Patents by Inventor Paul TERRIEN

Paul TERRIEN has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240132353
    Abstract: A method of purifying a gas composed of a product gas and one or more impurity gases including combining a feed stream with a second stream thereby forming a combined feed stream, introducing the combined feed stream into a pressure swing adsorption device, thereby producing a high purity product gas stream and an off-gas stream, and introducing the off-gas stream into a membrane separation device, thereby producing a gas stream lean in product gas and a permeate stream.
    Type: Application
    Filed: October 23, 2022
    Publication date: April 25, 2024
    Inventors: Paul TERRIEN, Pierre-Philippe GUERIF
  • Patent number: 11952270
    Abstract: A method and system for purification of helium and CO2 from a stream containing at least Helium, CO2, nitrogen or methane uses a combination of cryogenic, membrane and adsorption technologies.
    Type: Grant
    Filed: October 5, 2021
    Date of Patent: April 9, 2024
    Assignees: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Paul Terrien, Pierre-Philippe Guerif, Vincent Follaca, Alain Guillard, Youssef Tazi
  • Patent number: 11946692
    Abstract: A method for separating a mixture containing at least nitrogen and methane by cryogenic distillation in a first column operating in a first pressure and a second column operating at a second pressure lower than the first pressure, the mixture being separated in the first column to form a gas enriched in nitrogen and a liquid enriched in methane, at least a portion of the gas enriched in nitrogen being at least partially condensed in a heat exchanger and returned to the first column, the gas enriched in nitrogen is sent into the heat exchanger by the bottom, ascends in a first series of passages of the exchanger and condenses therein at least partially, the liquid formed descending in these passages of the first series and exiting by the bottom of the exchanger.
    Type: Grant
    Filed: April 8, 2022
    Date of Patent: April 2, 2024
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Paul Terrien, Nicolas Chantant, Jean-Marc Peyron
  • Patent number: 11874057
    Abstract: A process for the separation of nitrogen from a feed stream containing at least methane and nitrogen, with a methane content between 4 and 12% mol. consists of at least the following steps: separation of the feed stream by means of a rubbery-type membrane to produce a permeate enriched in methane at a pressure greater than 2 bara and a non-permeate which is a nitrogen-enriched residue gas at a pressure greater than 2 bara and processing of the high-pressure residue gas in a cryogenic separation unit to produce a methane rich liquid and a nitrogen-enriched gas wherein the pressure of the membrane permeate is controlled as a function of the nitrogen concentration in the nitrogen-enriched gas.
    Type: Grant
    Filed: July 16, 2021
    Date of Patent: January 16, 2024
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Martin Raventos, Paul Terrien
  • Publication number: 20230221067
    Abstract: A single compressor is used to separately compress permeate from cascaded first and second gas separation membrane-based separation units and residue from a fourth gas separation membrane-based separation unit in order to avoid too high a CO2 partial pressure in the compressed permeate. After the permeates from the first and second stages are compressed, the compressed stream is fed to a third gas separation membrane-based separation unit.
    Type: Application
    Filed: January 13, 2022
    Publication date: July 13, 2023
    Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Sandeep KARODE, Paul TERRIEN, Cyril DEFAYE
  • Publication number: 20230211281
    Abstract: A single compressor is used to separately compress permeate from cascaded first and second gas separation membrane-based separation units and residue from a fourth gas separation membrane-based separation unit in order to avoid too high a CO2 partial pressure in the compressed permeate. After the permeates from the first and second stages are compressed, the compressed stream is fed to a third gas separation membrane-based separation unit.
    Type: Application
    Filed: December 31, 2021
    Publication date: July 6, 2023
    Applicants: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Sandeep KARODE, Paul TERRIEN, Cyril DEFAYE
  • Publication number: 20230160634
    Abstract: A pressurized CO2 rich gas is cooled down to condense at least part of the stream in a heat exchanger. A bulk of the CO2 is separated by partial condensation and distillation in order to obtain at least one non-condensable gas from a separation vessel. The non-condensable gas is optionally heated up to a temperature lower than ?20° C. (membranes performances is greatly enhanced by low temperature operation). The non-condensable gas is introduced into a membrane permeation unit, producing a residue stream and a permeate stream (the permeate stream is enriched in CO2). The permeate stream is recycled to the process, optionally after compression. The method is auto-refrigerated, i. e. no external refrigerant is used to provide cooling below 0° C.
    Type: Application
    Filed: November 23, 2021
    Publication date: May 25, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Sandeep KARODE, Sudhir KULKARNI, Paul TERRIEN
  • Publication number: 20230022033
    Abstract: A process for the separation of nitrogen from a feed stream containing at least methane and nitrogen, with a methane content between 4 and 12% mol. consists of at least the following steps: separation of the feed stream by means of a rubbery-type membrane to produce a permeate enriched in methane at a pressure greater than 2 bara and a non-permeate which is a nitrogen-enriched residue gas at a pressure greater than 2 bara and processing of the high-pressure residue gas in a cryogenic separation unit to produce a methane rich liquid and a nitrogen-enriched gas wherein the pressure of the membrane permeate is controlled as a function of the nitrogen concentration in the nitrogen-enriched gas.
