Patents by Inventor Mario Marchionna

Mario Marchionna has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9598652
    Abstract: A process for converting a heavy charge such as a heavy crude oil, a tar from oil sand and a distillation residue, by combining a hydroconversion with catalysts in slurry phase process, a distillation or flash process, and a deasphalting process, wherein the three processes operate on mixed streams consisting of fresh charge and recycled streams.
    Type: Grant
    Filed: November 18, 2013
    Date of Patent: March 21, 2017
    Assignee: ENI S.p.A.
    Inventors: Mario Marchionna, Alberto Delbianco, Nicoletta Panariti, Romolo Montanari, Sergio Rosi, Sebastiano Correra
  • Publication number: 20140197070
    Abstract: A process for converting a heavy charge such as a heavy crude oil, a tar from oil sand and a distillation residue, by combining a hydroconversion with catalysts in slurry phase process, a distillation or flash process, and a deasphalting process, wherein the three processes operate on mixed streams consisting of fresh charge and recycled streams.
    Type: Application
    Filed: November 18, 2013
    Publication date: July 17, 2014
    Applicant: ENI S.p.A
    Inventors: Mario MARCHIONNA, Alberto DELBIANCO, Nicoletta PANARITI, Romolo MONTANARI, Sergio ROSI, Sebastiano CORRERA
  • Publication number: 20130112593
    Abstract: Process for the conversion of heavy charge stocks selected from heavy and extra-heavy crude oils, distillation residues, heavy oils from catalytic treatment, thermal tars, bitumens from oil sands, carbons of different origins and other high boiling charges of a hydrocarbon origin known as “black oils”, using at least the following process units: solvent deasphalting (SDA), hydroconversion with slurry phase catalysts (HT), distillation or flash (D), which process includes: solvent deasphalting, thereby forming a deasphthalted oil (DAO), as described; hydrotreating the DAO in the presence of a hydrogenation catalyst precursor and hydrogen or hydrogen and H2S, as described; sending the product therefrom to distillation or flash (D) step(s), and separating the most volatile fractions from the distillation residue (tar) or from the liquid coming from the flash unit, as described; recycling at least a portion of the tar or the liquid, to the hydrotreating section, as described.
    Type: Application
    Filed: June 7, 2012
    Publication date: May 9, 2013
    Applicant: ENI S.p.A.
    Inventors: Romolo MONTANARI, Mario Marchionna, Sergio Rosi, Nicoletta Panariti, Alberto Delbianco
  • Publication number: 20120261309
    Abstract: Process for the conversion of heavy charges such as heavy crude oils, tars from oil sands and distillation residues, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), deasphalting (SDA), characterized in that the three units operate on mixed streams consisting of fresh charge and recycled streams, by the use of the following steps: sending at least one fraction of the heavy charge to a deasphalting section (SDA) in the presence of hydrocarbon solvents obtaining two streams, one consisting of deasphalted oil (DAO), the other of asphalts; mixing the asphalt with a suitable hydrogenation catalyst and optionally with the remaining fraction of heavy charge not sent to the deasphalting section and sending the mixture obtained to a hydro-treatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S is charged; sending the stream containing the hydro-treatment reaction product and the catalyst in dispersed phase t
    Type: Application
    Filed: June 25, 2012
    Publication date: October 18, 2012
    Applicant: ENI S.p.A.
    Inventors: Mario MARCHIONNA, Alberto Delbianco, Nicoletta Panariti, Romolo Montanari, Sergio Rosi, Sebastiano Correra
  • Patent number: 8147675
    Abstract: A process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues from crude oil or coming from catalytic treatment, visbreaker tars, thermal tars, bitumens from oil sands, liquids from coats of different origins and other high-boiling feedstocks of a hydrocarbon nature known as “black oils.
    Type: Grant
    Filed: July 27, 2007
    Date of Patent: April 3, 2012
    Assignee: ENI S.p.A.
    Inventors: Mario Marchionna, Salvatore Meli, Luigi Patron, Alberto Delbianco, Nicoletta Panariti
  • Patent number: 8123932
    Abstract: A process for the conversion of heavy feedstocks using hydrotreatment, distillation or flash, and deasphalting that includes mixing a heavy feedstock with a hydrogenation catalyst and subjecting the thus-formed mixture to a hydrotreatment reactor for reaction with one or more of hydrogen and hydrogen sulfide to form a first product stream; subjecting the first product stream to a distillation or flash to form a plurality of distillate fractions; and recycling heavies from the distillation residue and/or tar by deasphalting in the presence of a solvent; where the hydrotreatment reaction product is pre-separated under high pressure to form light and heavy fractions and sending the heavy fraction to the distillation and/or flash.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: February 28, 2012
    Assignees: Eni S.p.A., Snamprogetti S.p.A., Enitechnologie S.p.A.
