Patents by Inventor Paolo Mutti
Paolo Mutti has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20090022930Abstract: A process for producing a single crystal silicon wafer comprising a front surface, a back surface, a lateral surface joining the front and back surfaces, a central+ axis perpendicular to the front and back surfaces, and a segment which is axially symmetric about the central axis extending substantially from the front surface to the back surface in which crystal lattice vacancies are the predominant intrinsic point defect, the segment having a radial width of at least about 25% of the radius and containing agglomerated vacancy defects and a residual concentration of crystal lattice vacancies wherein (i) the agglomerated vacancy defects have a radius of less than about 70 nm and (ii) the residual concentration of crystal lattice vacancy intrinsic point defects is less than the threshold concentration at which uncontrolled oxygen precipitation occurs upon subjecting the wafer to an oxygen precipitation heat treatment.Type: ApplicationFiled: October 2, 2008Publication date: January 22, 2009Applicant: MEMC ELECTRONIC MATERIALS, INC.Inventors: Robert J. Falster, Vladimir V. Voronkov, Paolo Mutti, Francesco Bonoli
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Patent number: 7442253Abstract: The present invention is directed to a process for producing a silicon wafer which, during the heat treatment cycles of essentially any arbitrary electronic device manufacturing process, may form an ideal, non-uniform depth distribution of oxygen precipitates and may additionally contain an axially symmetric region which is substantially free of agglomerated intrinsic point defects. The process either comprises exposing the wafer's front and back surfaces to different atmospheres, or thermally annealing two wafers in a face-to-face arrangement.Type: GrantFiled: May 24, 2007Date of Patent: October 28, 2008Assignee: MEMC Electronic Materials, Inc.Inventors: Robert J. Falster, Joseph C. Holzer, Marco Cornara, Daniela Gambaro, Massimiliano Olmo, Steve A. Markgraf, Paolo Mutti, Seamus A. McQuaid, Bayard K. Johnson
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Patent number: 7431765Abstract: A process for producing a single crystal silicon wafer comprising a front surface, a back surface, a lateral surface joining the front and back surfaces, a central axis perpendicular to the front and back surfaces, and a segment which is axially symmetric about the central axis extending substantially from the front surface to the back surface in which crystal lattice vacancies are the predominant intrinsic point defect, the segment having a radial width of at least about 25% of the radius and containing agglomerated vacancy defects and a residual concentration of crystal lattice vacancies wherein (i) the agglomerated vacancy defects have a radius of less than about 70 nm and (ii) the residual concentration of crystal lattice vacancy intrinsic point defects is less than the threshold concentration at which uncontrolled oxygen precipitation occurs upon subjecting the wafer to an oxygen precipitation heat treatment.Type: GrantFiled: March 24, 2005Date of Patent: October 7, 2008Assignee: MEMC Electronic Materials, Inc.Inventors: Robert J. Falster, Vladimir V. Voronkov, Paolo Mutti, Francesco Bonoli
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Publication number: 20070224783Abstract: The present invention is directed to a process for producing a silicon wafer which, during the heat treatment cycles of essentially any arbitrary electronic device manufacturing process, may form an ideal, non-uniform depth distribution of oxygen precipitates and may additionally contain an axially symmetric region which is substantially free of agglomerated intrinsic point defects. The process either comprises exposing the wafer's front and back surfaces to different atmospheres, or thermally annealing two wafers in a face-to-face arrangement.Type: ApplicationFiled: May 24, 2007Publication date: September 27, 2007Applicant: MEMC ELECTRONIC MATERIALS, INC.Inventors: Robert Falster, Joseph Holzer, Marco Cornara, Daniela Gambaro, Massimiliano Olmo, Steve Markgraf, Paolo Mutti, Seamus McQuaid, Bayard Johnson
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Patent number: 7229693Abstract: The present invention is directed to a silicon wafer which, during the heat treatment cycles of essentially any arbitrary electronic device manufacturing process, may form an ideal, non-uniform depth distribution of oxygen precipitates and may additionally contain an axially symmetric region which is substantially free of agglomerated intrinsic point defects.Type: GrantFiled: February 16, 2005Date of Patent: June 12, 2007Assignee: MEMC Electronic Materials, Inc.Inventors: Robert J. Falster, Joseph C. Holzer, Marco Cornara, Daniela Gambaro, Massimiliano Olmo, Steve A. Markgraf, Paolo Mutti, Seamus A. McQuaid, Bayard K. Johnson