    Type: Application
    Filed: July 16, 2021
    Publication date: January 26, 2023
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Martin RAVENTOS, Paul TERRIEN
  • Patent number: 11535803
    Abstract: A process for purifying a gaseous feed stream of natural gas including methane, CO2 and heavy hydrocarbons including step a): cooling the gaseous feed stream in a heat exchanger; step b): introducing the cooled stream into a phase-separating chamber to produce a liquid stream depleted in methane and enriched in heavy hydrocarbons and a gaseous stream; step c): separating the gaseous stream obtained from step b) in a first membrane producing at least one CO2-enriched permeate stream and a residual stream enriched in methane; step d): introducing the residual stream obtained from step c) into a phase-separator to produce a liquid stream and a gaseous stream; step e): heating the gaseous stream obtained from step d) by introducing it into the heat exchanger used in step a) counter-currentwise with the feed stream thereby producing a gaseous stream depleted in CO2 and enriched in methane.
    Type: Grant
    Filed: July 23, 2018
    Date of Patent: December 27, 2022
    Assignees: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Paul Terrien, Pascal Marty, Yong Ding
  • Patent number: 11491440
    Abstract: A feed containing methane and nitrogen gas is processed in a three-stage membrane system, each stage of which is selective for methane over nitrogen. The methane enriched permeate from the first stage is removed as product gas. The methane-depleted residue from the second stage is purified in second and third cascaded stages to provide second and third permeates and second and third residues. The third stage permeate is recycled to the feed.
    Type: Grant
    Filed: December 3, 2019
    Date of Patent: November 8, 2022
    Assignee: Air Liquide Advanced Technologies U.S. LLC
    Inventors: Paul Terrien, Alex Augustine, Kevin Weatherford, Yong Ding
  • Publication number: 20220325951
    Abstract: A method for separating a mixture containing at least nitrogen and methane by cryogenic distillation in a first column operating in a first pressure and a second column operating at a second pressure lower than the first pressure, the mixture being separated in the first column to form a gas enriched in nitrogen and a liquid enriched in methane, at least a portion of the gas enriched in nitrogen being at least partially condensed in a heat exchanger and returned to the first column, the gas enriched in nitrogen is sent into the heat exchanger by the bottom, ascends in a first series of passages of the exchanger and condenses therein at least partially, the liquid formed descending in these passages of the first series and exiting by the bottom of the exchanger.
    Type: Application
    Filed: April 8, 2022
    Publication date: October 13, 2022
    Inventors: Paul TERRIEN, Nicolas CHANTANT, Jean-Marc PEYRON
  • Publication number: 20220219114
    Abstract: An approach for separating a gaseous mixture includes a multi-stage membrane system in which a rubbery membrane is operated at a low temperature. Various streams are cooled and heated in a multi-fluid heat exchanger. In specific configurations, the multi-fluid heat exchanger is cooled by using no fluids other than fluids derived from the permeate and/or residue generated in the first membrane stage.
    Type: Application
    Filed: March 29, 2022
    Publication date: July 14, 2022
    Applicant: Air Liquide Advanced Technologies U.S. LLC
    Inventors: Paul TERRIEN, Alex AUGUSTINE, Kevin WEATHERFORD, Yong DING
  • Publication number: 20220214104
    Abstract: Process for extracting nitrogen from a feed stream of natural gas or of biomethane comprising at least nitrogen, methane, CO2 and/or H2S, wherein a liquid stream enriched in methane resulting from a cryogenic separation is recovered by pumping the bottom product of one or more of the columns and/or pumping a liquid stream to a pressure P2 greater than 25 bar absolute and preferably greater than the critical pressure of said product.
    Type: Application
    Filed: March 5, 2020
    Publication date: July 7, 2022
    Inventors: Marine ANDRICH, Oumar KHAN, Paul TERRIEN
  • Patent number: 11344842
    Abstract: In a method for separating a mixture containing carbon dioxide, the mixture is cooled in a heat exchanger and partially condensed and a first liquid is separated from the mixture in a first system operating at low temperature comprising at least one first phase separator and a gas from the first system is treated in a membrane system to produce a permeate and a non-permeate, the gas from the first system being divided into two portions, a first portion being sent to the membrane system without being heated and a second portion being heated to at least an intermediate temperature of the heat exchanger and then sent to the membrane system without being cooled.
