Patents by Inventor Naohiro Watanabe

Naohiro Watanabe has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7396627
    Abstract: A method including contacting a toner including: a binder resin including an unsaturated carboxylic acid derivative monomer; a vinyl polymerizing monomer; and a colorant; to a supercritical fluid or a sub-critical fluid to remove the unsaturated carboxylic acid derivative monomer.
    Type: Grant
    Filed: June 10, 2005
    Date of Patent: July 8, 2008
    Assignee: Ricoh Company, Ltd.
    Inventors: Naohiro Watanabe, Chiaki Tanaka, Masayuki Ishii, Kei Naitoh, Takuya Saito
  • Patent number: 7396630
    Abstract: A toner composition including toner particles including a binder resin including a modified polyester resin, and a second resin having a weight average molecular weight of from 2,000 to 10,000; a colorant; a release agent; and a particulate material which is present at least a surface portion of the toner particles while embedded into the surface portion, wherein the binder resin has a glass transition temperature not lower than 35° C. and lower than 55° C., and wherein the particulate material has an average particle diameter of from 0.002 to 0.2 times that of the toner particles. A developer including the toner composition and a carrier having a layer thereon which includes at least an acrylic resin and a silicone resin, and a method for fixing an image of the toner composition are also provided.
    Type: Grant
    Filed: October 11, 2006
    Date of Patent: July 8, 2008
    Assignee: Ricoh Company Limited
    Inventors: Yohichiroh Watanabe, Masanori Suzuki, Tsunemi Sugiyama, Hiroshi Yamashita, Takuya Saito, Naohiro Watanabe, Masami Tomita, Shigeru Emoto, Shinichiro Yagi, Hiroshi Yamada, Toshiki Nanya, Tadao Takigawa
  • Patent number: 7374848
    Abstract: A toner including a binder; a colorant; and a wax, wherein the binder includes a polyester resin; and a reaction product of a polymer having a group capable of reacting with an active hydrogen with a compound having an active hydrogen, wherein the polyester resin includes tetrahydrofuran(THF)-soluble resin components in an amount of from 50 to 85% by weight; and chloroform-insoluble components in an amount of from 0 to 30% by weight, and wherein the toner satisfies the following relationship (1): 5% by weight<(C1-C2)<60% by weight ??(1) wherein C1 represents a content of chloroform-insoluble components in the toner in units of % by weight and C2 represents a content of the colorant therein in units of % by weight.
    Type: Grant
    Filed: June 22, 2004
    Date of Patent: May 20, 2008
    Assignee: Ricoh Company, Limited
    Inventors: Sonoh Matsuoka, Ryohta Inoue, Masahiro Ohki, Takeshi Takada, Chiaki Tanaka, Naohiro Watanabe, Masahide Yamada
  • Publication number: 20080090165
    Abstract: To provide a toner containing an ethyl acetate-soluble polyester component and an ethyl acetate-insoluble polyester component, wherein the toner is granulated in an aqueous medium, the ethyl acetate-insoluble polyester component is obtained by elongating and/or cross-linking a modified polyester resin during granulating and/or after granulating, the modified polyester resin is produced by condensation polymerization of an acid component and at least one type of diol compound selected from aliphatic diol and alicyclic diol in the presence of a catalyst, and the mass average molecular weight of the modified polyester resin is 10,000 to 100,000.
    Type: Application
    Filed: November 12, 2007
    Publication date: April 17, 2008
    Inventors: Masahide YAMADA, Ryota Inoue, Naohiro Watanabe, Shigeru Emoto, Masahiro Ohki, Akinori Saitoh, Tsunemi Sugiyama, Shinichi Wakamatsu, Toshiki Nanya, Naohito Shimota, Hiroshi Yamada, Junichi Awamura, Tomomi Suzuki, Kazuyuki Hirai, Kazushige Yasumatsu
  • Patent number: 7348121
    Abstract: A toner including toner particles comprising a binder resin; and at least two kinds of particulate resins which are located on at least a surface of the toner particles, wherein the toner satisfies at least one of the following relationships (TgA?TgB)?20° C., wherein TgA and TgB represent glass transition temperatures (Tg) of a particulate resin (A) having a highest Tg and a particulate resin (B) having a lowest Tg among the at least two kinds of particulate resins, respectively; and 100,000?Mwc?6,000,000 and 8,000?Mwd?800,000, wherein Mwc and Mwd represent weight average molecular weights (Mw) of a particulate resin (C) having a highest Mw and a particulate resin (D) having a lowest Mw among the at least two kinds of particulate resins, respectively, wherein Mwc>Mwd.
