Patents by Inventor Paul-Ernst Frohberger

Paul-Ernst Frohberger has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4174398
    Abstract: 1-Alkyl-1-(1,3,4-thiadiazol-2-yl)-3-phenyl-ureas of the formula ##STR1## in which R.sup.1 is alkyl,R.sup.2 is phenyl or substituted phenyl, andX is hydrogen or halogen,which possess fungicidal properties.
    Type: Grant
    Filed: March 2, 1978
    Date of Patent: November 13, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Erik Regel, Paul-Ernst Frohberger, Volker Paul
  • Patent number: 4162329
    Abstract: Combating fungi with dicarboxylic acid mono-aryl-hydrazides of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylmercapto, trihalogenomethyl, trihalogenomethoxy, trihalogenomethylmercapto or nitro,X is an alkylene, alkenylene, cycloalkylene, cycloalkenylene, cycloalkadienylene or phenylene radical, andM is hydrogen or one equivalent of a metal, or a salt thereof.
    Type: Grant
    Filed: February 21, 1978
    Date of Patent: July 24, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Engelbert Kuhle, Erich Klauke, Paul-Ernst Frohberger
  • Patent number: 4156001
    Abstract: Synergistic fungicidal compositions comprising ##STR1## in which R.sup.1 is optionally substituted phenyl,R.sup.2 is hydrogen, alkyl or phenyl,R.sup.3 is alkyl, cycloalkyl, phenyl or chlorophenyl, andY is a keto group or a functional derivative thereof, and at least one member selected from the group consisting of(a) dithiocarbamates,(b) N-polyhaloalkylthio-amines or -amides,(c) imidazole and benzimidazole derivatives,(d) optionally nitrated polyhalobenzenes,(e) N-sulphinyl-N'-aryl-hydrazines, and(f) sulphur or alkaline earth metal polysulphides.
    Type: Grant
    Filed: January 18, 1978
    Date of Patent: May 22, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wilhelm Brandes, Paul-Ernst Frohberger, Hans Scheinpflug, Wolfgang Kramer
  • Patent number: 4154842
    Abstract: 1-Azolyl-4-hydroxy-1-phenoxy-butane derivatives of the formula ##STR1## in which R is hydrogen, --CO--R.sup.1 or --SO.sub.2 --R.sup.2,R.sup.1 is cycloalkyl, alkylamino, dialkylamino, alkenyl, alkynyl, or optionally substituted alkyl, phenyl, phenoxyalkyl, phenylalkyl or phenylamino,R.sup.2 is alkyl or optionally substituted phenyl,A is --CO--or CH(OH),X is H or --OR,X.sup.1 is alkyl or optionally substituted phenyl,Y is CH or N,Z is halogen, alkyl, halogenoalkyl, cycloalkyl, alkoxy, alkylthio, alkoxycarbonyl, amino, cyano, nitro, or optionally substituted phenyl, phenoxy or phenylalkyl, andN is 0, 1, 2, 3, 4 or 5,Or a salt thereof, which possess fungicidal and bactericidal properties.
    Type: Grant
    Filed: July 27, 1977
    Date of Patent: May 15, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Kramer, Karl H. Buchel, Paul-Ernst Frohberger, Peter Kraus
  • Patent number: 4145428
    Abstract: 1-Phenoxy-1-(1,2,4-triazolyl)-3,3-dimethyl-butanes of the formula ##STR1## in which R represents alkyl, alkenyl, alkynyl, cycloalkyl, halogenoalkyl, optionally substituted phenyl, optionally substituted phenoxyalkyl, alkylamino, dialkylamino or optionally substituted phenylamino,X represents halogen, alkyl, cycloalkyl, alkoxy, halogenoalkyl, alkylthio, alkoxycarbonyl, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl, amino, cyano or nitro,N represents 0, 1, 2, 3, 4 or 5, andAz represents the 1,2,4-triazolyl-1 or the 1,2,4-triazolyl-4 radical,In the form of the free base, a salt with a physiologically tolerated acid or a complex with a metal salt, which possess fungicidal properties.
