Patents by Inventor Makoto Dobashi

Makoto Dobashi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9307639
    Abstract: Present invention provides an electro-deposited copper foil having the equivalent low-profile surface as in a conventional low-profile electro-deposited copper foil and extremely large mechanical strength and a method for manufacturing the same. The electro-deposited copper foil is formed by depositing fine copper crystal grains having a small deviation of grain-diameter. The electro-deposited copper foil has a low-profile and glossy surface and has extremely large mechanical strength expressed by a tensile strength as received of 70 kgf/mm2 to 100 kgf/mm2 and has a tensile strength after heating (180° C. for 60 minutes) corresponding to 85% or more of the tensile strength as received. The electro-deposited copper foil is manufactured by electrolysis using a sulfuric acid base copper electrolytic solution containing a compound composed of a benzene ring having a sulfo group bonded thereto, a sulfonate of an active sulfur compound and a polymer of a quaternary ammonium salt having a cyclic structure.
    Type: Grant
    Filed: April 26, 2007
    Date of Patent: April 5, 2016
    Assignee: MITSUI MINING & SMELTING CO., LTD.
    Inventors: Hisao Sakai, Masaru Takahashi, Mitsuyoshi Matsuda, Makoto Dobashi
  • Publication number: 20150267305
    Abstract: An etchant composition may contain 100 parts by weight of an aqueous etchant containing an oxidant, an acid additive, and water and 5 to 40 parts by weight of an organic solvent having a viscosity lower than that of water. And the organic solvent may have a viscosity of 0.8 cP or less.
    Type: Application
    Filed: September 15, 2014
    Publication date: September 24, 2015
    Applicant: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Jae Hoon CHOI, Makoto Dobashi
  • Publication number: 20150156887
    Abstract: Disclosed herein are a method of forming an amorphous alloy film and a printed wiring board manufactured by the same. The amorphous alloy film may be formed on a copper foil as one of rust-proofing treatment methods of the copper foil to thereby simultaneously show and improve corrosion-resistance and conductivity, and the amorphous alloy film may be formed by the sputtering deposition method, such that high melting point materials may be manufactured as a thin film at a relatively low temperature and the amorphous alloy film having strong adhesion strength with a substrate may be obtained.
    Type: Application
    Filed: March 13, 2014
    Publication date: June 4, 2015
    Applicant: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Ji Sung Cho, Toshiko Yokota, Makoto Dobashi, Jin Gu Kim, Ichiro Ogura, Je Hong Kyoung
  • Publication number: 20150101848
    Abstract: Disclosed herein are a surface-treated copper foil, a copper-clad laminate plate including the same, a printed circuit board using the same, and a method for manufacturing the same. In detail, the copper-clad laminate plate according to one implementation embodiment of the present invention includes: carrier; a peel layer formed on the carrier; a copper-clad layer formed on the peel layer; and a surface-treated layer formed on the copper-clad layer, in which the surface-treated layer includes a thiol-based compound. Therefore, the present invention provides a printed circuit board capable of improving an adhesive force between a base and a copper-clad layer without treating a roughed surface by forming the surface-treated layer on the copper-clad layer.
    Type: Application
    Filed: September 19, 2014
    Publication date: April 16, 2015
    Applicant: SAMSUNG ELECTRO-MECHANICS CO., LTD.
    Inventors: Ji Sung CHO, Toshiko Yokota, Makoto Dobashi, Seung Min Baek, Ichiro Ogura, Eun Jung Lim, Yoon Su Kim, Sung Han
  • Patent number: 8722199
    Abstract: It is an object of the present invention to provide an electrodeposited copper foil which has a lower profile and a higher gloss than low-profile electrodeposited copper foil conventionally supplied in markets. For achieving this object, the present invention employs an electrodeposited copper foil which has a super low profile, the surface roughness (Rzjis) of the deposit side of lower than 1.0-micron meter, and the gloss [Gs(60-deg.)] thereof of not lower than 400 irrespective to its thickness. The present invention also provides a manufacturing method of an electrodeposited copper foil obtained by electrodeposition using a sulfuric acid base copper electrolytic solution obtained by adding 3-mercapto-1-propanesulfonic acid and/or bis(3-sulfopropyl)disulfide, a quaternary ammonium salt polymer having a cyclic structure, and chlorine.
    Type: Grant
    Filed: March 31, 2006
    Date of Patent: May 13, 2014
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Mitsuyoshi Matsuda, Hisao Sakai, Sakiko Tomonaga, Makoto Dobashi
  • Patent number: 8715836
    Abstract: It is an object to provide a surface-treated electro-deposited copper foil which has a low profile at a level equal to or excellent than that of low-profile surface-treated electro-deposited copper foils that have conventionally been supplied to the market and in which waviness affecting the straight line performance of wiring is small, and a method for manufacturing the same. In order to achieve this object, in the surface-treated electro-deposited copper foil, the maximum waviness height (Wmax) of the bonding surface to be bonded with an insulation layer-constituting material to be 0.05 ?m to 0.7 ?m, the maximum peak to valley height (PV) to be 0.05 to 1.5 ?m, and the surface roughness (Rzjis) to be 0.1 ?m to 1.0 ?m.
