Patents by Inventor Mikio Shiono

Mikio Shiono has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20030158295
    Abstract: In fluorinated curable compositions comprising alkenyl group-bearing perfluoropolyethers as the base polymer to ensure chemical resistance and solvent resistance together with an organohydrogensiloxane and a platinum group metal catalyst, a hydrophobized silica fine powder is used in combination therewith to render the compositions thixotropic.
    Type: Application
    Filed: December 19, 2002
    Publication date: August 21, 2003
    Inventors: Kenichi Fukuda, Mikio Shiono
  • Patent number: 6576737
    Abstract: A curable composition comprising (A) a fluorinated amide compound having at least one alkenyl radical, (B) a fluorinated organohydrogensiloxane, (C) a platinum group compound, (D) a first organosiloxane having at least one SiH radical and at least one epoxy and/or trialkoxysilyl radical, and (E) a second organosiloxane having at least one SiH radical, at least one cyclic carboxylic anhydride residue, and at least one monovalent perfluorooxyalkyl or perfluoroalkyl radical cures into a fluorinated elastomer that not only has good solvent resistance, chemical resistance, heat resistance, low-temperature properties, low moisture permeability and electrical properties, but also firmly bonds to a variety of substrates including PPS, polyamide and polyimide resins.
    Type: Grant
    Filed: October 4, 2001
    Date of Patent: June 10, 2003
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mikio Shiono, Takashi Matsuda, Masatoshi Arai
  • Patent number: 6517946
    Abstract: A curable composition comprising (A) a fluorinated amide compound, (B) a specific fluorinated organohydrogen-siloxane, (C) a platinum group compound, (D) an organosiloxane adhesion-imparting agent, (E) a silica powder having a BET specific surface area of at least 50 m2/g and (F) an organosilane or organosiloxane surface treatment agent for the silica powder provides a cured product endowed with excellent resistance to solvents, chemicals and heat, outstanding low-temperature properties, a low water-vapor permeability and outstanding electrical characteristics. When heated at a relatively low temperature for a relatively short period of time, the composition cures to a form having good adhesion and good durability of adhesion to base materials such as metals and plastics.
    Type: Grant
    Filed: February 7, 2001
    Date of Patent: February 11, 2003
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mikio Shiono, Takashi Matsuda
  • Patent number: 6500976
    Abstract: Organosilicon compounds each having in a molecule (A) a perfluoroalkyl group of at least 3 carbon atoms which may be separated by an etheric oxygen atom, (B) a monovalent hydrocarbon group containing a carboxylic acid anhydride structure, and (C) a hydrosilyl (SiH) group are novel and added to thermosetting elastomer compositions as adhesion aids whereby the compositions are improved in adhesion to various materials including metals, alloys, plastics, and ceramics.
    Type: Grant
    Filed: October 5, 2001
    Date of Patent: December 31, 2002
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Takashi Matsuda, Mikio Shiono, Kenichi Fukuda
  • Publication number: 20020193503
    Abstract: A fluoroelastomer composition is suited for FIPG comprising (A) a fluorinated amide compound having at least two alkenyl radicals, (B) a fluorinated organohydrogen-siloxane having at least two SiH radicals, (C) a platinum group catalyst, and (D) a hydrophobic silica powder. The composition cures into an elastomer or FIPG having good heat resistance, oil resistance, chemical resistance, solvent resistance, low-temperature properties, and moisture resistance, and especially superior oil resistance and chemical resistance, increasing the lifetime and reliability of seal performance.
    Type: Application
    Filed: May 1, 2002
    Publication date: December 19, 2002
    Inventors: Mikio Shiono, Makoto Saitoo
  • Publication number: 20020156198
    Abstract: A fluorinated curable composition in which a fluorinated organohydrogensiloxane as the curing agent is well compatible with a linear polyfluoro compound as the base yields a cured gel having good adhesion to substrates and improved chemical and solvent resistance.