    Type: Grant
    Filed: December 21, 1976
    Date of Patent: March 20, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Kramer, Karl H. Buchel, Wilhelm Brandes, Paul-Ernst Frohberger
  • Patent number: 4140782
    Abstract: Diphenyl-triazolyl-methanes of the formula ##STR1## in which R is alkyl, alkylcarbonyl or optionally substituted phenylcarbonyl,X and Y each independently is halogen, alkyl, halogenoalkyl, alkoxy, alkylthio, optionally substituted phenyl or phenoxy, nitro or cyano, andM and n each independently is an integer from 0 to 5, and their physiologically tolerated salts are used to combat fungi and nematodes.
    Type: Grant
    Filed: June 15, 1977
    Date of Patent: February 20, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Timmler, Wilfried Draber, Karl H. Buchel, Wolfgang Kramer, Wilhelm Brandes, Paul-Ernst Frohberger, Bernhard Homeyer
  • Patent number: 4134988
    Abstract: 2-Acyloxy-1-phenoxy-1-imidazolyl-(1)-3,3-dimethylbutanes of the formula ##STR1## in which R is alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, optionally substituted phenyl or phenoxyalkyl, alkylamino, dialkylamino or optionally substituted phenylamino,X is halogen, alkyl, cycloalkyl, alkoxy, haloalkyl, alkylthio, alkoxycarbonyl, optionally substituted phenyl or phenoxy, optionally substituted phenylalkyl, amino, cyano or nitro, andN is 0 or an integer from 1 to 5,Or salts or metal salt complexes thereof, which possess fungicidal and bactericidal properties.
    Type: Grant
    Filed: January 28, 1977
    Date of Patent: January 16, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Kramer, Karl H. Buchel, Wilhelm Brandes, Paul-Ernst Frohberger
  • Patent number: 4102891
    Abstract: 1-(2-Halogeno-2-phenyl-ethyl)-triazoles of the formula ##STR1## in which X represents halogen,R represents halogen, alkyl, alkoxy, alkylthio, alkylsulfonyl, halogenoalkyl, nitro, cyano, optionally substituted phenyl or optionally substituted phenoxy andn is 0, 1, 2 or 3,Or salts thereof, which possess fungicidal properties.
    Type: Grant
    Filed: October 6, 1976
    Date of Patent: July 25, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Timmler, Karl Heinz Buchel, Wilhelm Brandes, Paul-Ernst Frohberger
  • Patent number: 4098894
    Abstract: Triphenyl-1,2,3-triazolyl-(1)-methanes of the formula ##STR1## in which X and Z each independently is hydrogen, alkyl, halogen, nitrile or thiocyano, andY is hydrogen, halogen, alkyl, halogenoalkyl or nitro,Which possess fungicidal and bactericidal properties.
    Type: Grant
    Filed: February 5, 1975
    Date of Patent: July 4, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Heinz Buchel, Heinrich Gold, Paul-Ernst Frohberger, Helmut Kaspers
  • Patent number: 4073901
    Abstract: Metal complexes of N-trityl-azoles of the formula ##STR1## IN WHICH Me is a metal,X is halogen, nitro, cyano, hydroxyl, alkyl, alkoxy, alkylthio, alkoxycarbonyl, haloalkyl or alkylsulfonyl,Az is an imidazolyl radical or a 1,2,4-triazolyl radical,A is an anion of an inorganic acid,n is 0, 1, 2, 3 or 4,m is 1, 2, 3 or 4, andp is 1, 2, 3, 4, 5 or 6,Which possess fungicidal properties.
    Type: Grant
    Filed: January 14, 1976
    Date of Patent: February 14, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl H. Buchel, Paul-Ernst Frohberger, Helmut Kaspers
  • Patent number: 4067981
    Abstract: 7-Substituted-benzo-1,2,4-triazine-3-ethers of the formula ##STR1## in which R is alkyl with up to 8 carbon atoms optionally substituted by halogen or lower alkoxy, or alkenyl with 3 to 6 carbon atoms, andX is halogen, trifluoromethyl or alkoxy with up to 4 carbon atoms,Which possess fungicidal, bactericidal, insecticidal and acaricidal properties.