    Type: Grant
    Filed: March 9, 2007
    Date of Patent: May 6, 2014
    Assignee: Mitsui Mining & Smelting Co., Ltd
    Inventors: Makoto Dobashi, Mitsuyoshi Matsuda, Sakiko Tomonaga, Hisao Sakai, Tomohiro Sakata, Junshi Yoshioka, Jo Nishikawa, Takeo Taguchi
  • Patent number: 8419920
    Abstract: An object of the present invention is to provide a method for preparing a sulfuric acid base copper electrolytic solution used for formation of an electro-deposited copper film comprising a surface excellent in smoothness and gloss when formed by using the solution just after preparation and is prepared by using mono-sulfides. To achieve the object, a sulfuric acid base copper electrolytic solution is made to contain a sulfonated active sulfur compound, the bis(3-sulfopropyl)disulfide which is recommended for formation of a glossy electro-deposited copper film. And the bis(3-sulfopropyl)disulfide contained is obtained by converting a 3-mercapto-1-propanesulfonic acid into the bis(3-sulfopropyl)disulfide in an aqueous solution of the 3-mercapto-1-propanesulfonic acid by an oxidation reaction. In the oxidation reaction, an air bubbling method is preferably used to prevent oxidative decomposition of the 3-mercapto-1-propanesulfonic acid.
    Type: Grant
    Filed: October 2, 2007
    Date of Patent: April 16, 2013
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Sakiko Tomonaga, Makoto Dobashi, Junshi Yoshioka, Ayumu Tateoka, Mitsuyoshi Matsuda, Hisao Sakai
  • Patent number: 7811709
    Abstract: A negative electrode for a non-aqueous electrolyte secondary cell includes a current collector an, formed on a surface or both surfaces thereof, an active material structure containing an electroconductive material with a low capability of forming a compound with lithium, and the active material structure includes 5% to 80% by weight of active material particles containing a material having a high capability for forming a compound with lithium. The active material structure can include an active material layer containing the active material particles and a surface-covering layer on the active material layer.
    Type: Grant
    Filed: November 25, 2003
    Date of Patent: October 12, 2010
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Shinichi Musha, Hitohiko Honda, Yoshiki Sakaguschi, Kiyotaka Yasuda, Akihiro Modeki, Tomoyoshi Matsushima, Takeo Taguchi, Kazuko Taniguchi, Makoto Dobashi
  • Publication number: 20100089758
    Abstract: An object of the present invention is to provide a method for preparing a sulfuric acid base copper electrolytic solution used for formation of an electro-deposited copper film comprising a surface excellent in smoothness and gloss when formed by using the solution just after preparation and is prepared by using mono-sulfides. To achieve the object, a sulfuric acid base copper electrolytic solution is made to contain a sulfonated active sulfur compound, the bis(3-sulfopropyl)disulfide which is recommended for formation of a glossy electro-deposited copper film. And the bis(3-sulfopropyl)disulfide contained is obtained by converting a 3-mercapto-1-propanesulfonic acid into the bis(3-sulfopropyl)disulfide in an aqueous solution of the 3-mercapto-1-propanesulfonic acid by an oxidation reaction. In the oxidation reaction, an air bubbling method is preferably used to prevent oxidative decomposition of the 3-mercapto-1-propanesulfonic acid.
    Type: Application
    Filed: October 2, 2007
    Publication date: April 15, 2010
    Applicant: MITSUI MINING & SMELTING CO., LTD.
    Inventors: Sakiko Tomonaga, Makoto Dobashi, Junshi Yoshioka, Ayumu Tateoka, Mitsuyoshi Matsuda, Hisao Sakai
  • Publication number: 20100038115
    Abstract: It is an object of the present invention to provide an electrodeposited copper foil which has a lower profile and a higher gloss than low-profile electrodeposited copper foil conventionally supplied in markets. For achieving this object, the present invention employs an electrodeposited copper foil which has a super low profile, the surface roughness (Rzjis) of the deposit side of lower than 1.0-micron meter, and the gloss [Gs(60-deg.)] thereof of not lower than 400 irrespective to its thickness. The present invention also provides a manufacturing method of an electrodeposited copper foil obtained by electrodeposition using a sulfuric acid base copper electrolytic solution obtained by adding 3-mercapto-1-propanesulfonic acid and/or bis(3-sulfopropyl)disulfide, a quaternary ammonium salt polymer having a cyclic structure, and chlorine.