    Type: Application
    Filed: February 20, 2002
    Publication date: October 24, 2002
    Inventors: Kenichi Fukuda, Mikio Shiono
  • Publication number: 20020132902
    Abstract: A curable composition comprising (A) a fluorinated amide compound having alkenyl radicals, (B) a fluorinated organohydrogensiloxane having SiH radicals, (C) a platinum group compound, (D) a silica powder, (E) an organosilane or organosiloxane having a monovalent perfluorooxyalkyl or perfluoroalkyl, divalent perfluorooxyalkylene or perfluoroalkylene radical and a hydroxy and/or alkoxy radical, and (F) an organosilane or organosiloxane having an alkenyl radical, a monovalent perfluorooxyalkyl or perfluoroalkyl, divalent perfluorooxyalkylene or perfluoroalkylene radical, and a hydroxy and/or alkoxy radical cures into a fluorinated elastomer that has good solvent resistance, chemical resistance, heat resistance, low-temperature properties, mold release, water and oil repellency and weather resistance as well as significantly improved mechanical strength and compression set.
    Type: Application
    Filed: January 16, 2002
    Publication date: September 19, 2002
    Inventor: Mikio Shiono
  • Patent number: 6425294
    Abstract: A pressure sensor unit which comprises (i) a housing, (ii) pressure sensor members installed therein including a mount, the bottom of which is fixed to the inner base of the housing by means of an adhesive, a sensor chip firmly bonded to the top of the mount, terminals disposed on the inner base of the housing and bonding wires connecting the sensor chip to their respective terminals, and (iii) a sealant filling the housing so that all the pressure sensor members are completely buried therein; with the terminals being covered with a fluorinated polymer-containing composition functioning as adhesive in at least an upper part thereof and with the sealant being a fluorinated polymer-containing gel material, wherein the composition as adhesive is similar in fluorinated polymer to the gel material.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: July 30, 2002
    Assignee: Shin-Etsu Chemical Co., Ltd
    Inventors: Mikio Shiono, Kenichi Fukuda
  • Patent number: 6417311
    Abstract: A curable composition contains (A) a fluorinated amide compound having at least one alkenyl radical, (B) a fluorinated organohydrogensiloxane, (C) a platinum group compound, (D) an organosiloxane having at least one hydrogen atom directly attached to a silicon atom, and at least one epoxy and/or trialkoxysilyl radical attached to a silicon atom through a carbon atom or a carbon atom and an oxygen atom, and (E) a carboxylic anhydride. The composition firmly bonds to a variety of substrates such as PPS and nylon while curing into a fluorinated elastomer.
    Type: Grant
    Filed: September 1, 2000
    Date of Patent: July 9, 2002
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kenichi Fukuda, Mikio Shiono
  • Publication number: 20020087019
    Abstract: Organosilicon compounds each having in a molecule (A) a perfluoroalkyl group of at least 3 carbon atoms which may be separated by an etheric oxygen atom, (B) a monovalent hydrocarbon group containing a carboxylic acid anhydride structure, and (C) a hydrosilyl (SiH) group are novel and added to thermosetting elastomer compositions as adhesion aids whereby the compositions are improved in adhesion to various materials including metals, alloys, plastics, and ceramics.
    Type: Application
    Filed: October 5, 2001
    Publication date: July 4, 2002
    Inventors: Takashi Matsuda, Mikio Shiono, Kenichi Fukuda
  • Publication number: 20020061969
    Abstract: A curable composition comprising (A) a fluorinated amide compound having at least one alkenyl radical, (B) a fluorinated organohydrogensiloxane, (C) a platinum group compound, (D) a first organosiloxane having at least one SiH radical and at least one epoxy and/or trialkoxysilyl radical, and (E) a second organosiloxane having at least one SiH radical, at least one cyclic carboxylic anhydride residue, and at least one monovalent perfluorooxyalkyl or perfluoroalkyl radical cures into a fluorinated elastomer that not only has good solvent resistance, chemical resistance, heat resistance, low-temperature properties, low moisture permeability and electrical properties, but also firmly bonds to a variety of substrates including PPS, polyamide and polyimide resins.
