Abstract: There is disclosed a process for the production of tack-free, pourable, filler containing elastomer powder which comprises(a) dispersing a carbon black filler in water;(b) mixing the thus dispersed carbon black filler with an elastomer latex;(c) coagulating the thus produced mixture of elastomer latex and carbon black with a two-stage coagulation solution;(d) partitioning the thus coagulated suspension with a coating resin; and(e) filtering, washing and drying of the resultant powder, the improvement comprising using as a coating resin a mixture of a styrene/butadiene resin and a styrene/.alpha.-methylstyrene or a polystyrene resin wherein the weight ratio of the styrene/butadiene resin to the styrene/.alpha.

Abstract: Method and composite of forming an elastomer product which comprises (A) solvent solution polymerizing an olefin monomer in the presence of an organometallic catalyst, (B) shortstopping the reaction with an excess of a rosin acid which has not been submitted to a disproportionation process and (C) recovering the elastomer composite.

Abstract: The invention relates to elastomer composites which can be used for pneumatic tire sidewalls. Such composite particularly comprises a manipulated blend of (A) a hexadiene polymer, (B) high unsaturation rubber, and optionally, (C) a low unsaturation rubber. The sidewall composition particularly enhances the adhesion of the sidewall to the tire carcass stock.

Abstract: The invention relates to elastomer composites which can be used for pneumatic tire sidewalls. Such composite particularly comprises a manipulated blend of (A) a hexadiene polymer, (B) high unsaturation rubber, and optionally, (C) a low unsaturation rubber. The sidewall composition particularly enhances the adhesion of the sidewall to the tire carcass stock.

Abstract: The invention relates to a method of preparing a composite suitable as an oxidizing component in a redox aqueous emulsion polymerization initiator starting with the relatively harsh oxidation of p-diisopropylbenzene with oxygen and involving a manipulative separation procedure for obtaining the effective oxidizing component. The invention also relates to the oxidizing component, the redox polymerization initiator and to the aqueous emulsion polymerization of selected unsaturated monomers.

Abstract: The invention relates to a method of preparing a composite suitable as an oxidizing component in a redox aqueous emulsion polymerization initiator starting with the relatively harsh oxidation of p-diisopropylbenzene with oxygen and involving a manipulative separation procedure for obtaining the effective oxidizing component. The invention also relates to the oxidizing component, the redox polymerization initiator and to the aqueous emulsion polymerization of selected unsaturated monomers.

Abstract: Latex is stabilized by the addition of small amounts of salts of maleic anhydride/alpha-methylstyrene adduct and maleic anhydride/alpha-methylstyrene dimer adduct. The adduct salt is incorporated into the emulsifier solution used in the emulsion polymerization system.

Abstract: The green strength of synthetic elastomers is improved by forming interpolymers from at least one type of various synthetic elastomer forming monomers with an epoxy containing monomer having the formula: ##STR1## where R.sub.1 contains from 0 to 8 carbon atoms and R.sub.2 contains from 1 to 4 carbon atoms. Typical elastomer forming monomers include at least one conjugated diene having from 4 to 10 carbon atoms, olefins having from 2 to 14 carbon atoms along with a diene having from 4 to 6 carbon atoms, and combinations thereof. The interpolymer preferably is blended with synthetic elastomers or natural rubber (cis-1,4-polyisoprene) and utilized for various industrial uses such as tire carcasses including radial truck tire carcasses. The green strength is further improved if a small amount of an epoxy cross-linking agent is utilized. Examples of suitable cross-linking agents include monoamines and polyamines, monoanhydrides and polyanhydrides, and monocarboxylic acids, as well as polycarboxylic acids.

Abstract: This invention discloses homopolymers and interpolymers of nonconjugated diolefins defined by the formula: ##STR1## where R.sub.1, R.sub.2 and R.sub.3 may be hydrogen, a lower alkyl group containing up to 4 carbon atoms or an aryl group and R.sub.4 may be a lower alkyl group containing up to 4 carbon atoms or an aryl group. It is also disclosed that these homopolymers and interpolymers can be prepared by solution polymerization employing cationic catalyst systems and also coordination catalyst systems. The polymers are either resinous or rubbery in nature.

Abstract: This invention relates to a method of adhering polyurethane to a cured rubber stock of the natural or synthetic type, where the rubber was compounded with a sulfur curative of at least one part of a polyol of less than 7000 molecular weight and cured. This composition would be useful for making white sidewalls and related laminates.

Abstract: The invention relates to a pneumatic tire sidewall and to compositions useful therefor. Such elastomeric composition are comprised of a blend of (A) ethylene/propylene/diene terpolymer, (B) rubbery .alpha.-olefin interpolymer, (C) high unsaturation rubber comprised of about 30 to about 80 weight percent natural rubber and (D) especially experimentally selected and manipulated compound additives selected from triallyl cyanurate, various maleimides and various anhydrides. The particular elastomeric composition are evaluated to enhance the adhesion of the sidewall to the tire carcass stock.

Abstract: The invention relates to pneumatic tire sidewalls and to compositions useful therefor. Such sidewall composition particularly comprise a manipulated blend of (A) ethylene/propylene/diene terpolymer, (B) a rubbery .alpha.-olefin interpolymer and (C) a high unsaturation rubber comprised of about 30 to about 80 weight percent natural rubber. The sidewall composition particularly enhances the adhesion of the sidewall to the tire carcass stock.

Abstract: A method of preparing sulfur vulcanizable unsaturated interpolymers of at least one terminally unsaturated monoolefin selected from the group consisting of 1-butene and .alpha.-olefins containing from five to 12 carbon atoms with at least one nonconjugated diolefin selected from the group of 4- and 5-methyl-1,4-hexadienes in which 5-methyl-1,4-hexadiene is at least 15 mole percent and in which the terminally unsaturated monoolefin comprises from about 98 to about 50 mole percent of the total.

Abstract: A method of polymerizing butadiene and/or butadiene in mixture with other diolefins to form polymers with a high cis-1,4 addition wherein the improvement relates to improved catalysts for producing the high cis-1,4-polybutadiene.

Abstract: This invention discloses homopolymers and interpolymers of nonconjugated diolefins defined by the formula: ##EQU1## where R.sub.1, R.sub.2 and R.sub.3 may be hydrogen, a lower alkyl group containing up to 4 carbon atoms or an aryl group and R.sub.4 may be a lower alkyl group containing up to 4 carbon atoms or an aryl group. It is also disclosed that these homopolymers and interpolymers can be prepared by solution polymerization employing cationic catalyst systems and also coordination catalyst systems. The polymers are either resinous or rubbery in nature.

Abstract: A method of preparing sulfur vulcanizable unsaturated interpolymers of at least one terminally unsaturated monoolefin selected from the group consisting of 1-butene and .alpha.-olefins containing from five to 12 carbon atoms with at leeast one nonconjugated diolefin selected from the group of 4- and 5-methyl-1,4-hexadienes in which 5-methyl-1,4-hexadiene is at least 15 mole percent and in which the terminally unsaturated monoolefin comprises from about 98 to about 70 mole percent of the total.