Patents by Inventor Naohiro Watanabe

Naohiro Watanabe has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8431304
    Abstract: A toner containing: a non-crystalline polyester resin; a crystalline polyester resin; a releasing agent; a graft-modified polymer; and a colorant, wherein the graft-modified polymer is a polymer having a glass transition temperature of higher than 40° C. but lower than 80° C., and obtained by grafting an acrylic resin onto at least one of a hydrocarbon wax and a crystalline polyester resin, and wherein a SP value of the non-crystalline polyester resin is defined as SP1, a SP value of the crystalline polyester resin is defined as SP2, a SP value of the releasing agent is defined as SP3, and a SP value of the graft-modified polymer is defined as SP4, and SP1, SP2, SP3 and SP4 satisfy relations represented by Formulas (1) to (3): SP1 > SP4 > SP2 >SP3 Formula (1), 0.1 < SP1 ? SP4 < 1.0 Formula (2), and 0.1 < SP4 ? SP2 < 1.0 Formula (3).
    Type: Grant
    Filed: August 16, 2011
    Date of Patent: April 30, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Tsuyoshi Sugimoto, Naohiro Watanabe, Osamu Uchinokura, Tomoyuki Satoh, Shinya Hanatani, Mamoru Hozumi
  • Publication number: 20120295193
    Abstract: To provide a toner, which contains a binder resin containing a crystalline resin and a non-crystalline resin, a colorant, and a releasing agent, wherein the toner has ½ flow onset temperature T½ of 120° C. to 135° C., and wherein a peak intensity ratio of an intensity of a peak derived from the crystalline resin and the releasing agent to an intensity of a peak derived from the binder resin as measured in FTIR-ATR is 0.10 to 0.20.
    Type: Application
    Filed: April 16, 2012
    Publication date: November 22, 2012
    Inventors: Shinya HANATANI, Naohiro WATANABE, Tsuyoshi SUGIMOTO, Tomoyuki SATOH, Mamoru HOZUMI
  • Patent number: 8293442
    Abstract: Disclosed is a resin particle having a volume average particle diameter of 10 nm to 500 nm, obtained by polymerizing an addition polymerizable monomer containing a silsesquioxane (a) represented by Formula (I) or by copolymerizing the silsesquioxane (a) with an addition polymerizable monomer (b), where R1 to R7 each independently represent a group selected from the group consisting of hydrogen, alkyl having 1 to 40 carbon atoms, substituted or unsubstituted aryl, and substituted or unsubstituted arylalkyl; any hydrogen in the alkyl group is optionally substituted by fluorine and any —CH2— is optionally substituted by —O—, —CH?CH—, cycloalkylene or cycloalkenylene; any hydrogen in alkylene in the arylalkyl group is optionally substituted by fluorine and any —CH2— is optionally substituted by —O— or —CH?CH—; and A1 represents an addition polymerizable functional group.
    Type: Grant
    Filed: September 22, 2009
    Date of Patent: October 23, 2012
    Assignees: Ricoh Company, Ltd., JNC Corporation
    Inventors: Masaki Watanabe, Naohito Shimota, Hiroshi Yamashita, Naohiro Watanabe, Tsuneyasu Nagatomo, Tsuyoshi Sugimoto, Shinichi Wakamatsu, Kenya Itoh, Mikio Yamahiro
  • Publication number: 20120264043
    Abstract: An electrostatic image developing toner including: a binder resin; a colorant; and a wax, wherein the intensity ratio of an absorbance at 2,850 cm?1 derived from the wax to an absorbance at 828 cm?1 derived from the binder resin, represented by “absorbance derived from the wax/absorbance derived from the binder resin”, is in the range of 0.1 to 0.5, where the absorbances are measured by FTIR-ATR, and the intensity ratio serves as a value for determining the amount of the wax present within 0.3 ?m in depth from surfaces of particles of the toner after the toner has been heated to 140° C. and then cooled, and wherein the toner has a storage elastic modulus of 5,000 Pa or greater at 140° C.
    Type: Application
    Filed: December 1, 2010
    Publication date: October 18, 2012
    Inventors: Naohiro Watanabe, Naohito Shimota, Yasuaki Iwamoto, Masana Shiba, Satoshi Kojima
  • Publication number: 20120122027
    Abstract: To provide a toner, containing: a binder resin; a crystalline polyester resin; a colorant; and wax, wherein the toner has a fluidized powder characteristic value of 35% to 45%, and a BET specific surface area of 2.8 m2/g to 4 m2/g, and wherein the toner has an intensity ratio P2850/P828 of 0.10 to 0.20, where P2850 is an intensity of a peak at 2850 cm?1 which is attributed from the wax and the crystalline polyester resin, and P828 is an intensity of a peak at 828 cm?1 which is attributed from the binder resin, as measured by total reflectance infrared spectroscopy.
