Abstract: A monomer and polycarbonate resin are provided, as are methods of making the monomer. The resin may be used to provide a thin film that has a higher dielectric constant and higher glass transition temperature, and similar breakdown strength and similar dissipation factor to films prepared from polycarbonate resins not so modified. The thin films, in turn, may advantageously be used to form, wholly or in part, articles such as capacitors, sensors, batteries, flexible printed circuit boards, keyboard membranes, motor/transformer insulations, cable wrappings, industrial tapes, interior coverage materials, and the like. In particular, a capacitor comprising the polycarbonate resin is also provided.

Abstract: A composition is provided for use with an unsaturated elastomer. The composition may include a sulfur-functional linear polyorganosiloxane. The sulfur-functional linear polyorganosiloxane may include a chemically protected sulfur group. Under certain conditions, the sulfur group may react with the unsaturated elastomer. The invention includes embodiments that may relate to methods of making and using the sulfur-functional linear polyorganosiloxane in elastomer compositions.

Abstract: A system is provided for supplying reductants to an emission treatment unit. The system comprises a fuel tank adapted to directly or indirectly supply a first premixed fuel stream and a second premixed fuel stream, wherein each fuel stream comprises a primary fuel component and an oxygenate reductant component. An engine is in fluid communication with the fuel tank, wherein the engine is configured to receive the first premixed fuel stream and create an exhaust stream. The system further includes an emission treatment unit to treat the exhaust stream. A separation unit is configured to receive the second premixed fuel stream, separate the second premixed fuel stream into a first fraction stream and a second fraction stream, and supply the first fraction stream to the emission treatment unit, wherein the first fraction stream comprises a higher concentration of the oxygenate reductant component than the second fraction stream.

Abstract: A polyimide resin is provided. The polyimide resin comprises the reaction product of a polyimide resin and an amine comprising a C1-10 hydrocarbon substituted with CN, F, SO2, SO, S, SO3, SO3?, PO, PO2H, PO3H, PO2?, PO3?2, CO, CO2?, CO2H, CONH, CONH2, NHCOHN, OCONH, OCO2, N, NH, NH2, NO2, CSNH, CSNH2, NHCSNH, OTi(OR4)3, or OSi(OR4)3 or combinations of these, wherein R4 is a C1-10 aliphatic or aromatic hydrocarbon. The resin may be used to provide a thin film that in turn, may advantageously be used to form, wholly or in part, articles such as capacitors, sensors, batteries, flexible printed circuit boards, keyboard membranes, motor/transformer insulations, cable wrappings, industrial tapes, interior coverage materials, and the like. In particular, a capacitor comprising the thin film and methods of making the same are also provided.

Abstract: A monomer and polycarbonate resin are provided, as are methods of making the monomer. The resin may be used to provide a thin film that has a higher dielectric constant and higher glass transition temperature, and similar breakdown strength and similar dissipation factor to films prepared from polycarbonate resins not so modified. The thin films, in turn, may advantageously be used to form, wholly or in part, articles such as capacitors, sensors, batteries, flexible printed circuit boards, keyboard membranes, motor/transformer insulations, cable wrappings, industrial tapes, interior coverage materials, and the like. In particular, a capacitor comprising the polycarbonate resin is also provided.

Abstract: Disclosed herein is a method of making a polymer composite composition comprising blending a polymeric material precursor with nanoparticles, wherein each nanoparticle comprises a substrate and a coating composition disposed on the substrate; and polymerizing the polymeric material precursor to form a polymeric material, wherein the nanoparticles are dispersed within the polymeric material to form a polymer composition.

Abstract: A composition is provided that may include a sulfur-functional linear polyorganosiloxane. The sulfur-functional linear polyorganosiloxane may include a chemically protected sulfur group. Under certain conditions, the sulfur group may react with an unsaturated elastomer. The invention may include embodiments that relate to method of making and using the sulfur-functional linear polyorganosiloxane.

Abstract: A method comprises mixing a nano-filler and a polymer composition to form a nanocomposite; extruding the nanocomposite as a melt through a spiral mandrel die to form a molten tube; expanding the tube biaxially by means of mechanical force and air pressure to form a bubble; and collapsing the bubble to form at least one sheet of a biaxially oriented nanocomposite film, wherein the biaxially oriented nanocomposite film has a breakdown strength of at least 300 V/micrometer.

Abstract: A composition is provided for use with an unsaturated elastomer. The composition may include a sulfur-functional linear polyorganosiloxane. The sulfur-functional linear polyorganosiloxane may include a chemically protected sulfur group. Under certain conditions, the sulfur group may react with the unsaturated elastomer. The invention includes embodiments that may relate to methods of making and using the sulfur-functional linear polyorganosiloxane in elastomer compositions.

Abstract: A composition is provided for use with an unsaturated elastomer. The composition may include a sulfur-functional linear polyorganosiloxane. The sulfur-functional linear polyorganosiloxane may include a chemically protected sulfur group. Under certain conditions, the sulfur group may react with the unsaturated elastomer. The invention includes embodiments that may relate to methods of making and using the sulfur-functional linear polyorganosiloxane in elastomer compositions.

