Publication number: 20140272607
Abstract: A substantially non-aqueous electrolyte solution includes an alkali metal salt, a polar aprotic solvent, and an organophosphorus compound of Formula IA, IB, or IC: where R1, R2, R3 and R4 are each independently hydrogen, halogen, alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heterocyclyl, heteroaryl, alkoxy, alkenoxy, alkynoxy, cycloalkoxy, aryloxy, heterocyclyloxy, heteroaryloxy, siloxyl, silyl, or organophosphatyl; R5 and R6 are each independently alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heterocyclyl, or heteroaryl; R7 is and R8, R9 and R10 are each independently alkyl, cycloalkyl, aryl, heterocyclyl, or heteroaryl; provided that if the organophosphorus compound is of Formula IB, then at least one of R5, and R6 are other than hydrogen, alkyl, or alkenyl; and if the organophosphorus compound is of Formula IC, then the electrolyte solution does not include 4-methylene-1,3-dioxolan-2-one or 4,5-dimethylene-1,3-dioxolan-2-one.
Type:
Application
Filed:
March 14, 2013
Publication date:
September 18, 2014
Applicant:
UCHICAGO ARGONNE LLC
Inventors:
Khalil Amine, Lu Zhang, Zhengcheng Zhang
Publication number: 20140234703
Abstract: An electro lye includes a compound of Formula I or IA: where each instance of R1 is independently H, alkyl, alkoxy, alkenyl, aryl, heteroaryl, or cycloalkyl; each instance of R2 is independently H, alkyl, alkoxy, alkenyl, aryl, heteroaryl, or cycloalkyl; each instance of R3 is independently H, alkyl, alkenyl, aryl, or cycloalkyl; each instance of R4 is independently H, halogen, CN, NO2, phosphate, alkyl, alkenyl, aryl, heteroaryl, or cycloalkyl; x is 1, 2, 3, 4, or 5; y is 1 or 2; and z is 0, 1, 2, 3, or 4.
Type:
Application
Filed:
July 20, 2012
Publication date:
August 21, 2014
Applicant:
UChicago Argonne, LLC
Inventors:
Lu Zhang, Zhengcheng Zhang, Khalil Amine