Abstract: A three dimensional glass ceramic article with a thickness between 0.1 mm and 2 mm, having a dimensional precision control of less than or equal to ±0.1 mm. A method for forming a three dimensional glass ceramic article including placing a nucleated glass article into a mold, and heating the nucleated glass article to a crystallization temperature, where the nucleated glass article is in the mold during the heating. Then, holding the nucleated glass article at the crystallization temperature for a duration sufficient to crystallize the nucleated glass article and form a three dimensional glass ceramic article, where the nucleated glass article is in the mold during the holding, and removing the three dimensional glass ceramic article from the mold.

Abstract: Methods of manufacturing a glass-based article includes exposing a glass-based substrate having a lithium aluminosilicate composition to an ion exchange treatment to form the glass-based article. The ion exchange treatment including a molten salt bath having a concentration of a sodium salt in a range from 8 mol % to 100 mol %. The glass-based article includes sodium having a non-zero varying concentration extending from a surface of the glass-based article to a depth of the glass-based article The glass-based article has compressive stress layer extending from the surface to a spike depth of layer from 4 micrometers to 8 micrometers. The glass-based article includes a molar ratio of potassium oxide (K2O) to sodium oxide (Na2O) averaged over a distance from the surface to a depth of 0.4 micrometers that is greater than or equal to 0 and less than or equal to 1.8.

Abstract: A lithium containing glass article is provided. In aspects, the lithium containing glass article includes an intensity coupling profile including a plurality of coupling resonances. A first of the coupling resonances has a half-width half-maximum value that is at least 1.8 times greater than the half-width half-maximum value of a second of the coupling resonances. In aspects, the lithium containing glass article includes a smoothed intensity coupling profile including a plurality of coupling resonances. A second derivative of the smoothed intensity coupling profile at a first of the coupling resonances is at least 1.8 times greater than a second derivative of the smoothed coupling profile at a second of the coupling resonances.

Abstract: Methods for regenerating a salt bath composition include heating the salt bath composition to an ion exchange temperature to form a molten salt bath. The methods may further include contacting at least a portion of an ion-exchangeable article that includes lithium oxide (Li2O) with the molten salt bath. Lithium cations may diffuse from the ion-exchangeable article and into the molten salt bath. Additionally, the methods may include adding a first phosphate salt to the molten salt bath. A lithium phosphate salt that includes at least a portion of the lithium cations may be formed and precipitate from the molten salt bath. Furthermore, the methods may include adding a multivalent salt that includes a multivalent metal cation to the molten salt bath. A second phosphate salt that includes the multivalent metal cation may be formed and precipitate from the molten salt bath.

Abstract: Glass-based articles comprise stress profiles providing improved scratch resistance. A glass-based article comprises a lithium aluminosilicate composition and a molar ratio of potassium oxide (K2O) to sodium oxide (Na2O) averaged over a distance from the surface to a depth of 0.4 micrometers that is greater than or equal to 0 and less than or equal to 1.8. The article comprises sodium having a non-zero varying concentration extending from a surface of the glass-based article to a depth of the glass-based article and a spike depth of layer that is greater than or equal to 4 micrometers and less than or equal to 8 micrometers. The article may comprise an average compressive stress of greater than or equal to 150 MPa over a depth from 15 micrometers to 40 micrometers.

Abstract: Glass-based articles comprise stress profiles providing improved fracture resistance. The stress profiles contain a high peak tension and a region with a high degree of negative curvature. The glass-based articles herein provide high fracture resistance after multiple drops.

Abstract: A transparent article is described herein that includes: a glass-ceramic substrate comprising first and second primary surfaces opposing one another and a crystallinity of at least 40% by weight; and an optical film structure disposed on the first primary surface. The optical film structure comprises a plurality of alternating high refractive index (RI) and low RI layers and a scratch-resistant layer. The article also exhibits an average photopic transmittance of greater than 80% and a maximum hardness of greater than 10 GPa, as measured by a Berkovich Hardness Test over an indentation depth range from about 100 nm to about 500 nm. The glass-ceramic substrate comprises an elastic modulus of greater than 85 GPa and a fracture toughness of greater than 0.8 MPa·?m. Further, the optical film structure exhibits a residual compressive stress of ?700 MPa and an elastic modulus of ?140 GPa.

Abstract: A method of reworking lithium containing ion exchanged glass articles is provided. The method includes a reverse ion exchange process that returns the glass article to approximately the composition of the glass from which the glass article was produced, before being subjected to ion exchange. The reworked glass articles exhibit a K2O concentration profile comprising a portion wherein a K2O concentration increases to a local K2O concentration maximum.

Abstract: Glass-based articles comprise stress profiles providing improved fracture resistance. The glass-based articles herein provide high fracture resistance after multiple drops.