    Inventors: Romolo Montanari, Mario Marchionna, Nicoletta Panariti, Alberto Delbianco, Sergio Rosi
  • Patent number: 8057660
    Abstract: Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues from crude oil or catalytic treatment, “visbreaker tars”, “thermal tars”, bitumens from “oil sands” liquids from coals of different origins and other high boiling feedstocks of a hydrocarbon origin.
    Type: Grant
    Filed: July 27, 2007
    Date of Patent: November 15, 2011
    Assignee: ENI S.p.A.
    Inventors: Mario Marchionna, Salvatore Meli, Luigi Patron, Alberto Delbianco, Nicoletta Panariti
  • Publication number: 20110253594
    Abstract: Process for the conversion of heavy charges such as heavy crude oils, tars from oil sands and distillation residues, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), deasphalting (SDA), characterized in that the three units operate on mixed streams consisting of fresh charge and recycled streams, by the use of the following steps: sending at least one fraction of the heavy charge to a deasphalting section (SDA) in the presence of hydrocarbon solvents obtaining two streams, one consisting of deasphalted oil (DAO), the other of asphalts; mixing the asphalt with a suitable hydrogenation catalyst and optionally with the remaining fraction of heavy charge not sent to the deasphalting section and sending the mixture obtained to a hydro-treatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S is charged; sending the stream containing the hydro-treatment reaction product and the catalyst in dispersed phase t
    Type: Application
    Filed: June 27, 2011
    Publication date: October 20, 2011
    Applicant: ENI S.P.A.
    Inventors: Mario MARCHIONNA, Alberto Delbianco, Nicoletta Panariti, Romolo Montanari, Sergio Rosi, Sebastiano Correra
  • Patent number: 8017000
    Abstract: Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues, heavy oils coming from catalytic treatment, thermal tars, oil sand bitumens, various kinds of coals and other high-boiling feedstocks of a hydrocarbon origin known as black oils, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), and deasphalting (SDA).
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: September 13, 2011
    Assignees: ENI S.p.A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Romolo Montanari, Mario Marchionna, Nicoletta Panariti, Alberto Delbianco, Sergio Rosi
  • Publication number: 20100300934
    Abstract: Process for the conversion of heavy charges such as heavy crude oils, tars from oil sands and distillation residues, by the combined use of process units hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), deasphalting (SDA), that includes three units operating on mixed streams containing of fresh charge and recycled streams, by sending at least one fraction of the heavy charge to a deasphalting section (SDA) in the presence of hydrocarbon solvents obtaining two streams, one containing of deasphalted oil (DAO), the other of asphalts; mixing the asphalt with a suitable hydrogenation catalyst and sending the mixture obtained to a hydro-treatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S is charged; sending the stream containing the hydro-treatment reaction product and the catalyst in dispersed phase to one or more distillation or flash steps (D) whereby the most volatile fractions are separated, among which the gases produced in the hydro-treatment reaction; r
    Type: Application
    Filed: March 17, 2010
    Publication date: December 2, 2010
    Applicant: ENI S.P.A.
    Inventors: Mario MARCHIONNA, Alberto Delbianco, Nicoletta Panariti, Romolo Montanari, Sergio Rosi, Sebastiano Correra
  • Patent number: 7691256
    Abstract: Heavy hydrocarbon charges are converted in a deasphalting section in the presence of solvents and obtaining two streams, one consisting of deasphalted oil and the other one containing asphaltenes, mixing the deasphalted oil stream with a hydrogenation catalyst and passing the thus obtained mixture to a hydroprocessing section containing hydrogen or hydrogen/H2S, mixing the stream consisting of asphaltenes discharged from the deasphalting section with an appropriate hydrogenation catalyst and passing the obtained mixture to a second hydroprocessing section where it is reacted with hydrogen or a mixture of hydrogen and H2S, passing both the stream containing the reaction product with dispersed catalyst from the hydroprocessing section and the stream containing the reaction product with dispersed catalyst from the second hydroprocessing section, to one or more distillation or flash stages, whereby the more volatile fractions are separated from the distillation residue (tar) or from the liquid discharged from the
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: April 6, 2010
    Assignees: ENI S.p.A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Romolo Montanari, Mario Marchionna, Sergio Rosi, Nicoletta Panariti, Alberto Delbianco
  • Publication number: 20090314681
    Abstract: Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues from crude oil or catalytic treatment, “visbreaker tars”, “thermal tars”, bitumens from “oil sands” liquids from coals of different origins and other high boiling feedstocks of a hydrocarbon origin, comprising the following steps: •mixing the heavy feedstock with a suitable hydrogenation catalyst and sending the mixture obtained to a first hydrotreatment area (HT1) to which hydrogen or a mixture of hydrogen and H2S are introduced; •sending the effluent stream from the first hydrotreatment area (HT1), containing the hydrotreatment reaction product and the catalyst in dispersed phase, to a first distillation area (D1) having one or more flash steps and/or atmospheric distillation and/or vacuum distillation whereby the various fractions coming from the hydrotreatment reaction are separated; •sending at least part of the distillation residue (tar) or liquid leaving the flash unit of the first distillation area (D1
    Type: Application
    Filed: July 27, 2007
    Publication date: December 24, 2009
    Applicant: ENI S.P.A.