    Type: Application
    Filed: October 4, 2001
    Publication date: May 23, 2002
    Inventors: Mikio Shiono, Takashi Matsuda, Masatoshi Arai
  • Patent number: 6306999
    Abstract: A room temperature curable organopolysiloxane composition comprising (A) a diorganopolysiloxane both-side terminated with hydroxyl groups, represented by the general formula: HO(R12SiO)nH (wherein R1 represents a monovalent substituted or unsubstituted hydrocarbon group, and n represents an integer of 150 or more), (B) an organohydrogenpolysiloxane having in one molecule at least three hydrogen atoms bonded to silicon atoms, (C) a compound selected from the group consisting of an organosilane having in one molecule at least two alkoxyl groups bonded to silicon atoms and containing at least one primary amino group bonded to a silicon atom through an alkylene group and a partial hydrolysis-condensation product thereof, (D) a metal fatty acid salt, and (E) an organic compound having at least one C═O group in one molecule, capable of reacting the primary amino group of the component-(C) to form water.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: October 23, 2001
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Toshiyuki Ozai, Mikio Shiono
  • Publication number: 20010018491
    Abstract: A curable composition comprising (A) a fluorinated amide compound, (B) a specific fluorinated organohydrogen-siloxane, (C) a platinum group compound, (D) an organosiloxane adhesion-imparting agent, (E) a silica powder having a BET specific surface area of at least 50 m2/g and (F) an organosilane or organosiloxane surface treatment agent for the silica powder provides a cured product endowed with excellent resistance to solvents, chemicals and heat, outstanding low-temperature properties, a low water-vapor permeability and outstanding electrical characteristics. When heated at a relatively low temperature for a relatively short period of time, the composition cures to a form having good adhesion and good durability of adhesion to base materials such as metals and plastics.
    Type: Application
    Filed: February 7, 2001
    Publication date: August 30, 2001
    Inventors: Mikio Shiono, Takashi Matsuda
  • Patent number: 5854344
    Abstract: There is provided an organopolysiloxane composition for electrical insulation wherein the fluidity is good and an inorganic filler deposited on the bottom of a vessel during the storage can be easily and simply redispersed. The unfoamable organopolysiloxane composition for electrical insulation comprises (A) an organopolysiloxane containing at least two alkenyl groups each bonded to a silicon atom in the molecule, (B) an organohydrogenpolysiloxane containing at least two hydrogen atoms each bonded to a silicon atom in the molecule, (C) an organopolysiloxane containing at least one hydroxyl group bonded to a silicon atom in the molecule, (D) an inorganic filler having an average particle diameter of 1 to 50 .mu.m, and (E) platinum or a platinum compound.
    Type: Grant
    Filed: August 30, 1996
    Date of Patent: December 29, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mikio Shiono, Mitsuaki Igarashi, Hironao Fujiki
  • Patent number: 5661198
    Abstract: The invention relates to an ablator composition for providing ablation protection. The ablator composition comprises 100 parts by weight of a mixture of vinyl-containing organopolysiloxanes, the mixture containing 50-80 wt. % of a diorganopolysiloxane which contains vinyl groups and 20-50 wt. % of a silicone resin which contains vinyl groups; an organohydrogenpolysiloxane containing in one molecule thereof at least three hydrogen atoms which are directly bonded to silicon atoms thereof; a catalyst which is at least one selected from the group consisting of metallic platinum and platinum compounds; up to 150 parts by weight of silica microballoons; and at least one selected from the group consisting of up to 15 parts by weight of quartz glass fibers and up to 15 parts by weight of carbon fibers. An ablator material prepared by curing the ablator composition has a low surface recession rate even under a condition of a high heating rate such as about 4 MW/m.sup.
    Type: Grant
    Filed: September 27, 1994
    Date of Patent: August 26, 1997
    Assignees: Nissan Motor Co., Ltd., Yoshifumi Inatani, Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshifumi Inatani, Kazunori Kawasaki, Tadashi Harada, Hironao Fujiki, Mikio Shiono
  • Patent number: 5525660
    Abstract: An organopolysiloxane composition contains (A) a both end hydroxyl-blocked diorganopolysiloxane, (B) an inert diorganopolysiloxane, (C) a silane or siloxane having at least three hydrolyzable functional groups, (D) an organosilane having at least two alkoxy groups each attached to a silicon atom and one mercapto group separated from a silicon atom by an alkylene group or a partial hydrolyzate thereof, (E) an organosilane having at least two alkoxy groups each attached to a silicon atom and one amino group separated from a silicon atom by an alkylene group or a partial hydrolyzate thereof, (F) a condensation catalyst, and (G) a fine powder, typically of polycarbonate, having a mean particle size of 0.1-50 .mu.m. The composition is useful as a surface treating agent for cured rubber moldings for imparting non-tackiness, water repellency and lubricity to the rubber surface and forming a long-lasting abrasion resistant coating.
