Patents by Inventor Matthew T. Pretz
Matthew T. Pretz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 10688477Abstract: A process to react an oxygen containing regenerated catalyst stream prior to use in a fluidized bed reactor comprising providing a regenerated catalyst stream which comprises at least 0.001 wt % oxygen; reacting the regenerated catalyst stream with a fuel source thereby forming oxides and reducing the amount of oxygen in the regenerated catalyst stream to produce a usable regenerated catalyst stream; and injecting the usable regenerated catalyst stream into a hydrocarbon fluidized bed reactor is provided.Type: GrantFiled: May 5, 2017Date of Patent: June 23, 2020Assignee: Dow Global Technologies LLCInventors: Matthew T. Pretz, Liwei Li
-
Patent number: 10647634Abstract: A process for catalytic dehydrogenation comprising mixing fluidization gas a fluidization gas which comprises methane, natural gas, ethane, hydrogen, nitrogen or any combination thereof with a fluidized catalyst stream that has passed through a catalytic dehydrogenation reactor and has exited a catalyst separation zone to form a catalyst recycle stream; and recycling the catalyst recycle stream either directly or indirectly into a catalytic dehydrogenation reactor is provided.Type: GrantFiled: May 3, 2017Date of Patent: May 12, 2020Assignee: Dow Global Technologies LLCInventors: Matthew T. Pretz, Lin Luo
-
Patent number: 10632439Abstract: According to one or more embodiments disclosed herein, a system component of a fluid catalytic reactor system may include a catalyst separation section, a riser, and a reactor vessel. The catalyst separation section may include separation section walls defining an interior region of the catalyst separation section, a gas outlet port, a riser port, a separation device, and a catalyst outlet port. The riser may extend through the riser port of the catalyst separation section and include an external riser section and an internal riser section. The reactor vessel may include a reactor vessel inlet port, and a reactor vessel outlet port in fluid communication with the external riser section of the riser.Type: GrantFiled: May 31, 2017Date of Patent: April 28, 2020Assignee: Dow Global Technologies LLCInventors: Matthew T. Pretz, Donald F. Shaw, Fermin Alejandro Sandoval
-
Patent number: 10590048Abstract: An integrated process for producing C3-C4 olefins or di-olefins including: contacting a hydrocarbon feed and a catalyst feed in a fluidized dehydrogenation reactor under conditions such that a product mixture is formed and the catalyst is at least partially deactivated; transferring the product mixture and the catalyst from the reactor to a cyclonic separation system under conditions such that the product mixture is converted to form a new product mixture and is separated from the catalyst; transferring at least a portion of the catalyst to a regenerator vessel and heating it in order to combust the coke deposited thereon; subjecting the catalyst to a conditioning step to form an oxygen-containing, at least partially reactivated catalyst; and transferring the partially reactivated catalyst back to the fluidized dehydrogenation reactor.Type: GrantFiled: January 23, 2019Date of Patent: March 17, 2020Assignee: Dow Global Technologies LLCInventor: Matthew T. Pretz
-
Patent number: 10589242Abstract: According to one or more embodiments, a fluid catalytic reactor may include a riser, a lower reactor portion, a transition portion, and a flow director. The riser may include a cross-sectional area, and the lower reactor portion may include a cross-sectional area. The transition portion may attach the riser to the lower reactor portion. The cross-sectional area of the riser may be less than the cross-sectional area of the lower reactor portion such that the transition portion is tapered inward from the lower reactor portion to the riser. The flow director may be positioned at least within an interior region of the transition portion. The flow director may include a body which affects the velocity profile of fluids moving from the lower reactor portion to the riser.Type: GrantFiled: October 25, 2017Date of Patent: March 17, 2020Assignee: Dow Global Technologies LLCInventors: Matthew T. Pretz, Mark W. Stewart, Ben J. Freireich, Madhusudhan Kodam, Brien A. Stears
-
