Abstract: Force-sensing capacitor elements and deformable membranes useful in electronic devices that include touch screen displays or other touch sensors. The deformable membranes, generally, include a first, second, and third layers with a first arrangement of a plurality of first structures interposed between the first and third layers and a second arrangement of one or more second structures interposed between the second and third layers. Electrodes may be included proximate to or in contact with one or more of the major surfaces of the first, second, and third layers or embedded within one or more of the second and third layers of the deformable membranes, yielding force-sensing capacitor elements. The electrodes proximate to or in contact with the one or more of the major surfaces of the first and second layers or embedded within one or more of the second and third layers may be one or more plurality of electrodes.

Abstract: A method includes providing an elastomeric stamp including a stamping surface with a first pattern element having a fill factor of 20 to 99 percent and including a continuous region and at least one discontinuous region, the discontinuous region including at least one of: (1) one or more elongated concavities, and (2) one or more interior voids. A second pattern element of the stamping surface has a fill factor of 0.25 to 10 percent, and includes traces with a width from 0.1 micrometers to 50 micrometers. The stamping surface is inked with an ink composition including a functionalizing molecule with a functional group selected to bind to a surface of the ink-receptive material. The inked stamping surface is contacted with an ink-receptive material selected from a sheet or a web for a contact time sufficient to bind the functional group with the surface of the ink-receptive material to form a self-assembled monolayer (SAM) of the functionalizing material.

Abstract: Apparatus and methods of applying a pattern onto a web with improved uniformity are provided. One or more micro-contact printing stamps are disposed onto a roll with a seam between each adjacent stamp edge. The micro-contact printing stamps are configured and arranged such that the web always contacts the micro-contact printing stamps to provide a consistent contacting pressure to drive the roll.

Abstract: A touch screen sensor includes a visible light transparent substrate and an electrically conductive micropattern disposed on or in the visible light transparent substrate. The micropattern includes a first region micropattern within a touch sensing area and a second region micropattern. The first region micropattern has a first sheet resistance value in a first direction, is visible light transparent, and has at least 90% open area. The second region micropattern has a second sheet resistance value in the first direction. The first sheet resistance value is different from the second sheet resistance value.

Abstract: A fuel cell membrane electrode assembly is provided comprising a polymer electrolyte membrane comprising a first polymer electrolyte and at least one manganese compound; and one or more electrode layers comprising a catalyst and at least one cerium compound. The membrane electrode assembly demonstrates an unexpected combination of durability and performance.

Abstract: The present disclosure relates to deformable membranes and force-sensing capacitor elements useful, for example, in electronic devices that include, for example touch screen displays or other touch sensors. The deformable membranes, generally, include a first, second and third layers, with a first arrangement of a plurality of first structures interposed between the first and third layers and a second arrangement of a plurality of second structures interposed between the second and third layers. At least a portion, but not all, of the plurality of first structures have first and/or second surfaces that each overlap through the thickness of the deformable membrane with one or more of the first surfaces or with one or more of the second surfaces of the plurality of second structures. Electrodes or one or more electrode pairs are incorporated into the deformable membrane layer(s) to form force-sensing capacitors.

Abstract: The present disclosure provides an article having a substrate having a first nanostructured surface and an opposing second surface; and a conductor micropattern disposed on the first surface of the substrate, the conductor micropattern formed by a plurality of traces. The micropattern may have an open area fraction greater than 80%. The traces of the conductor micropattern may have a specular reflectance in a direction orthogonal to and toward the first surface of the substrate of less than 50%. The nanostructured surface may include nanofeatures having a height from 50 to 750 nanometers, a width from 15 to 200 nanometers, and a lateral spacing from 5 to 500 nanometers. The articles are useful in devices such as displays, in particular, touch screen displays useful for mobile hand held devices, tablets and computers. They also find use in antennas and for EMI shields.

Abstract: The present disclosure provides an article having (a) a substrate having opposing first and second surfaces; and (b) a conductor micropattern disposed on the first surface of the substrate. The conductor micropattern has a plurality of traces defining a plurality of open area cells. The conductor micropattern has an open area fraction greater than 80% and a uniform distribution of trace orientation. Each of the traces is non-linear and has a trace width from 0.5 to 10 micrometer. The articles are useful in devices such as displays, in particular, touch screen displays useful for mobile hand held devices, tablets and computers. They also find use in antennas and for EMI shields.

Abstract: The present disclosure provides an article having (a) a substrate having a first nanostructured surface that is antireflective when exposed to air and an opposing second surface; and (b) a conductor micropattern disposed on the first surface of the substrate, the conductor micropattern formed by a plurality of traces defining a plurality of open area cells. The micropattern has an open area fraction greater than 80% and a uniform distribution of trace orientation. The traces of the conductor micropattern have a specular reflectance in a direction orthogonal to and toward the first surface of the substrate of less than 50%. Each of the traces has a width from 0.5 to 10 micrometer. The articles are useful in devices such as displays, in particular, touch screen displays useful for mobile hand held devices, tablets and computers. They also find use in antennas and for EMI shields.