    Type: Grant
    Filed: February 2, 2007
    Date of Patent: March 25, 2008
    Assignee: Ricoh Company Limited
    Inventors: Ryohta Inoue, Naohiro Watanabe, Masahide Yamada, Sonoh Matsuoka, Chiaki Tanaka, Takeshi Takada, Masahiro Ohki, Akinori Saitoh
  • Patent number: 7348117
    Abstract: A toner including toner particles comprising a binder resin; and at least two kinds of particulate resins which are located on at least a surface of the toner particles, wherein the toner satisfies at least one of the following relationships (TgA-TgB)?20° C., wherein TgA and TgB represent glass transition temperatures (Tg) of a particulate resin (A) having a highest Tg and a particulate resin (B) having a lowest Tg among the at least two kinds of particulate resins, respectively; and 100,000?Mwc?6,000,000 and 8,000?Mwd?800,000, wherein Mwc and Mwd represent weight average molecular weights (Mw) of a particulate resin (C) having a highest Mw and a particulate resin (D) having a lowest Mw among the at least two kinds of particulate resins, respectively, wherein Mwc>Mwd.
    Type: Grant
    Filed: August 4, 2004
    Date of Patent: March 25, 2008
    Assignee: Ricoh Company Limited
    Inventors: Ryohta Inoue, Naohiro Watanabe, Masahide Yamada, Sonoh Matsuoka, Chiaki Tanaka, Takeshi Takada, Masahiro Ohki, Akinori Saitoh
  • Publication number: 20080069616
    Abstract: An image forming apparatus including an image bearing member to bear a latent electrostatic image, a charging member to charge a surface of the image bearing member, an irradiation member to irradiate the image bearing member to write the latent electrostatic image, a development member to develop the latent electrostatic image with a toner to form a visualized image, a transfer device to transfer the visualized image directly or via an intermediate transfer body to a recording medium, a fixing device to fix the transferred image transferred on the recording medium and a cleaning device to remove residual toner remaining on the image bearing member.
    Type: Application
    Filed: September 19, 2007
    Publication date: March 20, 2008
    Inventors: Satoshi Kojima, Naohiro Watanabe, Osamu Uchinokura, Tsuneyasu Nagatomo
  • Publication number: 20080070144
    Abstract: A toner including toner particles including a binder resin, and a modified layered inorganic material in which at least part of interlayer ions is replaced with an organic ion, and a fatty acid metal compound located on a surface of the toner particles; and an external additive located on the fatty acid metal compound, wherein the external additive is a material different from the fatty acid metal compound. An image forming apparatus including an image bearing member; a developing device configured to develop the electrostatic latent image with a developer including the toner; a transfer device; and a fixing device. A method for preparing the toner including dispersing or emulsifying a toner composition including a modified layered inorganic material to prepare toner particles; mixing a fatty acid metal compound with the toner particles; and second mixing the toner particles with an external additive.
    Type: Application
    Filed: September 10, 2007
    Publication date: March 20, 2008
    Inventors: Tsuneyasu Nagatomo, Naohiro Watanabe, Osamu Uchinokura, Satoshi Kojima
  • Patent number: 7306887
    Abstract: A toner is prepared by dissolving and/or dispersing a modified polyester resin in an organic solvent to yield a solution or dispersion, the modified polyester resin being reactive with a compound having an active hydrogen group, mixing the solution or dispersion with an aqueous medium containing resin particles, and subjecting the modified polyester resin to crosslinking and/or elongation in the aqueous medium. The binder resin further includes a crystalline polyester resin in addition to the modified polyester resin.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: December 11, 2007
    Assignee: Ricoh Company, Ltd.
    Inventors: Chiaki Tanaka, Takeshi Takada, Naohiro Watanabe
  • Patent number: 7303847
    Abstract: A dry toner is provided that is prepared by a method including the steps of (A) dissolving or dispersing a toner composition in an organic solvent to prepare a toner composition liquid and (B) dispersing the toner composition liquid in an aqueous liquid which contains a binder resin formed of a modified polyester (i) and a colorant containing a carbon black having a pH not greater than 7, wherein the toner has a volume average particle diameter (Dv) is from 3 to 7 ?m and a ratio of the volume average particle diameter (Dv) to a number average particle diameter (Dp) is from 1.00 to 1.25.
