Abstract: A method of operating an electrochemical conversion assembly is provided. According to the method, an assembly warm-up operation is executed by increasing the temperature TSTACK of the membrane electrode assembly. Next, stoichiometry-based control of the relative humidity (RH) of one of the reactant flowfields is initiated when the temperature TSTACK exceeds a threshold temperature T0. The stoichiometry-based RH control comprises a reduction in the relative humidity from a value RHWET exceeding 100% relative humidity to a value RHDRY less than 100% relative humidity. The relative humidity value RHDRY is sufficiently low to permit reduction of an initial membrane hydration ?WET in the membrane electrode assembly.

Abstract: A process for controlling the length of a purge and the purge rate of a fuel cell stack at system shut-down so as to provide the desired amount of stack humidity. The membrane humidification is measured at system shut-down by a high frequency resistance sensor that detects membrane humidification and provides the measurement to a controller. The controller controls the compressor that provides cathode input air to the fuel cell stack so that the time of the purge and the flow rate of the purge provide a desired membrane humidity for the next start-up.

Abstract: An blood infusion management system is described, including a scanner, a processor, and a display. The scanner derives scan data from a patient identifier and individual blood units and provides the scan data to the processor. The processor evaluates the scan data to ensure that the blood units match the patient identifier. If the blood units do not match, a blood infusion protocol is aborted. If the blood units match the patient identifier, then the blood infusion protocol is allowed to proceed. The blood infusion protocol requires at least two verification scans for any individual blood unit to achieve a transfusing status, and an additional scan of the patient identifier may be used to place the used blood units in a complete status.

Abstract: A system and method for providing dynamic cathode stoichiometry control in a fuel cell during stack load transients to minimize relative humidity excursions. Particularly, changes in the cathode stoichiometry is controlled as a function of time in response to a decrease or increase in stack current density. Thus, if the stack current density drops to a predetermined current density, the dynamic stoichiometry logic will monitor the low power condition and determine if the condition is sustained, i.e., for an extended period of time. If the low power condition is not sustained, then the cathode stoichiometry does not change, but if it is sustained, then the cathode stoichiometry is increased. The same delay in changing the cathode stoichiometry can be provided for a transition from a low power condition to a high power condition.

Abstract: A system and method for limiting the output current of a fuel cell stack as the stack degrades overtime. A look-up table identifies a predetermined voltage set-point for stack current density. A first comparator provides a voltage difference signal between the set-point and the stack voltage. The voltage difference signal is provided to a controller, such as a proportional-integral controller, that provides a current limiting signal. The current limiting signal and a current request signal are provided to a second comparator that selects which signal will be used to limit the maximum output current of the stack. A polarization curve estimator estimates parameters of the stack that will change over the life of the stack. The parameters are provided to a gain scheduler that provides gains to the controller that are based on where in the life of the stack it is currently operating.

Abstract: A system and method for determining when to provide an anode exhaust gas bleed from a fuel cell stack as the fuel cell stack ages. The method determines the amount of nitrogen flowing from a cathode side to an anode side of the fuel cell stack. The method also determines the amount of nitrogen flowing from the anode side to the cathode side by determining a standard deviation of voltage outputs of the fuel cells, and using the standard deviation as a model for determining the leak rate of nitrogen from the anode side to the cathode side. The method determines the concentration of nitrogen in the anode side based on the nitrogen flow between the cathode and anode side, and opens a bleed valve to bleed the anode exhaust gas if the concentration of nitrogen in the anode side goes above a predetermined value.

Abstract: A control system for a fuel cell stack that controls the relative humidity of the cathode outlet gas during stack power transients to provide better cathode outlet gas relative humidity control by reducing the dynamic pressure range and thus the dynamic cathode outlet gas relative humidity range. In one embodiment, the control system uses a first narrower cathode pressure range based on stack current density during stack power transients to provide better cathode outlet gas relative humidity control, and uses a second wider cathode pressure range based on stack current density during low current density and steady-state current density to improve system efficiency by decreasing compressor parasitics.

Abstract: A fuel cell system is provided, including an HFR measurement device in electrical communication with a fuel cell stack. The HFR measurement is used online to measure an HFR of the fuel cell stack suitable for calculation of a d(HFR)/d(RH) ratio. A humidity regulator is provided in fluid communication with the fuel cell stack. A controller periodically changes stack operating conditions to perturb an RH of the fuel cell stack, process the HFR response, and compute the d(HFR)/d(RH) ratio. A method for online identification and control of the fuel cell stack humidification is also provided. The d(HFR)/d(RH) ratio is an auxiliary measurement of membrane hydration which is used as a feedback for hydration control.

Abstract: A control strategy for bleeding an anode side of fuel cell stack in a fuel cell system that improves water management and addresses durability and performance concerns. The method includes determining when to begin the anode bleed, typically by estimating or measuring the amount of nitrogen in the anode side of the stack. The method also includes determining when to end the anode bleed based on the volume of gas that has been bled. The method determines the mole flow rate of the anode gas flowing through a bleed valve, integrates the mole flow rate to get the number of moles of the gas that have passed through the bleed valve, determines a desired amount of moles to be bled, and ends the bleed when the actual number of moles of the gas equals the desired number of moles of the gas.

Abstract: A method of operating an electrochemical conversion assembly is provided. According to the method, an assembly warm-up operation is executed by increasing the temperature TSTACK of the membrane electrode assembly. Next, stoichiometry-based control of the relative humidity (RH) of one of the reactant flowfields is initiated when the temperature TSTACK exceeds a threshold temperature T0. The stoichiometry-based RH control comprises a reduction in the relative humidity from a value RHWET exceeding 100% relative humidity to a value RHDRY less than 100% relative humidity. The relative humidity value RHDRY is sufficiently low to permit reduction of an initial membrane hydration ?WET in the membrane electrode assembly.