    Type: Application
    Filed: November 2, 2011
    Publication date: May 17, 2012
    Inventors: Naohiro WATANABE, Tsuyoshi Sugimoto, Shlnya Hanatanl, Mamru Hozumi, Osamu Uchinokura
  • Patent number: 8178268
    Abstract: A magenta toner, produced by a method including suspending an oily liquid comprising a binder resin and a colorant in an aqueous medium, wherein the colorant comprises a naphthol pigment and a quinacridone pigment, and the quinacridone pigment comprises a pigment having a specific formula.
    Type: Grant
    Filed: September 28, 2009
    Date of Patent: May 15, 2012
    Assignee: Ricoh Company, Limited
    Inventors: Naohiro Watanabe, Shinichi Wakamatsu, Naohito Shimota, Hiroshi Yamashita, Tsuyoshi Sugimoto, Masaki Watanabe, Tsuneyasu Nagatomo
  • Patent number: 8163455
    Abstract: Provided is a toner for image formation, granulated by dispersing, emulsifying, or both dispersing and emulsifying an oil phase containing toner constituting materials in an aqueous medium. The toner constituting materials contain a binder resin, a colorant and a pigment dispersant which is a polyester derivative having an acid value of 28 to 50 mgKOH/g and an amine value of 1 to 50 mgKOH/g, and satisfy the following Expressions 1 and 2, where Expression 1 represents a mass ratio, ? is a glass transition temperature of the binder resin, and ? is a glass transition temperature of a mixture of the binder resin and the pigment dispersant in the ratio of Expression 1. Binder resin:Pigment dispersant=100:5??Expression 1 0° C.?????10° C.
    Type: Grant
    Filed: March 13, 2009
    Date of Patent: April 24, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Naohiro Watanabe, Hiroshi Yamashita, Shinichi Wakamatsu, Tsuyoshi Sugimoto
  • Patent number: 8137883
    Abstract: A toner is provided including a binder resin and a wax having primarily C—H and C—C bonds, and having a melting point of 50 to 90° C., wherein the wax is present in a surface portion of the toner in an amount of from 0.1 to 4.0% by weight, wherein the amount of the wax is determined by Fourier transform infrared spectroscopy attenuated total reflectance (FTIR-ATR); and the use of the toner in an image forming method, image forming apparatus, developer and toner cartridge containing the toner.
    Type: Grant
    Filed: May 20, 2011
    Date of Patent: March 20, 2012
    Assignee: Ricoh Company Limited
    Inventors: Ryota Inoue, Shigeru Emoto, Naohiro Watanabe, Masahide Yamada, Akinori Saitoh, Masahiro Ohki, Tsunemi Sugiyama, Shinichi Wakamatsu, Takayuki Yoshii, Eiji Sawamura
  • Publication number: 20120064447
    Abstract: A toner containing toner particles, each toner particle containing: a releasing agent; a colorant; and a binder resin containing at least a crystalline polyester resin and a non-crystalline polyester resin, wherein in the case where a volume average particle diameter of the toner is defined as Dv, the toner contains a group of the toner particles having 4/5Dv, and a group of the toner particles having 6/5Dv, and wherein an endothermic value A of the crystalline polyester resin at a first temperature increase in DSC of the toner, an endothermic value B of the crystalline polyester resin at a first temperature increase in DSC of the group of the toner particle having 4/5Dv, and an endothermic value C of the crystalline polyester resin at a first temperature increase in DSC of the group of the toner particles having 6/5Dv satisfy the relation represented by the following formulas: 50<(B/A)×100<90, and 110<(C/A)×100<150.
    Type: Application
    Filed: September 14, 2011
    Publication date: March 15, 2012
    Inventors: Mamoru Hozumi, Tsuyoshi Sugimoto, Naohiro Watanabe, Tomoyuki Satoh, Shinya Hanatani, Osamu Uchinokura, Kiwako Hirohara
  • Publication number: 20120052431
    Abstract: To provide a toner, containing: a crystalline polyester resin; and a non-crystalline polyester resin, wherein the crystalline polyester resin has a melting point of 60° C. to 80° C., and wherein the toner satisfies the relationship represented by the following formula: (W1?W1?)/W1<0.50, where W1 is a temperature width at a 1/3 height of a height of an endothermic peak of the crystalline polyester resin at the time of an initial temperature elevation on a DSC curve of the toner as measured by differential scanning calorimetry, and W1? is a temperature width at a 1/3 height of a height of an endothermic peak of the crystalline polyester resin after the toner has been heated at 50° C. for 24 hours.
