Patents by Inventor Mareo Kimura

Mareo Kimura has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5945369
    Abstract: A catalyst for purifying exhaust gases includes a porous support; a cerium oxide or a solid solution of a cerium oxide and a zirconium oxide in a state of mutual solid solution, loaded on the porous support; and a noble metal element loaded on the porous support. The cerium oxide or the solid solution has an average particle diameter of from 5 to 100 nm. The cerium oxide is present in the solid solution in an amount of from 0.2 to 4.0 by molar ratio with respect to the zirconium oxide therein. The catalyst can be prepared by: coating and calcinating on a support substrate a slurry of a cerium oxide sol, a cerium oxide sol and a zirconium oxide sol, on a solid solution powder of a cerium oxide and a zirconium oxide in a state of mutual solid solution; and loading a noble metal element thereon.
    Type: Grant
    Filed: December 8, 1995
    Date of Patent: August 31, 1999
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Mareo Kimura, Yoriko Matsuoka, Hideo Sobukawa, Masayuki Fukui, Akihiko Suda, Toshio Kandori, Yoshio Ukyo
  • Patent number: 5922293
    Abstract: A catalyst for purifying carbon monoxide, hydrocarbons and nitrogen oxides in exhaust gases at the stoichiometric point or in oxygen-rich atmospheres, is disclosed, and it includes a support in which at least one element selected from the group consisting of alkali metals, alkaline-earth metals and rare-earth elements including La is dissolved in titania to form a solid solution, and a noble metal catalyst ingredient loaded on the support. A process for purifying, by bringing the exhaust gases into contact with the catalyst, is also disclosed.
    Type: Grant
    Filed: September 23, 1996
    Date of Patent: July 13, 1999
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Naoto Miyoshi, Mareo Kimura, Yuzo Kawai, Yoko Kumai
  • Patent number: 5804152
    Abstract: An automotive exhaust catalyst includes a support, which is less likely to adsorb SO.sub.x contained in exhaust gases thereon, an NO.sub.x storage compound loaded on the support, and a noble metal element loaded on the support. The support is an alumina support with a Ti--Zr composite oxide loaded thereon, or is formed of a Ti--Zr or Ti--Zr--Y composite oxide. The composite oxide inhibits the NO.sub.x storage compound, which is selected from alkali metals, alkaline-earth metals and rare-earth elements, from being poisoned by sulfur, and enhances the thermal resistance of the support. Thus, the automotive exhaust catalyst can effectively purify NO.sub.x contained in lean-side exhaust gases, even after it is subjected to a thermal durability test.
    Type: Grant
    Filed: October 23, 1995
    Date of Patent: September 8, 1998
    Assignees: Toyota Jidosha Kabushiki Kaisha, Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Naoto Miyoshi, Hiromasa Suzuki, Osamu Ogawa, Mareo Kimura, Yuzo Kawai, Koji Yokota, Naoki Takahashi, Toshiyuki Tanaka
  • Patent number: 5112790
    Abstract: A catalyst used for purifying exhaust gases resulting from the combustion of a lean fuel-air mixture mixture comprises a porous support material having a framework formed by MO.sub.2, where M is silicon or a metal, AlO.sub.2 and PO.sub.2, and at least one base metal and at least one metal of the platinum group which are carried on ion exchange sites of the support material a coexistent state. The catalyst exhibits a high level of NO.sub.x conversion for a long time even at a high temperature owing to the high heat resistance and durability of the support material, and the cooperative action of the two kinds of metals, i.e. the promotion of the catalytic action of the base metal (e.g. copper) by the metal of the platinum group (e.g. palladium) serving as cocatalyst.
    Type: Grant
    Filed: April 27, 1990
    Date of Patent: May 12, 1992
    Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki Kaisha
    Inventors: Yoshihide Watanabe, Mareo Kimura, Shinichi Matsumoto
  • Patent number: 5075276
    Abstract: A catalyst for purification of exhaust gases, comprising a support substrate, a catalyst carrier layer formed on the support substrate and catalyst ingredients loaded on the catalyst carrier layer, wherein the catalyst carrier layer comprises alumina, cerium oxide, zirconium oxide and at least one oxide of rare earth element except cerium and lanthanum, and at least a part of cerium oxide, zirconium oxide and oxide of rare earth element except cerium and lanthanum is present in the form of composite oxide and/or solid solution. The catalyst for purification of exhaust gases is capable of purifying exhaust gases containing carbon monoxide (CO), hydrocarbons (HC) and nitrogen oxides (NOx).