Abstract: A system and method for determining when to provide an anode exhaust gas bleed from a fuel cell stack as the fuel cell stack ages. The method determines the amount of nitrogen flowing from a cathode side to an anode side of the fuel cell stack. The method also determines the amount of nitrogen flowing from the anode side to the cathode side by determining a standard deviation of voltage outputs of the fuel cells, and using the standard deviation as a model for determining the leak rate of nitrogen from the anode side to the cathode side. The method determines the concentration of nitrogen in the anode side based on the nitrogen flow between the cathode and anode side, and opens a bleed valve to bleed the anode exhaust gas if the concentration of nitrogen in the anode side goes above a predetermined value.

Abstract: A system and method for preventing low performing cells in a fuel cell stack. The method includes periodically providing a pulse of the cathode input airflow at low stack current densities, and comparing the current density output of each cell in response to the pulse. Those cells that do not have significant water accumulation will provide one voltage signature and those cells that do have a significant water accumulation will provide another voltage signature. If one or more of the cells exhibit the voltage signature for water accumulation, then the cathode inlet airflow pulses can be provided more often to prevent the cells from failing.

Abstract: A control system for a fuel cell stack that controls the relative humidity of the cathode outlet gas during stack power transients to provide better cathode outlet gas relative humidity control by reducing the dynamic pressure range and thus the dynamic cathode outlet gas relative humidity range. In one embodiment, the control system uses a first narrower cathode pressure range based on stack current density during stack power transients to provide better cathode outlet gas relative humidity control, and uses a second wider cathode pressure range based on stack current density during low current density and steady-state current density to improve system efficiency by decreasing compressor parasitics.

Abstract: A system and method for providing dynamic cathode stoichiometry control in a fuel cell during stack load transients to minimize relative humidity excursions. Particularly, changes in the cathode stoichiometry is controlled as a function of time in response to a decrease or increase in stack current density. Thus, if the stack current density drops to a predetermined current density, the dynamic stoichiometry logic will monitor the low power condition and determine if the condition is sustained, i.e., for an extended period of time. If the low power condition is not sustained, then the cathode stoichiometry does not change, but if it is sustained, then the cathode stoichiometry is increased. The same delay in changing the cathode stoichiometry can be provided for a transition from a low power condition to a high power condition.

Abstract: A method for periodically removing water from cathode flow channels in a fuel cell stack that includes looking at the resulting cell voltage patterns in response to selectively pulsing the cathode airflow during. If the fuel cell stack has been in an extended low power condition for a predetermined period of time, the cathode airflow is pulsed, and the output voltage of each cell is measured to determine the difference between the cell voltages. If the cell voltages significantly vary, then the cathode airflow is pulsed more frequently, and if the cell voltages cells are sufficiently close, then the cathode air is pulsed less frequently. The propose water management diagnosis can be used in a control system to determine the frequency of cathode air pulsing.

Abstract: A temperature control system and method controls temperatures of front and back ends of a shift reactor. Front and back end temperature sensors sense temperatures of the front and back ends of the shift reactor and generate front and back end temperature signals. An actuator injects fluid into the front end of the shift reactor. A controller communicates with the front end temperature sensor, the back end temperature sensor and the actuator and controls the temperature of the front end and the back end. The controller includes primary and secondary control loops. The secondary control loop communicates with the back end temperature sensor. The primary control loop communicates with the front end temperature sensor. The secondary control loop generates a temperature setpoint for the primary control loop. The secondary control loop has a slower response time that the primary control loop.

Abstract: A strategy of controlling a state of hydration of a fuel cell(s) and actively managing operation of the fuel cell(s) to achieve a desired state of hydration. The control strategy monitors the state of hydration and a rate of change of the state of hydration which are used to control the operation of the fuel cell(s). A supervisory control strategy is implemented that alters the operating parameters of the fuel cell(s) based upon the state of hydration, the rate of change of the state of hydration, and a desired operational range for the state of hydration.

Abstract: A control strategy results in a relative humidity profile that is substantially the same or constant regardless of the operational power level of the fuel cell stack. The strategy maintains the relative humidity profile within a range that enables high current density operation of the fuel cell stack. The profile is achieved by adjusting a coolant flow rate through the fuel cell stack to maintain a temperature change across the coolant flow path from inlet to outlet substantially constant regardless of the operational power level of the fuel cell stack.

Abstract: A fuel cell distributed generation system that employs a load following control algorithm that provides the desired output power from a fuel cell on demand. The system includes a current sensor that measures the current drawn from the fuel cell available to satisfy the application load demands. A fuel cell controller receives the measured current and provides a command signal to the fuel cell to increase or decrease its power generation based on the demand. The controller also defines a maximum current that the system can draw from the fuel cell based on its fuel input. The system may include a battery current sensor that measures battery current to insure that the system battery is not being drained. Also, the system may include a battery voltage sensor that monitors battery voltage drift.

Abstract: A method and apparatus estimate hydrogen concentration in a reformate stream produced by a fuel processor of a fuel cell. A sensor measures carbon monoxide, carbon dioxide, and water in the reformate stream. A fuel meter controls fuel input to the fuel processor. An air meter controls air input to the fuel processor. A water meter controls water input to the fuel processor. A transport delay estimator recursively estimates transport delay of the fuel processor. A hydrogen estimator associated with the transport delay estimator, the air, water and fuel meters, and the sensor estimates hydrogen concentration in the reformate stream. The hydrogen estimator includes a fuel processor model that is adjusted using the estimated transport delay. The carbon monoxide, the carbon dioxide and the water are measured using a nondispersive infrared (NDIR) sensor.