Abstract: The invention provides the advantages of a metallic housing and those of a synthetic resin structure for electronic devices, home electrical devices, etc., achieves high productivity and mass productivity, and enables a desired configuration and structure to be designed freely. As a pretreatment, a shaped aluminum alloy material is dipped in an aqueous solution of at least one selected from the group consisting of ammonia, hydrazine, and a water-soluble amine compound. A thermoplastic resin composition containing polyphenylene sulfide as a component is integrally bonded to the surface of the treated shaped aluminum alloy material by injection molding or other method. The molded article is a product made of the shaped aluminum alloy material and the thermoplastic resin composition containing PPS. Thus, the characteristic features of metal can be utilized in terms of mechanical strength and external appearance design. Moreover, a complicated configuration and structure can be formed inside the housing.

Abstract: In the composite, an aluminum-plated steel sheet and a resin are securely and integrally joined together. Through chemical etching, the aluminum-plated steel sheet is caused to have a surface configuration, in which three-dimensional protrusions having shapes with a minor diameter of at least 0.3 ?m and a major diameter of at least 3 ?m are scattered over a plain part and a portion covered with shallow fine recesses with a diameter of 20 to 50 nm in a state of being distributed adjacent to each other on the plain part accounts for 30 to 50% of the surface area of the plain part. The surface of the three-dimensional protrusions is mainly ceramic containing silicon and the plain part is mainly ceramic containing aluminum. The resin is joined through injection molding with the aluminum-plated steel sheet having been inserted into a metallic mold.

Abstract: A composite of a magnesium part or a magnesium alloy part and a resin composition, improved to have high corrosion resistance, is manufactured by: a step of shaping a magnesium alloy part 1 from a casting or an intermediate material; a step of immersing and chemically etching the shaped part in an acidic aqueous solution; a step of immersing the chemically etched shaped part in an aqueous solution containing potassium permanganate and forming on the surface thereof a thin layer having manganese oxide as a component; a step of inserting the part, on which the thin layer has been formed, into a metallic mold for injection molding and injecting into the mold a resin composition selected out of a resin composition whose main component is polyphenylene sulfide, a resin composition whose main component is a polybutylene terephthalate resin and a resin composition whose main component is an aromatic polyamide resin and then integrally affixing the magnesium alloy part 1 and the resin composition 4; and a step of sub

Abstract: In the composite, an aluminum-plated steel sheet and a resin are securely and integrally joined together. Through chemical etching, the aluminum-plated steel sheet is caused to have a surface configuration, in which three-dimensional protrusions having shapes with a minor diameter of at least 0.3 ?m and a major diameter of at least 3 ?m are scattered over a plain part and a portion covered with shallow fine recesses with a diameter of 20 to 50 nm in a state of being distributed adjacent to each other on the plain part accounts for 30 to 50% of the surface area of the plain part. The surface of the three-dimensional protrusions is mainly ceramic containing silicon and the plain part is mainly ceramic containing aluminum. The resin is joined through injection molding with the aluminum-plated steel sheet having been inserted into a metallic mold.

Abstract: An object of the present invention is to obtain a composite in which a copper or copper alloy is securely integrated with and joined to PBT or PPS. A copper product that has been suitably roughened by chemical etching and also blackened can be used favorably. A surface-treated copper piece 1 is inserted into a cavity formed by a movable molding plate 2 and a stationary molding plate 3 of an injection molding mold 10, and a specific resin is injected to obtain an integrated product. PBT or PPS can be used as the resin component of a resin composition 4 that is used here. High injection joining strength is obtained if the resin composition contains, as an auxiliary component, PET and/or a polyolefin resin in the case of PBT, and a polyolefin resin in the case of PPS.

Abstract: A composite of a metal and a resin, in which a shaped metal and a shaped thermoplastic resin are integrally joined by injection molding, and in which the perpendicular precision of the thermoplastic shaped body with respect to the shaped metal is improved, as well as a method for manufacturing the composite. A composite 40 of a metal and a resin is composed of a shaped metal 20 and a shaped thermoplastic resin that is integrally joined to this shaped metal 20 by injection molding. The shaped thermoplastic resin comprises a seat 42 and a boss 41 that protrudes from the seat 42. A runner 43 is provided which communicates with the seat 42 via two sprues and through which a molten thermoplastic resin that has been injected through an injection gate 45 flows into the boss 41 and the thermoplastic resin injected through the injection gate 45 flows through the sprues 47 to opposite locations of the boss 41 substantially uniformly, thereby filling the locations.