Publication number: 20200055015Abstract: A method for processing a chemical stream includes contacting a feed stream with a catalyst in a reactor portion of a reactor system causing a reaction which forms a product stream. The method includes separating the product stream from the catalyst, passing the catalyst to a catalyst processing portion of the reactor system, processing the catalyst in the catalyst processing portion, and passing a portion of the catalyst from the catalyst processing portion of the reactor system into a catalyst withdrawal system that includes a catalyst withdrawal vessel and a transfer line coupling the catalyst withdrawal vessel to the catalyst processing portion. Each of the catalyst withdrawal vessel and the transfer line include an outer metallic shell and an inner refractory lining. The method further includes cooling the catalyst in the catalyst withdrawal vessel from greater than or equal to 680° C. to less than or equal to 350° C.Type: ApplicationFiled: May 3, 2018Publication date: February 20, 2020Applicant: Dow Global Technologies LLCInventor: Matthew T. Pretz
-
Publication number: 20200017426Abstract: According to one or more embodiments presently disclosed, light olefins may be formed by a method that may comprise introducing a feed stream into a reactor, reacting the feed stream with a cracking catalyst in the reactor to form a product stream, and processing the cracking catalyst. The reactor may comprise an upstream reactor section and a downstream reactor section. The upstream reactor section may be positioned below the downstream reactor section. The upstream reactor section may have an average cross-sectional area that is at least 150% of the average cross-sectional area of the downstream reactor section.Type: ApplicationFiled: March 9, 2018Publication date: January 16, 2020Applicant: Dow Global Technologies LLCInventors: Matthew T. Pretz, Yu Liu
-
Publication number: 20200017427Abstract: According to one or more embodiments of the present disclosure, chemical streams may be processed by a method which may comprise operating a first chemical process, stopping the first chemical process and removing the first catalyst from the reactor, and operating a second chemical process. The reaction of the first chemical process may be a dehydrogenation reaction, a cracking reaction, a dehydration reaction, or a methanol-to-olefin reaction. The reaction of the second chemical process may be a dehydrogenation reaction, a cracking reaction, a dehydration reaction, or a methanol-to-olefin reaction. The first reaction and the second reaction may be different types of reactions.Type: ApplicationFiled: March 9, 2018Publication date: January 16, 2020Applicant: Dow Global Technologies LLCInventor: Matthew T. Pretz
-
Patent number: 10507448Abstract: According to one or more embodiments of the present disclosure, a fluid catalytic reactor may be scaled-up by a method that includes one or more of constructing, operating, observing, or obtaining data related to a template fluid catalytic reactor comprising a template riser, a template lower reactor portion, and a template transition portion connecting the template riser and the template lower reactor portion. The method may further include one or more of constructing or operating a scaled-up fluid catalytic reactor based on the template fluid catalytic reactor.Type: GrantFiled: October 30, 2017Date of Patent: December 17, 2019Assignee: Dow Global Technologies LLCInventors: Matthew T. Pretz, Ben J. Freireich, Madhusudhan Kodam, Brien A. Stears
-
Patent number: 10464036Abstract: A catalyst regenerator for combusting carbonaceous deposits from a catalyst comprising a first chamber which comprises a catalyst inlet for feeding spent catalyst with carbonaceous deposits to said first chamber, a supplemental fuel gas distributor, and a distributor for an oxygen containing gas for distributing oxygen containing gas into said first chamber to contact said spent catalyst and combust carbonaceous deposits and supplemental fuel which further deactivates the spent catalyst and generates flue gas; a riser section extending from said first chamber for transporting the spent catalyst and the flue gas, the riser section comprising an outer wall, at least one slot in the outer wall, and a riser termination device which comprises a substantially internally flat cover plate, at least one arm extending from the cover plate, wherein the arm extends about the slot from the outer wall, the arm comprising an outer shell that encloses the arm and wherein no internal portion of the cover plate extends above aType: GrantFiled: September 28, 2016Date of Patent: November 5, 2019Assignee: Dow Global Technologies LLCInventors: Matthew T. Pretz, Don F. Shaw, Richard E. Walter, Madhusudhan Kodam
-
