Patents by Inventor Naoto Hirosaki

Naoto Hirosaki has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9738829
    Abstract: Phosphors include a CaAlSiN3 family crystal phase, wherein the CaAlSiN3 family crystal phase comprises at least one element selected from the group consisting of Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, Ho, Er, Tm, and Yb.
    Type: Grant
    Filed: June 11, 2015
    Date of Patent: August 22, 2017
    Assignees: MITSUBISHI CHEMICAL CORPORATION, National Institute for Materials Science, Nichia Corporation, Citizen Electronics CO., Ltd.
    Inventors: Naoto Hirosaki, Kyota Ueda, Hajime Yamamoto
  • Patent number: 9741908
    Abstract: A wavelength converting member includes silica glass and a plurality of fluorescent material particles including an oxynitride or nitride fluorescent material and dispersed in the silica glass. The plurality of fluorescent material particles include at least two kinds of fluorescent material particles including (i) first fluorescent material particles that emit a fluorescence having a first peak wavelength and (ii) second fluorescent material particles that emit a fluorescence having a second peak wavelength. The wavelength converting member has a density within a range from 0.8 g/cm3 to 1.2 g/cm3.
    Type: Grant
    Filed: January 25, 2016
    Date of Patent: August 22, 2017
    Assignees: SHARP KABUSHIKI KAISHA, NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Kenichi Yoshimura, Makoto Izumi, Masamichi Harada, Hiroshi Fukunaga, Kazunori Annen, Naoto Hirosaki, Hiroyo Segawa
  • Patent number: 9677000
    Abstract: A fluorophor includes: ?-type sialon crystal which is expressed by a general formula: (Lix1, Eux2)(Si12?(m+n)Alm+n)(OnN16?n), wherein x1 is an amount of solid solution of Li in a sialon unit cell, and x2 is an amount of solid solution of Eu in the sialon unit cell, wherein the parameters x1, x2, m, and n satisfy: 1.6?x1?2.4 (1), 0.001?x2?0.4 (2), 1.8?m?2.4 (3), 0.8?n?1.2 (4), wherein the ?-type sialon crystal emits fluorescence with a peak in a wavelength region of from 550 nm to 575 nm upon irradiation of an excitation source.
    Type: Grant
    Filed: October 6, 2014
    Date of Patent: June 13, 2017
    Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Naoto Hirosaki, Rong-Jun Xie, Mamoru Mitomo
  • Patent number: 9670405
    Abstract: A production method of a phosphor includes firing a starting material mixture in a nitrogen atmosphere at a temperature range between 1,500° C. inclusive and 2,200° C. inclusive. The starting material mixture is a mixture of metallic compounds, and is capable of constituting a composition including M, A, Al, O, and N (M is Eu; and A is one kind or two or more kinds of element(s) selected from C, Si, Ge, Sn, B, Ga, In, Mg, Ca, Sr, Ba, Sc, Y, La, Gd, Lu, Ti, Zr, Hf, Ta, and W) by firing.
    Type: Grant
    Filed: July 28, 2014
    Date of Patent: June 6, 2017
    Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventor: Naoto Hirosaki
  • Patent number: 9666767
    Abstract: Provided is fluorophore comprising: inorganic compound having: an inorganic crystal, where M element (M is one or more elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb) is solid solved, having the same crystal structure as the crystal represented by Ca2Si5O3N6 (including Ca2Si5O3N6 crystal or a solid solution thereof where one or more elements selected from Mg, Sr, Ba, Ge, Sn, Ti, Zr, Hf, B, Al, Ga, In, Sc, Y, La, and F are solid solved) and comprising: A element, D element, X element, and, if necessary, E element (A is one or more elements selected from Mg, Ca, Sr, and Ba; D is one or more elements selected from Si, Ge, Sn, Ti, Zr, and Hf; E is one or more elements selected from B, Al, Ga, In, Sc, Y, and La; and X is one or more elements selected from O, N, and F).
    Type: Grant
    Filed: July 25, 2013
    Date of Patent: May 30, 2017
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Eiichirou Narimatsu
  • Patent number: 9624428
    Abstract: A phosphor indicated by general formula MeaRebSicAldNeOf. In the formula: Me has Sr as an essential element thereof and can include one or more types of element selected from Na, Li, Mg, Ca, Ba, Sc, Y, and La; and Re has Eu as an essential element thereof and can include one or more types of element selected from Mn, Ce, Tb, Yb, and Sm. In addition, when a=1?x, b=x, c=(2+2p)×(1?y), d=(2+2p)×y, e=(1+4p)×(1?z), and f=(1+4p)×z, parameters p, x, y, and z fulfill the following: 1.620<p<1.635, 0.005<x<0.300, 0.200<y<0.250, and 0.070<z<0.110. A light-emitting device with high luminance is provided by using this phosphor.
