Abstract: A battery system includes an enclosure having opposed first and second major walls, a perimetral wall connecting the first and second major walls along respective perimeters thereof, and an interior defined by the first and second major walls and the perimetral wall, wherein the enclosure is configured for containing an anode assembly, a cathode assembly and an electrolyte within the interior. A longitudinal embossment is formed in the perimetral wall extending outward from the interior and extending along opposed adjacent portions of the first and second perimeters. A wall port is defined in the perimetral wall in fluid communication with the interior, wherein the wall port is configured for permitting flow of the electrolyte therethrough into and out of the interior. First and second electrodes extend through the perimetral wall and are configured for electrical connection with the anode assembly and cathode assembly, respectively.

Abstract: Lithium ion-exchanged zeolite particles and methods of making such lithium ion-exchanged zeolite particles are provided herein. The method includes combining precursor zeolite particles with (NH4)3PO4 to form a first mixture including intermediate zeolite particles including NH4+ cations. The method further includes adding a lithium salt to the first mixture to form the lithium ion-exchanged zeolite particles, or separating the intermediate zeolite particle from the first mixture and combining the intermediate zeolite particles with the lithium salt to form the lithium ion-exchanged zeolite particles.

Abstract: A hybrid solid-state electrolyte layer for use in an electrochemical cell is provided. The hybrid solid-state electrolyte layer includes a polymeric material, a ceramic material, and an interfacial material adhering the polymeric material and the ceramic material. The interfacial material includes a branched copolymer that includes dopamine and a second monomer. The second monomer forms a polymeric moiety in the copolymer that is the same or similar to the polymeric material. In certain variations, the polymeric material defines a polymeric layer, the ceramic material defines a ceramic layer, and the interfacial material defines an interfacial layer that is disposed between the polymeric layer and the ceramic layer. In other variations, the polymeric material defines a polymeric matrix, the ceramic material defines a plurality of ceramic particles dispersed in the polymeric matrix, and the plurality of ceramic particles are coated with the interfacial material.

Abstract: A method for manufacturing an interfacial lithium fluoride layer for an electrochemical cell that cycles lithium ions is disclosed. In the method, a substrate is positioned in a reaction chamber of an atomic layer deposition reactor and a lithium fluoride (LiF) precursor is introduced into the reaction chamber such that the LiF precursor contacts and chemically reacts with functional groups on the substrate. Then, an oxidant is introduced into the reaction chamber to form a single molecular layer of lithium fluoride on the substrate. The lithium fluoride layer is formed on the substrate at a temperature of greater than or equal to about 110 degrees Celsius to less than or equal to about 250 degrees Celsius.

Abstract: A hybrid functional particle for use in an electrochemical cell that cycle lithium ions is provided. The hybrid functional particle includes a lithiated zeolite having a plurality of pores and a plurality of lithium-containing particles disposed within one or more pores of the plurality of pores of the lithiated zeolite. For example, the lithiated zeolite has a porosity ranging from about 10 vol. % to about 90 vol. %, and the lithium-containing particles can fill an amount ranging from about 1% to about 100% of a total porosity of the lithiated zeolite. The electrochemical cell includes first and second electrodes separated by a separating layer, and the hybrid functional particle may be disposed within one or both of the electrodes, coated on one or more sides of one or both of the electrodes, disposed within the separating layer, and/or coated on one or more surfaces of the separating layer.

Abstract: A system for measuring a thickness of a coating arranged on an anode substrate includes an optical measurement system configured to transmit a light signal having a known first polarization toward the anode substrate through the coating such that the light signal is reflected from the surface of the anode substrate, a detection module positioned to receive the reflected light signal and configured to determine a second polarization of the reflected light signal that is different from the first polarization and measure a polarization difference between the first polarization and the second polarization, and a measurement module configured to receive the measured polarization difference, calculate the thickness of the coating based on the measured polarization difference, and generate an output based on the calculated thickness.

