Patents by Inventor Michael Graetzel

Michael Graetzel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8663821
    Abstract: Light emitting materials comprising multinuclear metal complexes comprising at least two metal atoms and a metal bridging ligand bound to said at least two metal atoms. It relates more particularly to a multinuclear complex of Formula (I): {-[L]2M-B-}n, wherein L is a bidentate ligand; M represents a transition metal having an atomic number of at least 40, and each M can be the same or different at each occurrence; B is a 2-connecting short metal bridging ligand bound to said at least two metal atoms, where the metal bridging ligand comprises coordinating atoms independently selected from the group consisting of nitrogen, phosphorous, carbon, oxygen, sulphur and selenium in 1,2 or 1,3 mutual position. (1,2-? or 1,3-? bonding mode); and n is an integer larger than 1.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: March 4, 2014
    Assignee: Solvay SA
    Inventors: Etienne David Baranoff, Mohammad Khaja Nazeeruddin, Michael Graetzel
  • Publication number: 20140005397
    Abstract: Disclosed is a metal complex having a partial structure represented by the following Formula (I-0) or a tautomer thereof: formula (I-0) Cy is a 5 to 7 membered heterocyclic ring, preferably a 6-membered ring, which may be aromatic, non aromatic or partially aromatic and which coordinates to the metal atom through a carbon atom; A is a nitrogen atom a is an integer equal or superior to 1; D is an electron donor group; and b is an integer equal or superior to 1.
    Type: Application
    Filed: November 21, 2011
    Publication date: January 2, 2014
    Applicant: SOLVAY SA
    Inventors: Michael Graetzel, Etienne David Baranoff, Mohammad Khaja Nazeeruddin
  • Publication number: 20130330632
    Abstract: The invention relates to electrochemical devices comprising complexes of cobalt comprising at least one ligand with a 5- or six membered, N-containing heteroring. The complex are useful as p- and n-dopants, as over of electrochemical devices, in particular in organic semiconductors. The complexes are further useful as over-discharge prevention and overvoltage protection agents.
    Type: Application
    Filed: February 24, 2012
    Publication date: December 12, 2013
    Inventors: Julian Burschka, Florian Kessler, Etienne Baranoff, Mohammad Khaja Nazeeruddin, Michael Graetzel
  • Publication number: 20130317212
    Abstract: The present invention relates to an organometallic complex, to the preparation of said material, to the use of said material and to a light emitting device which transform electric energy into light. The present invention is further related to provide phosphorescent complexes which contribute to extend the life time in operation of said OLEDs and especially when they are involved in the EL. The objectives of this invention are accomplished by iridium complex comprising 7-membered fused ring ligands which are tris-homoleptic or bis-homoleptic with an ancillary ligand.
    Type: Application
    Filed: August 3, 2011
    Publication date: November 28, 2013
    Applicant: SOLVAY SA
    Inventors: Mohammad Khaja Nazeeruddin, Etienne David Baranoff, Michael Graetzel
  • Patent number: 8518557
    Abstract: This invention pertains to light emitting materials comprising novel ortho-metalated transition metal complexes [C^N]2ML comprising two orthometalated ligands having imidazole moieties and an ancillary ligand of ?-diketonate type. The ortho-metalated transition metal complexes are represented by formula (I): It has been surprisingly found that when the metal has bound thereto both orthometalated ligands comprising imidazole moieties and an ancillary ligand of ?-diketonate type, the ligands advantageously participate in the emission process, significantly broadening emission in the visible region and enabling appreciable improvement of the white emission efficiency of complexes [C^N]2ML. Additional objects of the invention are the use of the light emitting materials and organic light emitting device comprising the light emitting material.
    Type: Grant
    Filed: October 11, 2007
    Date of Patent: August 27, 2013
    Assignee: Solvay (Societe Anonyme)
    Inventors: Mohammad Khaja Nazeeruddin, Cedric Klein, Michael Graetzel
  • Patent number: 8487119
    Abstract: The present invention relates to new organic sensitizer compounds and to photoelectric conversion devices, in particular dye-sensitised solar cells comprising the new sensitizers. The present invention also relates to flexible photoelectric conversion devices, which are based on ionic liquid electrolytes or organic charge transporting materials.
    Type: Grant
    Filed: February 3, 2009
    Date of Patent: July 16, 2013
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Mingfei Xu, Hao Qin, Feifei Gao, Peng Wang, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Patent number: 8440843
    Abstract: A dye sensitized solar cell, comprising a heteroleptic polypyridil complex of Ru, Os or Fe. The donating ligand has an extended conjugated ?-system increasing the light absorbance and keeing the LUMO energy level higher than that of the anchoring ligand. A compacting compound whose molecular structure comprises a terminal group, a hydrophobic part and an anchoring group may be co-adsorbed together with the dye on the semi-conductive metal oxide layer of the photoanode, forming a dense mixed self-assembled monolayer.