Abstract: An outer casing of a non-aqueous electrolyte battery is capable of being mass-produced as well as thin and resistant to damage. The outer casing 4 comprises a casing body 4a and a cover 4b. After being internally packaged, a non-aqueous electrolyte battery 2, e.g. a lithium-ion polymer secondary battery, is sandwiched between the casing body 4a and the cover 4b, which are then joined together integrally. The cover 4b is formed from a film-shaped sheet material 4c of a synthetic resin to make the outer casing 4 thin. The casing body 4a and the cover 4b have a casing body outer peripheral frame 9 and a cover outer peripheral frame 10, respectively, formed by injection molding. Joint portions of the casing body 4a and the cover 4b have stepped portions 9a and 10a, respectively. The stepped portions ensure the mechanical strength against shock and impact. With this structure, the outer casing 4 is resistant to damage.

Abstract: The surface of an aluminum alloy shaped product is covered with ultrafine recesses by being dipped in an eroding aqueous solution, or has formed thereon a metal oxide layer covered with the openings of ultrafine pores by anodizing. On the resin side, there is prepared a polyamide resin compounded with an impact resistance modifier, a mixture of an aliphatic polyamide and an aromatic polyamide, or a mixture of aromatic polyamides. The aluminum alloy shaped product is inserted into an injection mold, and a polyamide-type resin composition is injected onto the surface of the aluminum alloy shaped product, to manufacture an integrated composite.

Abstract: An optical sheet retaining tool for a liquid crystal display device that has a simple structure and low cost, wherein assembling and disassembling can be performed easily. The optical sheet retaining tool includes a first retaining piece 21 having a first retaining part 211 made of a soft material for retaining an optical sheet 13, a second retaining piece 22 having a second retaining part 221 made of a soft material opposed to and cooperating with the first retaining part for gripping and retaining the optical sheet, a latching section 24 for latching the first and second retaining parts with the optical sheet gripped therebetween, a fixing section 24 for retaining and fixing the first and second retaining pieces to a chassis 1, and a bearing section 23 disposed on at least one of the first and second retaining pieces for gripping the optical sheet.

Abstract: The invention is a technique for strongly integrating a galvanized steel sheet and a resin molded article. A hot-dip galvanized steel sheet “Z18” is immersed in an aqueous solution for aluminum degreasing at 75° C. for 7 minutes, to form roughness having an RSm of 0.8 to 2.3 ?m and an Rz of 0.3 to 1.0 ?m on the surface. The surface is covered with convex protrusions having a diameter of about 100 nm, and a chromate treatment layer appears in the surface. In other words, three conditions suitable for bonding are satisfied thereby. A resin composition comprising 70 to 97 wt % of polyphenylene sulfide and 3 to 30 wt % of a polyolefin resin is injected onto the surface. The resin composition penetrates into ultra-fine irregularities and is cured in that state, whereby a composite in which the galvanized steel sheet and the resin molded article are strongly integrated is obtained. The shear rupture strength of the composite is extremely high, in excess of 20 MPa.

Abstract: An object of the present invention is to obtain a composite in which a copper or copper alloy is securely integrated with and joined to PBT or PPS. A copper product that has been suitably roughened by chemical etching and also blackened can be used favorably. A surface-treated copper piece 1 is inserted into a cavity formed by a movable molding plate 2 and a stationary molding plate 3 of an injection molding mold 10, and a specific resin is injected to obtain an integrated product. PBT or PPS can be used as the resin component of a resin composition 4 that is used here. High injection joining strength is obtained if the resin composition contains, as an auxiliary component, PET and/or a polyolefin resin in the case of PBT, and a polyolefin resin in the case of PPS.

Abstract: It is an object of the present invention to securely and integrally join a metal and a resin, more particularly, a shaped titanium alloy substrate and a resin composition. A titanium alloy substrate is used that has undergone surface roughening by chemical etching or the like so as to have a ultrafine textured face in which bent, ridge-like protrusions having a width and height of from ten to a few hundred nanometers and a length of from a few to a few hundred microns rise up on the surface at a spacing period of from ten to a few hundred nanometers. A titanium alloy piece 1 with its surface treated is inserted into the cavity of a metallic mold for injection molding 10 and a specific resin composition 4 is injected to obtain an integrated composite 7. The main resin component of the resin composition 4 that is used can be a polyphenylene sulfide resin (PPS) or a polybutylene terephthalate resin (PBT).

Abstract: The present invention provides an air-permeable porous structural body that can be used for a vent plug or the like and imposes a low environmental load in waste treatment or the like after use, and also provides a vent plug using the porous structural body. Further, the invention provides an air-permeable porous structural body that can be molded by injection molding that has high productivity. The porous structural body has an overall structure entirely occupied by a structure composed of an infinite number of spherical or ellipsoidal cavities having a diameter of 1 ?m to 100 ?m. Holes are open in cavity walls and the cavity is linked to another cavity by the holes.