    Type: Grant
    Filed: June 12, 2017
    Date of Patent: May 31, 2022
    Assignee: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Ludovic Granados, Mathieu Leclerc, Frederick Lockwood, Paul Terrien
  • Patent number: 11318411
    Abstract: An approach for separating a gaseous mixture includes a multi-stage membrane system in which a rubbery membrane is operated at a low temperature. Various streams are cooled and heated in a multi-fluid heat exchanger. In specific configurations, the multi-fluid heat exchanger is cooled by using no fluids other than fluids derived from the permeate and/or residue generated in the first membrane stage.
    Type: Grant
    Filed: December 3, 2019
    Date of Patent: May 3, 2022
    Assignee: Air Liquide Advanced Technologies U.S. LLC
    Inventors: Paul Terrien, Alex Augustine, Kevin Weatherford, Yong Ding
  • Publication number: 20220106190
    Abstract: A method and system for purification of helium and CO2 from a stream containing at least Helium, CO2, nitrogen or methane uses a combination of cryogenic, membrane and adsorption technologies.
    Type: Application
    Filed: October 5, 2021
    Publication date: April 7, 2022
    Applicants: Air Liquide Advanced Technologies US LLC, L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Paul TERRIEN, Pierre-Philippe GUERIF, Vincent FOLLACA, Alain GUILLARD, Youssef TAZI
  • Patent number: 11291946
    Abstract: A process for producing biomethane by scrubbing a biogas feed stream includes introducing the feed gas stream into a pretreatment unit wherein a CO2-depleted gas stream is partially separated from a CO2 stream and an oxygen stream and is compressed to a pressure P1 above 25 bar abs. Subjecting the CO2-depleted gas stream to cryogenic separation in a distillation column to separate a nitrogen stream and produce a CH4-enriched stream, the distillation column comprising n plates, n being an integer between 8 and 100. Recovering a pressurized CH4-enriched stream by pumping the CO2-depleted gas stream to a pressure P2 above 25 bar absolute.
    Type: Grant
    Filed: December 17, 2018
    Date of Patent: April 5, 2022
    Assignee: L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Paul Terrien, Nicolas Chantant
  • Patent number: 11278843
    Abstract: A process for purifying a feed gas including methane and heavy hydrocarbons, including: step a): cooling the feed gas in a heat exchanger; step b): introducing the resulting into a first phase separator to produce a liquid stream depleted in methane and enriched in heavy hydrocarbons and a gas stream; step c): separating the gas stream in a membrane from which a methane-enriched permeate stream and a partially condensed residue stream exit; step d): introducing the residue stream from step c) into a second phase separator vessel in order to produce a liquid stream and a gas stream; step e): introducing at least one portion of the gas stream resulting from step d) into a JT expansion means; and step f): heating at least one portion of the expanded stream in the heat exchanger used in step a) counter-current to the feed stream in order to cool the latter.
    Type: Grant
    Filed: July 23, 2018
    Date of Patent: March 22, 2022
    Assignees: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Paul Terrien, Pascal Marty, Yong Ding
  • Patent number: 11154812
    Abstract: A process for purifying a natural gas feed gas stream including methane and hydrocarbons, including step a): cooling the feed gas stream; step b): introducing the cooled stream into a first phase separator vessel in order to produce a liquid stream and a gas stream; step c): separating the gas stream resulting from step b) in a membrane unit from which a methane-enriched permeate stream and one partially condensed residue stream enriched in hydrocarbons exit; step d): introducing the residue stream resulting from step c) into a second phase separator vessel to produce a liquid stream and a gas stream; step e): introducing at least one portion of the liquid stream resulting from step d) into a JT expansion means; step f): heating at least one portion of the expanded by introduction into the heat exchanger used in step a) counter-current to the feed stream.
    Type: Grant
    Filed: July 23, 2018
    Date of Patent: October 26, 2021
    Assignees: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude, Air Liquide Advanced Technologies U.S. LLC
    Inventors: Paul Terrien, Pascal Marty, Yong Ding
  • Publication number: 20210172677
    Abstract: A process for producing biomethane by scrubbing a biogas feed stream including introducing a feed gas stream into a pretreatment unit wherein the gas stream is partially separated from a CO2 stream and an oxygen stream, thereby producing a CO2-depleted gas stream, which is compressed, thereby producing a pressurized CO2-depleted gas stream; separating the pressurized CO2-depleted gas stream by cryogenic separation by introducing the pressurized CO2-depleted gas stream into a distillation column thereby producing a nitrogen stream and a CH4-enriched stream, recovering a pressurized CH4-enriched stream by pumping the CH4-enriched stream; wherein the separation of the CO2 stream and the oxygen stream from the feed gas stream is performed by a unit comprising at least two separating membrane stages in order that the CO2-depleted gas stream comprises between 0.3 mol % and 2 mol % of CO2.
    Type: Application
    Filed: December 17, 2018
    Publication date: June 10, 2021
    Inventors: Paul TERRIEN, Nicolas CHANTANT, Marine ANDRICH