    Type: Application
    Filed: March 31, 2006
    Publication date: February 18, 2010
    Applicant: MITSUI MINING & SMELTING CO., LTD
    Inventors: Mitsuyoshi Matsuda, Hisao Sakai, Sakito Tomonaga, Makoto Dobashi
  • Publication number: 20090166213
    Abstract: An object of the present invention is to provide a production method which enables efficient production of an electro-deposited copper foil with further lower profile when compared to the low-profile electro-deposited copper foils which have been supplied to the market and is excellent in mechanical strength. For the purpose of achieving the object, a production method adopted obtains the electro-deposited copper foil by electrolyzing a sulfuric acid based copper electrolytic solution which contains a quaternary ammonium salt polymer having cyclic structure and chlorine, wherein for the quaternary ammonium salt polymer contained in the sulfuric acid based copper electrolytic solution, a DDAC dimer or higher polymer is used. For the quaternary ammonium salt polymer, a diallyl dimethyl ammonium chloride polymer having a number average molecular weight of 300 to 10000 is preferably used.
    Type: Application
    Filed: October 31, 2006
    Publication date: July 2, 2009
    Applicant: MITSUI MINING & SMELTING CO., LTD.
    Inventors: Makoto Dobashi, Mitsuyoshi Matsuda, Sakiko Tomonaga, Hisao Sakai, Tomohiro Sakata, Ayumu Tateoka, Hiroshi Hata, Satoshi Mogi, Takeo Taguchi, Junshi Yoshioka
  • Patent number: 7524552
    Abstract: To provide a dielectric-layer-provided copper foil or the like for extremely improving the product yield while making the most use of the increase effect of an electric capacity of a thin dielectric layer using the sputtering vapor deposition method. In the case of dielectric-layer-provided copper foils respectively having a dielectric layer on one side of a copper foil, the dielectric layer 6 is an inorganic-oxide sputter film having a thickness of 1.0 ?m or less and formed on the one side of the copper foil in accordance with the sputtering vapor deposition method and the dielectric-layer-provided copper foils for respectively forming a capacitor layer, characterized in that a pit-like defective portion generated on the inorganic-oxide sputter film is sealed by polyimide resin are used.
    Type: Grant
    Filed: October 29, 2003
    Date of Patent: April 28, 2009
    Assignee: Mitsui Mining and Smelting Co., Ltd.
    Inventors: Toshiko Yokota, Tetsuhiro Matsunaga, Susumu Takahashi, Hideaki Matsushima, Takuya Yamamoto, Makoto Dobashi
  • Publication number: 20090095515
    Abstract: An object of the present invention is to provide an electro-deposited copper foil having the equivalent low-profile surface as in a conventional low-profile electro-deposited copper foil and extremely large mechanical strength and a method for manufacturing the same. To achieve the object, the electro-deposited copper foil is formed by depositing fine copper crystal grains having a small deviation of grain-diameter that has never been obtained in the art. The electro-deposited copper foil has a low-profile and glossy surface and has extremely large mechanical strength expressed by a tensile strength as received of 70 kgf/mm2 to 100 kgf/mm2 and has a tensile strength after heating (180° C. for 60 minutes) corresponding to 85% or more of the tensile strength as received.
    Type: Application
    Filed: April 26, 2007
    Publication date: April 16, 2009
    Applicant: MITSUI MINING & SMELTING CO., LTD.
    Inventors: Hisao Sakai, Masaru Takahashi, Mitsuyoshi Matsuda, Makoto Dobashi
  • Publication number: 20090047539
    Abstract: It is an object to provide a surface-treated electro-deposited copper foil which has a low profile at a level equal to or excellent than that of low-profile surface-treated electro-deposited copper foils that have conventionally been supplied to the market and in which waviness affecting the straight line performance of wiring is small, and a method for manufacturing the same. In order to achieve this object, in the surface-treated electro-deposited copper foil, the maximum waviness height (Wmax) of the bonding surface to be bonded with an insulation layer-constituting material to be 0.05 ?m to 0.7 ?m, the maximum peak to valley height (PV) to be 0.05 to 1.5 ?m, and the surface roughness (Rzjis) to be 0.1 ?m to 1.0 ?m.
    Type: Application
    Filed: March 9, 2007
    Publication date: February 19, 2009
    Applicant: MITSUI MINING & SMELTING CO., LTD
    Inventors: Makoto Dobashi, Mitsuyoshi Matsuda, Sakiko Tomonaga, Hisao Sakai, Tomohiro Sakata, Junshi Yoshioka, Jo Nishikawa, Takeo Taguchi
  • Patent number: 7455931
    Abstract: An anode for a nonaqueous secondary battery comprising a current collector having formed thereon a first covering layer containing tin, a tin alloy, aluminum or an aluminum alloy and a second covering layer containing a metal having low capability of forming a lithium compound in that order. The anode may have an additional first covering layer formed on the second covering layer. A covering layer containing a copper etc. may be formed as an uppermost layer. Each layer can be formed by heat treating to get desired property. As heat treatment can be done in a short time, it has a great cost merit.
