Abstract: A negative electrode for a lithium-metal secondary battery, which has a wide specific surface area and a current density distribution that can be uniformly implemented, and a lithium-metal secondary battery including the same.

Abstract: A method for manufacturing a lithium secondary battery, including the steps: (S1) forming a preliminary negative electrode by coating a negative electrode slurry including a negative electrode active material, conductive material, binder and a solvent onto at least one surface of a current collector, followed by drying and pressing the negative electrode slurry coated current collector, to form a negative electrode active material layer surface on the current collector; (S2) coating lithium metal foil onto the negative electrode active material layer surface of the preliminary negative electrode in the shape of a pattern in which pattern units are arranged; (S3) cutting the preliminary negative electrode on which the lithium metal foil is pattern-coated to obtain negative electrode units; (S4) impregnating the negative electrode units with an electrolyte to obtain a pre-lithiated negative electrode; and (S5) assembling the negative electrode obtained from step (S4) with a positive electrode and a separator.

Abstract: A negative electrode for a lithium secondary battery, which includes a negative electrode active material layer formed on a negative electrode collector, and a coating layer formed on the negative electrode active material layer and which includes lithium metal and metal oxide, a lithium secondary battery including the same, and a method of preparing the negative electrode.

Abstract: Disclosed is a method of preparing a negative electrode which includes the steps of: forming a cell by sequentially stacking a preliminary negative electrode, a separator, and a lithium metal, immersing the cell in an electrolyte solution comprising a lithium salt and a solvent; applying a current after the cell is immersed in the electrolyte solution containing the lithium salt and the solvent, separating the preliminary negative electrode from the cell after removing the cell immersed in the electrolyte solution from the electrolyte solution, washing the separated preliminary negative electrode, performing a first drying on the washed preliminary negative electrode at room temperature, and performing a second drying on the first dried preliminary negative electrode at a temperature ranging from 30° C. to 70° C. in a vacuum state.

Abstract: Disclosed is a method of manufacturing a negative electrode, wherein a negative electrode structure is electrochemically charged while being pressed with a plurality of pre-lithiation rolls in performing pre-lithiation of the negative electrode structure by a roll-to-roll method, and here, the pressing pressures of the plurality of pre-lithiation rolls are increased in a movement direction of the negative electrode structure. Since the pressing pressures are increased in the movement direction of the negative electrode structure, volume expansion, structural deformation, and damage to an active material due to the pre-lithiation may be prevented, and at the same time, the pre-lithiation may be performed uniformly, and thus it is preferable for improving lifespan characteristics of a negative electrode.

Abstract: A device for pre-lithiation including a pre-lithiation reactor sequentially divided into an impregnation section, a pre-lithiation section, and an aging section. The pre-lithiation reactor accommodates a pre-lithiation solution through which a negative electrode structure is moved. A negative electrode roll is arranged outside the pre-lithiation solution, and the pre-movement negative electrode structure is wound. A lithium metal counter electrode is arranged in the pre-lithiation solution of the pre-lithiation section, and is arranged to be spaced apart from the negative electrode structure to face the negative electrode structure moving in the pre-lithiation solution.

Abstract: A method for pre-lithiation of a negative electrode for a secondary battery, for reducing the time required for pre-lithiation and reducing changes in volume of the electrode. The method includes immersing a negative electrode for a secondary battery in the electrolyte to perform electrolyte impregnation, and pre-lithiating the negative electrode. Immersing the negative electrode for the secondary battery in an electrolyte includes introducing the prepared negative electrode into an electrolyte bath containing the electrolyte, and removing air bubbles and moisture in the negative electrode by applying a vacuum to the electrolyte bath in which the negative electrode is immersed.

