Abstract: A method of operating a compression ignition engine is disclosed. The method comprises, introducing an enriching component into a combustion chamber during an intake stroke, igniting the enriching component during the compression stroke, introducing a main injection of fuel to the combustion chamber after the ignition of the enriching component, igniting the main injection of fuel, and introducing a supplemental gas to the combustion chamber after igniting the main injection of fuel.

Abstract: An extended rich mode engine configured and operated extremely rich of stoichiometric to produce a substantially continuous hydrogen rich engine exhaust. Oxygen enrichment devices further optimize production of hydrogen rich engine exhaust. Engines include a free piston gas generator with rich homogenous charge compression, a rich internal combustion engine cylinder system with an oxygen generator, and a rich inlet turbo-generator system with exhaust heat recovery. Oxygen enrichment devices to enhance production of hydrogen rich engine exhaust include pressure swing absorption with oxygen selective materials, and oxygen separators such as a solid oxide fuel cell oxygen separator and a ceramic membrane oxygen separator.

Abstract: A trap for an energy conversion device comprises a trapping system comprising a filter element and a trap element, and fluidly coupled to a reforming system. The trapping system is monitored by a combination of devices including an on-board diagnostic system, a temperature sensor, and a pressure differential sensor, which can individually or in combination determine when to regenerate the trapping system. The method for trapping sulfur and particulate matter using the trapping system comprises dispensing fuel into the energy conversion device. The fuel is processed in a reformer system to produce a reformate. The reformate is introduced into the trapping system and filtered to remove particulate matter and sulfur.

Abstract: A method for fuel cell system thermal management includes: maintaining a first zone at a first selected temperature range, maintaining a second zone at a second selected temperature range, and maintaining a third zone at a third selected temperature range. The second zone is in thermal communication with a first sensor and comprises a reformer, while the third zone is in thermal communication with a second sensor and comprises a fuel cell stack. The second selected temperature range is greater than the first selected temperature range, while the third selected temperature range is greater than the second selected temperature range. The method may further include sensing a second zone temperature in the second zone, determining whether the second zone temperature is at the second selected temperature range, and adding a process air flow to the second zone if the second zone temperature rises above the second selected temperature range.

Abstract: A process for removing contaminants from a reformer comprises removal of particulate matter under operating, or stand-by conditions, or at the start of a shutdown procedure, by introducing a gas mixture to the reformer system having an oxidant-to-fuel ratio concentration leaner than a normal oxidant-to-fuel ratio concentration and at a gas flow rate less than a peak flow rate. The process produces elevated temperatures at the reformer inlet and elevated levels of carbon dioxide and water that combine to remove the contaminants. Another embodiment includes removal of particulate matter during a shutdown procedure by cycling the flow of fuel and air on and off; monitoring an exit temperature of a catalyst substrate and alternatively, cycling the oxidant flow on and off when the exit temperature is less than or greater than a threshold temperature such that the exit temperature of the catalyst substrate is maintained below the temperature at which aging of the catalyst and/or a washcoat material may occur.

Abstract: An apparatus and method for a preheated micro-reformer system is disclosed comprising a reformer and a micro-reformer in fluid communication with the reformer. The micro-reformer being electrically preheatable. An apparatus comprising a micro-reformer including a first zone and a second zone, the first zone being preheatable to a first temperature and the second zone being preheatable to a second temperature, the second temperature being higher than the first temperature. A method of using a micro-reformer that is electrically preheatable is disclosed comprising initiating an electrically preheatable micro-reformer. The micro-reformer is preheated. The preheating can be accomplished by converting electrical energy into thermal energy. A method of using a preheated micro-reformer is disclosed comprising preheating a first zone, preheating a second zone to a temperature higher than the first zone, vaporizing a fuel air mixture in the first zone, and reforming the fuel air mixture in the second zone.

Abstract: A power generation system and method providing an engine configured to produce hydrogen rich reformate to feed a solid oxide fuel cell includes an engine having an intake and an exhaust; an air supply in fluid communication with the engine intake; a fuel supply in fluid communication with the engine intake; at least one solid oxide fuel cell having an air intake in fluid communication with an air supply, a fuel intake in fluid communication with the engine exhaust, a solid oxide fuel cell effluent and an air effluent. Engines include a free piston gas generator with rich homogenous charge compression, a rich internal combustion engine cylinder system with an oxygen generator, and a rich inlet turbo-generator system with exhaust heat recovery. Oxygen enrichment devices to enhance production of hydrogen rich engine exhaust include pressure swing absorption with oxygen selective materials, and oxygen separators such as an solid oxide fuel cell oxygen separator and a ceramic membrane oxygen separator.

