Patents by Inventor Michael F. Zona

Michael F. Zona has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230324824
    Abstract: An emulsion aggregation toner including a toner particle comprising at least one resin; an optional colorant; an optional wax; and a charge control agent disposed on a surface of the toner particle; the charge control agent comprising a complex formed from a metal ion donor and at least one of a ligand selected from a member of the group consisting of a polyaromatic acid comprising humic acid, a pyranone based ligand, a furanone based ligand, or a combination thereof.
    Type: Application
    Filed: March 17, 2022
    Publication date: October 12, 2023
    Inventors: Genggeng Qi, Jordan A. Frank, Elizabeth K. Priebe, Chieh-Min Cheng, Michael F. Zona
  • Publication number: 20230296997
    Abstract: An emulsion aggregation toner including a toner particle comprising at least one resin; an optional colorant; an optional wax; and a reactive charge control agent comprising at least one positive charging compound comprising a member selected from the group consisting of an amine compound having at least 3 carbon atoms, an ammonium compound having at least 3 carbon atoms, a phosphonium compound having at least 3 carbon atoms, a boronium compound having at least 3 carbon atoms, and combinations thereof; at least one reactive anchoring compound comprising a member selected the group consisting of amino, epoxy, carboxylic, hydroxyl, silanol, cyanide, anhydride, aldehyde, ketone, vinyl, and combinations thereof; and wherein the charge control agent optionally further comprises a negative charging compound comprising a member selected from the group consisting of aromatic carboxylic acid, silanol, phenol, pyranone, furanone, and combinations thereof.
    Type: Application
    Filed: March 17, 2022
    Publication date: September 21, 2023
    Inventors: Jordan A. Frank, Genggeng Qi, Chieh-Min Cheng, Michael F. Zona, Elizabeth K. Priebe
  • Publication number: 20230296998
    Abstract: An emulsion aggregation toner including a toner particle comprising at least one resin; an optional colorant; an optional wax; and a charge control agent disposed on a surface of the toner particle; the control agent comprising a phenyl based siloxane; and a complex formed from a metal ion donor and at least one of a ligand selected from a member of the group consisting of a polyaromatic acid comprising humic acid, a pyranone based ligand, a furanone based ligand, or a combination thereof.
    Type: Application
    Filed: March 17, 2022
    Publication date: September 21, 2023
    Inventors: Jordan A. Frank, Genggeng Qi, Elizabeth K. Priebe, Chieh-Min Cheng, Michael F. Zona
  • Publication number: 20220244656
    Abstract: Toner particles including a core and a shell thereover; wherein the core comprises at least one styrene-acrylate copolymer selected from styrene-acrylate copolymer 1, styrene-acrylate copolymer 2, and styrene-acrylate copolymer 3, and combinations thereof a wax; and an optional colorant; wherein the shell comprises at least one styrene-acrylate copolymer selected from styrene-acrylate copolymer 1, styrene acrylate copolymer 2, styrene acrylate copolymer 3, and combinations thereof.
    Type: Application
    Filed: February 4, 2021
    Publication date: August 4, 2022
    Inventors: Jordan A. Frank, Daniel W. Asarese, Chieh-Min Cheng, Paul K. Acquaviva, Richard P. N. Veregin, Michael F. Zona
  • Publication number: 20210263435
    Abstract: A toner including a parent toner particle comprising at least one resin, in combination with an optional colorant, and an optional wax; and a surface additive formulation comprising at least one medium silica surface additive; at least one large silica surface additive; at least one positive charging surface additive, wherein the at least one positive charging surface additive is (a) a titanium dioxide surface additive; and wherein the parent toner particles further contain a small silica; or (b) a non-titanium dioxide positive charging metal oxide surface additive; and wherein the parent toner particles further optionally contain a small silica; and wherein a total surface area coverage of all of the surface additives combined is 100 to 140 percent of the parent toner particle surface area.
    Type: Application
    Filed: February 25, 2020
    Publication date: August 26, 2021
    Inventors: Richard P. N. Veregin, Michael F. Zona, Jordan A. Frank, Daniel W. Asarese, Paul K. Acquaviva, Chieh-Min Cheng
  • Publication number: 20210263436
    Abstract: A toner composition including a first wax; a second wax that is different from the first wax; wherein the first wax comprises a paraffin wax; wherein the second wax comprises a polymethylene wax; at least one polyester; and an optional colorant.