Abstract: An electrolyte for a lithium metal battery including a nonaqueous aprotic organic solvent and a lithium salt dissolved or ionized in the nonaqueous aprotic organic solvent. The nonaqueous aprotic organic solvent includes a cyclic carbonate, an acyclic carbonate, and an acyclic fluorinated ether. The lithium salt includes an aliphatic fluorinated disulfonimide lithium salt.

Abstract: An example of a negative electrode includes silicon nanoparticles having a carbon coating thereon. The carbon coating has an oxygen-free structure including pentagon rings. The negative electrode with the silicon nanoparticles having the carbon coating thereon may be incorporated into a lithium-based battery. In an example of a method, silicon nanoparticles are provided. A carbon precursor is applied on the silicon nanoparticles. The carbon precursor is an oxygen-free, fluorene-based polymer. Then the silicon nanoparticles are heated in an inert gas atmosphere to form the carbon coating on the silicon nanoparticles. The carbon coating formed on the silicon nanoparticles has an oxygen-free structure including pentagon rings.

Abstract: Methods for forming sulfur polyacrylonitrile are provide. In certain variations, the method includes contacting sulfur and polyacrylonitrile to form an admixture, sealing a container holding the admixture, heating the admixture to a first temperature venting the container holding the admixture to release gases generated during the heating of the admixture to the first temperature, re-sealing the container holding the admixture, and heating the admixture to a second temperature. In other variations, the method includes contacting sulfur and polyacrylonitrile to form an admixture, heating the admixture to a first temperature, sealing a container holding the admixture, and heating the admixture to a second temperature. The second temperature is greater than the first temperature.

Abstract: A method for forming a protective electrode coating on an electrode to be used in a lithium-sulfur battery is provided. The method includes contacting one or more surfaces of the electrode with a polymeric admixture, and polymerizing the polymeric admixture to form the protective electrode coating. The polymeric admixture includes a plurality of monomers, for example heterocyclic acetal monomers and/or cyclic ether monomers, and a lithium difluoro(oxalato)borate (LiDFOB) initiator. In certain instances, the polymeric admixture may also include a structural additive and/or a lithium salt. The contacting may include applying a thin film on the one or more surfaces of the electrode, and the polymerization may be heat activated.

Abstract: The present disclosure provides an electrolyte system for an electrochemical cell that cycles lithium ions. The electrolyte system may include an aliphatic fluorinated disulfonimide lithium salt in a mixture of organic solvents. The mixture of organic solvents may include a first solvent and a second solvent. The first solvent may include an ether solvent, a carbonate solvent, or a mixture of ether and carbonate solvents. The second solvent may include a fluorinated ether. A molar ratio of the aliphatic fluorinated disulfonimide lithium salt to the first solvent may be greater than or equal to about 1:1.2 to less than or equal to about 1:2. A molar ratio of the first solvent to the second solvent may be greater than or equal to about 1:1 to less than or equal to about 1:4.

Abstract: A negative electrode for an electrochemical cell of a secondary lithium metal battery is manufactured by a method in which a precursor solution is applied to a major surface of a lithium metal substrate to form a precursor coating thereon. The precursor solution includes an organophosphate, a nonpolar organic solvent, and a lithium-containing inorganic ionic compound dissolved therein. At least a portion of the nonpolar organic solvent is removed from the precursor coating to form a protective interfacial layer on the major surface of the lithium metal substrate. The protective interfacial layer exhibits a composite structure including a carbon-based matrix component and a lithium-containing dispersed component. The lithium-containing dispersed component is embedded in the carbon-based matrix component and includes a plurality of lithium-containing inorganic ionic compounds, e.g., lithium phosphate (Li3PO4) and lithium nitrate (LiNO3).

Abstract: A battery module comprises a plurality of secondary battery cells arranged side-by-side; and a flame-retardant composition disposed atop the plurality of secondary battery cells; where the flame-retardant composition comprises a first composition and a second composition. The first composition comprises porous particles upon which are disposed a first metal catalyst particle and a first flame-retardant particle. The second composition comprises a fibrous composition that comprises a fibrous substrate upon which is disposed a second metal catalyst particle and a second flame-retardant particle.