Abstract: A heating, venting, and air conditioning system utilizes a reformer to provide supplemental heat to a passenger compartment and to improve start-up emissions of an engine of a vehicle or power system. A pump circulates a fluid through the engine and throughout the system. A radiator and heater core transfer heat from the fluid. A first circuit cools the fluid upon circulation through the radiator after circulation through the engine to cool the engine, and a second circuit heats the passenger compartment and cools the fluid upon circulation through the heater core after circulation through the engine to cool the engine. The reformer, which converts a hydrocarbon or alcohol fuel into a reformate, generates heat. A third circuit, defined between the reformer and the pump and interconnected with the heater core, provides the supplemental heat from the reformer to the passenger compartment through the heater core and also to the engine.

Abstract: A heating, venting, and air conditioning system utilizes a reformer to provide supplemental heat to a passenger compartment and to improve start-up emissions of an engine of a vehicle or power system. A pump circulates a fluid through the engine and throughout the system. A radiator and heater core transfer heat from the fluid. A first circuit cools the fluid upon circulation through the radiator after circulation through the engine to cool the engine, and a second circuit heats the passenger compartment and cools the fluid upon circulation through the heater core after circulation through the engine to cool the engine. The reformer, which converts a hydrocarbon or alcohol fuel into a reformate, generates heat. A third circuit, defined between the reformer and the pump and interconnected with the heater core, provides the supplemental heat from the reformer to the passenger compartment through the heater core and also to the engine.

Abstract: The present invention relates a method of detecting leaks and blockages in a fuel system. The leaks are detected using a RAMPOFF mode and a TANK mode. The RAMPOFF mode modifies the evaporative diagnostic purge logic to increase the ramp down rates of the evaporative purge duty cycle to aggressively shut off the purge solenoid valve for tests used to detect leaks as small as 0.02 inches in diameter. The TANK mode modifies the evaporative diagnostic purge logic to support aggressive purging requirements for tests used to detect larger leaks of greater than 0.04 inches in diameter. The MASS FLOW mode modifies the evaporative diagnostic purge logic to hold a constant purge mass flow rate necessary to detect blockages across a vent solenoid valve. The RAMPOFF mode, TANK mode, and MASS FLOW modes support evaporative diagnostics that are run continuously within a fuel system when acceptable engine operating conditions are present.

Abstract: An extended rich mode engine configured and operated extremely rich of stoichiometric to produce a substantially continuous hydrogen rich engine exhaust. Oxygen enrichment devices further optimize production of hydrogen rich engine exhaust. Engines include a free piston gas generator with rich homogenous charge compression, a rich internal combustion engine cylinder system with an oxygen generator, and a rich inlet turbo-generator system with exhaust heat recovery. Oxygen enrichment devices to enhance production of hydrogen rich engine exhaust include pressure swing absorption with oxygen selective materials, and oxygen separators such as an SOFC oxygen separator and a ceramic membrane oxygen separator.

Abstract: A method for fuel cell system thermal management includes: maintaining a first zone at a first selected temperature range, maintaining a second zone at a second selected temperature range, and maintaining a third zone at a third selected temperature range. The second zone is in thermal communication with a first sensor and comprises a reformer, while the third zone is in thermal communication with a second sensor and comprises a fuel cell stack. The second selected temperature range is greater than the first selected temperature range, while the third selected temperature range is greater than the second selected temperature range.

Abstract: An integrated fuel reformer-engine system and method provides an on-board fuel reformer for preparing a hydrogen-rich reformate; an engine operating on one or a combination of reformate and liquid fuel, in combination with an exhaust catalyst for treating engine exhaust. The supply of air, reformate, and liquid fuel to the engine and exhaust catalyst is metered so as to provide low hydrocarbon and NOx emissions over a range of operating conditions from cold-start and idle through vehicle road-loads. In one embodiment, the system provides near-zero cold start hydrocarbon and NOx emissions with ultra-lean start using substantially 100% reformate fueling. In another embodiment, accelerated catalyst heating is provided by supplying reformate mixed with engine exhaust to the catalyst. Alternately, an ignition source is employed to ignite the engine exhaust or reformate-exhaust mixture.

