Abstract: A nickel-based braze composition is described, containing nickel, palladium, and restricted amounts of boron and silicon. The composition can also contain tantalum, titanium, and zirconium, as well as aluminum, chromium, and cobalt. A method for joining two metal components, using the braze composition, is also described. The braze composition can also be used to fill cracks or other cavities in a component, e.g., a gas turbine part formed from a nickel-based superalloy. Articles of manufacture which contain the braze composition are also described.

Abstract: A process for heating powder materials by microwave radiation so that heating and sintering or melting progressively and directionally occurs within the powder materials. The process generally entails forming a structure from a powder by arranging the powder in a mass according to size of particles of the powder so that the particles are progressively arranged within at least a region of the mass from smallest to largest. The mass is then subjected to microwave radiation so that the particles within the mass progressively couple with the microwave radiation according to size, the smallest particles coupling first and heating faster than larger particles of the powder, and the largest particles coupling last and heating slower than smaller particles of the powder. As a result of the progressive arrangement of the particles, the mass is progressively and directionally heated by the microwave radiation.

Abstract: A process for heating a powder material by microwave radiation so that heating of the powder material is selective and sufficient to cause complete melting of the particles. The process entails providing a mass of powder comprising a quantity of filler particles of a metallic composition, and subjecting the mass to microwave radiation so that the filler particles within the mass couple with the microwave radiation and are completely melted. According to one aspect, the mass further contains at least one constituent that is more highly susceptible to microwave radiation than the filler particles, and the filler particles are melted as a result of heating by microwave radiation and thermal contact with the at least one constituent. According to another aspect, the powder mass is thermally pretreated to induce an irreversible increase in its dielectric loss factor prior to melting by microwave irradiation.

Abstract: A shell mold for casting molten material to form an article is described. The mold includes a shell for containing the molten material, formed from at least one of yttrium silicates, zirconium silicates, hafnium silicates, and rare earth silicates. The mold also includes a facecoat disposed on an inner surface of the shell that contacts the molten material. The facecoat can be made from the materials described above. A method of casting a niobium-silicide article is also described, using the shell mold described herein. A method of making the ceramic shell mold is described as well, along with a slurry composition used in the manufacture of the shell mold.

Abstract: A refractory composition is described, containing niobium, silicon, titanium, and at least one of rhenium and ruthenium. The amount of silicon in the composition is at least about 9 atom %, and the amount of titanium present is less than about 26 atom %, based on total atomic percent. Turbine engine components formed from such a composition are also disclosed.

Abstract: A turbine component formed from a niobium silicide-based composition is described. The component can be compositionally-graded through at least a portion of its structure. A turbine blade formed from a composition which includes a niobium silicide alloy is also described. The blade includes an airfoil; an airfoil tip region; a platform on which the airfoil is mounted; and a dovetail root attached to an underside of the platform. The niobium silicide alloy in at least one portion of the turbine blade is compositionally different from the niobium silicide alloy in another portion of the blade. Processes for fabricating a niobium silicide-based turbine article are also described, using laser cladding techniques. Repair methods are also set forth in the application.

Abstract: A nickel-based high-temperature braze alloy composition includes Cr, Hf, and B. Furthermore, a cobalt-based high-temperature braze alloy composition includes Cr, Hf, and B. The braze alloys can be used, for example, as a single homogenous braze. The braze alloys can also be used, for example, as a component in a wide gap braze mixture where higher or lower melting point superalloy and/or brazing powder is used. The braze alloys may permit joining/repairing of superalloy articles with complex shape and may be used in high temperature applications.

Abstract: A method for removing an oxide material from a crack in a substrate, the method includes: applying a slurry paste comprising a fluoride salt to the crack; heating the slurry paste and the crack to at least a melting point of the fluoride salt to form a reaction product; and removing the reaction product.

Abstract: A refractory composition comprising niobium and silicon is disclosed. The amount of silicon present is less than about 9 atom %, based on total atomic percent for the composition. A turbine engine component (e.g., a gas turbine) is also described herein. The component comprises an alloy of niobium and silicon, wherein the amount of silicon present is less than about 9 atom %.

Abstract: A shell mold for casting molten material to form an article is described. The mold includes a shell for containing the molten material, formed from at least one of yttrium silicates, zirconium silicates, hafnium silicates, and rare earth silicates. The mold also includes a facecoat disposed on an inner surface of the shell that contacts the molten material. The facecoat can be made from the materials described above. A method of casting a niobium-silicide article is also described, using the shell mold described herein. A method of making the ceramic shell mold is described as well, along with a slurry composition used in the manufacture of the shell mold.

Abstract: A process for repairing a turbine component comprises overlaying a preform of a brazing material onto a surface of the turbine component, wherein the surface comprises a damaged portion; securing the preform of a brazing material to the surface; and heating the turbine component to a temperature effective to form a brazed joint between the brazing material and the turbine component. Also disclosed is a repaired turbine component repaired by the process.

Abstract: A process for repairing a turbine component comprises overlaying a preform of a brazing material onto a surface of the turbine component, wherein the surface comprises a damaged portion; securing the preform of a brazing material to the surface; and heating the turbine component to a temperature effective to form a brazed joint between the brazing material and the turbine component. Also disclosed is a repaired turbine component repaired by the process.

Abstract: A method for removing an oxide material from a crack in a substrate, the method includes: applying a slurry paste comprising a fluoride salt to the crack; heating the slurry paste and the crack to at least a melting point of the fluoride salt to form a reaction product; and removing the reaction product.

Abstract: A nickel-based braze composition is described, containing nickel, palladium, and restricted amounts of boron and silicon. The composition can also contain tantalum, titanium, and zirconium, as well as aluminum, chromium, and cobalt. A method for joining two metal components, using the braze composition, is also described. The braze composition can also be used to fill cracks or other cavities in a component, e.g., a gas turbine part formed from a nickel-based superalloy. Articles of manufacture which contain the braze composition are also described.