Publication number: 20190314782Abstract: According to one or more embodiments disclosed herein, a system component of a fluid catalytic reactor system may include a catalyst separation section, a riser, and a reactor vessel. The catalyst separation section may include separation section walls defining an interior region of the catalyst separation section, a gas outlet port, a riser port, a separation device, and a catalyst outlet port. The riser may extend through the riser port of the catalyst separation section and include an external riser section and an internal riser section. The reactor vessel may include a reactor vessel inlet port, and a reactor vessel outlet port in fluid communication with the external riser section of the riser.Type: ApplicationFiled: May 31, 2017Publication date: October 17, 2019Applicant: Dow Global Technologies LLCInventors: Matthew T. Pretz, Donald F. Shaw, Fermin Alejandro Sandoval
-
Publication number: 20190282987Abstract: According to one or more embodiments of the present disclosure, a fluid catalytic reactor may be scaled-up by a method that includes one or more of constructing, operating, observing, or obtaining data related to a template fluid catalytic reactor comprising a template riser, a template lower reactor portion, and a template transition portion connecting the template riser and the template lower reactor portion. The method may further include one or more of constructing or operating a scaled-up fluid catalytic reactor based on the template fluid catalytic reactor.Type: ApplicationFiled: October 30, 2017Publication date: September 19, 2019Applicant: Dow Global Technologies LLCInventors: Matthew T. Pretz, Ben J. Freireich, Madhusudhan Kodam, Brien A. Stears
-
Patent number: 10392319Abstract: Manage sulfur present as sulfur or a sulfur compound in a hydrocarbon feedstream while effecting dehydrogenation of hydrocarbon(s) (e.g. propane) contained in the hydrocarbon feedstream to its/their corresponding olefin (e.g. propylene where the hydrocarbon is propane) without subjecting the feedstream to desulfurization before it contacts a fluidizable dehydrogenation catalyst that is both a desulfurant and a dehydrogenation catalyst and comprises gallium and platinum on an alumina or alumina-silica catalyst support with optional alkali or alkaline earth metal such as potassium. Contact with such a catalyst yields a desulfurized crude olefin product that corresponds to the hydrocarbon and has a reduced amount of sulfur or sulfur compounds relative to the sulfur or sulfur compounds present in the hydrocarbon feedstream prior to contact with the catalyst.Type: GrantFiled: December 3, 2014Date of Patent: August 27, 2019Assignee: Dow Global Technologies LLCInventors: Matthew T. Pretz, Lin Luo, Brien A. Stears, Mark W. Stewart
-
Publication number: 20190255498Abstract: According to one or more embodiments, a fluid catalytic reactor may include a riser, a lower reactor portion, a transition portion, and a flow director. The riser may include a cross-sectional area, and the lower reactor portion may include a cross-sectional area. The transition portion may attach the riser to the lower reactor portion. The cross-sectional area of the riser may be less than the cross-sectional area of the lower reactor portion such that the transition portion is tapered inward from the lower reactor portion to the riser. The flow director may be positioned at least within an interior region of the transition portion. The flow director may include a body which affects the velocity profile of fluids moving from the lower reactor portion to the riser.Type: ApplicationFiled: October 25, 2017Publication date: August 22, 2019Applicant: Dow Global Technologies LLCInventors: Matthew T. Pretz, Mark W. Stewart, Ben J. Freireich, Madhusudhan Kodam, Brien A. Stears
-
Publication number: 20190225563Abstract: An integrated process for producing C3-C4 olefins or di-olefins including: contacting a hydrocarbon feed and a catalyst feed in a fluidized dehydrogenation reactor under conditions such that a product mixture is formed and the catalyst is at least partially deactivated; transferring the product mixture and the catalyst from the reactor to a cyclonic separation system under conditions such that the product mixture is converted to form a new product mixture and is separated from the catalyst; transferring at least a portion of the catalyst to a regenerator vessel and heating it in order to combust the coke deposited thereon; subjecting the catalyst to a conditioning step to form an oxygen-containing, at least partially reactivated catalyst; and transferring the partially reactivated catalyst back to the fluidized dehydrogenation reactor.Type: ApplicationFiled: January 23, 2019Publication date: July 25, 2019Applicant: Dow Global Technologies LLCInventor: Matthew T. Pretz
