Abstract: Braze materials and processes for using braze materials, such as for use in the manufacturing, coating, repair, and build-up of superalloy components. The braze material contains a plurality of first particles of a metallic material having a melting point, and a plurality of second particles comprising at least one nonmetallic material chosen from the group consisting of oxides, carbides, and nitrides of at least one metal. The nonmetallic material is more susceptible to heating by microwave radiation than the metallic material of the first particles, and the nonmetallic material is present in the braze material in an amount sufficient to enable the first particles to completely melt when the first and second particles are subjected to heating by microwave radiation.

Abstract: A casting apparatus is presented. The casting apparatus includes a first chamber and a second chamber. The first chamber includes a crucible and a sealed discharge outlet. The second chamber includes a casting mold for casting a plurality of filaments of a superalloy composition. The second chamber further includes a discharge inlet aligned with the sealed discharge outlet of the first chamber. The casting apparatus further includes a first port for applying a positive pressure to the first chamber and a second port for applying a vacuum to the second chamber. The sealed discharge outlet includes a hermetic seal comprising a material having a melting temperature equal to or greater than a melting temperature of the superalloy composition.

Abstract: A system for repairing a crack in a component, or forming a joint between two components, is described. The system includes a filler material; a plasma-generating material; and a ceramic cover that is positioned around the crack, or around an interface region between two components that are to be joined. The filler material is positioned proximate to the crack or the interface region; and the plasma generating material is positioned in the vicinity of the crack or the interface region. A microwave generator for generating a microwave field inside an enclosure region enclosed by the cover, and proximate to the crack or interface region, also forms part of the system. Related methods for filling at least one cavity in a casting component are also described.

Abstract: One embodiment is a method. The method includes providing a casting apparatus including a first chamber and a second chamber, wherein the first chamber is isolated from the second chamber. The method includes charging a superalloy composition into a crucible present in the first chamber and melting the superalloy composition in the crucible to form a molten superalloy composition. The method includes discharging the molten superalloy composition into a casting mold present in the second chamber; applying a positive pressure to the first chamber to create a first chamber pressure; and applying a vacuum to the second chamber to create a second chamber pressure, wherein the first chamber pressure is greater than the second chamber pressure. The method further includes casting at least one filament from the molten superalloy composition in the casting mold. An apparatus for casting a plurality of filaments is also provided.

Abstract: A braze material and processes for making and using the material, such as for use in the manufacturing, coating, repair, and build-up of superalloy components. The braze material is composed of particles with melt-modifying constituents that are limited to the surfaces of the particles, yet are capable of sufficiently promoting the heating of the particles by conventional means and microwave radiation to achieve at least partial melting of the particles. The melt-modifying constituents are in the form of particulates embedded in the outer surface region of each particle. The particulates are formed of melting point depressant(s) and/or microwave coupling enhancer(s), are much smaller than the particle in which they are embedded.

Abstract: A gamma prime nickel-base superalloy and components formed therefrom that exhibit improved high-temperature dwell capabilities, including creep and hold time fatigue crack growth behavior. A particular example of a component is a powder metallurgy turbine disk of a gas turbine engine. The gamma-prime nickel-base superalloy contains, by weight, 16.0 to 30.0% cobalt, 11.5 to 15.0% chromium, 4.0 to 6.0% tantalum, 2.0 to 4.0% aluminum, 1.5 to 6.0% titanium, up to 5.0% tungsten, 1.0 to 7.0% molybdenum, up to 3.5% niobium, up to 1.0% hafnium, 0.02 to 0.20% carbon, 0.01 to 0.05% boron, 0.02 to 0.10% zirconium, the balance essentially nickel and impurities, wherein the titanium:aluminum weight ratio is 0.5 to 2.0.

Abstract: A gamma prime nickel-base superalloy and components formed therefrom that exhibit improved high-temperature dwell capabilities, including creep and hold time fatigue crack growth behavior. A particular example of a component is a powder metallurgy turbine disk of a gas turbine engine. The gamma-prime nickel-base superalloy contains, by weight, 18.0 to 30.0% cobalt, 11.4 to 16.0% chromium, up to 6.0% tantalum, 2.5 to 3.5% aluminum, 2.5 to 4.0% titanium, 5.5 to 7.5% molybdenum, up to 2.0% niobium, up to 2.0% hafnium, 0.04 to 0.20% carbon, 0.01 to 0.05% boron, 0.03 to 0.09% zirconium, the balance essentially nickel and impurities, wherein the titanium:aluminum weight ratio is 0.71 to 1.60.

Abstract: A brazing process and assembly utilizing microwave radiation and a plasma generator that is heated by microwave radiation and generates a localized plasma capable of selectively heating and melting a braze alloy. The plasma generator contains a microwave-susceptible material that is susceptible to heating by microwave radiation, and a plasma-generating material capable of volatilizing and generating the plasma when the plasma generator is subjected to heating and microwave radiation. The brazing process includes applying a braze material to a surface of a substrate, positioning the plasma generator in proximity to the braze material, and then subjecting the plasma generator to microwave radiation to volatilize the plasma-generating material and generate a plasma that melts the braze alloy within the braze material.

Abstract: A refractory composition is described, containing niobium, silicon, titanium, and at least one of rhenium and ruthenium. The amount of silicon in the composition is at least about 9 atom %, and the amount of titanium present is less than about 26 atom %, based on total atomic percent. Turbine engine components formed from such a composition are also disclosed.

Abstract: A nickel-based braze composition is described, containing nickel, palladium, and restricted amounts of boron and silicon. The composition can also contain tantalum, titanium, and zirconium, as well as aluminum, chromium, and cobalt. A method for joining two metal components, using the braze composition, is also described. The braze composition can also be used to fill cracks or other cavities in a component, e.g., a gas turbine part formed from a nickel-based superalloy. Articles of manufacture which contain the braze composition are also described.