Abstract: A method of forming a 3D glass article from a glass sheet includes locating the glass sheet on a mold assembly including a mold surface with a 3D surface profile corresponding to that of the 3D glass article. The glass sheet is heated to a forming temperature. The forming temperature is greater than a temperature of the mold surface. The heated glass sheet is forced onto the mold surface by applying a pressurized gas to a first surface of the glass sheet opposite the mold surface to conform the glass sheet to the mold surface with the glass sheet at the forming temperature that is greater than the temperature of the mold surface.

Abstract: An article comprises a first plate, a second plate and a cured adhesive layer. The first plate is made of a first chemically-strengthened glass-based material. The first plate comprises: a first major surface opposing a second major surface and a thickness equal to or greater than 0.4 mm and less than or equal to 3.0 mm. The second plate is made of a second chemically-strengthened transparent glass-based material. The second plate comprises: a first major surface opposing a second major surface and a thickness equal to or greater than 0.4 mm and less than or equal to 3.0 mm. The cured adhesive layer adheres a portion of the first major surface of the plate to the second major surface of the second plate. The second plate has an area equal to or less than 25% of the area of the first plate.

Abstract: Glass-based articles comprise stress profiles providing improved fracture resistance. The glass-based articles herein provide high fracture resistance after multiple drops.

Abstract: Glass-based articles, such as glass-ceramic articles, and the properties thereof are disclosed. In embodiments, the glass-based article may comprise the glass-based article has a phase assemblage comprising petalite and lithium disilicate.

Abstract: A cover glass article includes a glass body having a three-dimensional shape, an inside surface, and an outside surface. Each of the inside and outside surfaces has a surface roughness (Ra) less than 1 nm and is free of indentations having diameters larger than 150 ?m.

Abstract: A glass-ceramic article is provided that includes a surface passivation layer. The passivation layer is an oxide layer and has a thickness of greater than or equal to 20 nm to less than or equal to 200 nm and a RMS surface roughness of less than or equal to 3 nm. The surface passivation layer may be formed with a liquid phase deposition process. The glass-ceramic article may include an easy to clean layer disposed on the surface passivation layer, and the glass-ceramic article may be chemically strengthened. The glass-ceramic article may be used in a consumer electronic product.

Abstract: A process for forming a textured 3-D glass-based substrate includes texturing a first surface of a glass-based substrate and shaping the glass-based substrate into a three-dimensional shape. The surface profile of the substrate is non-planar. In some embodiments, texturing the first surface of the glass-based substrate provides the first surface with an average roughness of 10 nm to 2000 nm.

Abstract: A method for determining crystal phases of a glass ceramic sample, including the steps of applying energy to the sample using an excitation source, detecting raw Raman spectral energy that is given off by the sample using a detector, wherein the raw Raman spectral energy includes peak values, determining a plurality of predetermined energy peaks based off a composition of the sample, superimposing the plurality of predetermined energy peaks over the raw Raman spectral energy, applying a baseline value between each predetermined energy peak, subtracting the baseline value from the raw Raman spectral energy, calculating corrected peak values based on the raw Raman spectral energy and baseline value, and determining the crystal phases of the glass ceramic sample based on the corrected peak values.

Abstract: Ion-exchanged glass ceramic articles described herein have a stress that decreases with increasing distance according to a substantially linear function from a depth of about 0.07t to a depth of about 0.26t from the outer surface of the ion-exchanged glass ceramic article from a compressive stress to a tensile stress. The stress transitions from the compressive stress to the tensile stress at a depth of from about 0.18t to about 0.25t from the outer surface of the ion-exchanged glass ceramic article. An absolute value of a maximum compressive stress at the outer surface of the ion-exchanged glass article is from 1.8 to 2.2 times an absolute value of a maximum central tension (CT) of the ion-exchanged glass article, and the glass ceramic article has a fracture toughness of 1 MPa?m or more as measured according to the double cantilever beam method.

Abstract: Methods for regenerating poisoned salt bath comprising providing a salt bath comprising at least one of KNO3 and NaNO3, providing an ion-exchangeable substrate comprising lithium cations, contacting at least a portion of the ion-exchangeable substrate with the salt bath, whereby lithium cations in the salt bath diffuse from the ion-exchangeable substrate and are dissolved in the salt bath, and selectively precipitating dissolved lithium cations from the salt bath using phosphate salt. The methods further include preventing or reducing the formation of surface defects in the ion-exchangeable substrate by preventing or reducing the formation of crystals on the surface of the ion-exchangeable substrate upon removal from the salt bath.

Abstract: A method of reworking lithium containing ion exchanged glass articles is provided. The method includes a reverse ion exchange process that returns the glass article to approximately the composition of the glass from which the glass article was produced, before being subjected to ion exchange. The reworked glass articles exhibit a K2O concentration profile comprising a portion wherein a K2O concentration increases to a local K2O concentration maximum.