    Type: Grant
    Filed: February 3, 2012
    Date of Patent: April 18, 2017
    Assignees: NATIONAL INSTITUTE FOR MATERIALS SCIENCE, DENKA COMPANY LIMITED
    Inventors: Naoto Hirosaki, Ryo Yoshimatsu, Shintaro Watanabe
  • Patent number: 9617471
    Abstract: Provided is a chemically and thermally stable phosphor having different light-emitting characteristics than a conventional phosphor and having high light-emitting intensity even when combined with an LED of 410 nm or lower. The phosphor comprises an inorganic compound in which an inorganic crystal including A element, D element, X element (A is one or more elements selected from Mg, Ca, Sr, and Ba; D is one or more elements selected from Si, Ge, Sn, Ti, Zr, and Hf; and X is one or more elements selected from O, N, and F), and, if necessary, E element (where E is one or more elements selected from B, Al, Ga, In, Sc, Y, and La) includes Li element and M element (where M is one or more elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb).
    Type: Grant
    Filed: April 24, 2014
    Date of Patent: April 11, 2017
    Assignee: National Institute of Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Eiichirou Narimatsu
  • Publication number: 20170062668
    Abstract: The present invention provides a light emitting device that makes it possible to provide an image display apparatus having a wide color reproduction range. The light emitting device includes a light emitting element that emits blue light; a Mn2+-activated ?-AlON phosphor that is a green phosphor; and a Mn4+-activated phosphor that is a red phosphor. The green light emitted by the Mn2+-activated ?-AlON phosphor has an emission-spectrum peak wavelength of not less than 518 nm and not more than 528 nm.
    Type: Application
    Filed: August 15, 2016
    Publication date: March 2, 2017
    Inventors: Kenichi YOSHIMURA, Shigetoshi ITO, Makoto IZUMI, Masamichi HARADA, Hiroshi FUKUNAGA, Naoto HIROSAKI
  • Publication number: 20170037313
    Abstract: Provided are an oxynitride phosphor comprising a JEM crystal as a main component and being characterized by light-emitting properties (light emission color or excitation property, light emission spectrum) that is different from the known JEM phosphor, and an application thereof. The phosphor of the present invention comprises the JEM crystal activated with Eu and represented by MAl(Si, Al)6(O, N)10 (where the M element is one or more elements selected from the group consisting of Ca, Sr, Eu, La, Sc, Y, and lanthanoid elements; and includes at least Eu as well as Ca and/or Sr).
    Type: Application
    Filed: November 21, 2014
    Publication date: February 9, 2017
    Applicant: National Institute for Materials Science
    Inventors: Naoto HIROSAKI, Takashi TAKEDA, Shiro FUNAHASHI, Eiichirou NARIMATSU
  • Patent number: 9534171
    Abstract: To provide a phosphor being chemically-thermally stable and having high luminous intensity if combined with LED of not exceeding 470 nm. A phosphor of the present invention includes: inorganic compound including: a crystal represented by Li1Ba2Al1Si7N12; a crystal represented by (Li, A)3(D, E)8X12; and an inorganic crystal having the same crystal structure as the crystal represented by Li1Ba2Al1Si7N12; and a solid-solution crystal thereof, which contains Li, A, D, E, and X elements (A represents at least one selected from Mg, Ca, Sr, Ba, Sc, Y and La; D represents at least one selected from Si, Ge, Sn, Ti, Zr and Hf; E represents at least one selected from B, Al, Ga and In; and X represents at least one selected from O, N and F), wherein M element (M represents at least one selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy and Yb) is solid-solved into each.
    Type: Grant
    Filed: June 26, 2013
    Date of Patent: January 3, 2017
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Eiichirou Narimatsu
  • Patent number: 9512358
    Abstract: A phosphor with a high light-emitting intensity and indicated by general formula MeaRebSicAldNeOf. Me has Sr as an essential element thereof and can include one or more types of element selected from Na, Li, Mg, Ca, Ba, Sc, Y, and La. Re has Eu as an essential element thereof and can include one or more types of element selected from Mn, Ce, Tb, Yb, and Sm. When composition ratios a, b, c, d, e, and f fulfill a=1?x, b=x, c=(2+2p)×(1?y), d=(2+2p)×y, e=(1+4p)×(1?z), and f=(1+4p)×z, parameters p, x, y, and z fulfill the following: 1.630<p<1.650, 0.005<x<0.300, 0.180<y<0.220, and 0.060<z<0.100. A light-emitting device with high luminance is provided by using this phosphor.
