Abstract: A cell stack device includes a manifold and a fuel cell. The manifold includes a gas supply chamber and a gas collection chamber. The fuel cell includes a support substrate and a power generation element portion. The support substrate includes first and second gas channels. The first gas channel is connected to the gas supply chamber, and the second gas channel is connected to the gas collection chamber. The first gas channel is open in the gas supply chamber at a proximal end portion. The second gas channel is open in the gas collection chamber at a proximal end portion. The first and second gas channels are connected to each other on the distal end portion side. The first and second gas channels are configured such that a pressure loss of gas in the first gas channel is smaller than a pressure loss of gas in the second gas channel.

Abstract: A fuel cell has an anode, a cathode and a solid electrolyte layer. The cathode contains a perovskite oxide as a main component. The perovskite oxide is expressed by a general formula ABO3 and includes at least Sr at the A site. The solid electrolyte layer is disposed between the anode and the cathode. The cathode includes a surface region which is within 5 ?m from a surface opposite the solid electrolyte layer. The surface region contains a main phase containing the perovskite oxide and a secondary phase containing strontium sulfate. An occupied surface area ratio of the secondary phase in a cross section of the surface region is greater than or equal to 0.25% to less than or equal to 8.5%.

Abstract: An interconnector made of a lanthanum chromite is provided on a fuel electrode of an SOFC, and a P-type semiconductor film which is a conductive ceramics film is formed on a surface of the interconnector. When a maximum value (maximum joining width) of the “lengths of a plurality of portions at which the interconnector and the P-type semiconductor film are brought into contact with each other” on a “line (boundary line) corresponding to an interface between the interconnector and the P-type semiconductor film in a cross section including the interconnector and the P-type semiconductor film” is 40 ?m or less, peeling becomes less liable to occur in a portion corresponding to the maximum joining width at the interface.

Abstract: A fuel cell stack (100) includes a first power generation element, a first supporting substrate (5a), a second power generation element, a second supporting substrate (5b) and a communicating member (3). The first supporting substrate (5a) includes a first substrate main portion, a first dense layer, and a first gas flow passage. The first dense layer covers the first substrate main portion. The first gas flow passage extends from a proximal end portion (501a) to a distal end portion (502a). The second supporting substrate (5b) includes a second substrate main portion, a second dense layer, and a second gas flow passage. The second dense layer covers the second substrate main portion. The second gas flow passage extends from a proximal end portion (501b) to a distal end portion (501b).

Abstract: A method of power generation for a solid alkaline fuel cell includes the step of exposing a cathode-side surface of the inorganic solid electrolyte to an atmosphere containing carbon dioxide of greater than or equal to 600 ppm and less than or equal to 20000 ppm.

Abstract: The fuel cell has an anode, a cathode, and a solid electrolyte layer. The cathode contains a main component containing a perovskite oxide of the general formula ABO3 and includes at least Sr at the A site. The solid electrolyte layer is disposed between the anode and the cathode. The cathode has a surface region and an inner region. The surface region is within 5 ?m from a surface opposite the solid electrolyte layer. The inner region is formed on a solid electrolyte layer side of the surface region. The surface region and the inner region respectively include a main phase containing the perovskite oxide and a secondary phase containing strontium sulfate. An occupied surface area ratio of the secondary phase in a cross section of the surface region is greater than an occupied surface area ratio of the secondary phase in a cross section of the inner region.

Abstract: The solid alkaline fuel cell has a cathode that is supplied with an oxidant which contains oxygen, an anode that is supplied with a fuel which contains hydrogen atoms, and an inorganic solid electrolyte that is disposed between the anode and the cathode and that exhibits hydroxide ion conductivity. The inorganic solid electrolyte enables permeation of a fuel in an amount that produces carbon dioxide at the cathode of greater than or equal to 0.04 ?mol/s·cm2 and less than or equal to 2.5 ?mol/s·cm2 per unit surface area of a cathode-side surface.

Abstract: An electrochemical device includes an electrochemical cell, an oxidizer gas supply portion, and a first contaminant trap portion. The electrochemical cell includes an anode, a cathode, and a solid electrolyte layer provided between the fuel cell and the cathode. The oxidizer gas supply portion includes an oxidizer gas supply port for supplying oxidizer gas to the cathode. The first contaminant trap portion is provided between the cathode and the oxidizer gas supply port and configured to adsorb contaminants contained in the oxidizer gas. At least part of the first contaminant trap portion is disposed 20 mm or less from the oxidizer gas supply port in a gas supply direction in which the oxidizer gas is supplied from the oxidizer gas supply port.

Abstract: The solid alkaline fuel cell has a cathode that is supplied with an oxidant which contains oxygen, an anode that is supplied with a fuel which contains hydrogen atoms, and an inorganic solid electrolyte that is disposed between the anode and the cathode and that exhibits hydroxide ion conductivity. The inorganic solid electrolyte enables permeation of water of greater than or equal to 80 ?g/min·cm2 and less than or equal to 5400 ?g/min·cm2 per unit surface area of a cathode-side surface.

Abstract: A method of power generation for a solid alkaline fuel cell includes the step of exposing a cathode-side surface of the inorganic solid electrolyte to an atmosphere containing carbon dioxide of greater than or equal to 600 ppm and less than or equal to 20000 ppm.

