Patents by Inventor Michael R. Roberts
Michael R. Roberts has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20040259041Abstract: The present invention is directed to a method of forming a positive image in a photothermographic element comprising a potentially negative-working emulsion wherein fog density development is imagewise inhibited in exposed areas of the image upon thermal development. In one embodiment of the invention, a density-inhibiting agent is released during thermal development which agent inhibits the thermal development of unexposed silver salts in the exposed areas relative to the unexposed areas. The method preferably comprises imagewise exposing the film with a non-solarizing amount of radiation/energy to form a latent image and thermally developing the latent image in a single development step to produce a positive image in the element. The present invention is also directed to a photothermographic element that can be used in the present process in which a positive image characterized by high speed and discrimination is formed when exposed and thermally heated above 150° C.Type: ApplicationFiled: June 12, 2003Publication date: December 23, 2004Inventors: Michael R. Roberts, Paul B. Gilman, Donald L. Black, Kurt M. Schroeder
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Publication number: 20040253552Abstract: The present invention is directed to a method of forming a positive image in a photothermographic element comprising a potentially negative-working emulsion wherein fog density development is imagewise inhibited in exposed areas of the image upon thermal development, the element further comprising a developer or precursor thereof and an oxidized developer scavenging agent to accelerate development by removing oxidized developer as it is formed during the thermal development step. In one embodiment of the invention, in which a density-inhibiting agent is released during thermal development that inhibits the thermal development of unexposed silver salts in the exposed areas relative to the unexposed areas, the method comprises imagewise exposing the film with a non-solarizing amount of radiation/energy to form a latent image and thermally developing the latent image in a single development step to produce a positive image in the element.Type: ApplicationFiled: June 12, 2003Publication date: December 16, 2004Inventors: Michael R. Roberts, Paul B. Gilman, Donald L. Black, Kurt M. Schroeder
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Patent number: 6479225Abstract: A silver halide photographic element for forming a sepia image comprising a support and an image forming layer which contains a cyan dye forming coupler, a magenta dye forming coupler and a yellow dye forming coupler, wherein the support has CIELAB a* and b* values within the following ranges at L*>90:0<b*<6.0, 0<a*<1.Type: GrantFiled: July 30, 2001Date of Patent: November 12, 2002Assignee: Eastman Kodak CompanyInventors: David J. Valvo, Kurt M. Schroeder, Michael R. Roberts
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Patent number: 6426178Abstract: The invention relates to a photographic element for forming neutral images comprising a cyan dye-forming coupler, a magenta dye-forming coupler of formula wherein Ra and Rb represents H or a substituent; X is hydrogen or a coupling-off group; Za, Zb, and Zc are a substituted methine group, ═N—, ═C—, or —NH—; and yellow dye-forming coupler of formula, wherein R5 is an alkoxy group with more than one carbon atom, aryloxy, anilino, arylthio, alkylthio, or dialkylamino groups linked to the anilide phenyl ring by oxygen, sulfur or nitrogen; R6 is selected from hydrogen, halogen, alkoxycarbonyl(—CO2R), carbamoyl(—CONRR′), carbonamido(—NRCOR′), sulfonate(—OSO2R), sulfamoyl (—SO2NRR′), sulfonamido(—NRSO2R′), or sulfonyl(—SO2R); R and R′ may be hydrogen, alkyl or aryl groups; q is 1 to 4; R7 is alkyl, cyclic, or multicyclic alky, aryl, heterocyclic, heteroaromatic, andType: GrantFiled: August 7, 2000Date of Patent: July 30, 2002Assignee: Eastman Kodak CompanyInventors: Michael R. Roberts, Kurt M. Schroeder, Frank D. Coms
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Patent number: 6312880Abstract: The invention relates to a multilayer photographic element comprising a reflective support wherein the color record 1 adjacent to the support comprises at least one light sensitive layer and a non-light sensitive dye-forming interlayer; and wherein color record 2 above said color record 1 comprises at least one light sensitive layer and at least two non-light sensitive dye-forming interlayers and wherein color record 3 above said color record 2 comprises at least one light sensitive layer and a non-light sensitive dye-forming interlayer; and a top overcoat layer comprising gelatin and ultraviolet absorbing material; and wherein each interlayer is substantially scavenger free, and color records 1, 2, and 3 comprise silver halide grains comprising greater than 90% silver chloride, and wherein the reciprocity characteristics of the silver halide grains are such that for a separation exposure of 1 microsecond and 0.4 sec, at least one color record develops to a density of at least 2.Type: GrantFiled: December 27, 1999Date of Patent: November 6, 2001Assignee: Eastman Kodak CompanyInventors: Michael R. Roberts, Hwei-Ling Yau, Glenn M. Brown