    Type: Grant
    Filed: December 6, 1994
    Date of Patent: June 11, 1996
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mikio Shiono, Kazumi Okada
  • Patent number: 5506302
    Abstract: An organopolysiloxane composition contains (A) a both end hydroxyl-blocked diorganopoly-siloxane, (B) a hydroxyl-free diorganopoly-siloxane having a degree of polymerization equal to or greater than that of (A), (C) an organo-hydrogenpolysiloxane having at least three hydrogen atoms in a molecule, (D) an organosilane containing at least two alkoxy groups and an amino group attached to a silicon atom through an alkylene group in a molecule and/or a partial hydrolyzate thereof, (E) a fatty acid metal salt, (F) polycarbonate powder having a mean particle size of up to 50 .mu.m, and optionally (G) an organo-silane containing at least two alkoxy groups and a mercapto group attached to a silicon atom through an alkylene group in a molecule and/or a partial hydrolyzate thereof. It is applied to a rubber substrate to form a wear resistance coating thereon.
    Type: Grant
    Filed: June 21, 1995
    Date of Patent: April 9, 1996
    Assignee: Shin-Etsu Chemical Co., Inc.
    Inventors: Mikio Shiono, Kazumi Okada, Hironao Fujiki
  • Patent number: 5438094
    Abstract: An adhesive silicone composition comprising (A) an alkenyl group-containing organopolysiloxane, (B) an organohydrogen-polysiloxane having at least three hydrogen atoms each directly bonded to a silicon atom in a molecule, (C) a compound having at least one aliphatic unsaturated group and at least two phenyl skeletons in a molecule, and (D) a platinum catalyst is well adhesive to both metals and reins, and even to difficult-to-adhere resins such as nylon, polycarbonate and acryl resins.
    Type: Grant
    Filed: July 1, 1994
    Date of Patent: August 1, 1995
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hironao Fujiki, Hiroyasu Hara, Mikio Shiono, Masayuki Ikeno
  • Patent number: 5120810
    Abstract: This invention discloses an adhesive organopolysiloxane compositions which cure in the presence of addition reaction catalysts and adhere firmly to various materials when they harden comprising;(1) 100 parts by weight of an organopolysiloxane containing at least alkenyl groups bonded to silicon atoms in 1 molecule,(2) an organohydrogenpolysiloxane containing at least 3 hydrogen atoms bonded to silicon atoms in 1 molecule, in sufficient quantity to donate 0.5-10 hydrogen atoms bonded to silicon atoms to 1 alkenyl group in said 1st constituent,(3) 0.1-20 parts by weight of an organosilicone compound containing at least 1 hydrogen atom bonded to silicon atoms, at least 1 fluoroalkyl group or fluoroalkylether group bonded to silicon atoms via carbon atoms and at least 1 epoxy group and/or trialkoxysilyl group bonded to silicon atoms via carbon atoms in 1 molecule, and(4) platinum or a platinum compound in suitable quantity to act as a catalyst.
    Type: Grant
    Filed: May 11, 1990
    Date of Patent: June 9, 1992
    Assignee: Shin-Etsu Chemical Company, Limited
    Inventors: Hironao Fujiki, Mikio Shiono, Toshiaki Takahashi
  • Patent number: 5064891
    Abstract: A curable silicone composition comprising:(A) an organopolysiloxane having at least two silicon-bonded aliphatic unsaturated hydrocarbon radicals in its molecule;(B) an organohydrogenpolysiloxane having at least three silicon-bonded hydrogen atoms in its molecule;(C) a platinum family metal catalyst; and(D) a nonionic surface active agent having a hydrophobic silicone portion and at least one hydrophilic polyol portion in its molecule. The curable silicone composition gives cured products having good hydrophilic properties and dimensional stability, and are especially suitable for use as a dental impression material.
    Type: Grant
    Filed: May 18, 1990
    Date of Patent: November 12, 1991
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hironao Fujiki, Mikio Shiono, Toshiaki Takahashi