Abstract: A method for making an electronic assembly includes applying a protective layer including an organosulfur compound to at least a portion of a patterned conductive interconnect circuit, wherein the conductive interconnect circuit overlies at least a portion of a conductive layer on a substrate, and wherein the conductive layer includes nanowires; and engaging an electrical contact of an electronic component with the protective layer to electrically connect the electronic component and the patterned conductive layer.

Abstract: Methods and systems for flexographic printing are described and include curing of material to be printed while the material is in contact with both a feature of a flexographic printing plate and a recipient substrate. The systems and method are useful in preventing slippage between the feature and the recipient substrate, and are particularly useful when printing at high resolution.

Abstract: An electronic assembly includes a substrate having in a first zone a low contrast first conductive pattern; a high contrast fiducial mark in a second zone of the substrate different from the first zone, wherein the fiducial mark and the first conductive pattern are in registration; and a second conductive pattern aligned with the first conductive pattern.

Abstract: A method of achieving precision registration in a roll to roll process by simultaneously depositing multiple inks onto a printing roll. One of these inks prints a pattern of fiducial marks onto a substrate while another ink prints a predetermined pattern on the same substrate such that the predetermined pattern bears a predictable spatial relationship to the pattern of fiducial marks. Consequently, even if the ink forming the predetermined pattern is invisible, or has such low contrast with the substrate that it is effectively invisible, or even has been dissolved away in a subsequent processing step, it is still possible to know where the predetermined pattern is by referring to the pattern of fiducial marks.

Abstract: A method for making an electronic assembly includes applying a conductive adhesive to a resist layer overlying a patterned conductive nanowire layer on a substrate and engaging an electrical contact of an electronic component with the conductive adhesive to provide an electrical connection between the electronic component and the conductive nanowire layer.

Abstract: Methods and systems for flexographic printing are described and include curing of material to be printed while the material is in contact with both a feature of a flexographic printing plate and a recipient substrate. The systems and method are useful in preventing slippage between the feature and the recipient substrate, and are particularly useful when printing at high resolution.

Abstract: A method of achieving precision registration in a roll to roll process by simultaneously depositing multiple inks onto a printing roll. One of these inks prints a pattern of fiducial marks onto a substrate while another ink prints a predetermined pattern on the same substrate such that the predetermined pattern bears a predictable spatial relationship to the pattern of fiducial marks. Consequently, even if the ink forming the predetermined pattern is invisible, or has such low contrast with the substrate that it is effectively invisible, or even has been dissolved away in a subsequent processing step, it is still possible to know where the predetermined pattern is by referring to the pattern of fiducial marks.

Abstract: Retroreflective articles and constructions are disclosed. One exemplary retroreflective article or construction includes a retroreflective layer and a low refractive index layer. In one exemplary embodiment, the low refractive index layer is adjacent to at least a portion of a retroreflective structured major surface of the retroreflective layer.

Abstract: A method includes unwinding a web material from a support and providing an elastomeric stamp, wherein the stamp includes a base surface and an arrangement of pattern elements extending away from the base surface, and wherein each pattern element has a stamping surface with a lateral dimension of less than about 5 microns and a height with respect to the base surface, and wherein an aspect ratio of the height to the lateral dimension is at least 1.5. The stamping surfaces of the pattern elements are inked with an ink composition including a functionalizing molecule, wherein the functionalizing molecule includes a functional group selected to bind to said substrate material.

Abstract: A system, including a moving web of material unwound from a support and a stamp mounted on a roller, wherein the stamp includes a base surface and a continuous, regular array of pattern elements having a trapezoidal cross-sectional shape and extending above the base surface, and wherein the stamping elements each have a substantially planar stamping surface. An inking roller with an inking surface at least periodicially contacts the stamping surface of the stamping elements. The inking surface is impregnated with an ink composition including an organosulfur compound having a thiol functional group selected to bind to a major surface of the web material to form a self-assembled monolayer (SAM) thereon according to the array of pattern elements on the stamping surface.