Abstract: A power generation system and method providing an engine configured to produce hydrogen rich reformate to feed a solid oxide fuel cell includes an engine having an intake and an exhaust; an air supply in fluid communication with the engine intake; a fuel supply in fluid communication with the engine intake; at least one SOFC having an air intake in fluid communication with an air supply, a fuel intake in fluid communication with the engine exhaust, a SOFC effluent and an air effluent. Engines include a free piston gas generator with rich homogenous charge compression, a rich internal combustion engine cylinder system with an oxygen generator, and a rich inlet turbo-generator system with exhaust heat recovery. Oxygen enrichment devices to enhance production of hydrogen rich engine exhaust include pressure swing absorption with oxygen selective materials, and oxygen separators such as an SOFC oxygen separator and a ceramic membrane oxygen separator.

Abstract: An integrated fuel reformer-engine system and method provides an on-board fuel reformer for preparing a hydrogen-rich reformate; an engine operating on one or a combination of reformate and liquid fuel, in combination with an exhaust catalyst for treating engine exhaust. The supply of air, reformate, and liquid fuel to the engine and exhaust catalyst is metered so as to provide low hydrocarbon and NOx emissions over a range of operating conditions from cold-start and idle through vehicle road-loads. In one embodiment, the system provides near-zero cold start hydrocarbon and NOx emissions with ultra-lean start using substantially 100% reformate fueling. In another embodiment, accelerated catalyst heating is provided by supplying reformate mixed with engine exhaust to the catalyst. Alternately, an ignition source is employed to ignite the engine exhaust or reformate-exhaust mixture.

Abstract: A power generation system providing an engine configured to produce hydrogen rich reformate to feed a solid oxide fuel cell includes an engine having an intake and an exhaust; an air supply in fluid communication with the engine intake; a fuel supply in fluid communication with the engine intake; at least one SOFC having an air intake in fluid communication with an air supply, a fuel intake in fluid communication with the of, engine exhaust, a SOFC effluent and an air effluent. Engines include a free piston gas generator with rich homogenous charge compression, a rich internal combustion engine cylinder system with an oxygen generator, and a rich inlet turbo-generator system with exhaust heat recover. Oxygen enrichment devices to enhance production of hydrogen rich engine exhaust include pressure swing absorption with oxygen selective materials, and oxygen separators such as an SOFC oxygen separator and a ceramic membrane oxygen separator.

Abstract: A process for removing contaminants from a reformer comprises removal of particulate matter under operating, or stand-by conditions, or at the start of a shutdown procedure, by introducing a gas mixture to the reformer system having an oxidant-to-fuel ratio concentration leaner than a normal oxidant-to-fuel ratio concentration and at a gas flow rate less than a peak flow rate. The process produces elevated temperatures at the reformer inlet and elevated levels of carbon dioxide and water that combine to remove the contaminants. Another embodiment includes removal of particulate matter during a shutdown procedure by cycling the flow of fuel and air on and off; monitoring an exit temperature of a catalyst substrate and alternatively, cycling the oxidant flow on and off when the exit temperature is less than or greater than a threshold temperature such that the exit temperature of the catalyst substrate is maintained below the temperature at which aging of the catalyst and/or a washcoat material may occur.

Abstract: A trap for an energy conversion device comprises a trapping system comprising a filter element and a trap element, and fluidly coupled to a reforming system. The trapping system is monitored by a combination of devices including an on-board diagnostic system, a temperature sensor, and a pressure differential sensor, which can individually or in combination determine when to regenerate the trapping system. The method for trapping sulfur and particulate matter using the trapping system comprises dispensing fuel into the energy conversion device. The fuel is processed in a reformer system to produce a reformate. The reformate is introduced into the trapping system and filtered to remove particulate matter and sulfur.

Abstract: A method of controlling temperature at a fuel reformer comprises sensing the temperature at the fuel reformer and adding air to the fuel reformer. A dual air actuator system for use with a fuel reformer comprises air control valves in fluid communication with the fuel reformer and a temperature sensor in electrical communication with the air control valves.

Abstract: An apparatus and method for a preheated micro-reformer system is disclosed comprising a reformer and a micro-reformer in fluid communication with the reformer. The micro-reformer being electrically preheatable. An apparatus comprising a micro-reformer including a first zone and a second zone, the first zone being preheatable to a first temperature and the second zone being preheatable to a second temperature, the second temperature being higher than the first temperature.