Abstract: A method for pre-sodiation of a negative electrode, including the steps of: interposing a separator between a sodium ion-supplying metal sheet and a negative electrode to prepare a simple cell; dipping the simple cell in an electrolyte for pre-sodiation; and electrochemically charging the simple cell dipped in the electrolyte for pre-sodiation to carry out pre-sodiation of the negative electrode wherein the electrochemical charging is carried out while the simple cell is pressurized under a pressure of from 100 kPa to 1,000 kPa. A pre-sodiated negative electrode is also disclosed, including: a current collector; a negative electrode active material layer on at least one surface of the current collector. The negative electrode active material layer includes a negative electrode active material; and a coating layer on the surface of the negative electrode active material layer. The coating layer includes Na-carbonate and Na.

Abstract: A method for pre-lithiation and pre-sodiation of a negative electrode, including the steps of: preparing a negative electrode including a negative electrode current collector, and a negative electrode active material layer on at least one surface of the negative electrode current collector. Then, applying and drying a first composition containing a lithium metal powder, a polymer binder and a dispersion medium onto the negative electrode active material layer to form a lithium metal layer. Next, applying and drying a second composition containing a sodium metal powder, a polymer binder and a dispersion medium onto the lithium metal layer to form a sodium metal layer. Then, dipping the negative electrode having the lithium metal layer and the sodium metal layer in an electrolyte for pre-lithiation and pre-sodiation. A pre-lithiated and pre-sodiated negative electrode obtained by the method and a lithium secondary battery including the same are also disclosed.

Abstract: A method for pre-lithiation and pre-sodiation of a negative electrode, including the steps of: interposing a first separator between a lithium ion-supplying metal sheet and a negative electrode to prepare a first simple cell. Then, dipping the first simple cell in an electrolyte for pre-lithiation. Next, carrying out a primary electrochemical charging of the first simple cell dipped in the electrolyte for pre-lithiation to obtain a pre-lithiated negative electrode. Then, interposing a second separator between a sodium ion-supplying metal sheet and the pre-lithiated negative electrode to prepare to prepare a second simple cell. Next, dipping the second simple cell in an electrolyte for pre-sodiation; and carrying out secondary electrochemical charging of the second simple cell dipped in the electrolyte for pre-sodiation to obtain a pre-lithiated and pre-sodiated negative electrode.

Abstract: A lithium secondary battery including a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode, wherein the negative electrode is lithiated by pre-lithiation, a total capacity of a negative electrode active material of the negative electrode is larger than a total capacity of a positive electrode active material of the positive electrode, and a charge capacity of the negative electrode is smaller than a charge capacity of the positive electrode by the pre-lithiation.

Abstract: A device for producing a negative electrode, which includes: a pre-lithiation bath containing a pre-lithiation solution, which is sequentially divided into an impregnation section, a pre-lithiation section, and an aging section; a negative electrode roll present outside the pre-lithiation solution, wherein the negative electrode roll is configured to allow a negative electrode structure to be wound and unwound; and one or more pre-lithiation rolls which are present inside the pre-lithiation solution, wherein the one or more pre-lithiation rolls allow the negative electrode structure unwound from the negative electrode roll to move in the pre-lithiation bath, wherein the pre-lithiation roll includes an inner ring, an outer ring which is formed on the inner ring and is rotatable, and a rolling element present between the inner ring and the outer ring, and the outer ring in the pre-lithiation roll comprises a non-conductor.

Abstract: A method of producing a negative electrode, which includes: providing a negative electrode roll on which a negative electrode structure is wound, the negative electrode structure includes a negative electrode current collector and a negative electrode active material layer on at least one surface of the negative electrode current collector; providing a pre-lithiation bath containing a pre-lithiation solution, which is sequentially divided into an impregnation section, a pre-lithiation section, and an aging section; impregnating the negative electrode structure with the pre-lithiation solution while unwinding the negative electrode structure from the negative electrode roll and moving the same through the sections. The pre-lithiation is performed by disposing a lithium metal counter electrode, which is spaced apart from the negative electrode structure and impregnated with the pre-lithiation solution, in the pre-lithiation section and electrochemically charging the negative electrode structure.

