Abstract: Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and acid copolymer ionomer. The cover composition also can contain hydroxyl-containing compounds. The golf ball having the thermoplastic polyurethane cover can be treated with an isocyanate compound. The golf ball also can be treated with an amine and/or silane-containing compound. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls have good physical properties.

Abstract: Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and epoxy compound. Mixtures of multi-functional amines and imines, and multi-functional isocyanates, and epoxy curing agents; and solvent, can be applied to the outer cover. The resulting coating may contain polyurethanes, polyureas, and hybrids, copolymers, and blends thereof. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls have good physical properties.

Abstract: Multi-layered golf balls having at least one layer made from silicone (polysiloxane) elastomers; silicone (polysiloxane) elastomer/polyurethane blends; polycarbonate-polysiloxane blends and copolymers; and polycarbonate-polysiloxane/polyurethane blends are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core and cover structures can be made. The polysiloxane compositions have good thermal stability and durability without sacrificing resiliency. The polysiloxane compositions also have high elongation, tensile strength, chemical/fluid-resistance, and weatherability properties. These compositions can be used to form any layer, for example, core, intermediate, or cover, in the golf ball.

Abstract: Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and polydimethylsiloxane compound. Functionalized polydimethylsiloxane compounds also can be used to treat thermoplastic polyurethane golf ball covers. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls with thermoplastic polyurethane covers have good physical properties.

Abstract: Golf ball incorporating thermoplastic blend of (i) ionomer(s); (ii) different thermoplastic polymer(s) selected from thermoplastic polyurethane(s), thermoplastic urea(s), thermoplastic urea-urethane hybrid(s), or combinations thereof; and (iii) polymethyl (meth)acrylate-based copolymer(s) and/or core-shell polymer(s) having a core and/or a shell containing polymethyl (meth)acrylate-based copolymer(s). Ionomer(s) are present in thermoplastic blend in amount of about 45 wt % or greater. Different thermoplastic polymer present in blend in amount of: from about 8 wt % to about 50 wt %; or greater than 20 wt %, or from about 25 wt % to about 45 wt %; or from about 35 wt % to about 50 wt %. In a particular embodiment, amount of ionomer(s) is greater than thermoplastic polyurethane amount.

Abstract: Golf ball comprising a colorless coating surrounding and adjacent to a TiO2 white-pigmented layer comprising a polymeric composition that comprises throughout: (i) passivated TiO2 particulates amount of from about 1 wt. %-10 wt. % based on total weight of second polymeric composition; and (ii) silane-containing adhesion promoter(s), for example, organosilanes and/or organosiloxanes in an amount of from about 0.1 wt. % to about 5.0 wt. % of the total weight of the polymeric composition. The coating comprises a coating composition that is different than the polymeric composition and does not contain any silane-containing adhesion promoter; and there is no surface treatment with adhesion promoter at an interface between the colorless coating and TiO2 white-pigmented layer. In lieu of the colorless coating, the golf ball may include a coating that is clear tinted or translucent.

Abstract: Golf ball incorporating polyurethane mixture having wt. % NCO content of ˜4-20 and including a prepolymer polyol portion comprised of trans-?-Farnesene diol(s) in an amount of about 3-70 wt. % of total weight of prepolymer. Trans-?-Farnesene diol may be 15 carbon, long chain, branched, unsaturated 3,4-vinyl-containing bio-hydrocarbon having the formula: Prepolymer can include a 1:99 to 99:1 blend (wt. % ratio) of Trans-?-Farnesene diol(s) and polybutadiene-based polyol(s) in an amount of about 35-85 wt. %, along with about 15 wt. %-65 wt. % of diisocyanate(s). Curative may be combined with prepolymer in amount of about 3-25 wt. % of total weight of curative and prepolymer combined, and may be mixture of aromatic diamine(s) and white dispersion in a wt. % ratio of about 90:10 to 50:50, plus catalyst. Hardness of polyurethane mixture can be from 75. Shore A to 75 Shore D or a material hardness can be from about 40 Shore D to about 65 Shore D.

Abstract: Golf balls having a multi-layered core made of a foamed composition are provided. The core preferably has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition is used to form the foam center. The foam inner core preferably includes a fully-foamed center region and a partially or completely-collapsed foam outer region. The hardness of the fully-foamed region is different than the hardness of the collapsed foam region. Non-foamed thermoset or thermoplastic materials such as polybutadiene rubbers or ethylene acid copolymer ionomer may be used to form the outer core layer. The ball further includes a cover that may be multi-layered. The foam cores have good resiliency.

Abstract: Multi-layered golf balls having at least one layer made from silicone (polysiloxane) elastomers; silicone (polysiloxane) elastomer/polyurethane blends; polycarbonate-polysiloxane blends and copolymers; and polycarbonate-polysiloxane/polyurethane blends are provided. For example, three-piece, four-piece, and five-piece golf balls containing different core and cover structures can be made. The polysiloxane compositions have good thermal stability and durability without sacrificing resiliency. The polysiloxane compositions also have high elongation, tensile strength, chemical/fluid-resistance, and weatherability properties. These compositions can be used to form any layer, for example, core, intermediate, or cover, in the golf ball.

Abstract: Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and acid copolymer ionomer. The cover composition also can contain hydroxyl-containing compounds. The golf ball having the thermoplastic polyurethane cover can be treated with an isocyanate compound. The golf ball also can be treated with an amine and/or silane-containing compound. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls have good physical properties.