    Type: Grant
    Filed: April 21, 2003
    Date of Patent: November 25, 2008
    Assignee: Mitsui Mining & Smelting Company, Ltd.
    Inventors: Kiyotaka Yasuda, Yoshiki Sakaguchi, Kazuko Taniguchi, Makoto Dobashi
  • Patent number: 7217464
    Abstract: The object is to provide a method of manufacturing electrodeposited copper foil with a carrier foil for high-temperature heat-resistance in which the peeling of the carrier foil is easy even by press working at temperatures of not less than 200°C.
    Type: Grant
    Filed: May 12, 2003
    Date of Patent: May 15, 2007
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Akitoshi Takanashi, Kenichiro Iwakiri, Akiko Sugimoto, Junshi Yoshioka, Shinichi Obata, Makoto Dobashi
  • Publication number: 20060147802
    Abstract: A negative electrode for nonaqueous secondary batteries is disclosed. The negative electrode has a pair of current collecting surface layers of which the surfaces are adapted to be brought into contact with an electrolyte and at least one active material layer interposed between the surface layers. The active material layer contains particles of an active material having high capability of forming a lithium compound. The material constituting the surfaces is preferably present over the whole thickness of the active material layer to electrically connect the surfaces so that the electrode exhibits a current collecting function as a whole. The surface layers each preferably have a thickness of 0.3 to 10 ?m.
    Type: Application
    Filed: January 5, 2005
    Publication date: July 6, 2006
    Inventors: Kiyotaka Yasuda, Yoshiki Sakaguchi, Shinichi Musha, Makoto Dobashi, Akihiro Modeki, Tomoyoshi Matsushima, Hitohiko Honda, Takeo Taguchi
  • Publication number: 20060115735
    Abstract: An anode for nonaqueous secondary batteries is disclosed. The anode has a pair of current collecting surface layers of which the surfaces are adapted to be brought into contact with an electrolytic solution and at least one active material layer interposed between the surface layers. The active material layer contains particles of an active material having high capability of forming a lithium compound. The material constituting the surfaces is preferably present over the whole thickness of the active material layer to electrically connect the surfaces so that the electrode exhibits a current collecting function as a whole. The surface layers each preferably have a thickness of 0.3 to 10 ?m.
    Type: Application
    Filed: December 17, 2003
    Publication date: June 1, 2006
    Inventors: Kiyotaka Yasuda, Yoshiki Sakaguchi, Shinichi Musha, Makoto Dobashi, Akihiro Modeki, Tomoyoshi Matsushima, Hitohiko Honda, Takeo Taguchi
  • Publication number: 20060087794
    Abstract: It is an object to provide a capacitor layer forming material useful for a printed wiring board with a substrate of fluorine resin, liquid-crystal polymer or the like, which is fabricated by hot-pressing at 300 to 400° C., and showing no deterioration in strength after the hot-pressing. In order to achieve the object, the capacitor layer forming material, comprising a first electroconductive layer used for forming an upper electrode and second electroconductive layer used for forming a lower electrode with a dielectric layer in-between for a printed wiring board, has the second electroconductive layer made of a composite foil comprising a copper layer coated with one or more layers of, plated hard nickel, plated cobalt and plated nickel/cobalt alloy.
    Type: Application
    Filed: October 27, 2005
    Publication date: April 27, 2006
    Applicant: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Tomohiro Sakata, Kazuko Taniguchi, Makoto Dobashi
  • Publication number: 20060057420
    Abstract: To provide a dielectric-layer-provided copper foil or the like for extremely improving the product yield while making the most use of the increase effect of an electric capacity of a thin dielectric layer using the sputtering vapor deposition method. In the case of dielectric-layer-provided copper foils respectively having a dielectric layer on one side of a copper foil, the dielectric layer 6 is an inorganic-oxide sputter film having a thickness of 1.0 ?m or less and formed on the one side of the copper foil in accordance with the sputtering vapor deposition method and the dielectric-layer-provided copper foils for respectively forming a capacitor layer, characterized in that a pit-like defective portion generated on the inorganic-oxide sputter film is sealed by polyimide resin are used.
    Type: Application
    Filed: October 29, 2003
    Publication date: March 16, 2006
    Inventors: Toshiko Yokota, Tetsuhiro Matsunaga, Susumu Takahashi, Hideaki Matsushima, Takuya Yamamoto, Makoto Dobashi