    Type: Application
    Filed: February 25, 2020
    Publication date: August 26, 2021
    Inventors: Jordan A. Frank, Daniel W. Asarese, Paul K. Acquaviva, Chieh-Min Cheng, Michael F. Zona, Richard P. N. Veregin
  • Publication number: 20210263437
    Abstract: A toner including a parent toner particle comprising at least one resin, in combination with an optional colorant, and an optional wax; and a surface additive formulation comprising at least one medium silica surface additive; at least one large cross-linked organic polymeric additive; at least one positive charging surface additive, wherein the at least one positive charging surface additive is (a) a titanium dioxide surface additive; and wherein the parent toner particles further contain a small silica; or (b) a non-titanium dioxide positive charging metal oxide surface additive; and wherein the parent toner particles further optionally contain a small silica; and wherein a total surface area coverage of all of the surface additives combined is 100 to 140 percent of the parent toner particle surface area.
    Type: Application
    Filed: February 25, 2020
    Publication date: August 26, 2021
    Inventors: Richard P. N. Veregin, Michael F. Zona, Jordan A. Frank, Daniel W. Asarese, Chieh-Min Cheng, Paul K. Acquaviva
  • Patent number: 11092906
    Abstract: A toner including a parent toner particle comprising at least one resin, in combination with an optional colorant, and an optional wax; and a surface additive formulation comprising at least one medium silica surface additive; at least one large silica surface additive; at least one positive charging surface additive, wherein the at least one positive charging surface additive is (a) a titanium dioxide surface additive; and wherein the parent toner particles further contain a small silica; or (b) a non-titanium dioxide positive charging metal oxide surface additive; and wherein the parent toner particles further optionally contain a small silica; and wherein a total surface area coverage of all of the surface additives combined is 100 to 140 percent of the parent toner particle surface area.
    Type: Grant
    Filed: February 25, 2020
    Date of Patent: August 17, 2021
    Assignee: Xerox Corporation
    Inventors: Richard P. N. Veregin, Michael F. Zona, Jordan A. Frank, Daniel W. Asarese, Paul K. Acquaviva, Chieh-Min Cheng
  • Patent number: 11086244
    Abstract: A toner including a parent toner particle comprising at least one resin, in combination with an optional colorant, and an optional wax; and a surface additive formulation comprising at least one medium silica surface additive; at least one large cross-linked organic polymeric additive; at least one positive charging surface additive, wherein the at least one positive charging surface additive is (a) a titanium dioxide surface additive; and wherein the parent toner particles further contain a small silica; or (b) a non-titanium dioxide positive charging metal oxide surface additive; and wherein the parent toner particles further optionally contain a small silica; and wherein a total surface area coverage of all of the surface additives combined is 100 to 140 percent of the parent toner particle surface area.
    Type: Grant
    Filed: February 25, 2020
    Date of Patent: August 10, 2021
    Assignee: Xerox Corporation
    Inventors: Richard P. N. Veregin, Michael F. Zona, Jordan A. Frank, Daniel W. Asarese, Chieh-Min Cheng, Paul K. Acquaviva
  • Patent number: 11086243
    Abstract: A toner composition including a first wax; a second wax that is different from the first wax; wherein the first wax comprises a paraffin wax; wherein the second wax comprises a polymethylene wax; at least one polyester; and an optional colorant.
    Type: Grant
    Filed: February 25, 2020
    Date of Patent: August 10, 2021
    Assignee: Xerox Corporation
    Inventors: Jordan A. Frank, Daniel W. Asarese, Paul K. Acquaviva, Chieh-Min Cheng, Michael F. Zona, Richard P. N. Veregin
  • Patent number: 10875241
    Abstract: A three-dimensional (3-D) printer includes build and support material development stations positioned to transfer layers of build and support materials to an intermediate transfer surface. The intermediate transfer surface transfers a layer of the build and support materials to a platen each time the platen contacts the intermediate transfer surface. A sensor detects the thickness of the layer on the platen, and a mechanical planer is positioned to contact and level the layer on the platen as the platen moves past the mechanical planer. Additionally, a feedback loop is electrically connected to the sensor and the mechanical planer. The mechanical planer adjusts the amount of the build material and the support material removed from the layer based on the thickness of the layer on the platen, as determined by the sensor.