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Patent number: 6986925Abstract: A single crystal silicon wafer comprising a front surface, a back surface, a lateral surface joining the front and back surfaces, a central axis perpendicular to the front and back surfaces, and a segment which is axially symmetric about the central axis extending substantially from the front surface to the back surface in which crystal lattice vacancies are the predominant intrinsic point defect, the segment having a radial width of at least about 25% of the radius and containing agglomerated vacancy defects and a residual concentration of crystal lattice vacancies wherein (i) the agglomerated vacancy defects have a radius of less than about 70 nm and (ii) the residual concentration of crystal lattice vacancy intrinsic point defects is less than the threshold concentration at which uncontrolled oxygen precipitation occurs upon subjecting the wafer to an oxygen precipitation heat treatment.Type: GrantFiled: January 2, 2002Date of Patent: January 17, 2006Assignee: MEMC Electronic Materials, Inc.Inventors: Robert J. Falster, Vladimir V. Voronkov, Paolo Mutti, Francesco Bonoli
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Publication number: 20050238905Abstract: The present invention relates to single crystal silicon, in ingot or wafer form, having an axially symmetric vacancy dominated region and an axially symmetric silicon self-interstitial dominated region. Both the vacancy dominated and the silicon self-interstitial dominated regions are substantially free of agglomerated intrinsic point defects. The vacancy dominated region has a radial width of at least 15 mm and/or includes the central axis and the silicon self-interstitial dominated region is annular in shape and extends radially outward from the vacancy dominated region to the peripheral edge of the ingot or wafer. In ingot form, the axially symmetric regions have an axial length which is at least 20% of the length of the constant diameter portion of the ingot.Type: ApplicationFiled: April 8, 2005Publication date: October 27, 2005Applicant: MEMC Electronic Materials, Inc.Inventors: Robert Falster, Joseph Holzer, Steve Markgraf, Paolo Mutti, Seamus McQuaid, Bayard Johnson
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Publication number: 20050170610Abstract: The present invention is directed to a silicon wafer which, during the heat treatment cycles of essentially any arbitrary electronic device manufacturing process, may form an ideal, non-uniform depth distribution of oxygen precipitates and may additionally contain an axially symmetric region which is substantially free of agglomerated intrinsic point defects.Type: ApplicationFiled: February 16, 2005Publication date: August 4, 2005Applicant: MEMC Electronic Materials, Inc.Inventors: Robert Falster, Joseph Holzer, Marco Cornara, Daniela Gambaro, Massimiliano Olmo, Steve Markgraf, Paolo Mutti, Seamus McQuaid, Bayard Johnson
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Publication number: 20050160967Abstract: A process for producing a single crystal silicon wafer comprising a front surface, a back surface, a lateral surface joining the front and back surfaces, a central axis perpendicular to the front and back surfaces, and a segment which is axially symmetric about the central axis extending substantially from the front surface to the back surface in which crystal lattice vacancies are the predominant intrinsic point defect, the segment having a radial width of at least about 25% of the radius and containing agglomerated vacancy defects and a residual concentration of crystal lattice vacancies wherein (i) the agglomerated vacancy defects have a radius of less than about 70 nm and (ii) the residual concentration of crystal lattice vacancy intrinsic point defects is less than the threshold concentration at which uncontrolled oxygen precipitation occurs upon subjecting the wafer to an oxygen precipitation heat treatment.Type: ApplicationFiled: March 24, 2005Publication date: July 28, 2005Applicant: MEMC Electronic Materials, Inc.Inventors: Robert Falster, Vladimir Voronkov, Paolo Mutti, Francesco Bonoli
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Patent number: 6896728Abstract: The present invention is directed to a process for producing a silicon wafer which, during the heat treatment cycles of essentially any arbitrary electronic device manufacturing process, may form an ideal, non-uniform depth distribution of oxygen precipitates and may additionally contain an axially symmetric region which is substantially free of agglomerated intrinsic point defects. The process including growing a single crystal silicon ingot from molten silicon, and as part of the growth process, controlling (i) a growth velocity, v, (ii) an average axial temperature gradient, G0, during the growth of a constant diameter portion of the crystal over a temperature range from solidification to a temperature of no less than about 1325° C., and (iii) a cooling rate of the crystal from a solidification temperature to about 1,050° C., in order to cause the formation of an axially symmetrical segment which is substantially free of agglomerated intrinsic point defects.Type: GrantFiled: February 25, 2003Date of Patent: May 24, 2005Assignee: MEMC Electronic Materials, Inc.Inventors: Robert J. Falster, Joseph C. Holzer, Marco Cornara, Daniela Gambaro, Massimiliano Olmo, Steve A. Markgraf, Paolo Mutti, Seamus A. McQuaid, Bayard K. Johnson
