Abstract: A soda-lime-silica glass for solar collector cover plates and solar mirrors has less than 0.010 weight percent total iron as Fe2O3, a redox ratio of less than 0.350, less than 0.0025 weight percent CeO2, and spectral properties that include a visible transmission, and a total solar infrared transmittance, of greater than 90% at a thickness of 5.5 millimeters, and reduced solarization. In one non-limiting embodiment of invention, the glass is made by heating a pool of molten soda-lime-silica with a mixture of combustion air and fuel gas having an air firing ratio of greater than 11, or an oxygen firing ratio of greater than 2.31. In another non-limiting embodiment of the invention, streams of oxygen bubbles are moved through a pool of molten glass. In both embodiments, the oxygen oxidizes ferrous iron to ferric iron to reduce the redox ratio.

Abstract: A glass composition for forming a blue colored glass is disclosed. The glass composition is made up of a base glass portion, iron oxide, and at least one first additive compound selected from Nd2O3 in an amount up to 1 weight percent and/or CuO in an amount up to 0.5 weight percent. The base glass portion has the following components: SiO2 from 66 to 75 weight percent; Na2O from 10 to 20 weight percent; CaO from 5 to 15 weight percent; MgO from 0 to 5 weight percent; Al2O3 from 0 to 5 weight percent; B2O3 from 0 to 5 weight percent; and K2O from 0 to 5 weight percent. The total iron in the glass composition ranges from 0.3 to 1.2 weight percent, and the glass composition has a redox ratio ranging from 0.15 to 0.65.

Abstract: A glass composition that includes a base glass composition including: SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent, and a colorant and property modifying portion including total iron ranging from of equal to or less than 0.6 weight percent; and TiO2 ranging from 0.1 to 1.0 weight percent, wherein the redox ratio ranges from 0.33 to 0.45 and the weight percents are based on the total weight of the composition.

Abstract: A glass composition that includes a base glass composition including: SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent and BaO 0 to 1 weight percent, and a colorant and property modifying portion including total iron from 0.25 to 0.9 weight percent, Cr2O3 from 6 PPM to 400 PPM, Er2O3 from 0.3 to 3.0 weight percent, and TiO2 from 0.1 to 0.8 weight percent, wherein the glass composition has a redox ratio ranging from 0.15 to 0.62.

Abstract: The present invention provides a blue glass that can be essentially free of selenium and cobalt but still has a blue color and desired luminous transmittance. Additionally, the amount of iron present is comparable to conventional soda-lime-silica glass. The glass of the present invention can have a soda-lime-silica glass base portion, with major colorants that provide the blue color.

Abstract: A glass composition for chemical tempering includes oxides in wt % ranges of: SiO2 60 to 75; Al2O3 18 to 28; Li2O 3 to 9; Na2O 0 to 3; K2O 0 to 0.5; CaO 0 to 3; MgO 0 to 3; ZrO2 0 to 3; where MgO+CaO is 0 to 6 wt %; Al2O3+ZrO2 is 18 to 28 wt %, and Na2O+K2O is 0.05 to 3.00 wt %. The glass has a log 10 viscosity temperature in the temperature range of 1328° F. (720° C.) to 1499° F. (815° C.); a liquidus temperature in the temperature range of 2437° F. (1336° C.) to 2575° F. (1413° C.), and a log 7.6 softening point temperature in the temperature range of 1544° F. (840° C.) to 1724° F. (940° C.). The chemically tempered glass has, among other properties, an abraded modulus of rupture of 72 to 78 KPSI, and a modulus of rupture of 76 to 112 KPSI.

Abstract: A glass composition that includes a base glass composition including: SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent and BaO from 0 to 1 weight percent, and a colorant and property modifying portion including total iron from 0.5 to 0.8 weight percent, Er2O3 from 0.05 to 0.5 weight percent, Se from 1 PPM to 4 PPM, and CoO from 1 PPM to 15 PPM, wherein the glass composition has a redox ratio ranging from 0.25 to 0.35.