Abstract: A method of producing a negative electrode is disclosed which is capable of preventing volume expansion and structural deformation caused by pre-lithiation, maintaining proximity and contact between negative electrode active materials, preventing an increase in resistance of a negative electrode, and realizing an excellent capacity retention rate by performing pre-lithiation while pressurizing a negative electrode at a specific pressure. In addition, the method of producing a negative electrode is capable of improving quality consistency of a product and processability by performing pre-lithiation of a negative electrode in a roll-to-roll manner.

Abstract: A pre-lithiation apparatus that pre-lithiates a negative electrode structure having a first surface on which a negative electrode is disposed to produce a negative electrode unit of a battery, the apparatus includes a first roll rotatable to wind or unwind the negative electrode structure before the pre-lithiation is performed, a second roll installed to be spaced apart from the first roll and rotatable to wind and collect the negative electrode structure, on which the pre-lithiation is performed, and a lithium roll crossing a direction in which the negative electrode structure is transferred from the first roll to the second roll to come into contact with at least one of a first surface and a second surface of the negative electrode structure while being transferred from the first roll to the second roll. The lithium roll includes a lithium foil and an elastic member.

Abstract: TA negative electrode, a secondary battery including the same, and a method of preparing the negative electrode are provided. The negative electrode, which includes a current collector; a negative electrode active material layer disposed on the current collector; a first layer disposed on the negative electrode active material layer and including Li; and a second layer disposed on the first layer and including an inorganic material is provided. A loading amount of the first layer may satisfy Equation 1: 0.65×(x1?y1)<loading amount of the first layer<0.95×(x1?y1).

Abstract: A method for pre-lithiation of a negative electrode and a negative electrode formed by the method, the method including forming a mixture of inorganic material powder and molten lithium, forming a lithium metal-inorganic material composite ribbon, rolling the ribbon into a film and bonding the lithium metal-inorganic material composite film on a surface of a negative electrode to form a lithium metal-inorganic material composite layer on the surface of the negative electrode. This method reduces the deterioration of lithium during application of a mixture slurry and a negative electrode for a secondary battery, manufactured by the method for pre-lithiation, has improved initial irreversibility, and a secondary battery manufactured using such a negative electrode has excellent charging and discharging efficiency.

Abstract: A method of pre-lithiating a negative electrode for a secondary battery, including: dispersing a lithium metal powder, an inorganic material powder and a binder in a solvent to prepare a mixed solution; and applying the mixed solution to the negative electrode to form a lithium metal-inorganic composite layer on the negative electrode, thereby forming the pre-lithiated negative electrode. Also, a method for pre-lithiating a negative electrode having a high capacity by a simple process. Further, a negative electrode for a secondary battery manufactured through the pre-lithiation method provided in the present invention has an improved initial irreversibility, and secondary batteries manufactured using such a negative electrode for a secondary battery have excellent charge/discharge efficiency.

Abstract: A pre-lithiation apparatus which prevents an electrode from being damaged by the byproducts produced by contact between a lithium source, such as a lithium metal sheet or lithium metal powder, and an electrolyte for pre-lithiation. The pre-lithiation apparatus includes a first reaction vessel comprising a first electrolyte and a first organic solvent and a second reaction vessel comprising a second electrolyte and a second organic solvent, wherein the first electrolyte of the first reaction vessel and the second electrolyte of the second reaction vessel are linked to each other by a salt bridge. A negative electrode to be pre-lithiated is dipped at least partially in the first electrolyte of the first reaction vessel, and a lithium source capable of supplying lithium ions is dipped at least partially in the second electrolyte of the second reaction vessel.

Abstract: A method for pre-lithiation of an electrode, including a first step of providing a pre-lithiation reaction system which includes a first reaction system including lithium metal, a separator, an electrolyte for pre-lithiation and carbon felt, and a second reaction system including the electrolyte for pre-lithiation and an electrode to be pre-lithiated, wherein the lithium metal and the electrode to be pre-lithiated are not in direct contact with each other. The first reaction system and the second reaction system communicate with each other. The first step is followed by a second step of preparing an electrode including an electrode current collector, and an electrode active material layer formed on at least one surface of the electrode current collector; and a third step of allowing the electrode to pass through the second reaction system by a conveying roll to carry out pre-lithiation of the electrode.