    Type: Grant
    Filed: April 7, 2011
    Date of Patent: May 14, 2013
    Assignee: Ecole Polytechnique Fédérale de Lausanne
    Inventors: Shaik Mohammad Zakeeruddin, Cêdric Klein, Peng Wang, Michael Graetzel
  • Patent number: 8357800
    Abstract: The present invention relates to light emitting materials comprising novel ortho-metalated transition metal complexes [C^N]2M[N^N] comprising two orthometalated ligands (C^N ligands) and a neutral bidentate bipyridine ligand (N^N). Surprisingly, it has been found that when the metal binds both orthometalated chelate C^N ligands and a neutral bidentate bipyridine ligand (N^N), these ligands participate in the emission process, thus greatly improving the red emission efficiency of complexes [C^N]2M[N^N]. The present invention further relates to the use of such light emitting materials and an organic light emitting device comprising such light emitting material.
    Type: Grant
    Filed: June 5, 2008
    Date of Patent: January 22, 2013
    Assignee: SOLVAY (Societe Anonyme)
    Inventors: Mohammad Khaja Nazeeruddin, Etienne David Baranoff, Michael Graetzel
  • Patent number: 8357799
    Abstract: This invention pertains to light emitting materials comprising novel ortho-metalated transition metal complexes [C^N]2M[P^O] comprising two orthometalated chelate C^N ligands and an ancillary ligand of bidentate phosphinocarboxylate type. It has been surprisingly found that when the metal has bound thereto both orthometalated chelate C^N ligands and an ancillary ligand of bidentate phosphinocarboxylate type (P^O), these ligands advantageously participate in the emission process, enabling appreciable improvement of the blue emission efficiency of complexes [C^N]2M[P^O]. Still objects of the invention are the use of such light emitting materials and organic light emitting device comprising such light emitting material.
    Type: Grant
    Filed: June 5, 2008
    Date of Patent: January 22, 2013
    Assignee: SOLVAY (Societe Anonyme)
    Inventors: Mohammad Khaja Nazeeruddin, Nicholas Evans, Michael Graetzel
  • Publication number: 20120258148
    Abstract: Endosseous implant to be applied to a human or animal bone, wherein the surface of the implant is made from titanium or a titanium alloy, said implant having a smooth or rough surface texture, which is characterized in that said surface has been treated with at least one selected organic phosphonate compound or a pharmaceutically acceptable salt or ester or an amide thereof; process for producing said implants.
    Type: Application
    Filed: June 8, 2012
    Publication date: October 11, 2012
    Inventors: Pierre DESCOUTS, Björn-Owe ARONSSON, Michael GRÄTZEL, Carine VIORNERY, Peter PÉCHY
  • Publication number: 20120253043
    Abstract: The present invention provides new bi- and polypyridine ligands of ruthenium dyes. The invention also provides solar cells, in particular dye-sensitized solar cells comprising the dyes.
    Type: Application
    Filed: September 29, 2010
    Publication date: October 4, 2012
    Applicants: Ecole Polytechnique Federale De Lausanne (EPFL), Consiglio Nazionale Delle Ricerche, Universita Degli Studi Di Milano-Bicocca
    Inventors: Mohammad Khaja Nazeeruddin, Michael Graetzel, Alessandro Abbotto, Chiara Marinzi, Norberto Manfredi, Filippo De Angelis
  • Patent number: 8216601
    Abstract: Endosseous implant to be applied to a human or animal bone, wherein the surface of the implant is made from titanium or a titanium alloy, said implant having a smooth or rough surface texture, which is characterized in that said surface has been treated with at least one selected organic phosphonate compound or a pharmaceutically acceptable salt or ester or an amide thereof; process for producing said implants.
    Type: Grant
    Filed: May 27, 2010
    Date of Patent: July 10, 2012
    Assignees: Universite de Geneve, Ecole Polytechnique Federale de Lausanne
    Inventors: Pierre Descouts, Björn-Owe Aronsson, Michael Grätzel, Carine Viornery, Peter Péchy
  • Publication number: 20120090679
    Abstract: Solid state dye sensitized photovoltaic cells, as well as related components, systems, and methods, are disclosed.
    Type: Application
    Filed: March 16, 2010
    Publication date: April 19, 2012
    Applicant: Konarka Technologies, Inc.
