percent, and Nd2O3 up to 2 weight percent, wherein the glass composition has a redox ratio up to 0.55.Type: GrantFiled: January 12, 2006Date of Patent: November 2, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Dennis G. Smith, Larry J. Shelestak
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Publication number: 20100233407Abstract: An aircraft transparency in a glass piece, wherein the glass piece includes a chemically tempered first major surface and a chemically tempered opposite second major surface, a first case depth begins at the first major surface, a second case depth begins at the second major surface, and a tensile stress zone is within the glass piece between the end points of the first and the second case depths. The glass between the end points of the first and second case depth has a glass composition including: Ingredient Percent by weight SiO2 60 to 75; Al2O3 18 to 28; and Li2O 3 to 9, and the glass has at least one of the following properties (a) a log 10 viscosity temperature of at least 1413° F. and (b) a liquidus temperature of at least 2436° F.Type: ApplicationFiled: May 28, 2010Publication date: September 16, 2010Applicant: PPG INDUSTRIES OHIO, INC.Inventors: Larry J. Shelestak, George B. Goodwin, Amarendra Mishra, James M. Baldauff
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Patent number: 7727917Abstract: A glass composition for chemical tempering includes oxides in wt % ranges of: SiO2 60 to 75; Al2O3 18 to 28; Li2O 3 to 9; Na2O 0 to 3; K2O 0 to 0.5; CaO 0 to 3; MgO 0 to 3; ZrO2 0 to 3; where MgO+CaO is 0 to 6 wt %; Al2O3+ZrO2 is 18 to 28 wt %, and Na2O+K2O is 0.05 to 3.00 wt %. The glass has a log 10 viscosity temperature in the temperature range of 1328° F. (720° C.) to 1499° F. (815° C.); a liquidus temperature in the temperature range of 2437° F. (1336° C.) to 2575° F. (1413° C.), and a log 7.6 softening point temperature in the temperature range of 1544° F. (840° C.) to 1724° F. (940° C.). The chemically tempered glass has, among other properties, an abraded modulus of rupture of 72 to 78 KPSI, and a modulus of rupture of 76 to 112 KPSI.Type: GrantFiled: October 1, 2004Date of Patent: June 1, 2010Assignee: Schott AGInventors: Larry J. Shelestak, George B. Goodwin, Amarendra Mishra, James M. Baldauff