Abstract: A novel glass composition is disclosed. The glass composition includes a base glass composition made up of SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent, B2O3 0 to 5%, and MnO2 0 to 0.5%, and a colorant and property modifying material portion made up of total iron up to 0.65 weight percent, Se ranging from 2 PPM to 10 PPM, at least one UV absorber selected from CeO2, V2O5, TiO2 and MoO3, CoO up to 20 PPM, and Cr2O3 up to 75 PPM, wherein the glass composition has a redox ratio ranging from 0.2 to 0.6.

Abstract: A method for modifying the appearance of a substrate is disclosed. The method includes providing a substrate having first and second opposing surfaces and depositing a reflectance modifying coating on at least a portion of the first surface of the substrate, wherein the second surface has a visible light reflectance (R1) ranging from 5 to 20 percent.

Abstract: A neutral gray colored glass composition for automotive vision panels having reduced transmitted color shift characteristics is provided. The glass composition has a base portion including 65 to 75 weight percent SiO2, 10 to 20 weight percent Na2O, 5 to 15 weight percent CaO, 0 to 5 weight percent MgO, 0 to 5 weight percent Al2O3, and 0 to 5 weight percent K2O. The composition also includes major colorants including 0.30 to 0.75 weight percent Fe2O3, 0 to 15 ppm CoO, and 1 to 15 ppm Se. The glass has a luminous transmittance of at least 65 percent at a thickness of 3.9 mm, a redox ratio of 0.2 to 0.675, a TSET of less than or equal to 65 percent, and a standard color shift of less than 6.

Abstract: A blue colored, infrared and ultraviolet absorbing glass composition having a luminous transmittance of up to 60 percent can form transparent glass panel sets for mounting in automobiles. A non-limiting glass composition includes a standard soda-lime-silica glass base composition and a solar radiation absorbing and colorant portion having 0.9 to 2.0 percent by weight total iron, 0.15 to 0.65 percent by weight FeO, 90 to 250 PPM CoO, and optionally up to 12 PPM Se and up to 0.9 wt % TiO2, and preferably 1 to 1.4 percent by weight total iron, 0.20 to 0.50 percent by weight FeO, 100 to 150 PPM CoO, up to 8 PPM Se, and up to 0.5 wt % TiO2, at a thickness of 0.160 inches (4.06 millimeters) the glass has a dominant wavelength in the range of 480 to 489 nanometers and an excitation purity of at least 8 percent.

Abstract: A method is provided for adjusting, e.g., lowering, the melting and/or forming temperatures of a glass composition without substantially changing the bending and annealing temperatures of the glass composition. The method includes increasing the amount of CaO and decreasing the amount of MgO in the glass composition by the same or about the same amount.

Abstract: A blue-green colored glass composition includes a base portion, such as a conventional soda-lime-silica base, and major colorants. In one embodiment, the major colorants include 0.7 to 0.9 weight percent total iron (Fe2O3), 0.2 to 0.3 weight percent FeO, and 0 to 5 ppm CoO. The glass is characterized by a dominant wavelength in the range of 490 nm to 495 nm and an excitation purity in the range of 3% to 11%. The glass of the invention can be essentially free of Se.

Abstract: A blue-green colored glass composition includes a base portion, such as a conventional soda-lime-silica base, and major colorants. In one embodiment, the major colorants include 0.7 to 0.9 weight percent total iron (Fe2O3), 0.2 to 0.3 weight percent FeO, and 0 to 5 ppm CoO. The glass is characterized by a dominant wavelength in the range of 490 nm to 495 nm and an excitation purity in the range of 3% to 11%. The glass of the invention can be essentially free of Se.

Abstract: The present invention provides a high redox, ultraviolet and/or infrared absorbing radiation absorbing, and colored glass using a standard soda-lime-silica glass base composition and additionally at least on essential solar absorbing and colorant set of components. The solar absorbing flat glass article has two opposing major surfaces with a thickness of 1.5 to 12 mm. and a redox value in the range of greater than 0.38 to about 0.6, a retained sulfate measured as (SO3) value in the range of greater than 0.005 to less than 0.18 weight percent, and is essentially free of coloration from inorganic polysulfides.