    Type: Grant
    Filed: February 3, 2012
    Date of Patent: December 6, 2016
    Assignees: NATIONAL INSTITUTE FOR MATERIALS SCIENCE, DENKA COMPANY LIMITED
    Inventors: Naoto Hirosaki, Ryo Yoshimatsu, Shintaro Watanabe
  • Patent number: 9515230
    Abstract: Provided is chemically and thermally stable phosphor having light-emitting characteristics different from the conventional phosphor and high emission intensity when combined with LED of not exceeding 470 nm. The phosphor comprises inorganic compound having crystal represented by A2(D,E)5X9; crystal represented by Ca2Si5O3N6; or inorganic crystal having the same crystal structure as crystal represented by Ca2Si5O3N6, which includes A, D, E, and X elements (A is one or more kinds selected from Mg, Ca, Sr, and Ba; D is one or more kinds selected from Si, Ge, Sn, Ti, Zr, and Hf; E is one or more kinds selected from B, Al, Ga, In, Sc, Y, and La; and X is one or more kinds selected from O, N, and F), in which M element (M is one or more kinds of elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb) is solid-solved.
    Type: Grant
    Filed: July 25, 2013
    Date of Patent: December 6, 2016
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Eiichirou Narimatsu
  • Patent number: 9512979
    Abstract: A phosphor with a high light-emitting intensity, indicated by general formula MeaRebSicAld—NeOf. In the formula: Me has Sr as an essential element thereof and can include one or more types of element selected from Na, Li, Mg, Ca, Ba, Sc, Y, and La; and Re has Eu as an essential element thereof and can include one or more types of element selected from Mn, Ce, Tb, Yb, and Sm. When a=1?x, b=x, c=(2+2p)×(1?y), d=(2+2p)×y, e=(1+4p)×(1?z), and f=(1+4p)×z, parameters, p, x, y, and z fulfill the following: 1.610<p<1.620, 0.005<x<0.300, 0.190<y<0.260, and 0.060<z<0.120. A light-emitting device with high luminance is provided by using this phosphor.
    Type: Grant
    Filed: February 3, 2012
    Date of Patent: December 6, 2016
    Assignees: DENKA COMPANY LIMITED, NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Naoto Hirosaki, Ryo Yoshimatsu, Shintaro Watanabe
  • Patent number: 9458379
    Abstract: A chemically and thermally stable phosphor having unconventional light emitting properties and high light emitting intensity with an LED of 470 nm or less, includes an inorganic compound comprising: a crystal designated by A3(D,E)8X14, a crystal designated by Sr3Si8O4N10 or an inorganic crystal having the identical crystal structure of the Sr3Si8O4N10 crystal, which comprises A element, D element, X element, and optionally E element if necessary (A is one or more kinds selected from Li, Mg, Ca, Sr, and Ba; D is one or more kinds selected from Si, Ge, Sn, Ti, Zr, and Hf; X is one or more kinds selected from O, N, and F; and E is one or more kinds selected from B, Al, Ga, In, Sc, Y, and La.), into which M element is solid-solved (M is one or more kinds selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb.).
    Type: Grant
    Filed: May 30, 2013
    Date of Patent: October 4, 2016
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi
  • Publication number: 20160225963
    Abstract: A wavelength converting member includes silica glass and a plurality of fluorescent material particles including an oxynitride or nitride fluorescent material and dispersed in the silica glass. The plurality of fluorescent material particles include at least two kinds of fluorescent material particles including (i) first fluorescent material particles that emit a fluorescence having a first peak wavelength and (ii) second fluorescent material particles that emit a fluorescence having a second peak wavelength. The wavelength converting member has a density within a range from 0.8 g/cm3 to 1.2 g/cm3.