    Inventors: Kethinni G. Chittibabu, Michael Graetzel, David P. Waller, Srini Balasubramanian, Kevin Coakley, Jin-An He, Jean Francois Penneau, Igor Sokolik
  • Patent number: 8114318
    Abstract: The present invention relates to electrolytes comprising tetracyanoborate and an organic cation as components of electrolytes in electrochemical and/or optoelectronic devices, in particular solar cells. This ionic liquid has low viscosity and can be used as electrolyte in the absence of a solvent. Importantly, the ionic liquid remains stable in solar cells even after prolonged thermal stress at 80° C. for 1000 hours. Photovoltaic conversion efficiency remained stable and keeping more than 90% of the initial value.
    Type: Grant
    Filed: February 13, 2007
    Date of Patent: February 14, 2012
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Daibin Kuang, Peng Wang, Shaik Mohammad Zakeeruddin, Michaël Graetzel
  • Patent number: 8105865
    Abstract: The present invention relates to optoelectronic and/or electrochemical devices comprising an organic charge transporting material which is liquid at a temperature of ?180° C. In particular in dye-sensitised solar cells, quantum efficiency higher than with prior art solid organic hole-transporters is reported. The melting point of a large quantity of organic charge transporting materials may be adjusted to a desired value by selecting suitable substituents. Accordingly, general advantages of the liquid state may be associated with the properties of organic charge transporting materials.
    Type: Grant
    Filed: March 21, 2007
    Date of Patent: January 31, 2012
    Assignee: Ecole Polytechnique Fédérale de Lausanne (EPFL)
    Inventors: Henry J. Snaith, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Publication number: 20120012790
    Abstract: White light emitting material comprising a complex salt of the general formula [M1m+]x [M2n?]y wherein: x m=y n, [M13+] and [M2n?] are ionic light emitting moieties which have complementary emission spectra, one emitting in the blue region of the visible spectra and the other, in the red region of the visible spectra, and wherein at least one of M1 and M2 is a metallic complex.
    Type: Application
    Filed: February 8, 2010
    Publication date: January 19, 2012
    Applicant: SOLVAY SA
    Inventors: Mohammad Khaja Nazeeruddin, Etienne David Baranoff, Michael Graetzel
  • Publication number: 20120010411
    Abstract: The present invention relates to modified surfaces. The surfaces comprise an inorganic material on which a phosphinic acid derivative is adsorbed. The phosphinic acid thus turns out to be a new anchoring group useful for surface derivatisation. The invention has many applications for photoelectric conversion devices, batteries, capacitors, electrochromic displays, chemical sensors, biological sensors, light emitting diodes, electrodes, semiconductors, separation membranes, selective adsorbents, adsorbents for HPLC, catalysts, implants, nanoparticles, antiadhesives, and anticorrosion coatings, for example.
    Type: Application
    Filed: March 19, 2010
    Publication date: January 12, 2012
    Applicant: ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL)
    Inventors: Shaik Mohammad Zakeeruddin, Péter Péchy, Michael Graetzel
  • Publication number: 20110303267
    Abstract: The present invention provides novel dyes for dye sensitized photovoltaic conversion devices. The dyes contain novel anchoring ligands, which have a vinyl or phenylethenyl moiety incorporated in the anchoring bipyridine. Such dyes exhibit an increased molar extinction coefficient and enhanced red response in the visible regions.
    Type: Application
    Filed: November 11, 2009
    Publication date: December 15, 2011
    Inventors: Mohammad Nazeeruddin, Michael Graetzel
  • Publication number: 20110282059
    Abstract: A light emitting material comprising a complex of formula (I): (L1)x-M-(L2)y wherein L1 is a mono-anionic bidentate carbon-coordinating ligand comprising the structural element (II) in a ring system, wherein R1 is a substituent selected from the group consisting of R1-1 to R1-8, the use thereof as emissive materials in organic light emitting devices, and organic light emitting devices comprising said emissive material.
    Type: Application
    Filed: February 8, 2010
    Publication date: November 17, 2011
    Applicant: SOLVAY SA
    Inventors: Etienne David Baranoff, IL Jung, Mohammad Khaja Nazeeruddin, Michael Graetzel
  • Publication number: 20110265876
    Abstract: The present invention relates to novel pyridine compounds that can be used as anchoring ligands in metal-based sensitizing dyes of dye sensitized solar cells (DSCS). The dyes comprising the polypyridine compounds exhibit improved light harvesting ability and lead to increased conversion efficiencies, in particular in thin TiO2 film devices.
    Type: Application
    Filed: November 11, 2009
    Publication date: November 3, 2011
    Applicants: UNIVERSITÄT ULM, ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL)
    Inventors: Shaik Mohammad Zakeeruddin, Cédric Klein, Mohammad Khaja Nazeeruddin, Michael Graetzel, Amaresh Mishra, Markus Fischer, Peter Bäuerle