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Patent number: 6280916Abstract: The invention relates to a multilayer photographic element comprising a reflective support wherein the color record 1 adjacent to the support comprises at least one light sensitive layer and a non-light sensitive dye-forming interlayer; and wherein color record 2 above said color record 1 comprises at least one light sensitive layer and at least two non-light sensitive dye-forming interlayers and wherein color record 3 comprises at least one light sensitive layer and a non-light sensitive dye-forming interlayer; an optional UV dye containing interlayer; and top overcoat; and wherein each interlayer is substantially scavenger free, silver halide grains comprising greater than 90% silver chloride, and wherein the reciprocity characteristics of the silver halide grains are such that for a separation exposure of 1 microsecond and 0.4 sec, each color record develops to a density of at least 2.0 within a log exposure range of 1.2 or less relative to the exposure point producing a density 0.04 above Dmin.Type: GrantFiled: December 27, 1999Date of Patent: August 28, 2001Assignee: Eastman Kodak CompanyInventor: Michael R. Roberts
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Patent number: 6268116Abstract: The invention relates to a multilayer photographic element comprising a reflective support wherein the color record 1 adjacent to the support comprises at least one light sensitive layer and a non-light sensitive dye-forming interlayer; and wherein color record 2 above said color record 1 comprises at least one light sensitive layer and at least two non-light sensitive dye-forming interlayers and wherein color record 3 comprises at least one light sensitive layer and a non-light sensitive dye-forming interlayer; an optional UV dye containing interlayer and a top overcoat; and wherein each interlayer is completely or substantially scavenger free, silver halide grains comprising greater than 90% silver chloride, and wherein the reciprocity characteristics of the silver halide grains are such that for a separation exposure of 1 microsecond and 0.4 sec, each color record develops to a density of at least 2.0 within a log exposure range of 1.2 or less relative to the exposure point producing a density 0.Type: GrantFiled: December 27, 1999Date of Patent: July 31, 2001Assignee: Eastman Kodak CompanyInventors: Michael R. Roberts, Gary J. McSweeney, Alphonse D. Camp
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Patent number: 6030756Abstract: The invention relates to an photographic element comprising a transparent polymer sheet, at least one layer of biaxially oriented polyolefin sheet and at least one image layer, wherein said polymer sheet has a stiffness of between 20 and 100 millinewtons said biaxially oriented polyolefin sheet has a spectral transmission between 35% and 90%, said biaxially oriented polyolefin sheet has a reflection density less than 65%.Type: GrantFiled: September 17, 1998Date of Patent: February 29, 2000Assignee: Eastman Kodak CompanyInventors: Robert P. Bourdelais, Peter T. Aylward, Alphonse D. Camp, Michael R. Roberts
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Patent number: 5958661Abstract: The invention relates to a color photographic element comprising a red light sensitive layer comprising a cyan dye forming coupler, a green light sensitive layer comprising a magenta dye forming coupler, a blue light sensitive layer comprising a yellow dye forming coupler, wherein said magenta dye forming coupler comprises ##STR1## wherein R.sub.a and R.sub.b independently represent H or a substituent; X is hydrogen or a coupling-off group; and Z.sub.a, Z.sub.b, and Z.sub.c are independently a substituted methine group, .dbd.N--, .dbd.C--, or --NH--, provided that one of either the Z.sub.a --Z.sub.b bond or the Z.sub.b --Z.sub.c bond is a double bond and the other is a single bond, and when the Z.sub.b --Z.sub.c bond is a carbon--carbon double bond, it may form part of an aromatic ring, and at least one of Z.sub.a, Z.sub.b, and Z.sub.c represents a methine group connected to the group R.sub.Type: GrantFiled: July 15, 1997Date of Patent: September 28, 1999Assignee: Eastman Kodak CompanyInventors: John B. Rieger, Alphonse D. Camp, Michael R. Roberts, Thomas A. Chuhta
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Patent number: 5451490Abstract: An electronic printing method which comprises subjecting a radiation sensitive silver halide emulsion layer of a recording element to actinic radiation of at least 10.sup.-4 ergs/cm.sup.2 for up to 100 microseconds duration in a pixel-by-pixel mode is disclosed. The radiation sensitive silver halide emulsion layer contains a silver halide grain population comprising at least 50 mole percent chloride, based on silver, forming the grain population projected area. At least 50 percent of the grain population projected area is accounted for by tabular grains that are bounded by {100} major faces having adjacent edge ratios of less than 10, each having an aspect ratio of at least 2.Type: GrantFiled: January 7, 1994Date of Patent: September 19, 1995Assignee: Eastman Kodak CompanyInventors: Jerzy A. Budz, Julie K. Ligtenberg, Michael R. Roberts, Susan K. Mroczek