-
Publication number: 20190161422Abstract: A process for catalytic dehydrogenation comprising mixing fluidization gas a fluidization gas which comprises methane, natural gas, ethane, hydrogen, nitrogen or any combination thereof with a fluidized catalyst stream that has passed through a catalytic dehydrogenation reactor and has exited a catalyst separation zone to form a catalyst recycle stream; and recycling the catalyst recycle stream either directly or indirectly into a catalytic dehydrogenation reactor is provided.Type: ApplicationFiled: May 3, 2017Publication date: May 30, 2019Applicant: Dow Global Technologies LLCInventors: Matthew T. PRETZ, Lin LUO
-
Patent number: 10272407Abstract: An apparatus used in a fluidized reaction process comprising a vessel; a riser housed within the vessel; and a plurality of angled guide supports, wherein each guide support comprises an tubular section having a first end and a second end; a first hinge wherein a first end of the first hinge is connected to the first end of the tubular section, a second hinge wherein a first end of the second hinge is connected to the second end of the tubular section, wherein a second end of the first hinge is connected to an inside surface of the vessel and a second end of the second hinge is connected to the riser guide is provided.Type: GrantFiled: December 14, 2015Date of Patent: April 30, 2019Assignee: Dow Global Technologies LLCInventors: Matthew T. Pretz, Don F. Shaw
-
Publication number: 20190099745Abstract: A process to react an oxygen containing regenerated catalyst stream prior to use in a fluidized bed reactor comprising providing a regenerated catalyst stream which comprises at least 0.001 wt % oxygen; reacting the regenerated catalyst stream with a fuel source thereby forming oxides and reducing the amount of oxygen in the regenerated catalyst stream to produce a usable regenerated catalyst stream; and injecting the usable regenerated catalyst stream into a hydrocarbon fluidized bed reactor is provided.Type: ApplicationFiled: May 5, 2017Publication date: April 4, 2019Applicant: Dow Global Technologies LLCInventors: Matthew T. Pretz, Liwei Li
-
Patent number: 10227271Abstract: An integrated process, suitable for use in a new or retrofitted plant, produces an olefin or di-olefin via the dehydrogenation of an appropriate C3-C4 hydrocarbon feed includes (1) contacting the feed and a dehydrogenation catalyst having a Geldart A or Geldart B classification in a fluidized bed at a temperature from 550° C. to 760° C. and a pressure from about 41.4 to about 308.2 kPa (about 6.0 to about 44.7 psia) and a catalyst to feed ratio, w/w, from 5 to 100 to form a dehydrogenate product; separating the dehydrogenate product and unreacted starting feed mixture from a portion of the catalyst by means of a cyclonic separation system; reactivating the catalyst in a fluidized regenerator by combustion at 660° C. to 850° C., followed by contact with an oxygen-containing fluid at 660° C.Type: GrantFiled: March 7, 2016Date of Patent: March 12, 2019Assignee: Dow Global Technologies LLCInventor: Matthew T. Pretz
-
Publication number: 20180264424Abstract: A catalyst regenerator for combusting carbonaceous deposits from a catalyst comprising a first chamber which comprises a catalyst inlet for feeding spent catalyst with carbonaceous deposits to said first chamber, a supplemental fuel gas distributor, and a distributor for an oxygen containing gas for distributing oxygen containing gas into said first chamber to contact said spent catalyst and combust carbonaceous deposits and supplemental fuel which further deactivates the spent catalyst and generates flue gas; a riser section extending from said first chamber for transporting the spent catalyst and the flue gas, the riser section comprising an outer wall, at least one slot in the outer wall, and a riser termination device which comprises a substantially internally flat cover plate, at least one arm extending from the cover plate, wherein the arm extends about the slot from the outer wall, the arm comprising an outer shell that encloses the arm and wherein no internal portion of the cover plate extends above aType: ApplicationFiled: September 28, 2016Publication date: September 20, 2018Applicant: Dow Global Technologies LLCInventors: Matthew T. Pretz, Don F. Shaw, Richard E. Walter, Madhusudhan Kodam