    Type: Grant
    Filed: April 24, 1989
    Date of Patent: December 24, 1991
    Assignees: Kabushiki Kaisha Toyota Chuo Kenkyusho, Toyota Jidosha Kabushiki Kaisha
    Inventors: Masakuni Ozawa, Mareo Kimura, Akio Isogai, Shinichi Matsumoto, Naoto Miyoshi
  • Patent number: 4927799
    Abstract: A catalyst for the purification of exhaust gases comprising a catalyst carrier layer and catalyst ingredients carried thereon, is capable of enhancing the purification property by suppressing the growth of cerium oxide particles and preventing the formation of LaAlO.sub.3. This catalyst has two composition types. One is a binary composition catalyst comprising oxides of cerium and zirconium in the catalyst carrier layer and the other is a ternary composition catalyst comprising oxides of cerium, zirconium and lanthanum in the catalyst carrier layer.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: May 22, 1990
    Assignees: Toyota Jidosha Kabushiki Kaisha, Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Shinichi Matsumoto, Naoto Miyoshi, Mareo Kimura, Masakuni Ozawa, Akio Isogai
  • Patent number: 4921829
    Abstract: A catalyst for purifying exhaust gases comprises: a perovskite-type complex oxide represented by the general formula Ln.sub.1-x A.sub.x MO.sub.3, wherein Ln represents at least one rare earth metal, A presents at least one alkaline earth metal and M represents at least one transition metal, and 0<x<1; at least one heat resistant complex oxide; and at least one precious metal. The heat resistant complex oxide is one of ABO.sub.3, LnAlO.sub.3 or Ln.sub.2 B.sub.2 O.sub.7, wherein A represents at least one alkaline earth metal, B represents at least one of Ti, Zr and Hf, and Ln represents at least one rare earth metal, and the precious metal is at least one of Pt, Pd, Rh, Ir, Ru and Os. The catalyst is usable as a temperature of 900.degree. C. or above without sintering or reduction of a catalytic activity.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: May 1, 1990
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Masakuni Ozawa, Mareo Kimura, Akio Isogai
  • Patent number: 4843056
    Abstract: An exhaust gas purifying catalyst for oxidizing HC and CO and for reducing NOx is provided, which comprises at least one oxide of rare earth element, rhodium, and at least one of platinum and palladium loaded on alumina grains. The major amount of rhodium is dispersed on the oxide of rare earth element. Thus, the rhodium solidification into the alumina grains is prevented. Further, when cerium oxide accompanying lanthanum oxide, neodymium oxide or a mixture thereof is used as the oxide of rare earth element, the sintering of cerium oxide or palladium at a high temperature is suppressed since it forms a complex oxide with lanthanum oxide, neodymium oxide or a mixture thereof. Additionally, when stabilized alumina grains in which a rare earth element and an alkali earth element are present in a solid solution state are used, the deterioration of NOx purifying activity of the catalyst at a high temperature is suppressed.
    Type: Grant
    Filed: March 4, 1988
    Date of Patent: June 27, 1989
    Assignees: Kabushiki Kaisha Toyota Chuo Kenkusho, Toyota Jidosha Kabushiki Kaisha
    Inventors: Shinichi Matsumoto, Naoto Miyoshi, Hideaki Muraki, Hideo Sobukawa, Masayuki Fukui, Mareo Kimura, Hirofumi Shinjoh
  • Patent number: 4722920
    Abstract: An alumina catalyst support stable at high temperatures comprises transformative alumina having a purity not less than 99.95% impregnated with lanthanum in an amount of 1.5 to 6 wt % based on the weight of the alumina. The alumina catalyst support has a surface area of at least 60 m.sup.2 /g after heating at 1200.degree. C. for 5 hours.
    Type: Grant
    Filed: February 3, 1987
    Date of Patent: February 2, 1988
    Assignee: Kabushiki Kaisha Toyota Chuo Kenyusho
    Inventors: Mareo Kimura, Masakuni Ozawa, Akio Isogai
  • Patent number: 4655892
    Abstract: An oxygen sensor for sensing the oxygen content of an exhaust gas from an automotive engine and a process for producing the same, which sensor is less sensitive to lead poisoning than conventional sensors. In the inventive sensor, a first platinum electrode is formed on the side of a solid electrolyte body exposed to the gas to be detected, and a second electrode is formed on the other side of the electrolyte body. The first electrode comprises a platinum layer and a layer of at least one of rhodium and palladium. Preferably, the layer of rhodium or palladium has a thickness of 10 to 5,000 .ANG..
    Type: Grant
    Filed: July 24, 1985
    Date of Patent: April 7, 1987
    Assignee: Kabushiki Kaisha Toyota Chuo Kenkyusho
    Inventors: Kozo Satta, Hideo Hasegawa, Mareo Kimura