Abstract: The invention provides an amorphous copolymerized polyester raw material for a film. The raw material contains ethylene terephthalate as a main constituent component, and contains from 18% by mol to 30% by mol of neopentyl glycol when a total amount of a glycol component in a total polyester resin component is taken as 100% by mol. The raw material contains from 8% by mol to 16% by mol of a constituent unit derived from diethylene glycol in the total amount (100% by mol) of the glycol component in the total polyester resin component. The raw material has an intrinsic viscosity of from 0.70 dl/g to 0.86 dl/g. The raw material has a melt viscosity of 200 Pa·S or less, when measured at a shear rate of 6080/S at 250° C.

Abstract: The present invention provides a void-containing heat-shrinkable polyester film which has satisfactory shrinkage finishing properties and printability even if productivity is improved. The void-containing heat-shrinkable polyester film is a multilayer structure having a non-foamed layer on both outer sides of the foamed layer, and by controlling the film thickness, density, and number of moles of the amorphous component on both outer sides, specific heat shrinkage characteristics and gloss can be improved.

Abstract: The present invention provides a void-containing heat-shrinkable polyester film which has satisfactory shrinkage finishing properties and printability even if productivity is improved. The void-containing heat-shrinkable polyester film is a multilayer structure having a non-foamed layer on both outer sides of the foamed layer, and by controlling the film thickness, density, and number of moles of the amorphous component on both outer sides, specific heat shrinkage characteristics and gloss can be improved.

Abstract: The polyester film is formed with a polyester resin whose main constituent component is ethylene terephthalate. The polyester film has two or more layers that include at least one fold holding layer, which is present on at least one of the film surfaces and has a total of at least one monomer component that can form an amorphous component of 12-30% by mol in all monomer components of the fold holding layer and a difference in amount of an amorphous component of 4-30% by mol obtained by deducting an amount of an amorphous component in a layer other than the fold holding layer from the amount of the amorphous component in the fold holding layer. The polyester film has a fold holding angle of 20-70 degrees and a heat shrinkage rate of 0-15% in the longitudinal and width directions when treated in 80° C. hot water for 10 seconds.

Abstract: The invention provides a heat-shrinkable polyester film which has sufficient heat shrinkage properties in the main shrinkage direction that is the longitudinal direction without containing a monomer component that can form an amorphous component in a large amount, and which has a low heat shrinkage and a low shrinkage stress in the width direction orthogonal to the main shrinkage direction. The film has a heat shrinkage of 15-50% in a main shrinkage direction of the film and 0-12% in a direction orthogonal to the main shrinkage direction of the film, when treated for 10 seconds in hot water of 90° C., and a maximum shrinkage stress of 2-10 MPa in the main shrinkage direction of the film when measured under hot air of 90° C. The film contains 7-30 mol % of a constituent unit derived from diethylene glycol in 100 mol % of the whole polyester resin component.

Abstract: The invention provides a polyester film for sealant use. The polyester film contains a polyester resin having ethylene terephthalate as a main structural component and including one or more monomer components that may serve as amorphous components so that the total amount of the monomer components are not less than 12 mol % and not more than 30 mol % among total monomer components. The polyester film is uniaxially or biaxially stretched, and has a particular heat-sealing strength and crystal melting heat capacity. The invention also provides a laminate including as at least one layer of the polyester film for sealant use, as well as a packaging bag that utilizes the laminate.

Abstract: The invention provides a heat-shrinkable polyester-based film comprising ethylene terephthalate units, constituent units derived from at least one monomer which forms an amorphous component, and constituent units derived from butanediol. The amount of the constituent units derived from at least one monomer which forms an amorphous component is 18 mol % or more, and the amount of the constituent units derived from butanediol is 1 to 25 mol % based on 100 mol % of all polyester resin components. The heat-shrinkable polyester-based film is characterized by particular values for the secondary shrinkage ratio of the film, the hot-water heat shrinkage ratio of the film, and the reversing heat capacity difference before and after the glass transition temperature of the film.