    Inventors: Mario Marchionna, Salvatore Meli, Luigi Patron, Albert Delbianco, Nicoletta Panariti
  • Publication number: 20090261016
    Abstract: Process for the conversion of heavy feedstocks comprising the following steps: mixing the heavy feedstock with a suitable hydrogenation catalyst and sending the mixture obtained to a first hydrotreatment area (HT1) to which hydrogen or a mixture of hydrogen and H2S are introduced; sending the effluent stream from the first hydrotreatment area (HT1), containing the hydrotreatment reaction product and the catalyst in dispersed phase, to a first distillation area (D1) having one or more flash steps and/or atmospheric distillation and/or vacuum distillation whereby the various fractions coming from the hydrotreatment reaction are separated; sending at least part of the distillation residue (tar) or liquid leaving the flash unit of the first distillation area (D1), containing the catalyst in dispersed phase, rich in metallic sulfides produced by demetallation of the feedstock and optionally minimum quantities of coke, to a deasphalting area (SDA) in the presence of solvents or to a physical separation area, obtain
    Type: Application
    Filed: July 27, 2007
    Publication date: October 22, 2009
    Applicant: ENI S.p.A.
    Inventors: Mario Marchionna, Salvatore Meli, Luigi Patron, Alberto Delbianco, Nicoletta Panariti
  • Publication number: 20090101540
    Abstract: Process for the conversion of heavy charges such as heavy crude oils, tars from oil sands and distillation residues, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), deasphalting (SDA), characterized in that the three units operate on mixed streams consisting of fresh charge and recycled streams, by the use of the following steps: sending at least one fraction of the heavy charge to a deasphalting section (SDA) in the presence of hydrocarbon solvents obtaining two streams, one consisting of deasphalted oil (DAO), the other of asphalts; mixing the asphalt with a suitable hydrogenation catalyst and optionally with the remaining fraction of heavy charge not sent to the deasphalting section and sending the mixture obtained to a hydro-treatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S is charged; sending the stream containing the hydro-treatment reaction product and the catalyst in dispersed phase t
    Type: Application
    Filed: October 9, 2008
    Publication date: April 23, 2009
    Applicants: ENI S.P. A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Mario MARCHIONNA, Alberto Delbianco, Nicoletta Panariti, Romolo Montanari, Sergio Rosi, Sebastiano Correra
  • Patent number: 7339086
    Abstract: A process is described for the hydrogenation of olefinic streams containing sulfurated compounds, obtained starting from hydrocarbon cuts containing isobutene (by means of selective dimerization), characterized by fractionating said streams in one or more distillation columns and hydrogenating separately the two fractions obtained. The stream at the head, with a minimum content of sulfurated compounds, is hydrogenated with conventional catalysts based on nickel or noble metals (Platinum and/or Palladium), extremely active but also very sensitive to sulfur, whereas the bottom of the column, rich in sulfurated compounds, is treated with bimetallic catalysts (for example Ni/Co and/or Ni/Mo), less active but not deactivated by sulfur.
    Type: Grant
    Filed: October 7, 2002
    Date of Patent: March 4, 2008
    Assignee: SNAMPROGETTI S.p.A.
    Inventors: Marco Di Gerolamo, Roberto Catani, Mario Marchionna
  • Patent number: 7235113
    Abstract: Use of a liquid oxygenated product with a cetane number higher than 50, consisting of one or more compounds selected from dialkyl-polyformals represented by the formula RO(CH2O)mR wherein R is an alkyl chain CnH2n+1, m is an integer equal to or higher than 2, n is an integer between 1 and 10, as a substitute of gas oil in diesel engines.