Abstract: The electrochemical cell according to the present invention has an anode, a cathode, and a solid electrolyte layer disposed between the anode and the cathode. The cathode includes a solid electrolyte layer-side region within 3 ?m from a surface on the solid electrolyte layer side. The solid electrolyte layer-side region has a main phase that is configured by a perovskite oxide, and a second phase that is configured by SrSO4 and (Co, Fe)3O4. The perovskite oxide is expressed by the general formula ABO3 and contains at least one of Sr and La at the A site. The (Co, Fe)3O4 contained in the electrolyte layer-side region contains Co and Fe. An occupied surface area ratio of the second phase in a cross section of the solid electrolyte layer-side region is less than or equal to 10.5%.

Abstract: A fuel cell comprises an anode, a cathode, a solid electrolyte layer, and a current collecting member. The cathode contains a perovskite composite oxide as a main component and contains a compound that includes at least one of S and Cr as a secondary component. The cathode has a surface facing the current collecting member. The surface of the cathode includes a first region that is electrically connected to the current collecting member and a second region that is separated from the current collecting member. The first region and the second region respectively contain a main phase that is configured from a perovskite composite oxide and a secondary phase that is configured from the compound. The occupied surface area ratio of the secondary phase in the first region is greater than the occupied surface area ratio of the secondary phase in the second region.

Abstract: A cathode material used in an anode and a cathode contains (Co,Fe)3O4 and a perovskite type oxide that is expressed by the general formula ABO3 and includes at least one of La and Sr at the A site. A content ratio of (Co,Fe)3O4 in the cathode material is at least 0.23 wt % and no more than 8.6 wt %.

Abstract: A cathode material used in an anode and a cathode contains (Co,Fe)3O4 and a perovskite type oxide that is expressed by the general formula ABO3 and includes at least one of La and Sr at the A site. A content ratio of (Co,Fe)3O4 in the cathode material is at least 0.23 wt % and no more than 8.6 wt %.

Abstract: An electrochemical cell stack according to a second aspect of the present invention includes an electrochemical cell and a manifold supporting a base end of the electrochemical cell. The electrochemical cell includes an electric conductive support substrate and a power generation unit disposed on the support substrate. Additionally, a gas flow path is provided in the support substrate. The power generation unit includes an anode disposed on a first main surface of the support substrate, a cathode, and a solid electrolyte layer disposed between the anode and the cathode. Additionally, the solid electrolyte layer contains a zirconia-based material as a main component thereof. The solid electrolyte layer includes a base end portion positioned on a side of the base end and a separated portion positioned separated from the base end. The base end portion includes a first area covering within 3 ?m from an anode side surface, and a second area provided on the first area.

Abstract: An electrochemical cell stack includes a first separator, a second separator, and an electrochemical cell disposed between the first separator and the second separator. The electrochemical cell includes an anode, a cathode and a solid electrolyte layer. The solid electrolyte layer is disposed between the anode and the cathode and contains zirconia-based material as a main component. The solid electrolyte layer has an upstream part and a downstream part. The upstream part is positioned on the upstream side in the flow direction of fuel gas that flows in the fuel flow passage between the anode and the first separator. The downstream part is positioned on the downstream side in the flow direction. The upstream part includes a first region within 3 ?m from the anode side surface, and a second region provided on the first region.

Abstract: An electrochemical cell stack according to a second aspect of the present invention includes an electrochemical cell and a manifold supporting a base end of the electrochemical cell. The electrochemical cell includes an electric conductive support substrate and a power generation unit disposed on the support substrate. Additionally, a gas flow path is provided in the support substrate. The power generation unit includes an anode disposed on a first main surface of the support substrate, a cathode, and a solid electrolyte layer disposed between the anode and the cathode. Additionally, the solid electrolyte layer contains a zirconia-based material as a main component thereof. The solid electrolyte layer includes a base end portion positioned on a side of the base end and a separated portion positioned separated from the base end. The base end portion includes a first area covering within 3 ?m from an anode side surface, and a second area provided on the first area.

Abstract: The electrochemical cell has an anode, a cathode, and a solid electrolyte layer disposed between the anode and the cathode. The cathode contains a main phase which is configured by a perovskite oxide expressed by the general formula ABO3 and including at least one of La or Sr at the A site, and a second phase which is configured by Co3O4 and (Co, Fe)3O4. An occupied surface area ratio of the second phase in a cross section of the cathode is less than or equal to 10.5%.

Abstract: The electrochemical cell has an anode, a cathode, and a solid electrolyte layer. The cathode contains a perovskite oxide expressed by the general formula ABO3 and including at least one of Sr and La at the A site as a main component. The solid electrolyte layer is disposed between the anode and the cathode. The cathode includes a solid electrolyte layer-side region within 3 ?m from a surface of the solid electrolyte layer side. The solid electrolyte layer-side region includes a main phase which is configured by the perovskite oxide and a second phase which is configured by CO3O4 and (Co, Fe)3O4. An occupied surface area ratio of the second phase in a cross section of the solid electrolyte layer-side region is less than or equal to 10.5%.

Abstract: The electrochemical cell includes an anode, a cathode active layer, and a solid electrolyte layer disposed between the anode and the cathode active layer. The cathode active layer includes a first region which is disposed facing the solid electrolyte layer, and a second region which is disposed on the first region. An average particle diameter of first constituent particles which constitute the first region is smaller than an average particle diameter of second constituent particles which constitute the second region.