Abstract: The invention provides a roll of a white heat-shrinkable polyester-based film containing titanium oxide which can suppress occurrence of a processing trouble of a label or the like cut out from the roll, even when widening the roll. The roll of the white heat-shrinkable polyester-based film satisfies the following requirements: (1) the length of the film is 1,000-20,000 m and the width of the film is 400-10,000 mm, (2) the heat-shrinkage ratio in a main shrinkage direction is 50-85%, (3,4) the difference between the maximum and minimum heat-shrinkage ratio in the main shrinkage direction is 0-3% among samples which are sampled in each of the width and longitudinal directions of the film, and (5,6) the difference between the maximum and minimum apparent specific gravity is 0-0.01 g/cm3 among samples which are sampled in each of the width and longitudinal directions of the film.

Abstract: Provided is a heat-shrinkable polyester film that suppresses deterioration of the shrinkage finish property associated with a decline in performance during aging and does not loosen even after being used as a label. This heat-shrinkable polyester film comprising a polyester of a predetermined composition fulfills all of the following: (1) a ratio A1/A2 of the absorbancy (A1) at 1340 cm?1 and the absorbancy (A2) at 1410 cm?1 of the film measured by polarized ATR-FTIR from 0.45 to 0.75 or from 0.40 to less than 0.45 in either the width direction or longitudinal direction of the film; (2) a ratio (shrinkage stress after 30 seconds/maximum shrinkage stress) of the shrinkage stress after 30 seconds when the film is heat shrunk for 30 seconds in 90° C. hot air (shrinkage stress after 30 seconds) and the maximum shrinkage stress of from 75% to 100%; and (3) a hot-water shrinkage in the width direction of from 30% to 55% when, after aging the film for 672 hours in a 30° C.

Abstract: The invention provides a heat-shrinkable polyester film, which has a main shrinkage direction in a longer direction, exhibits a higher shrinkage ratio in the main shrinkage direction, has small difference in shrinkage ratio at a high temperature and a low temperature so as not likely to generate wrinkles or the like when being used as a label, and exhibits small over-time decrease in shrinkage ratio at a low temperature. The heat-shrinkable polyester film has, as a main component, ethyleneterephthalate, and an amount of a diethyleneglycol (DEG) component is 10-25 mol % with respect to 100 mol % of a polyhydric alcohol component in all of polyester resin that composes the film.

Abstract: A heat-shrinkable polyester-based film is provided, which is heat-shrinkable in the longitudinal direction and which is freed from various problems, particularly curling-up or peeling in a bonded area. The heat-shrinkable polyester-based film is characterized by an A1/A2 (absorbance) ratio in the longitudinal direction, which is the main shrinking direction of the film, of 0.55 to 1, with an A1/A2 ratio in the width direction perpendicular to the main shrinking direction of 0.5 to 0.9, wherein A1 is the absorbance of the film at 1340 cm?1 and A2 is the absorbance of the film at 1410 cm?1 as determined by polarized ATR-FTIR spectroscopy, and a hot-water shrinkage of 35 to 60% in the longitudinal direction of the film and ?3 to 12% in the width direction of the film, wherein the hot-water shrinkage is determined by dipping the film in hot water at 90° C. for 10 seconds.

Abstract: The present invention provides a polyester film suitable for use as a sealant, which not only has high heat sealing strength, but also is less liable to adsorb various organic compounds, and has a less shrinkage in heating and high tensile strength. Further, the present invention provides a laminate comprising at least one layer of the polyester film, and a packaging bag including the same. The polyester film which is formed with a polyester resin whose main constituent is ethylene terephthalate. The film has at least one heat sealing layer. The film has a predetermined heat sealing strength, a predetermined difference in reversing heat capacity measured with a temperature modulated DSC, and a predetermined heat shrinkage. Further, the laminate comprises at least one layer of the polyester film, and the packaging bag includes the same.

Abstract: A heat-shrinkable polyester film comprising ethylene terephthalate as a main component, containing not less than 0 mol % and not more than 5 mol % of a monomer component capable of serving as an amorphous component relative to the total of a polyester resin component, and having a main shrinkage direction in a lengthwise direction, wherein the heat-shrinkable polyester film satisfies heat shrinkage characteristics of the width direction and the lengthwise direction and the molecular orientation angle difference which is a difference between a molecular orientation angle of an edge of one end in the width direction and a molecular orientation angle of an edge of the other end.