Abstract: Multi-piece golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The outer core layer is preferably formed from a non-foamed thermoset composition such as polybutadiene rubber. The inner and outer core layers can have different hardness gradients. Preferably, the specific gravity (density) of the foam inner core is less than the density of the outer core layer. The ball further includes a cover of at least one layer and may include at least one casing layer. The core structure and resulting ball have relatively good resiliency.

Abstract: Multi-layered golf balls having a core made of a foamed composition, preferably polyurethane foam, are provided. The ball includes a dual-layered core having a foam inner core (center) and surrounding outer core layer. The outer core layer may be made from a non-foamed thermoset material such as polybutadiene rubber. The ball further includes an inner cover, preferably made from an ionomer composition comprising an O/X-type acid copolymer, wherein O is ?-olefin, and X is a C3-C8 ?,?-ethylenically unsaturated carboxylic acid. The outer cover may be made from a non-foamed thermoset or thermoplastic material such as polyurethane. Preferably, the specific gravity of the inner cover is greater than the specific gravity of the outer core, which is greater than the specific gravity of the inner core. The finished ball has good distance and low-spin properties.

Abstract: Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and polydimethylsiloxane compound. Functionalized polydimethylsiloxane compounds also can be used to treat thermoplastic polyurethane golf ball covers. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls with thermoplastic polyurethane covers have good physical properties.

Abstract: Multi-layered golf balls having a core, intermediate layer, and cover are provided. The ball includes a non-foamed inner core (center) made of a thermoplastic or thermoset composition such as polybutadiene rubber. An intermediate layer comprising a foamed composition, such as polyurethane foam, is disposed about the inner core. The foamed intermediate layer may have a specific gravity gradient within the layer, wherein the outer surface specific gravity is greater than the midpoint specific gravity. Ball constructions having two intermediate layers, wherein at least one layer is a foamed layer can be made. A cover having at least one layer is disposed about the intermediate layer.

Abstract: Multi-piece golf balls having a solid core made of a foamed composition and a cover are provided. Preferably, the core is dual-layered having has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition containing mineral filler particulate, for example, nanoclay particles, is used to form the foam center. The concentration of clay particulate is preferably in a range of 0.1 to 60% by weight. The surrounding outer core layer may be made from non-foamed or foamed compositions. For example, polybutadiene rubber or highly neutralized olefin acid copolymers may be used in the outer core layer. The core layers have different hardness gradients and specific gravity values.

Abstract: Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and acid copolymer ionomer. The cover composition also can contain hydroxyl-containing compounds. The golf ball having the thermoplastic polyurethane cover can be treated with an isocyanate compound. The golf ball also can be treated with a hydroxyl and/or silane-containing compound. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls have good physical properties.

Abstract: Golf ball incorporating polyurethane mixture having wt. % NCO content of ˜4-20 and including a prepolymer polyol portion comprised of trans-?-Farnesene diol(s) in an amount of about 3-70 wt. % of total weight of prepolymer. Trans-?-Farnesene diol may be 15 carbon, long chain, branched, unsaturated 3,4-vinyl-containing bio-hydrocarbon having the formula: Prepolymer can include a 1:99 to 99:1 blend (wt. % ratio) of Trans-?-Farnesene diol(s) and polybutadiene-based polyol(s) in an amount of about 35-85 wt. %, along with about 15 wt. %-65 wt. % of diisocyanate(s). Curative may be combined with prepolymer in amount of about 3-25 wt. % of total weight of curative and prepolymer combined, and may be mixture of aromatic diamine(s) and white dispersion in a wt. % ratio of about 90:10 to 50:50, plus catalyst. Hardness of polyurethane mixture can be from 75 Shore A to 75 Shore D or a material hardness can be from about 40 Shore D to about 65 Shore D.

Abstract: Multi-piece golf balls having a solid core made of a foamed composition and a cover are provided. Preferably, the core is dual-layered having has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition containing mineral filler particulate, for example, nanoclay particles, is used to form the foam center. The concentration of clay particulate is preferably in a range of 0.1 to 60% by weight. The surrounding outer core layer may be made from non-foamed or foamed compositions. For example, polybutadiene rubber or highly neutralized olefin acid copolymers may be used in the outer core layer. The core layers have different hardness gradients and specific gravity values.

Abstract: Golf balls having a multi-layered core made of a foamed composition are provided. The core preferably has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition is used to form the foam center. The foam inner core preferably includes a fully-foamed center region and a partially or completely-collapsed foam outer region. The hardness of the fully-foamed region is different than the hardness of the collapsed foam region. Non-foamed thermoset or thermoplastic materials such as polybutadiene rubbers or ethylene acid copolymer ionomer may be used to form the outer core layer. The ball further includes a cover that may be multi-layered. The foam cores have good resiliency.

Abstract: Golf ball comprising a colorless coating surrounding and adjacent to a TiO2 white-pigmented layer comprising a polymeric composition that comprises throughout: (i) passivated TiO2 particulates amount of from about 1 wt. %-10 wt. % based on total weight of second polymeric composition; and (ii) silane-containing adhesion promoter(s), for example, organosilanes and/or organosiloxanes in an amount of from about 0.1 wt. % to about 5.0 wt. % of the total weight of the polymeric composition. The coating comprises a coating composition that is different than the polymeric composition and does not contain any silane-containing adhesion promoter; and there is no surface treatment with adhesion promoter at an interface between the colorless coating and TiO2 white-pigmented layer. In lieu of the colorless coating, the golf ball may include a coating that is clear tinted or translucent.