Abstract: A core-shell particle including a core with poly(arylene ether) and a shell with an ethylenically unsaturated copolymer is described. Also described are a method of forming the particle, a composition including the particle, and an article including such a composition.

Abstract: A method for manufacturing an ultra-thin polymeric film is disclosed. The method includes the steps of melt blending of a polymeric composition or a nanocomposite composition in an extruder. Next, the molten composition is conveyed through a flat die with a small die lip gap. A melt pump may also be used to provide a constant, non-pulsating flow of the melted composition through the die. The melted composition may be passed through a filtration device to remove contaminants that could adversely affect the dielectric performance of the film. Next, the film is stretched by passing the film through take-up rollers at relatively high take-up speeds. Then, the composition is cooled to form a film or sheet. The edges of the film may be trimmed, and the film wound up on a roll using a tension-controlled winding mechanism. A heated roll may be used to temper/anneal the film, thereby eliminating frozen-in internal stresses.

Abstract: A vulcanizable rubber composition including an unsaturated rubber, core-shell particles, and a vulcanizing agent is described. The core-shell particles include a core with poly(arylene ether) and a shell with an ethylenically unsaturated copolymer. Also described are a vulcanized rubber composition and an article that includes it.

Abstract: The present invention relates to various embodiments of a system and method for separating polymer from a solvent. In one embodiment a system for separating polymer from a solvent comprises an extrusion apparatus includes a hollow member having a first end portion, a second end portion, and a feed port between the first end portion and the second end portion. The extrusion apparatus includes a back flash vent port disposed upstream of the feed port and a forward flash vent port disposed downstream of the feed port. The extrusion apparatus further includes a vent insert located at the forward flash vent port, a screw disposed inside the hollow member, and an internal superheating section disposed between the feed port and the downstream vent opening of the hollow member such that the length of the internal superheating section is greater than about four times the diameter, 4D, of the hollow member.

Abstract: A system is provided for supplying reductants to an emission treatment unit. The system comprises a fuel tank adapted to directly or indirectly supply a first premixed fuel stream and a second premixed fuel stream, wherein each fuel stream comprises a primary fuel component and an oxygenate reductant component. An engine is in fluid communication with the fuel tank, wherein the engine is configured to receive the first premixed fuel stream and create an exhaust stream. The system further includes an emission treatment unit to treat the exhaust stream. A separation unit is configured to receive the second premixed fuel stream, separate the second premixed fuel stream into a first fraction stream and a second fraction stream, and supply the first fraction stream to the emission treatment unit, wherein the first fraction stream comprises a higher concentration of the oxygenate reductant component than the second fraction stream.

Abstract: A vulcanizable rubber composition including an unsaturated rubber, core-shell particles, and a vulcanizing agent is described. The core-shell particles include a core with poly(arylene ether) and a shell with an ethylenically unsaturated copolymer. Also described are a vulcanized rubber composition and an article that includes it.

Abstract: A core-shell particle including a core with poly(arylene ether) and a shell with an ethylenically unsaturated copolymer is described. Also described are a method of forming the particle, a composition including the particle, and an article including such a composition.

Abstract: The present invention provides a method of separating a polymer from a solvent comprising introducing a superheated polymer-solvent mixture into an extruder, and isolating a polymer product, said extruder being equipped with at least one vent operated at subatmospheric pressure and at least one vent operated at about atmospheric pressure, said extruder having a screw diameter D, said extruder being operated at a feed rate FR and at a screw speed RPM such that a devolatilization performance ratio (DPR) given by Equation (I) DPR=FR/RPM??Equation (I) is selected from a predetermined set of devolatilization performance ratios which correlate with a target characteristic of the polymer product.

Abstract: A method is disclosed to prepare a polymeric material by filtering solutions of poly(arylene ether) and/or poly(alkenyl aromatic) through one or more filtration systems to provide a material having reduced levels of particulate impurities. The polymeric material prepared is suitable for use in data storage media applications.

Abstract: This invention relates to an extrusion method preparing polycarbonates from a solution of an oligomeric polycarbonate. A mixture of bis(methyl salicyl)carbonate (BMSC), BPA and a transesterification catalyst are first equilibrated at moderate temperatures to provide a solution of polycarbonate oligomer in methyl salicylate. The solution is then fed to a devolatilizing extruder, where the polymerization reaction is completed and the methyl salicylate solvent is removed. The solution comprising the oligomeric polycarbonate can also be pre-heated under pressure to a temperature above the boiling point of methyl salicylate and subsequently fed to a devolatilizing extruder equipped for rapid flashing off the solvent. The method provides polycarbonate with greater efficiency than the corresponding process in which unreacted monomers are fed to the extruder. Additionally, the method of the invention does not require the isolation of a precursor polycarbonate comprising ester-substituted phenoxy terminal groups.