Abstract: The invention provides a heat-shrinkable polyester film which has a high heat shrinkage rate in the width direction, exhibits a low heat shrinkage rate in the longitudinal direction, and has a great mechanical strength in the longitudinal direction, good openability along perforations, and excellent shrink finish. The film has a hot-water heat shrinkage rate of 40% to 85% in the main shrinking direction and ?5% to 15% in the perpendicular direction when the film is immersed in hot water at 98° C. for 10 seconds, and a maximum shrinkage stress of 2-7 MPa in the main shrinking direction when measured in hot air of 90° C. and the shrinkage stress 30 seconds after measurement of the shrinkage stress has started is of 60-100% of the maximum shrinkage stress. The film contains 6 mol % or more of diethylene glycol-derived constituent units with respect to 100 mol % of all polyester resin components.

Abstract: The inventive label is prepared from a polyester with an intrinsic viscosity of 0.58 dl/g or more. The label has a base film with a thickness of 8-30 ?m and a difference in specific heat capacity ?Cp between temperatures lower and higher than Tg of 0.2 J/(g·° C.) or more. The label has a tensile elongation at break of 5% or more in both a main shrinkage direction and an orthogonal direction. A difference between the absorbancy ratio (absorbancy at 1340 cm?1/absorbancy at 1410 cm?1) in the main shrinkage direction of the label and the absorbancy ratio in the direction orthogonal to the main shrinkage direction of the label is 0.2 or more. The label has a difference between a maximum value and a minimum value of a length in a vertical direction of the label of 3 mm or less.

Abstract: The invention provides a heat-shrinkable polyester film which has sufficient heat shrinkage properties in the main shrinkage direction that is the longitudinal direction without containing a monomer component that can form an amorphous component in a large amount, and which has a low heat shrinkage and a low shrinkage stress in the width direction orthogonal to the main shrinkage direction. The film has a heat shrinkage of 15-50% in a main shrinkage direction of the film and 0-12% in a direction orthogonal to the main shrinkage direction of the film, when treated for 10 seconds in hot water of 90° C., and a maximum shrinkage stress of 2-10 MPa in the main shrinkage direction of the film when measured under hot air of 90° C. The film contains 7-30 mol % of a constituent unit derived from diethylene glycol in 100 mol % of the whole polyester resin component.

Abstract: The invention provides a heat shrinkable polyester film which has (1) a hot-water heat shrinkage of not less than 55% and not more than 90% in a main shrinking direction of the film when dipped in hot water at 98° C.; (2) a hot-water heat shrinkage of not less than ?5% and not more than 12% in a direction orthogonal to the main shrinking direction of the film when dipped in hot water at 98° C.; (3) a difference in specific heat capacity ?Cp between at a lower and a higher temperature than Tg of not less than 0.1 J/(g·° C.) and not more than 0.7 J/(g·° C.) when a reverse heat flow is measured with a temperature modulated DSC; and (4) a tensile breaking strength of not less than 70 MPa and not more than 150 MPa in the direction orthogonal to the main shrinking direction of the film.

Abstract: The invention provides a heat-shrinkable polyester film which has a high heat shrinkage rate in the width direction, exhibits a low heat shrinkage rate in the longitudinal direction, and has a great mechanical strength in the longitudinal direction, good openability along perforations, and excellent shrink finish. The film has a hot-water heat shrinkage rate of 40% to 85% in the main shrinking direction and ?5% to 15% in the perpendicular direction when the film is immersed in hot water at 98° C. for 10 seconds, and a maximum shrinkage stress of 2-7 MPa in the main shrinking direction when measured in hot air of 90° C. and the shrinkage stress 30 seconds after measurement of the shrinkage stress has started is of 60-100% of the maximum shrinkage stress. The film contains 6 mol % or more of diethylene glycol-derived constituent units with respect to 100 mol % of all polyester resin components.

Abstract: The invention provides a heat-shrinkable polyester film which has sufficient heat shrinkage properties in a main shrinkage direction that is in the longitudinal direction, has low heat shrinkage in the width direction orthogonal to the main shrinkage direction, does not have excessively high shrinkage stress in the main shrinkage direction, and has small attenuation of the shrinkage stress, whereby the followability to a container which is an object to be packaged is high, and slack is less likely to be generated.