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Patent number: 6840997Abstract: The present invention relates to a process for growing a single crystal silicon. The process including controlling a growth velocity, v, and an average axial temperature gradient, G0, during the growth of the constant diameter portion of the crystal over the temperature range from solidification to a temperature of no less than about 1325° C., to cause the formation of a first axially symmetrical region in which vacancies, upon cooling of the ingot from the solidification temperature, are the predominant intrinsic point defect and which is substantially free of agglomerated intrinsic point defects, wherein the first axially symmetric region has a width of at least about 50% of the radius of the constant diameter portion of the ingot.Type: GrantFiled: October 24, 2001Date of Patent: January 11, 2005Assignee: MEMC Electronic Materials, Inc.Inventors: Robert A. Falster, Joseph C. Holzer, Steve A. Markgraf, Paolo Mutti, Seamus A. McQuaid, Bayard K. Johnson
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Publication number: 20040089224Abstract: The present invention relates to single crystal silicon, in ingot or wafer form, which contains an axially symmetric region which is free of agglomerated intrinsic point defects, and a process for the preparation thereof.Type: ApplicationFiled: October 14, 2003Publication date: May 13, 2004Applicant: MEMC Electronic Materials, Inc.Inventors: Robert J. Falster, Joseph C. Holzer, Steve A. Markgraf, Paolo Mutti, Seamus A. McQuaid, Bayard K. Johnson
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Patent number: 6726764Abstract: A control method for use with a crystal puller for growing a monocrystalline semiconductor crystal from a melt according to the Czochralski process. The method includes defining an initial interval of time for observing growth of the crystal being pulled from the melt and determining diameter variations occurring during the interval. Based on the variations in the crystal diameter, the method defines a function r(t). By performing a best fit routine on the function r(t), the method deduces current values of crystal radius rf, meniscus height hf and growth rate Vgf at the end of the observation interval. The method also includes determining pull rate and heater power parameters as a function of the growth rate to control the crystal puller to minimize variations in both crystal diameter and growth rate during subsequent growth of the crystal.Type: GrantFiled: November 13, 2001Date of Patent: April 27, 2004Assignee: MEMC Electronic Materials, Inc.Inventors: Paolo Mutti, Vladmir V. Voronknov
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Publication number: 20040025782Abstract: The present invention is directed to a process for producing a silicon wafer which, during the heat treatment cycles of essentially any arbitrary electronic device manufacturing process, may form an ideal, non-uniform depth distribution of oxygen precipitates and may additionally contain an axially symmetric region which is substantially free of agglomerated intrinsic point defects. The process including growing a single crystal silicon ingot from molten silicon, and as part of the growth process, controlling (i) a growth velocity, v, (ii) an average axial temperature gradient, G0, during the growth of a constant diameter portion of the crystal over a temperature range from solidification to a temperature of no less than about 1325° C., and (iii) a cooling rate of the crystal from a solidification temperature to about 1,050° C., in order to cause the formation of an axially symmetrical segment which is substantially free of agglomerated intrinsic point defects.Type: ApplicationFiled: February 25, 2003Publication date: February 12, 2004Applicant: MEMC Electronic Materials, Inc.Inventors: Robert J. Falster, Joseph C. Holzer, Marco Cornara, Daniela Gambaro, Massimiliano Olmo, Steve A. Markgraf, Paolo Mutti, Seamus A. McQuaid, Bayard K. Johnson
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Patent number: 6652646Abstract: A process for growing a single crystal silicon ingot having an axially symmetric region substantially free of agglomerated intrinsic point defects. The ingot is grown generally in accordance with the Czochralski method; however, the manner by which the ingot is cooled from the temperature of solidification to a temperature which is in excess of about 900° C. is controlled to allow for the diffusion of intrinsic point defects, such that agglomerated defects do not form in this axially symmetric region. Accordingly, the ratio v/G0 is allowed to vary axially within this region, due to changes in v or G0, between a minimum and maximum value by at least 5%.Type: GrantFiled: September 30, 2002Date of Patent: November 25, 2003Assignee: MEMC Electronic Materials, Inc.Inventors: Robert J. Falster, Vladimir Voronkov, Paolo Mutti