    Type: Grant
    Filed: March 14, 2019
    Date of Patent: December 29, 2020
    Assignee: Xerox Corporation
    Inventors: Robert A. Clark, Michael F. Zona, William J. Nowak, Chu-heng Liu, Jorge A. Alvarez, Paul J. McConville
  • Patent number: 10688717
    Abstract: A 3-D printer includes build and support material development stations that electrostatically transfer build material and support material to an ITB. The ITB transfers a layer of build and support material to a platen each time the platen contacts one of the layers on the ITB, to successively form a freestanding stack of the layers on the platen. A sensor is positioned to generate a topographic measurement of the layer on the platen, and an aerosol applicator is positioned to propel build and support material on to the layer on the platen. The aerosol applicator controls the build and support material being propelled, based on the topographic measurement from the sensor through a feedback loop, to adjust the amount and location of the build material and the support material propelled on to the layer, and thereby control the flatness of surface topology of the layers in the freestanding stack on the platen.
    Type: Grant
    Filed: August 27, 2018
    Date of Patent: June 23, 2020
    Assignee: Xerox Corporation
    Inventors: William J. Nowak, Jorge A. Alvarez, Robert A. Clark, Michael F. Zona, Chu-heng Liu, Paul J. McConville
  • Publication number: 20190217535
    Abstract: A method of additive manufacturing includes forming a plurality of build layers, each of the plurality of build layers formed by transferring a first build material having a first particle size to form a first build material and transferring a second build material on the first build material to form one of the plurality of build layers, a particle size of the second build material is smaller than the first build material and each transfer step is performed by a xerographic engine. Each transfer step is involves transfer to a conveyor which can take the form of a belt or drum.
    Type: Application
    Filed: March 27, 2019
    Publication date: July 18, 2019
    Inventors: Michael F. Zona, William J. Nowak, Jorge A. Alvarez, Paul J. McConville, Robert A. Clark
  • Publication number: 20190210279
    Abstract: A three-dimensional (3-D) printer includes build and support material development stations positioned to transfer layers of build and support materials to an intermediate transfer surface. The intermediate transfer surface transfers a layer of the build and support materials to a platen each time the platen contacts the intermediate transfer surface. A sensor detects the thickness of the layer on the platen, and a mechanical planer is positioned to contact and level the layer on the platen as the platen moves past the mechanical planer. Additionally, a feedback loop is electrically connected to the sensor and the mechanical planer. The mechanical planer adjusts the amount of the build material and the support material removed from the layer based on the thickness of the layer on the platen, as determined by the sensor.
    Type: Application
    Filed: March 14, 2019
    Publication date: July 11, 2019
    Applicant: Xerox Corporation
    Inventors: Robert A. Clark, Michael F. Zona, William J. Nowak, Chu-heng Liu, Jorge A. Alvarez, Paul J. McConville
  • Patent number: 10293547
    Abstract: A three-dimensional (3-D) printer includes build and support material development stations positioned to transfer layers of build and support materials to an intermediate transfer surface. The intermediate transfer surface transfers a layer of the build and support materials to a platen each time the platen contacts the intermediate transfer surface. A sensor detects the thickness of the layer on the platen, and a mechanical planer is positioned to contact and level the layer on the platen as the platen moves past the mechanical planer. Additionally, a feedback loop is electrically connected to the sensor and the mechanical planer. The mechanical planer adjusts the amount of the build material and the support material removed from the layer based on the thickness of the layer on the platen, as determined by the sensor.
    Type: Grant
    Filed: June 7, 2016
    Date of Patent: May 21, 2019
    Assignee: Xerox Corporation
    Inventors: Robert A. Clark, Michael F. Zona, William J. Nowak, Chu-heng Liu, Jorge A. Alvarez, Paul J. McConville
  • Patent number: 10183443
    Abstract: 3-D printers include an intermediate transfer surface that transfers a layer of material to a platen each time the platen contacts the intermediate transfer surface to successively form a freestanding stack of layers of the material on the platen. A sensor detects the thickness of the layer on the platen after a fusing station fuses the layer. A feedback loop is electrically connected to the sensor and a development station (that includes a photoreceptor, a charging station providing a static charge to the photoreceptor, a laser device exposing the photoreceptor, and a development device supplying the material to the photoreceptor). The development station adjusts the development bias of the development device, based on a layer thickness measurement from the sensor through the feedback loop, to control the thickness of subsequent ones of the layers transferred from the intermediate transfer surface to the freestanding stack on the platen.