Abstract: A method of achieving precision registration in a roll to roll process by simultaneously depositing multiple inks onto a printing roll. One of these inks prints a pattern of fiducial marks onto a substrate while another ink prints a predetermined pattern on the same substrate such that the predetermined pattern bears a predictable spatial relationship to the pattern of fiducial marks. Consequently, even if the ink forming the predetermined pattern is invisible, or has such low contrast with the substrate that it is effectively invisible, or even has been dissolved away in a subsequent processing step, it is still possible to know where the predetermined pattern is by referring to the pattern of fiducial marks.

Abstract: This application describes a front-lit reflective display assembly including a reflective display and an illumination article for front-lighting the display when the article is optically coupled to a light source. The illumination article includes a variable index light extraction layer optically coupled to a lightguide. The variable index light extraction layer has first and second regions, the first region comprising nanovoided polymeric material, the second region comprising the nanovoided polymeric material and an additional material, the first and second regions being disposed such that for light being transported at a supercritical angle in the lightguide, the variable index light extraction layer selectively extracts the light in a predetermined way based on the geometric arrangement of the first and second regions. Front-lit reflective display devices including the front-lit reflective display assembly optically coupled to a light source are also described.

Abstract: A method of patterning a conductive layer to form transparent electrical conductors that does not require etching is disclosed. The method includes peeling a strippable polymer layer from a substrate coated with the conductive layer to pattern the conductive layer. In some embodiments, a resist matrix material is patterned over the conductive layer to prevent removal of the conductive layer beneath the resist matrix material. In other embodiments, a liner having a pressure sensitive adhesive surface is brought into contact with the patterned strippable polymer material to remove both the patterned strippable polymer material and the conductive layer beneath it.

Abstract: Retroreflective articles and constructions are disclosed. One exemplary retroreflective article or construction includes a retroreflective layer and a low refractive index layer. In one exemplary embodiment, the low refractive index layer is adjacent to at least a portion of a retroreflective structured major surface of the retroreflective layer.

Abstract: Variable index light extraction layers that contain a first region with a first material and a second region including a second material are described, where the first region has a lower effective index of refraction than the second region. Optical films and stacks may use the variable index light extraction layers in front lit or back lit display devices and luminaires.

Abstract: Variable index light extraction layers (100) that contain a plurality of microreplicated posts (120) are described. The variable index light extraction layers contain a plurality of microreplicated posts (120), a first region including a first lower-index substance (130) and a second region including a second higher-index substance (140). Optical films can use the variable index light extraction layers (100) in front lit or back lit display devices.

Abstract: A method of forming an article is provided. The method can include providing a substrate comprising a surface. The method can further include forming a solvent soluble layer on or over the surface of the substrate in a pattern, the pattern defining one or more first portions of the surface that are overlaid by the solvent soluble layer, and one or more second portions of the surface that are free of the solvent soluble layer. The method can further include forming a second layer on or over at least one of the first portions and at least one of the second portions, wherein the step of forming the second layer includes buffing an exfoliatable material on or over at least one of the first portions and at least one of the second portions. The method can further include removing the solvent soluble layer by applying a solvent to the substrate.

Abstract: A method of microcontact printing comprises (a) providing an elastomeric stamp comprising a printing surface inked with an ink comprising surface-functionalizing molecules, (b) treating the inked printing surface of the stamp with solvent, and (c) contacting the treated inked printing surface of the stamp to a surface of a substrate. The printing surface of the stamp comprises a first relief pattern, or the surface of the substrate comprises a second relief pattern, or both of the surfaces comprise the relief patterns, and a pattern of surface-functionalizing molecules is transferred to the substrate according to one or both of the relief patterns.

Abstract: Methods of forming patterned coatings are disclosed. The methods include the steps of disposing a composition onto a substrate to form a liquid coating on the substrate and providing or removing energy through a first pattern of areas on the coated film to form a morphologically patterned coating, the morphological pattern corresponding to the first pattern of areas.

Abstract: The present disclosure relates to prismatic retroreflective articles that includes a security mark and to methods of making such articles.