Abstract: The present invention provides a blue colored, infrared and ultraviolet absorbing glass composition having a luminous transmittance of up to 60 percent. The glass uses a standard soda-lime-silica glass base composition and additionally iron and cobalt, and optionally selenium and/or titanium, as infrared and ultraviolet radiation absorbing materials and colorants. The glass of the present invention has a color characterized by a dominant wavelength in the range of 480 to 489 nanometers and an excitation purity of at least 8 percent at a thickness of 0.160 inches (4.06 millimeters). In one embodiment of the invention, the glass composition of a blue colored, infrared and ultraviolet radiation absorbing soda-lime-silica glass article includes a solar radiation absorbing and colorant portion consisting essentially of 0.9 to 2.0 percent by weight total iron, 0.15 to 0.65 percent by weight FeO, 90 to 250 PPM CoO, and optionally up to 12 PPM Se and up to 0.9 wt % TiO2, and preferably 1 to 1.

Abstract: A neutral gray colored glass composition for automotive vision panels having reduced transmitted color shift characteristics is provided. The glass composition has a base portion including 65 to 75 weight percent SiO2, 10 to 20 weight percent Na2O, 5 to 15 weight percent CaO, 0 to 5 weight percent MgO, 0 to 5 weight percent Al2O3, and 0 to 5 weight percent K2O. The composition also includes major colorants including 0.30 to 0.75 weight percent Fe2O3, 0 to 15 ppm CoO, and 1 to 15 ppm Se. The glass has a luminous transmittance of at least 65 percent at a thickness of 3.9 mm, a redox ratio of 0.2 to 0.675, a TSET of less than or equal to 65 percent, and a standard color shift of less than 6.

Abstract: Glass is made from batch components having a source of ferrous iron to increase the starting amount of ferrous iron in the glass batch. The ferrous iron source is an iron silicate material, such as fayalite (2FeO.SiO2), iron garnet (3FeO.Fe2O3.3SiO2) magnesium-iron olivine (2(Mg,Fe)O.SiO2), grunerite (6FeO.8SiO2FeOH)2, actinolite (CaO.3(Mg,Fe)O.4SiO2) or iron rich anthophyllite ((Mg,Fe)O.SiO2). The presence of the ferrous iron source in the glass batch components decreases or eliminates the amount of coal and also leads to a glass article having a redox ratio greater than about 0.25.

Abstract: The present invention provides a green tinted, ultraviolet absorbing, soda lime silica glass having a luminous transmittance of at least 70 percent and ultraviolet transmittance of no more than 38 percent at thickness ranging from 0.154 to 0.189 inches (3.9 to 4.9 mm). These properties are achieved in the present invention by using a colorant portion that is either (a) greater than 0.6 percent by weight total iron (expressed as Fe2O3) with a redox (FeO/total iron) of from 0.275 to less than 0.35 or (b) from greater than 0.6 to 0.85 percent by weight total iron with a redox of less than 0.35. It is preferred that the glass have a dominant wavelength of 495 to 535 nanometers.

Abstract: The present invention provides a blue colored, infrared and ultraviolet absorbing glass composition having a luminous transmittance of up to 60 percent. This glass composition can form transparent glass panels that have varying limited LTA from one another as panel sets for mounting in automobiles. The glass uses a standard soda-lime-silica glass base composition and additionally iron and cobalt, and optionally selenium and/or titanium, as infrared and ultraviolet radiation absorbing materials and colorants. The glass of the present invention has a color characterized by a dominant wavelength in the range of 480 to 489 nanometers and an excitation purity of at least 8 percent at a thickness of 0.160 inches (4.06 millimeters). In one embodiment of such a blue colored, infrared and ultraviolet radiation absorbing soda-lime-silica glass article includes a solar radiation absorbing and colorant portion having 0.9 to 2.0 percent by weight total iron, 0.15 to 0.