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Patent number: 5432245Abstract: The invention provides acrylamide polymers that, when mixed with water solvent, provide thermoreversible solutions that form low viscosity melts at temperatures separated by a third region of maximum viscosity.Type: GrantFiled: May 7, 1993Date of Patent: July 11, 1995Assignee: Eastman Kodak CompanyInventors: Michael R. Roberts, Glenn T. Pearce, Elizabeth V. Patton
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Patent number: 5380642Abstract: A process for preparing a thin tabular grain silver halide emulsion comprised of silver halide grains which have a halide content of at least 50 mole percent bromide, wherein tabular grains of less than 0.15 micrometers in thickness and having an aspect ratio of greater than 8 account for greater than 50 percent of the total grain projected area, comprises the steps of nucleating the silver halide grains with a gelatino-peptizer or with the use of certain synthetic polymers that serve as effective nucleation peptizers and then growing the silver halide grains with the use of either a gelatino-peptizer or certain synthetic polymers that serve as effective growth peptizers.Type: GrantFiled: December 22, 1993Date of Patent: January 10, 1995Assignee: Eastman Kodak CompanyInventors: Michael R. Roberts, Wai K. Lam, Wayne A. Bowman, John E. Keevert, Jr., Byron H. Rubin
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Patent number: 5254441Abstract: This invention provides a photographic element containing a polymer layer which reflects a development inhibitor or its precursor released from a DIR compound thereby retarding the diffusion of the development inhibitor to another layer. The polymers used in the barrier layer contain from about 1.times.10.sup.-5 to about 4.times.10.sup.-3 ion forming functional groups. The preferred polymers comprise repeating units of the formula --(A).sub.m -(B).sub.n -- with A derived from a hydrophobic monomer and B derived from an ionic hydrophilic monomer with the more preferred monomers being acrylates, methacrylates, acrylamides and methacrylamides. The invention also provides a method of processing a photographic element containing such a barrier layer.Type: GrantFiled: October 1, 1991Date of Patent: October 19, 1993Assignee: Eastman Kodak CompanyInventors: Glenn T. Pearce, Elizabeth V. Patton, Michael R. Roberts, Ignazio S. Ponticello, George Villard, Susan C. Gross, deceased, Marjorie M. Datskow, executrix
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Patent number: 5219717Abstract: The invention is accomplished by providing an iodide ion absorbing method and article. The article is a composite article comprising a surfactant, an iodide absorbing medium, and a polymer that is permeable to iodide ion overlaying the iodide absorbing medium. In a preferred embodiment of the invention the polymer is an ionic polymer and the surfactant is an ionic surfactant with a charge opposite to that of the polymer. The surfactant can be incorporated in the absorbing medium, in the polymer, or it can overlay the polymer. In a preferred form of the invention, a substrate is coated with the iodide absorbing medium, a layer of an ionic polymer is overlaid on the absorbing medium, and a layer incorporating an ionic surfactant is overlaid onto the polymer. The ionic surfactant also may be placed in a layer between the polymer and the absorbing medium. A preferred absorbing medium is silver bromide.Type: GrantFiled: January 2, 1992Date of Patent: June 15, 1993Assignee: Eastman Kodak CompanyInventors: Eric R. Schmittou, Glenn T. Pearce, Michael R. Roberts, Jacob J. Hastreiter, Jr.
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Patent number: 5100970Abstract: Dye-containing polymers wherein the dyes are organic in nature are incorporated into glasses produced by a sol-gel technique. The glasses may be inorganic or organic-modified metal oxide heteropolycondensates. The dye-containing polymers are covalently bonded to the glass through a linking group. The products of this invention can be used to make optically clear colored films which can be employed in the imaging, optical, solar heat energy and related arts.Type: GrantFiled: December 4, 1990Date of Patent: March 31, 1992Assignee: Eastman Kodak CompanyInventors: Michael R. Roberts, Bradley K. Coltrain, Sharon M. Melpolder
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Patent number: 4950587Abstract: Dye polymers are disclosed that J-aggregate in solution and when adsorbed to silver halide. These polymers comprise polymer repeat units having covalently bonded thereto cyanine dye units comprising two benzimidazole nuclei, in an amount sufficient to J-aggregate.Type: GrantFiled: September 2, 1988Date of Patent: August 21, 1990Assignee: Eastman Kodak CompanyInventors: Michael R. Roberts, Derrick C. Tabor, Paul B. Gilman
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Patent number: 4948843Abstract: Dye-containing polymers wherein the dyes are organic in nature are incorporated into glasses produced by a sol-gel technique. The glasses may be inorganic or organic-modified metal oxide heteropolycondensates. The dye-containing polymers are covalently bonded to the glass through a linking group. The products of this invention can be used to make optically clear colored films which can be employed in the imaging, optical, solar heat energy and related arts.Type: GrantFiled: May 30, 1989Date of Patent: August 14, 1990Assignee: Eastman Kodak CompanyInventors: Michael R. Roberts, Bradley K. Coltrain, Sharon M. Melpolder