    Type: Application
    Filed: August 12, 2011
    Publication date: March 1, 2012
    Inventors: Mamoru HOZUMI, Tsuyoshi Sugimoto, Naohiro Watanabe, Tomoyuki Satoh, Shinya Hanatani, Osamu Uchinokura
  • Publication number: 20120052434
    Abstract: A toner containing: a non-crystalline polyester resin; a crystalline polyester resin; a releasing agent; a graft-modified polymer; and a colorant, wherein the graft-modified polymer is a polymer having a glass transition temperature of higher than 40° C. but lower than 80° C., and obtained by grafting an acrylic resin onto at least one of a hydrocarbon wax and a crystalline polyester resin, and wherein a SP value of the non-crystalline polyester resin is defined as SP1, a SP value of the crystalline polyester resin is defined as SP2, a SP value of the releasing agent is defined as SP3, and a SP value of the graft-modified polymer is defined as SP4, and SP1, SP2, SP3 and SP4 satisfy relations represented by Formulas (1) to (3): SP1>SP4>SP2>SP3??Formula (1), 0.1<SP1?SP4<1.0??Formula (2), and 0.1<SP4?SP2<1.0??Formula (3).
    Type: Application
    Filed: August 16, 2011
    Publication date: March 1, 2012
    Inventors: Tsuyoshi SUGIMOTO, Naohiro Watanabe, Osamu Uchinokura, Tomoyuki Satoh, Shinya Hanatani, Mamoru Hozumi
  • Patent number: 8124308
    Abstract: Toner and a developer which are excellent in cleaning property and fixing property at low temperature, and capable of forming images with high quality are provided, along with a method for their production. A toner producing method involves dispersing and/or emulsifying an oil phase or a monomer phase containing a toner composition and/or a toner composition precursor in a water-based medium to granulate, wherein the toner has an average circularity of 0.925 to 0.970, and the toner composition and/or the toner composition precursor has a layered inorganic material in which at least a part of interlayer ions in the layered inorganic material has been exchanged with organic ions.
    Type: Grant
    Filed: December 13, 2010
    Date of Patent: February 28, 2012
    Assignee: Ricoh Company. Ltd.
    Inventors: Naohiro Watanabe, Shigeru Emoto, Yohichiroh Watanabe, Masahide Yamada, Tsunemi Sugiyama, Masahiro Ohki, Akinori Saitoh, Ryota Inoue, Osamu Uchinokura, Junichi Awamura
  • Patent number: 8076051
    Abstract: A method for preparing a particulate image forming material such as toner, which includes providing a particulate material including a chain transfer agent; and contacting the particulate material with at least one of a supercritical fluid and a sub-critical fluid under pressure to remove the chain transfer agent from the particulate material. A toner prepared by the method. A toner container containing the toner. A developer including the toner. An image forming method including preparing an electrostatic latent image and developing the latent image with the developer. An image forming apparatus including an image bearing member configured to bear an electrostatic latent image, a developing device configured to develop the electrostatic latent image with the developer to form a toner image on the surface of the image bearing member, a transfer device, a fixing device, and a cleaner configured to clean the image bearing member.
    Type: Grant
    Filed: June 14, 2005
    Date of Patent: December 13, 2011
    Assignee: Ricoh Company Limited
    Inventors: Takuya Saito, Chiaki Tanaka, Masayuki Ishii, Naohiro Watanabe, Kei Naitoh
  • Patent number: 8043778
    Abstract: A toner including toner particles including a binder resin, and a modified layered inorganic material in which at least part of interlayer ions is replaced with an organic ion, and a fatty acid metal compound located on a surface of the toner particles; and an external additive located on the fatty acid metal compound, wherein the external additive is a material different from the fatty acid metal compound. An image forming apparatus including an image bearing member; a developing device configured to develop the electrostatic latent image with a developer including the toner; a transfer device; and a fixing device. A method for preparing the toner including dispersing or emulsifying a toner composition including a modified layered inorganic material to prepare toner particles; mixing a fatty acid metal compound with the toner particles; and second mixing the toner particles with an external additive.
    Type: Grant
    Filed: September 10, 2007
    Date of Patent: October 25, 2011
    Assignee: Ricoh Company Limited
    Inventors: Tsuneyasu Nagatomo, Naohiro Watanabe, Osamu Uchinokura, Satoshi Kojima
  • Publication number: 20110255899
    Abstract: A toner, including a binder; a colorant; and a wax including a molecular chain constituted of only a C—H bond and a C—C bond, and having a melting point of from 50 to 78° C. and a melt viscosity of from 5 to 15 mPa·S at 140° C., wherein the toner has a weight reduction rate of from 0.001 to 0.1% by weight/min when measured by TGA (Thermogarvimetric Analysis) method in an atmosphere at 165° C. for 10 min.