Abstract: Disclosed is a composite in which an aluminum-plated steel sheet and a resin are securely and integrally joined together, as well as a corrosion resistant steel sheet. Through chemical etching the aluminum-plated steel sheet is caused to have a surface configuration, in which three-dimensional protrusions having pebble-like shapes with a diameter of at least about 0.3 ?m or having irregular shapes with a minor diameter of at least 0.3 ?m and a major diameter of at least several microns are scattered over a plain-like part, where 30 to 50% of the surface area of the plain-like part is accounted for by a portion covered with shallow recesses having a diameter of 20 to 50 nm in a state of being distributed adjacent to each other. The surface of the three-dimensional protrusions is mainly ceramic containing silicon and the flat part is mainly a ceramic containing aluminum.

Abstract: The present invention provides an excellent structural material for movable equipment, structural members for building materials, electronic and electrical equipment and the like by bonding an ordinary steel material and an FRP prepreg strongly to each other to facilitate mechanical joining and disassembly using bolts and nuts or the like. It has been found that a steel material having surface configuration with specifically determined ultra-fine irregularities is compatible with an epoxy resin adhesive and exhibits thus strong adhesion. This technique can be utilized to produce a composite component 26 that comprises steel plates 28, as a cover material, integrated with FRP 27. The composite component can be assembled with other metallic members through fastening using bolts 30. Also, structural members having the FRP 27 in the main structure and the steel material at the ends can be easily produced by virtue of the above strong adhesion.

Abstract: A metal and resin composite in which a metal and a resin, especially a shaped base made of an ordinary steel material and a resin composition can be strongly joined to and integrated with each other; and a method for producing the composite. The surface of a shaped ordinary steel material is treated by chemical etching or the like to form a thin layer of a natural oxide of iron, substantially completely covered with ultra-fine irregularities, onto which hydrazine, ammonia or a water-soluble amine is chemically adsorbed. The resulting ferrous material shaped article 1 is inserted into an injection mold 10 and a specific resin composition 4 is injected thereinto. The surface of the ferrous material formed-article 1 may have a thin layer of a metal oxide or metal phosphate. The above injection yields a composite 7 in which an ordinary steel material is strongly joined to a resin.

Abstract: An outer casing of a non-aqueous electrolyte battery is capable of being mass-produced as well as thin and resistant to damage. The outer casing 4 comprises a casing body 4a and a cover 4b. After being internally packaged, a non-aqueous electrolyte battery 2, e.g. a lithium-ion polymer secondary battery, is sandwiched between the casing body 4a and the cover 4b, which are then joined together integrally. The cover 4b is formed from a film-shaped sheet material 4c of a synthetic resin to make the outer casing 4 thin. The casing body 4a and the cover 4b have a casing body outer peripheral frame 9 and a cover outer peripheral frame 10, respectively, formed by injection molding. Joint portions of the casing body 4a and the cover 4b have stepped portions 9a and 10a, respectively. The stepped portions ensure the mechanical strength against shock and impact. With this structure, the outer casing 4 is resistant to damage.

Abstract: An integrated product whose joint strength between a copper alloy and a carbon fiber prepreg is extremely high. A copper alloy given a certain special surface shape yields tremendous bonding strength through compatibility with an epoxy resin adhesive. With a composite part in which this technology is utilized to integrate a copper alloy member as a cover material with a CFRP, it is possible to take advantage of the characteristics of both the copper alloy and the FRP due to the tremendous bonding strength. In a step in which an FRP prepreg is put into a mold and heated and cured, usually the mold is first coated with a release agent to facilitate release from the mold, but with high-technology CFRP, bleeding of the release agent often diminishes the properties. A copper alloy sheet 21 is used as a cover material, and a CFRP 22 is cured.

Abstract: An object of the present invention is to create, from a titanium alloy and an FRP prepreg, a composite of a titanium alloy and an FRP material that is suitable for bolt fastening. The composite can bring out excellent characteristics in CFRP members in mobile electronic-electric devices, mobile equipment, medical instruments, marine devices and the like. It has been found that titanium alloy having a special constant surface shape adheres strongly with an epoxy adhesive. In a composite obtained using this technique to integrate a titanium alloy member as a cover material and a CFRP material, the metal alloy portion deforms and disperses locally strong forces so that the CFRP material is not damaged, even when the composite is assembled to another metal member through bolt-fastening. As a result, the composite is expected to be effective for applications in mobile equipment or mobile device casings, where lightweightness, corrosion resistance, toughness and ease of assembly are required.

Abstract: A CFRP-integrated stainless steel complex used for a hydrogen containing tank, a food processing machine, a medical device, a general-purpose machine, and other machines can be designed as a further rational design product with a smaller weight. It has been found that a stainless steel material (22) having particular ultra-micro convex/concave shapes exhibits an excellent adhesive force in combination with an epoxy resin adhesive agent. By using the technique, a stainless steel thick plate piece (22) is used as a cover material in combination with a CFRP (21) to obtain a stainless steel complex (20). This can be assembled with other metal member by tightening bolts. Moreover, by using the excellent adhesive force, it is possible to easily create a structure member having a main portion of CFRP (21) and an end portion of metal. This can be easily assembled with and disassembled from other part by using bolts/nuts and screws.