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Publication number: 20030196587Abstract: The present invention relates to a process for growing a single crystal silicon ingot, which contains an axially symmetric region having a predominant intrinsic point defect and which is substantially free of agglomerated intrinsic point defects in that region. The process comprising cooling the ingot from the temperature of solidification to a temperature of less than 800° C. and, as part of said cooling step, quench cooling a region of the constant diameter portion of the ingot having a predominant intrinsic point defect through the temperature of nucleation for the agglomerated intrinsic point defects for the intrinsic point defects which predominate in the region.Type: ApplicationFiled: May 6, 2003Publication date: October 23, 2003Applicant: MEMC Electronic Materials, Inc.Inventors: Kirk D. McCallum, W. Brock Alexander, Mohsen Banan, Robert J. Falster, Joseph C. Holzer, Bayard K. Johnson, Chang Bum Kim, Steven L. Kimbel, Zheng Lu, Paolo Mutti, Vladimir V. Voronkov, Luciano Mule'Stagno, Jeffrey L. Libbert
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Patent number: 6632278Abstract: The present invention relates to an epitaxial wafer comprising single crystal silicon substrate and an epitaxial layer deposited thereon. The substrate comprises an axially symmetric region which is free of agglomerated intrinsic point defects and wherein silicon self-interstitials are the predominant intrinsic point defect in the axially symmetric region. The present invention further relates to a process for producing such an epitaxial wafer.Type: GrantFiled: April 30, 2002Date of Patent: October 14, 2003Assignee: MEMC Electronic Materials, Inc.Inventors: Robert A. Falster, Joseph C. Holzer, Steve A. Markgraf, Paolo Mutti, Seamus A. McQuaid, Bayard K. Johnson
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Publication number: 20030116081Abstract: A process for growing a single crystal silicon ingot having an axially symmetric region substantially free of agglomerated intrinsic point defects. The ingot is grown generally in accordance with the Czochralski method; however, the manner by which the ingot is cooled from the temperature of solidification to a temperature which is in excess of about 900° C. is controlled to allow for the diffusion of intrinsic point defects, such that agglomerated defects do not form in this axially symmetric region. Accordingly, the ratio v/G0 is allowed to vary axially within this region, due to changes in v or G0, between a minimum and maximum value by at least 5%.Type: ApplicationFiled: September 30, 2002Publication date: June 26, 2003Applicant: MEMC Electronic Materials, Inc.Inventors: Robert J. Falster, Vladimir Voronkov, Paolo Mutti
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Patent number: 6555194Abstract: The present invention is directed to a process for producing a silicon wafer which, during the heat treatment cycles of essentially any arbitrary electronic device manufacturing process, may form an ideal, non-uniform depth distribution of oxygen precipitates and may additionally contain an axially symmetric region which is substantially free of agglomerated intrinsic point defects. The process including growing a single crystal silicon ingot from molten silicon, and as part of the growth process, controlling (i) a growth velocity, v, (ii) an average axial temperature gradient, G0, during the growth of a constant diameter portion of the crystal over a temperature range from solidification to a temperature of no less than about 1325° C., and (iii) a cooling rate of the crystal from a solidification temperature to about 1,050° C., in order to cause the formation of an axially symmetrical segment which is substantially free of agglomerated intrinsic point defects.Type: GrantFiled: November 2, 2000Date of Patent: April 29, 2003Assignee: MEMC Electronic Materials, Inc.Inventors: Robert A. Falster, Joseph C. Holzer, Marco Cornara, Daniela Gambaro, Massimiliano Olmo, Steve A. Markgraf, Paolo Mutti, Seamus A. McQuaid, Bayard K. Johnson
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Publication number: 20030051657Abstract: The present invention relates to single crystal silicon, in ingot or wafer form, which contains an axially symmetric region in which vacancies are the predominant intrinsic point defect and which is substantially free of agglomerated vacancy intrinsic point defects, wherein the first axially symmetric region has a width which is at least about 50% of the length of the radius of the ingot, and a process for the preparation thereof.Type: ApplicationFiled: July 3, 2002Publication date: March 20, 2003Applicant: MEMC Electronic Materials, Inc.Inventors: Robert J. Falster, Joseph C. Holzer, Steve A. Markgraf, Paolo Mutti, Seamus A. McQuaid, Bayard K. Johnson