    Type: Application
    Filed: January 25, 2016
    Publication date: August 4, 2016
    Inventors: Kenichi Yoshimura, Makoto Izumi, Masamichi Harada, Hiroshi Fukunaga, Kazunori Annen, Naoto Hirosaki, Hiroyo Segawa
  • Patent number: 9399731
    Abstract: A blue phosphor having an emission peak wavelength different from that of conventional blue phosphors, a method for producing the same, and a high-intensity luminescent device using the phosphor are provided. The phosphor of the present invention is represented by a general formula MeaRebAlcSidOeNf (Me may contain one or more elements selected from Mg, Ca, Sc, Y, and La as second elements, provided that Sr or Ba is contained as an essential first element, and Re may contain one or more elements selected from Mn, Ce, Tb, Yb, and Sm as second elements, provided that Eu is contained as an essential first element), where the composition ratio represented by a, b, c, d, e, and f has the following relations: a+b=1, 0.005<b<0.25, 1.60<c<2.60, 2.50<d<4.05, 3.05<e<5.00, and 2.75<f<4.40.
    Type: Grant
    Filed: April 2, 2013
    Date of Patent: July 26, 2016
    Assignee: DENKA COMPANY LIMITED
    Inventors: Go Takeda, Ryo Yoshimatsu, Naoto Hirosaki
  • Patent number: 9359551
    Abstract: Provided is a chemically and thermally stable phosphor having different emission characteristics than the conventional phosphor and exhibiting high emission intensity if combined with an LED of 470 nm or less. The phosphor of the present invention is represented by a composition formula: MdAeDfEgXh (d+e+f+g+h=1; M is one or more kinds of elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb; A is one or more kinds of elements selected from Mg, Ca, Sr, and Ba; D is one or more kinds of elements selected from Si, Ge, Sn, Ti, Zr, and Hf; E is one or more kinds of elements selected from B, Al, Ga, In, Sc, Y, and La; and X is one or more kinds of elements selected from O, N, and F) and parameters d, e, f, g, and h satisfy the predetermined condition.
    Type: Grant
    Filed: November 30, 2012
    Date of Patent: June 7, 2016
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi
  • Publication number: 20160096991
    Abstract: A phosphor having different light emission characteristics from the conventional phosphor, having high emission intensity and chemical and thermal stability, combined with LED of less than 450 nm. This phosphor includes an inorganic compound comprising: a crystal represented by Ba1Si4Al3N9, an inorganic crystal having the same crystal structure as Ba1Si4Al3N9 crystal, or a solid solution crystal thereof, comprising A element, D element, E element, and X element (A is one or more elements selected from Li, Mg, Ca, Sr, Ba, and La; D is one or more elements selected from Si, Ge, Sn, Ti, Zr, and Hf; E is one or more elements selected from B, Al, Ga, In, Sc, and Y; X is one or more elements selected from O, N, and F), into which M element is solid-solved (M is one or more elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb).
    Type: Application
    Filed: May 13, 2014
    Publication date: April 7, 2016
    Applicant: National Institute for Materials Science
    Inventors: Naoto HIROSAKI, Takashi TAKEDA, Shiro FUNAHASHI, Eiichirou NARIMATSU
  • Patent number: 9279079
    Abstract: A method of manufacturing a first phosphor of which emission spectrum shape well matches with a color filter of three primary colors of light, a light-emitting device including the first phosphor, and an image display apparatus including the light-emitting device are provided. The light-emitting device includes a semiconductor light-emitting element emitting excitation light and the first phosphor absorbing the excitation light and emitting green light. The first phosphor contains a solid solution of aluminum element and a metal element M selected from the group consisting of Mn, Ce and Eu in crystals of an oxynitride having a ?-type Si3N4 crystal structure, an amount of oxygen in the crystals being not higher than 0.8 mass %.
    Type: Grant
    Filed: May 29, 2008
    Date of Patent: March 8, 2016
    Assignees: SHARP KABUSHIKI KAISHA, NATIONAL INSTITUTE FOR MATERIALS SCIENCE
    Inventors: Kohsei Takahashi, Masamichi Harada, Naoto Hirosaki
  • Publication number: 20160060518
    Abstract: Provided is a chemically and thermally stable phosphor having different light-emitting characteristics than a conventional phosphor and having high light-emitting intensity even when combined with an LED of 410 nm or lower. The phosphor comprises an inorganic compound in which an inorganic crystal including A element, D element, X element (A is one or more elements selected from Mg, Ca, Sr, and Ba; D is one or more elements selected from Si, Ge, Sn, Ti, Zr, and Hf; and X is one or more elements selected from O, N, and F), and, if necessary, E element (where E is one or more elements selected from B, Al, Ga, In, Sc, Y, and La) includes Li element and M element (where M is one or more elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb).
    Type: Application
    Filed: April 24, 2014
    Publication date: March 3, 2016
    Applicant: National Institute for Materials Science
    Inventors: Naoto HIROSAKI, Takashi TAKEDA, Shiro FUNAHASHI, Eiichirou NARIMATSU