    Type: Application
    Filed: April 13, 2011
    Publication date: October 20, 2011
    Applicant: RICOH COMPANY, LTD.
    Inventors: Yasuaki Iwamoto, Naohito Shimota, Naohiro Watanabe, Satoshi Kojima, Masana Shiba
  • Patent number: 8034524
    Abstract: A toner satisfying at least one of the following relationships: 10° C.<(T1?T2)<60° C. and 0<Q2/Q1<? wherein T1 represents a glass transition temperature of the toner and Q1 represents an endothermic quantity at a melting point thereof before melting when heated from ?20° C. to 150° C. at a heating speed of 10° C./min, and T2 represents a glass transition temperature thereof and Q2 represents a an endothermic quantity at a melting point thereof after melting after heated from ?20° C. to 150° C. at a heating speed of 10° C./min, cooled to ?20° C. at a cooling speed of 10° C./min and heated again at a heating speed of 10° C./min.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: October 11, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Ryota Inoue, Sonoh Matsuoka, Chiaki Tanaka, Naohiro Watanabe, Masahide Yamada, Masahiro Ohki, Akinori Saitoh
  • Patent number: 8029960
    Abstract: A toner, including a parent particulate material including a colorant and a binder resin, and an external additive including particles having an average primary particle diameter from 80 to less than 150 nm in an amount of from 0.03 to 2% by number, particles having an average primary particle diameter from 5 nm to less than 15 nm in an amount of from 50 to 95% by number, and particles having an average primary particle diameter from 15 to less than 40 nm in an amount of from 5 to 40% by number, and the particles having an average primary particle diameter from 80 to less than 150 nm include particles having an average primary particle diameter not less than 200 nm in an amount of from 10 to 30% by number, and have a weight reduction rate not greater than 3.00% when heated from 30 to 250° C.
    Type: Grant
    Filed: March 11, 2008
    Date of Patent: October 4, 2011
    Assignee: Ricoh Company Limited
    Inventors: Tsuneyasu Nagatomo, Naohiro Watanabe, Osamu Uchinokura, Satoshi Kojima
  • Patent number: 8026031
    Abstract: Toner and a developer which are excellent in cleaning property and fixing property at low temperature, and capable of forming images with high quality are provided. A toner prepared by dispersing and/or emulsifying an oil phase or a monomer phase comprising a toner composition and/or a toner composition precursor in a water-based medium to granulate, wherein the toner has an average circularity of 0.925 to 0.970, and the toner composition and/or the toner composition precursor has a layered inorganic material in which at least a part of interlayer ions in the layered inorganic material has been exchanged with organic ions.
    Type: Grant
    Filed: March 5, 2007
    Date of Patent: September 27, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Naohiro Watanabe, Shigeru Emoto, Yohichiroh Watanabe, Masahide Yamada, Tsunemi Sugiyama, Masahiro Ohki, Akinori Saitoh, Ryota Inoue, Osamu Uchinokura, Junichi Awamura
  • Publication number: 20110223530
    Abstract: A toner is provided including a binder resin and a wax having primarily C—H and C—C bonds, and having a melting point of 50 to 90° C., wherein the wax is present in a surface portion of the toner in an amount of from 0.1 to 4.0% by weight, wherein the amount of the wax is determined by Fourier transform infrared spectroscopy attenuated total reflectance (FTIR-ATR); and the use of the toner in an image forming method, image forming apparatus, developer and toner cartridge containing the toner.
    Type: Application
    Filed: May 20, 2011
    Publication date: September 15, 2011
    Inventors: Ryota Inoue, Shigeru Emoto, Naohiro Watanabe, Masahide Yamada, Akinori Saitoh, Masahiro Ohki, Tsunemi Sugiyama, Shinichi Wakamatsu, Takayuki Yoshii, Eiji Sawamura
  • Patent number: 8007977
    Abstract: A toner satisfying at least one of the following relationships: 10° C.<(T1?T2)<60° C. and 0<Q2/Q1<2/3 wherein T1 represents a glass transition temperature of the toner and Q1 represents an endothermic quantity at a melting point thereof before melting when heated from ?20° C. to 150° C. at a heating speed of 10° C./min, and T2 represents a glass transition temperature thereof and Q2 represents a an endothermic quantity at a melting point thereof after melting after heated from ?20° C. to 150° C. at a heating speed of 10° C./min, cooled to ?20° C. at a cooling speed of 10° C./min and heated again at a heating speed of 10° C./min.
    Type: Grant
    Filed: September 14, 2005
    Date of Patent: August 30, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Ryota Inoue, Sonoh Matsuoka, Chiaki Tanaka, Naohiro Watanabe, Masahide Yamada, Masahiro Ohki, Akinori Saitoh