    Type: Grant
    Filed: August 26, 1976
    Date of Patent: January 10, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Sasse, Paul-Ernst Frohberger, Hans Scheinpflug
  • Patent number: 4053598
    Abstract: 2,4-Dioxo-1,2,3,4-tetrahydro-s-triazino-[1,2-a]-benzimidazoles of the formula ##STR1## are produced by reacting a benzimidazole compound of the formula ##STR2## with a diphenyl carbonate of the formula ##STR3## wherein R.sup.1 is optionally substituted alkyl or aryl, alkenyl or dialkylamino,R.sup.2 is hydrogen, alkyl or trifluoromethyl,R.sup.3 is any of the R.sup.1 radicals or hydroxycarbonylalkyl, andR.sup.4 is hydrogen, alkyl or halogen.The reaction can be effected employing the benzimidazole in impure form, without isolation, in the vessel in which it is formed. Those compounds wherein R.sup.1 is a variously .omega.-substituted alkyl radical and R.sup.2 is hydrogen or methyl are new and all the compounds exhibit fungicidal activity.
    Type: Grant
    Filed: June 9, 1976
    Date of Patent: October 11, 1977
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Daum, Paul-Ernst Frohberger
  • Patent number: 4053620
    Abstract: Fungicidal compositions containing, and methods of combating fungi, using 1-aryl-5-alkylidene-2,4-dioxo-imidazolidines of the formula ##STR1## in which R is aryl optionally substituted by nitro; by halogen; by alkyl, alkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl each with up to 6 carbon atoms; by haloalkyl with up to 5 halogen atoms and 1 or 2 carbon atoms; by cycloalkyl with 5 or 6 carbon atoms; by hydroxyl; by cyano; by thiocyanato; by acetyl; by formyl; by phenyl or phenoxy each optionally carrying halogen or nitro as substituents; by phenylthio; by phenylsulfonyl; by halosulfonyl; by benzyl; by anilino; by monoalkylamino or dialkylamino, each with up to 4 carbon atoms in each alkyl moiety; or by a cyclic amine radical in which the amine nitrogen is a constituent of a 5-membered or 6-membered heterocyclic structure which can in addition contain at least one further hetero-atom selected from the group consisting of nitrogen, oxygen and sulfur ring members; it being possible for an aryl radical to be sub
    Type: Grant
    Filed: March 19, 1976
    Date of Patent: October 11, 1977
    Assignee: Bayer Aktiengesellschaft
    Inventors: Edgar Enders, Paul-Ernst Frohberger
  • Patent number: 4053616
    Abstract: The compound 1-[1, 2, 4 -triazolyl-(1')]-1-(4'-phenyl-phenoxy)-3,3-dimethyl-butan-2-one of the formula ##STR1## has a particularly good selective fungicidal activity against rust fungi.
    Type: Grant
    Filed: June 11, 1975
    Date of Patent: October 11, 1977
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Heinz Buchel, Wolfgang Kramer, Wilhelm Brandes, Paul-Ernst Frohberger
  • Patent number: 4034104
    Abstract: Carbamic acid esters of gallic acid, their esters, and heavy metal salts of the formula ##STR1## in which R represents alkyl with up to 8 carbon atoms, which alkyl group can be substituted by halogen or cyano groups, andR' represents hydrogen, optionally halogen-substituted alkyl with up to 6 carbon atoms or one equivalent of a heavy metal atom,Which possess fungicidal properties.