    Type: Grant
    Filed: November 20, 2003
    Date of Patent: June 26, 2007
    Assignees: ENI S.p.A., Snamprogetti S.p.A.
    Inventors: Domenico Sanfilippo, Renata Patrini, Mario Marchionna
  • Publication number: 20060272982
    Abstract: Process for the conversion of heavy charge stocks selected from heavy and extra-heavy crude oils, distillation residues, heavy oils from catalytic treatment, thermal tars, bitumens from oil sands, carbons of different origins and other high boiling charges of a hydrocarbon origin known as “black oils”, by means of the combined used of at least the three following process units: solvent deasphalting (SDA), hydroconversion with slurry phase catalysts (HT), distillation or flash (D), characterized in that it comprises the following steps: sending the heavy charge stock to a deasphalting section (SDA) in the presence of solvents, obtaining two streams, one consisting of deasphalted oil (DAO), the other containing asphaltenes; mixing the stream consisting of deasphalted oil (DAO) with a suitable hydrogenation catalyst precursor and sending the mix obtained to a hydrotreating reactor (HT), introducing, into the same reactor, hydrogen or a mix containing hydrogen and H2S; sending the stream containing the product
    Type: Application
    Filed: December 20, 2005
    Publication date: December 7, 2006
    Applicants: ENI S.p.A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Romolo Montanari, Mario Marchionna, Sergio Rosi, Nicoletta Panariti, Alberto Delbianco
  • Publication number: 20060186021
    Abstract: Process for the conversion of heavy charges such as heavy crude oils, tars from oil sands and distillation residues, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), deasphalting (SDA), characterized in that the three units operate on mixed streams consisting of fresh charge and recycled streams, by the use of the following steps: sending at least one fraction of the heavy charge to a deasphalting section (SDA) in the presence of hydrocarbon solvents obtaining two streams, one consisting of deasphalted oil (DAO), the other of asphalts; mixing the asphalt with a suitable hydrogenation catalyst and optionally with the remaining fraction of heavy charge not sent to the deasphalting section and sending the mixture obtained to a hydro-treatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S is charged; sending the stream containing the hydro-treatment reaction product and the catalyst in dispersed phase t
    Type: Application
    Filed: April 17, 2006
    Publication date: August 24, 2006
    Applicants: ENI S.p.A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Mario Marchionna, Alberto Delbianco, Nicoletta Panariti, Romolo Montanari, Sergio Rosi, Sebastiano Correra
  • Publication number: 20060175229
    Abstract: Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues, heavy oils coming from catalytic treatment, thermal tars, oil sand bitumens, various kinds of coals and other high-boiling feedstocks of a hydrocarbon origin known as black oils, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), deasphalting (SDA), comprising the following steps: mixing at least part of the heavy feedstock and/or at least most of the stream containing asphaltenes obtained in the deasphalting unit with a suitable hydrogenation catalyst and sending the mixture obtained to a hydrotreatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S is charged; sending the stream containing the hydrotreatment reaction product and the catalyst in dispersed phase to one or more distillation or flash steps (D) whereby the different fractions coming from the hydrotreatment reaction are separated; recycling a
    Type: Application
    Filed: December 12, 2003
    Publication date: August 10, 2006
    Applicants: edni s.p.a, snamprogetti s.p.a, enitechologie s.pa.
    Inventors: Romolo Montanari, Mario Marchionna, Nicoletta Panariti, Alberto Delbianco, Sergio Rosi
  • Publication number: 20060163115
    Abstract: Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues, heavy oils coming from catalytic treatment, thermal tars, oil sand bitumens, various kinds of coals and other high-boiling feedstocks of a hydrocarbon origin known as black oils, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), deasphalting (SDA), comprising the following steps: • mixing at least part of the heavy feedstock and/or at least most of the stream containing asphaltenes obtained in the deasphalting unit with a suitable hydrogenation catalyst and sending the mixture obtained to a hydrotreatment reactor (HT) into which hydrogen or a mixture of hydrogen and H2S is charged; • sending the stream containing the hydrotreatment reaction product and the catalyst in dispersed phase to one or more distillation or flash steps (D) whereby the different fractions coming from the hydrotreatment reaction are separated; • recyc
    Type: Application
    Filed: December 12, 2003
    Publication date: July 27, 2006
    Applicants: ENI S.P.A., SNAMPROGETTI S.P.A., ENITECNOLGIE S.P.A.
    Inventors: Romolo Montanari, Mario Marchionna, Nicoletta Panariti, Alberto Delbianco, Sergio Rosi