    Type: Grant
    Filed: December 1, 2003
    Date of Patent: December 4, 2007
    Assignee: Ricoh Company Limited
    Inventors: Masami Tomita, Toshiki Nanya, Shigeru Emoto, Shinichiro Yagi, Hiroshi Yamada, Naohiro Watanabe, Tadao Takigawa
  • Patent number: 7294442
    Abstract: A toner for developing an electrostatic image having a good combination of hot offset resistance and low temperature fixability. The toner includes (1) a resin having at least one group that can react with a compound having an active hydrogen in an amount of 2 pieces per molecule of the resin, and a colorant. The toner satisfies the following relationship: 3?G=R?Rideal?20, where G represents a ratio of a weight of components other than the colorant and the resin that are insoluble in the organic solvent to total weight of the toner, R represents a weight ratio of components included in the toner that are insoluble in the organic solvent to the total weight of the toner, and Rideal represents an ideal weight ratio of the colorant and the resin, which is calculated from a formula of the toner.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: November 13, 2007
    Assignee: Ricoh Company. Ltd.
    Inventors: Takeshi Takada, Chiaki Tanaka, Naohiro Watanabe
  • Publication number: 20070218392
    Abstract: A toner containing a colorant, and a binder resin, wherein the toner is prepared by dissolving or dispersing a colorant, a precursor of the binder resin having a site capable of reacting with an active hydrogen group-containing compound, the active hydrogen group-containing compound, in an organic solvent, to prepare a toner constituent mixture liquid, dispersing or emulsifying the toner constituent mixture liquid, in an aqueous medium while subjecting the precursor to a reaction with the active hydrogen group-containing compound, to prepare a toner dispersion, and removing the organic solvent from the toner dispersion; the binder resin contains a modified polyester having an isocyanate-derived binding site; the Sn content in the toner is 800 ppm or less; the content of a metal which is non Sn and derived from a polyesterified catalyst is 10 ppm to 200 ppm; and the content of a metal which is non Sn and derived from an isocyanated catalyst is 10 ppm to 200 ppm.
    Type: Application
    Filed: March 16, 2007
    Publication date: September 20, 2007
    Inventors: Masahide Yamada, Shigeru Emoto, Naohiro Watanabe, Masahiro Ohki, Akinori Saitoh, Shinichi Wakamatsu
  • Publication number: 20070218381
    Abstract: It is an object to provide toner excellent in charge stability, fixing property at low temperature, durability, microdot reproducibility and cleaning ability. An excellent image forming apparatus using the toner is provided. Said toner has at least a plurality of resins, a colorant and a layered inorganic material in which at least a part of ions in the layered inorganic material has been exchanged with organic ions in the toner prepared by dispersing and/or emulsifying an oil phase comprising at least a toner composition and/or a toner composition precursor in a water-based medium to granulate, and wherein a first resin in said a plurality of resins has a weight average molecular weight of 3,000 to 10,000 in a molecular weight distribution obtained by gel permeation chromatography (GPC).
    Type: Application
    Filed: March 14, 2007
    Publication date: September 20, 2007
    Inventors: Osamu Uchinokura, Naohiro Watanabe, Junichi Awamura
  • Publication number: 20070218380
    Abstract: A toner containing a colorant, a binder resin and a laminar inorganic mineral in which part or all of the ions present between layers are modified by organic ions. The toner can be prepared by a method including dispersing or emulsifying a toner constituent mixture liquid containing the colorant, the binder resin and/or a precursor thereof, and the laminar inorganic mineral, in an aqueous medium. The density of the laminar inorganic mineral measured by XPS for the toner surface before (A) and after(B) mixing and kneading satisfies the following relationship: A>B.
    Type: Application
    Filed: March 14, 2007
    Publication date: September 20, 2007
    Inventors: Osamu UCHINOKURA, Naohiro Watanabe, Junichi Awamura
  • Publication number: 20070218382
    Abstract: A toner containing a toner particle containing a binder resin, a colorant, a releasing agent and a laminar inorganic mineral in which part or all ions present between layers are modified by organic ions. The toner particle has a structure such that when the particle is heated at a temperature ranging from 65 to 90° C. the releasing agent is melted on the outside of the toner particle to form a particle having a sea-island structure.