    Type: Grant
    Filed: June 10, 1976
    Date of Patent: July 5, 1977
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Daum, Wilhelm Brandes, Paul-Ernst Frohberger
  • Patent number: 4027032
    Abstract: Combating fungi of the genus Helminthosporium with the known compound 2-[3',5'-dimethylpyrazolyl-(1')]-benzimidazole of the formula ##STR1##
    Type: Grant
    Filed: October 30, 1975
    Date of Patent: May 31, 1977
    Assignee: Bayer Aktiengesellschaft
    Inventors: Paul-Ernst Frohberger, Walter Gauss
  • Patent number: 4010174
    Abstract: Thiazolinone-(2)-carboxylic acid esters having the formula: ##STR1## ARE PREPARED BY REACTING A .beta.-AMINO ACRYLIC ACID ESTER WITH CHLOROCARBOXYL SULPHENYL CHLORIDE (COCl-SCl) at a temperature of from 0.degree. to 200.degree. C. The esters are useful as plant protecting agents such as a fungicide.
    Type: Grant
    Filed: September 5, 1975
    Date of Patent: March 1, 1977
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Grohe, Paul-Ernst Frohberger
  • Patent number: 3981885
    Abstract: 2-Alkyl-phenylhydrazonoimidazolenines of the formula ##SPC1##In whichR' is hydrogen, alkylcarbonyl, alkoxycarbonyl, arylcarbonyl, aryloxycarbonyl, alkylsulfonyl and optionally substituted arylsulfonyl,X is halogen, alkyl, haloalkyl, alkoxy, alkylthio, alkylamino, dialkylamino or nitro, andA. R is alkyl of up to 16 carbon atoms, and m is 1 to 4, orB. R is alkyl of 2 to 16 carbon atoms, and m is 0 to 4,Which possess fungicidal, bactericidal, microbicidal, insecticidal and acaricidal properties.
    Type: Grant
    Filed: July 24, 1975
    Date of Patent: September 21, 1976
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Heinz Buchel, Paul-Ernst Frohberger, Hans Scheinpflug, Edgar Enders
  • Patent number: 3979411
    Abstract: 2-Trifluoromethylimino-benzo-heterocyclic compounds of the general formula ##SPC1##In whichX is oxygen or sulfur,Y is oxygen, sulfur or the radical ##EQU1## R is lower alkyl, cycloalkyl, aryl, aryl substituted by at least one of halogen, nitro, methyl and methoxy, alkylcarbalkoxy with up to 6 carbon atoms, alkylsulfonyl, arylsulfonyl, dialkylamidosulfonyl, or --CO--R',R' is alkyl or alkoxy with up to 12 carbon atoms, aryl, amino, lower alkylamino, di-lower alkylamino, or arylamino, each Z independently is halogen, trifluoromethyl, nitro, lower alkyl, lower alkoxy, di-lower alkylamino, acyl with up to 6 carbon atoms, a sulfonic acid group, a sulfonic acid amide group, or a sulfonic acid amide group substituted by alkyl with up to 6 carbon atoms, andm is an integer from 0 to 4,Which possess fungicidal, insecticidal and acaricidal properties, and a process for their preparation wherein a compound of the general formula ##SPC2##Is reacted with perfluoroazapropene of the formulaF.sub.2 C=N-CF.sub.
    Type: Grant
    Filed: January 30, 1975
    Date of Patent: September 7, 1976
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerhard Buttner, Erich Klauke, Paul-Ernst Frohberger, Ingeborg Hammann
  • Patent number: 3978222
    Abstract: Compositions and methods of using 3-amino-propionic acid chloroanilides of the formula ##SPC1##In whichX and Y are each halogen, methyl or trifluoromethyl, provided that at least one of them is halogen,R is alkyl, cycloalkyl or alkenyl of up to 7 carbon atoms, andR' is hydrogen, or alkyl or alkenyl of up to 6 carbon atoms, orR and R' conjointly form an alkylene group of 4 or 5 carbon atoms which forms a ring with the nitrogen atoms to which R and R' are attached,Some of which are new, which possess strong fungicidal, bactericidal, insecticidal and bird-repellent properties.
    Type: Grant
    Filed: February 5, 1975
    Date of Patent: August 31, 1976
    Assignee: Bayer Aktiengesellschaft
    Inventors: Edgar Enders, Paul-Ernst Frohberger