Abstract: A turbine component formed from a niobium silicide-based composition is described. The component can be compositionally-graded through at least a portion of its structure. A turbine blade formed from a composition which includes a niobium silicide alloy is also described. The blade includes an airfoil; an airfoil tip region; a platform on which the airfoil is mounted; and a dovetail root attached to an underside of the platform. The niobium silicide alloy in at least one portion of the turbine blade is compositionally different from the niobium silicide alloy in another portion of the blade. Processes for fabricating a niobium silicide-based turbine article are also described, using laser cladding techniques. Repair methods are also set forth in the application.

Abstract: Various braze alloy compositions are described, along with methods for using them. In one instance, a boron-free, high-temperature braze alloy includes selected amounts of chromium, hafnium, and nickel. The braze alloy can be used, for example, as a component in a wide gap braze mixture where a higher or lower melting point superalloy and/or brazing powder is used. The braze alloys may permit joining or repairing of superalloy articles with complex shapes, and may be used in high temperature applications. In some other braze alloy embodiments, a nickel- or cobalt-based braze composition can contain selected amounts of boron, but includes restricted amounts of chromium.

Abstract: A braze formulation for superalloys including nickel, chromium, optionally, cobalt, optionally, aluminum, optionally, boron, hafnium and tantalum, said braze formulation having a solidus temperature of no greater than about 1180° C. and a liquidus temperature of no greater than about 1250° C. Methods for brazing are also provided. The brazing formulations are robust with good ductility and have minimal embrittled phases or otherwise decreased braze integrity.

Abstract: Braze compositions containing flux compositions and processes for using such braze compositions, such as for use in the manufacturing, coating, repair, and build-up of superalloy components. The braze composition contains an aqueous binder system, multiple inorganic compounds, titanium hydride, and a metallic braze alloy. The braze composition is useful when brazing superalloys that are prone to oxidation at elevated brazing temperatures.

Abstract: A process for heating powder materials by microwave radiation so that heating and sintering or melting progressively and directionally occurs within the powder materials. The process generally entails forming a structure from a powder by arranging the powder in a mass according to size of particles of the powder so that the particles are progressively arranged within at least a region of the mass from smallest to largest. The mass is then subjected to microwave radiation so that the particles within the mass progressively couple with the microwave radiation according to size, the smallest particles coupling first and heating faster than larger particles of the powder, and the largest particles coupling last and heating slower than smaller particles of the powder. As a result of the progressive arrangement of the particles, the mass is progressively and directionally heated by the microwave radiation.

Abstract: A process and apparatus for brazing a metal alloy component, such as a superalloy component of a gas turbine engine. The process employs a plasma torch in a non-transferred arc mode to generate an electric arc between an electrode and a housing in which an orifice is defined. A plasma gas is flowed through the arc so as to ionize the plasma gas, and the resulting ionized plasma gas is discharged through the orifice to form a plasma jet. The plasma torch is configured so that the plasma jet is shrouded from a surrounding oxidizing atmosphere by a shielding gas flowing cocurrently with the plasma jet. A braze alloy material is introduced into the plasma jet, which is directed at a surface of the component to form a brazement that is metallurgically bonded to the component without melting the component.

Abstract: Braze materials and processes for using braze materials, such as for use in the manufacturing, coating, repair, and build-up of superalloy components. The braze material contains a plurality of first particles of a metallic material having a melting point, and a plurality of second particles comprising at least one nonmetallic material chosen from the group consisting of oxides, carbides, and nitrides of at least one metal. The nonmetallic material is more susceptible to heating by microwave radiation than the metallic material of the first particles, and the nonmetallic material is present in the braze material in an amount sufficient to enable the first particles to completely melt when the first and second particles are subjected to heating by microwave radiation.

Abstract: A process and apparatus for forming wires, such as wires used as feedstock in welding, brazing, and coating deposition processes. The process and apparatus generally entail feeding through a passage a quantity of powder particles of a size and composition that render the particles susceptible to microwave radiation. As the particles travel through the passage, the particles within the passage are subjected to microwave radiation so that the particles couple with the microwave radiation and are sufficiently heated to melt at least a radially outermost quantity of particles within the passage. The particles are then cooled so that the radially outermost quantity of particles solidifies to yield a wire having a consolidated outermost region surrounding an interior region of the wire.

Abstract: A braze material and processes for making and using the material, such as for use in the manufacturing, coating, repair, and build-up of superalloy components. The braze material is composed of particles with melt-modifying constituents that are limited to the surfaces of the particles, yet are capable of sufficiently promoting the heating of the particles by conventional means and microwave radiation to achieve at least partial melting of the particles. The melt-modifying constituents are in the form of particulates embedded in the outer surface region of each particle. The particulates are formed of melting point depressant(s) and/or microwave coupling enhancer(s), are much smaller than the particle in which they are embedded.

Abstract: A process for forming a coating on a surface of a substrate, so that heating of the coating material is selective and sufficient to cause at least partial melting of the coating material and permit bonding to the substrate without excessively heating the substrate so as not to significantly degrade its properties. The process generally entails forming a brazing paste containing powder particles dispersed in a binder. The particles are formed of a composition that is susceptible to microwave radiation. The brazing paste is then applied to the surface of the substrate and subjected to microwave radiation so that the particles couple with the microwave radiation and are sufficiently heated to burn off the binder and then at least partially melt to form an at least partially molten layer on the substrate. The microwave radiation is then interrupted to allow the at least partially molten layer to cool, solidify, and form the coating.