    Type: Grant
    Filed: May 10, 2016
    Date of Patent: January 22, 2019
    Assignee: Xerox Corporation
    Inventors: Jorge A. Alvarez, Michael F. Zona, William J. Nowak, Robert A. Clark, Chu-heng Liu, Paul J. McConville
  • Patent number: 10180649
    Abstract: A system and method are provided for implementing a unique electrophotographic layered manufacturing scheme for creating higher fidelity electrophotographic composite laminate layers using tri-level electrophotography or electrostatic imaging scheme as a process for rendering individual laminate layers to be built up to form and/or manufacture three-dimensional objects, parts and components as 3D objects. A multi-stage 3D object forming scheme is described involving steps of multi-component laminate forming in a particularized electrophotographic layer forming process. This process renders a part component and a support component precisely next to one another with a single exposure by an exposing device to form a latent image of variable discharge voltages. Multiple toner product sources are used to dispose part component toner and support component toner in the forming of the multi-component laminate layer.
    Type: Grant
    Filed: December 4, 2015
    Date of Patent: January 15, 2019
    Assignee: Xerox Corporation
    Inventors: Willam J Nowak, Jorge A Alvarez, Paul J McConville, Robert A Clark, Michael F Zona
  • Publication number: 20180361661
    Abstract: A 3-D printer includes build and support material development stations that electrostatically transfer build material and support material to an ITB. The ITB transfers a layer of build and support material to a platen each time the platen contacts one of the layers on the ITB, to successively form a freestanding stack of the layers on the platen. A sensor is positioned to generate a topographic measurement of the layer on the platen, and an aerosol applicator is positioned to propel build and support material on to the layer on the platen. The aerosol applicator controls the build and support material being propelled, based on the topographic measurement from the sensor through a feedback loop, to adjust the amount and location of the build material and the support material propelled on to the layer, and thereby control the flatness of surface topology of the layers in the freestanding stack on the platen.
    Type: Application
    Filed: August 27, 2018
    Publication date: December 20, 2018
    Applicant: Xerox Corporation
    Inventors: William J. Nowak, Jorge A. Alvarez, Robert A. Clark, Michael F. Zona, Chu-heng Liu, Paul J. McConville
  • Patent number: 10118337
    Abstract: A 3-D printer includes build and support material development stations that electrostatically transfer build material and support material to an ITB. The ITB transfers a layer of build and support material to a platen each time the platen contacts one of the layers on the ITB, to successively form a freestanding stack of the layers on the platen. A sensor is positioned to generate a topographic measurement of the layer on the platen, and an aerosol applicator is positioned to propel build and support material on to the layer on the platen. The aerosol applicator controls the build and support material being propelled, based on the topographic measurement from the sensor through a feedback loop, to adjust the amount and location of the build material and the support material propelled on to the layer, and thereby control the flatness of surface topology of the layers in the freestanding stack on the platen.
    Type: Grant
    Filed: June 6, 2016
    Date of Patent: November 6, 2018
    Assignee: Xerox Corporation
    Inventors: William J. Nowak, Jorge A. Alvarez, Robert A. Clark, Michael F. Zona, Chu-heng Liu, Paul J. McConville
  • Patent number: 10076869
    Abstract: A three-dimensional (3-D) printer includes build and support material development stations positioned to transfer layers of build and support materials to an intermediate transfer surface. A platen having a flat surface is positioned to contact the intermediate transfer surface. The intermediate transfer surface transfers a layer of the build and support materials to the flat surface of the platen as the platen contacts one of the layers on the intermediate transfer surface. A dispenser is positioned to deposit a leveling material on the layer on the platen, and a mechanical planer is positioned to contact and level the leveling material on the layer on the platen to make the top of the leveling material parallel to the flat surface of the platen.
    Type: Grant
    Filed: June 7, 2016
    Date of Patent: September 18, 2018
    Assignee: Xerox Corporation
    Inventors: Chu-heng Liu, Paul J. McConville, William J. Nowak, Michael F. Zona, Robert A. Clark, Jorge A. Alvarez