Abstract: A method for forming a solid-state battery includes preparing a cell, heating the cell to a first temperature, and cycling the cell while maintaining the cell at the first temperature and/or while the cell is cooled to room temperature from the first temperature. The cell includes a solid-state electrolyte adjacent to a negative electrode, including a negative electroactive material selected from the group consisting of: lithium metal, lithium alloys, silicon, silicon alloys, and combinations thereof. The first temperature is between about 50° C. and about 175° C. The cell is cycled for between about 1 cycle and about 10 cycles, where current densities are between about 0.01 mA/cm2 and about 10 mA/cm2, and capacity per cycle between about 0.01 mAh/cm2 and about 1 mAh/cm2.

Abstract: The present disclosure provides a coated separator including a porous separator and a ceramic coating disposed on one or more surfaces thereof. The ceramic coating includes a ceramic material and an additive selected from the group consisting of: lithium nitrate (LiNO3), lithium phosphate (LiPO3), lithium orthophosphate (Li3PO4), lithium difluoro (oxalate) borate (LiDBoB), cyclic sulfone, polysulfide, lithium halide salts, and combinations thereof. In certain variations, the coated separator is prepared by contacting the porous separator with a slurry including the ceramic material and the additive. In other variations, the coated separator is prepared by forming a ceramic coating on one or more surfaces of a porous separator and contacting the porous separator with the additive, for example by immersing, or alternatively, a spraying process.

Abstract: An electrode includes an electroactive material layer and a protective layer disposed on or adjacent to a surface of the electroactive material layer. The protective layer includes a polymerized cyclic ether and a salt dispersed therewithin. The salt includes a nitrate salt and a phosphate salt. The salt may also include a Lewis acid salt. The protective layer is formed by disposing a solution, including the salt and solvent, on or adjacent to the surface of the electroactive material layer, and polymerizing the solvent. The solvent includes the cyclic ether, and also, one or more organic phosphates.

Abstract: The present disclosure relates to electrolyte systems and/or separators for electrochemical cells that cycle lithium ions and which may have lithium metal electrodes. The electrochemical cell includes a liquid electrolyte system that fills voids and pores within the electrochemical cell. The electrolyte system includes two or more lithium salts and two or more solvents. The two or more lithium salts include bis(fluorosulfonyl)imide (LiN(FSO2)2) (LIFSI) and lithium perchlorate (LiClO4). The two or more solvents include a first solvent and a second solvent. The first solvent may be a fluorinated cyclic carbonate. The second solvent may be a linear carbonate. A volumetric ratio of the first solvent to the second solvent may be 1:4. The electrochemical cell may include a surface-modified separator that has one or more coatings or fillers.

Abstract: A system for measuring a thickness of a coating arranged on an anode substrate includes an optical measurement system configured to transmit a light signal having a known first polarization toward the anode substrate through the coating such that the light signal is reflected from the surface of the anode substrate, a detection module positioned to receive the reflected light signal and configured to determine a second polarization of the reflected light signal that is different from the first polarization and measure a polarization difference between the first polarization and the second polarization, and a measurement module configured to receive the measured polarization difference, calculate the thickness of the coating based on the measured polarization difference, and generate an output based on the calculated thickness.

Abstract: An electrochemical cell for a lithium battery includes a negative electrode, a positive electrode, a polymeric separator, and composite flame retardant particles including a particulate host material and a flame retardant material carried by the particulate host material. The composite flame retardant particles may be positioned within the electrochemical cell along a lithium-ion transport path or an electron transport path that extends through or between one or more components of the electrochemical cell. The composite flame retardant particles may be positioned within polymeric portions of a laminate structure that defines a housing in which the electrochemical cell is enclosed.

Abstract: A method of preparing a lithium metal electrode for an electrochemical cell, such as a lithium metal battery, includes introducing a treatment gas into a chamber including an electrode precursor. The treatment gas may include a reactant gas and/or a plasma. The electrode precursor includes lithium metal and a passivation layer. The method further includes forming the lithium metal electrode by contacting the treatment gas with the passivation layer to remove at least a portion of the passivation layer. The present disclosure also provides pretreated electrodes and electrode assemblies.