    Type: Application
    Filed: March 16, 2007
    Publication date: September 20, 2007
    Inventors: Shigeru Emoto, Akinori Saitoh, Naohiro Watanabe, Masahide Yamada, Masahiro Ohki, Ryota Inoue
  • Patent number: 7241545
    Abstract: A toner has a storage elastic modulus (G?) of 500 Pa or more at a frequency of 1 Hz and temperature of 180° C., while the toner is obtained by dissolving or dispersing a toner composition in an organic solvent, further dispersing the solution or dispersion thereof in an aqueous medium containing fine resin particles as well as being reacted with a compound having an active hydrogen group, and removing the solvent from the obtained aqueous dispersion.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: July 10, 2007
    Assignee: Ricoh Company, Ltd.
    Inventors: Toshiki Nanya, Masami Tomita, Shigeru Emoto, Shinichiro Yagi, Naohiro Watanabe, Tadao Takikawa
  • Publication number: 20070141506
    Abstract: A toner including toner particles comprising a binder resin; and at least two kinds of particulate resins which are located on at least a surface of the toner particles, wherein the toner satisfies at least one of the following relationships (TgA?TgB)?20° C., wherein TgA and TgB represent glass transition temperatures (Tg) of a particulate resin (A) having a highest Tg and a particulate resin (B) having a lowest Tg among the at least two kinds of particulate resins, respectively; and 100,000?Mwc?6,000,000 and 8,000?Mwd?800,000, wherein Mwc and Mwd represent weight average molecular weights (Mw) of a particulate resin (C) having a highest Mw and a particulate resin (D) having a lowest Mw among the at least two kinds of particulate resins, respectively, wherein Mwc>Mwd.
    Type: Application
    Filed: February 2, 2007
    Publication date: June 21, 2007
    Inventors: Ryohta INOUE, Naohiro Watanabe, Masahide Yamada, Sonoh Matsuoka, Chiaki Tanaka, Takeshi Takada, Masahiro Ohki, Akinori Saitoh
  • Patent number: 7217487
    Abstract: A toner has a storage elastic modulus (G?) of 500 Pa or more at a frequency of 1 Hz and temperature of 180° C., while the toner is obtained by dissolving or dispersing a toner composition in an organic solvent, further dispersing the solution or dispersion thereof in an aqueous medium containing fine resin particles as well as being reacted with a compound having an active hydrogen group, and removing the solvent from the obtained aqueous dispersion.
    Type: Grant
    Filed: August 7, 2006
    Date of Patent: May 15, 2007
    Assignee: Ricoh Company, Ltd.
    Inventors: Toshiki Nanya, Masami Tomita, Shigeru Emoto, Shinichiro Yagi, Naohiro Watanabe, Tadao Takikawa
  • Patent number: 7208256
    Abstract: A toner for image formation is provided, which is produced by dispersing in an aqueous solvent a toner composition which includes a composition thermally soluble in an organic solvent and a coloring agent, thereby forming toner particles, wherein the thermally soluble composition includes (a) a polyester having an acid value and (b) a metal alcolate and/a metal chelate compound. The toner is capable of attaining image fixing at a sufficiently low image fixing temperature and a sufficiently broad image fixing temperature range for use in practice. Furthermore, toner containers such as a toner cartridge and a process cartridge are provided, which are loaded with the toner. Such toner containers can be detachably mounted on an image forming apparatus.
    Type: Grant
    Filed: March 18, 2004
    Date of Patent: April 24, 2007
    Assignee: Ricoh Company, Ltd.
    Inventors: Chiaki Tanaka, Naohiro Watanabe, Takeshi Takada, Ryohta Inoue
  • Publication number: 20070059626
    Abstract: A toner is provided including a binder resin and a wax having primarily C—H and C—C bonds, and having a melting point of 50 to 90° C., wherein the wax is present in a surface portion of the toner in an amount of from 0.1 to 4.0% by weight, wherein the amount of the wax is determined by Fourier transform infrared spectroscopy attenuated total reflectance (FTIR-ATR); and the use of the toner in an image forming method, image forming apparatus, developer and toner cartridge containing the toner.
    Type: Application
    Filed: September 13, 2006
    Publication date: March 15, 2007
    Inventors: Ryota Inoue, Shigeru Emoto, Naohiro Watanabe, Masahide Yamada, Akinori Saitoh, Masahiro Ohki, Tsunemi Sugiyama, Shinichi Wakamatsu, Takayuki Yoshii, Eiji Sawamura