Abstract: A fuel cell membrane electrode assembly is provided comprising a polymer electrolyte membrane comprising a first polymer electrolyte and at least one manganese compound; and one or more electrode layers comprising a catalyst and at least one cerium compound. The membrane electrode assembly demonstrates an unexpected combination of durability and performance.

Abstract: The present disclosure provides an article having a substrate having opposing first and second surfaces. A conductor micropattern is disposed on the first surface of the substrate. The conductor micropattern has a plurality of traces defining a plurality of cells. The conductor micropattern may have an open area fraction greater than 80% and a uniform distribution of trace orientation. Each of the traces has a trace width from 0.5 to 10 micrometer. The conductor micropattern is a tri-layer material comprising in sequence a semi-reflective metal, a transparent layer, and a reflective layer disposed on the transparent layer. The articles are useful in devices such as displays, in particular, touch screen displays useful for mobile hand held devices, tablets and computers. They also find use in antennas and for EMI shields.

Abstract: A photochromic article is provided, containing a polymer and a polyoxometalate derivative anion and counter cation complex distributed in the polymer. A method of forming a photochromic film is also provided, including forming a composition containing a polymer or a precursor of the polymer and a polyoxometalate derivative and counter cation complex and preparing a film from the composition, the film containing the polyoxometalate derivative and counter cation complex distributed in the polymer. Further, a precursor composition is provided, including a polymer or a precursor of the polymer and a polyoxometalate derivative anion and a counter cation.

Abstract: A photochromic article is provided, containing a polymer and a polyoxometalate and counter cation complex distributed in the polymer. A method of forming a photochromic film is also provided, including forming a composition containing a polymer or a precursor of the polymer and a polyoxometalate and counter cation complex and preparing a film from the composition, the film containing the polyoxometalate and counter cation complex distributed in the polymer. Further, a precursor composition is provided, including a polymer or a precursor of the polymer and a polyoxometalate anion and a counter cation.

Abstract: Force-sensing capacitor elements and deformable membranes useful in electronic devices that include touch screen displays or other touch sensors. The deformable membranes, generally, include a first, second, and third layers with a first arrangement of a plurality of first structures interposed between the first and third layers and a second arrangement of one or more second structures interposed between the second and third layers. Electrodes may be included proximate to or in contact with one or more of the major surfaces of the first, second, and third layers or embedded within one or more of the second and third layers of the deformable membranes, yielding force-sensing capacitor elements. The electrodes proximate to or in contact with the one or more of the major surfaces of the first and second layers or embedded within one or more of the second and third layers may be one or more plurality of electrodes.

Abstract: Designs for touch sensor circuitry and touch sensor incorporating such circuitry are described. More particularly, touch sensor circuitry including multiple elongate electrodes that are interleaved with one another is described.

Abstract: The present disclosure provides an article having a substrate having opposing first and second surfaces. A conductor micropattern disposed on the first surface of the substrate. The conductor micropattern has a plurality of traces defining a plurality of cells. The conductor micropattern has an open area fraction greater than 80% and a uniform distribution of trace orientation. Each of the traces has a trace width from 0.5 to 10 micrometer. The conductor micropattern is a tri-layer material comprising in sequence a semi-reflective metal, a transparent layer, and a reflective layer disposed on the transparent layer. The articles are useful in devices such as displays, in particular, touch screen displays useful for mobile hand held devices, tablets and computers. They also find use in antennas and for EMI shields.

Abstract: A touch screen sensor includes a visible light transparent substrate and an electrically conductive micropattern disposed on or in the visible light transparent substrate. The micropattern includes a first region micropattern within a touch sensing area and a second region micropattern. The first region micropattern has a first sheet resistance value in a first direction, is visible light transparent, and has at least 90% open area. The second region micropattern has a second sheet resistance value in the first direction. The first sheet resistance value is different from the second sheet resistance value.

Abstract: A method of patterning a conductor on a substrate includes providing an inked elastomeric stamp inked with self-assembled monolayer-forming molecules and having a relief pattern with raised features. Then the raised features of the inked stamp contact a metal-coated visible light transparent substrate. Then the metal is etched to form an electrically conductive micropattem corresponding to the raised features of the inked stamp on the visible light transparent substrate.

Abstract: A process for making inorganic, metal oxide spheres that includes exposing solidified, molded microparticles that include a glass precursor composition to a temperature sufficient to transform the molded microparticles into molten glass and cooling the molten glass to form inorganic, metal oxide spheres.

Abstract: A method of patterning a conductor on a substrate includes providing an inked elastomeric stamp inked with self-assembled monolayer-forming molecules and having a relief pattern with raised features. Then the raised features of the inked stamp contact a metal-coated visible light transparent substrate. Then the metal is etched to form an electrically conductive micropattern corresponding to the raised features of the inked stamp on the visible light transparent substrate.